CN104962006A - Polyvinyl chloride resin nano environment-friendly cable material and preparation method thereof - Google Patents
Polyvinyl chloride resin nano environment-friendly cable material and preparation method thereof Download PDFInfo
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- CN104962006A CN104962006A CN201510409108.0A CN201510409108A CN104962006A CN 104962006 A CN104962006 A CN 104962006A CN 201510409108 A CN201510409108 A CN 201510409108A CN 104962006 A CN104962006 A CN 104962006A
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- polyvinyl chloride
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/02—Organic and inorganic ingredients
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/02—Elements
- C08K3/04—Carbon
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K5/00—Use of organic ingredients
- C08K5/16—Nitrogen-containing compounds
- C08K5/34—Heterocyclic compounds having nitrogen in the ring
- C08K5/3467—Heterocyclic compounds having nitrogen in the ring having more than two nitrogen atoms in the ring
- C08K5/3477—Six-membered rings
- C08K5/3492—Triazines
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- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/30—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes
- H01B3/44—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins
- H01B3/443—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances plastics; resins; waxes vinyl resins; acrylic resins from vinylhalogenides or other halogenoethylenic compounds
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/30—Sulfur-, selenium- or tellurium-containing compounds
- C08K2003/3009—Sulfides
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/32—Phosphorus-containing compounds
- C08K2003/321—Phosphates
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/014—Additives containing two or more different additives of the same subgroup in C08K
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- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/02—Flame or fire retardant/resistant
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2201/00—Properties
- C08L2201/08—Stabilised against heat, light or radiation or oxydation
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention discloses a polyvinyl chloride resin nano environment-friendly cable material and a preparation method thereof, raw materials of which comprise the following main ingredients in parts by weight: 40 to 50 parts of polyvinyl chloride resin, 20 to 25 parts of calcium zirconate, 10 to 15 parts of nano barium titanate, 8 to 10 parts of graphene, 12 to 16 parts of melamine cyanurate, 5 to 10 parts of antimony sulfide, 5 to 8 parts of aluminium hypophosphite, 122 to 18 parts of plasticizer, 4 to 6 parts of cross-linking agent and 35 to 45 parts of filler. By means of cross-linking, the temperature resistance of the cable material is greatly improved, and the strength and elongation property are also remarkably improved.
Description
Technical field
The present invention relates to compound cable field of material technology, specifically refer to cable material of a kind of polyvinyl chloride (PVC) RESINS nano environmental protection and preparation method thereof.
Background technology
Electric wire, as the transmission body of energy and information, is all widely used in every field.Their great majority all adopt plastics and rubber to insulate and sheath material, after it is heated, melts, decomposes, inflammable gas can be produced, fire is occurred, China is only due to fire losses that cable causes, reach more than 5,000,000,000 every year, therefore, the fire-retardant problem of electric wire more and more causes the concern of people.
Polychloroprene material has excellent mechanical and physical performance, snappiness, chemical reagent-resistant performance, low price, and processing characteristics is excellent, is widely used in producing various articles for use.As footwear, daily necessities, convenient bag etc., in addition, on electric wire, purposes is also a lot.Tradition polyvinyl chloride electrical wire and cable material temperature tolerance is poor, and intensity is low, and elongation is poor.
Summary of the invention
One is the object of the present invention is to provide to have good processibility, cable material of the polyvinyl chloride (PVC) RESINS nano environmental protection of good intensity and elongation and preparation method thereof.
The present invention is achieved through the following technical solutions: a kind of cable material of polyvinyl chloride (PVC) RESINS nano environmental protection, it is characterized in that: represent with weight part, the main component of raw material comprises: polyvinyl chloride (PVC) RESINS 40-50, calcium zirconate 20-25, nano barium phthalate 10-15 part, Graphene 8-10 part, melamine cyanurate 12-16 part, antimony sulfide 5-10 part, hypo-aluminum orthophosphate 5-8 part, softening agent 12-18 part, linking agent 4-6 part, filler 35-45 part.
In order to realize the present invention better, further, represent with weight part, the composition of described raw material also comprises stablizer 4-6 part, lubricant 0.5-1.5 part, oxidation inhibitor 0.5-1.5 part.
In order to realize the present invention better, further, described filler is mineral filler.
In order to realize the present invention better, further, described mineral filler is calcium carbonate or calcium oxide.
In order to realize the present invention better, further, described softening agent is adipic acid dioctyl ester.
In order to realize the present invention better, further, described linking agent is Viscoat 295.
In order to realize the present invention better, further, described stablizer is zinc acetylacetonate, and described lubricant is gama wax, and oxidation inhibitor is diphosphorous acid pentaerythritol stearic acid ester 2.
A preparation method for the cable material of polyvinyl chloride (PVC) RESINS nano environmental protection, comprises the following steps:
(1) in high-speed mixer, add polyvinyl chloride (PVC) RESINS, calcium zirconate, nano barium phthalate, Graphene, melamine cyanurate, antimony sulfide, hypo-aluminum orthophosphate, softening agent, linking agent, filler successively respectively, mix under high-speed mixer effect;
(2) material mixed is transferred on twin screw plasticator plasticates, until it plasticates evenly;
(3) uniform material will be plasticated after water cooling bracing, carry out pelletizing;
(4) carry out drying by the particle cut importing drying machine, obtain this cable material afterwards.
The present invention compared with prior art, has the following advantages and beneficial effect:
The present invention is by after crosslinked, and the heat resistance of cable material improves greatly, and intensity and elongation all have remarkable lifting.The interpolation of the compositions such as calcium zirconate, nano barium phthalate, Graphene, not only mechanical property can be improved, also enhance the thermotolerance of rubber plate, wear resistance and resistance of aging, adding of melamine cyanurate, antimony sulfide and hypo-aluminum orthophosphate, the flame retardant properties of rubber plate can be improved, adding of reinforcing aids, improve the overall performance of rubber plate, make longer service life.
Embodiment
Set forth the present invention further below in conjunction with specific embodiment, should be understood that embodiment is only not used in for illustration of the present invention and limit the scope of the invention.
Embodiment:
Cable material of the present invention, represents with weight part, and the component of raw material is as follows:
A kind of cable material of polyvinyl chloride (PVC) RESINS nano environmental protection, it represents with weight part, the main component of raw material comprises: polyvinyl chloride (PVC) RESINS 40, calcium zirconate 20, nano barium phthalate 10, Graphene 8, melamine cyanurate 12, antimony sulfide 5, hypo-aluminum orthophosphate 5,15 parts, softening agent, linking agent 5 parts, filler 40 parts.
Wherein, the composition of described raw material also comprises stablizer 5 parts, lubricant 1 part, 1 part, oxidation inhibitor; Described filler is mineral filler; Described mineral filler agent is calcium carbonate or calcium oxide; Described softening agent is adipic acid dioctyl ester; Described linking agent is Viscoat 295, and described stablizer is zinc acetylacetonate, and described lubricant is gama wax, and oxidation inhibitor is diphosphorous acid pentaerythritol stearic acid ester 2.
A preparation method for the cable material of polyvinyl chloride (PVC) RESINS nano environmental protection, comprises the following steps:
(1) in high-speed mixer, add polyvinyl chloride (PVC) RESINS, calcium zirconate, nano barium phthalate, Graphene, melamine cyanurate, antimony sulfide, hypo-aluminum orthophosphate, softening agent, linking agent, filler successively respectively, mix under high-speed mixer effect;
(2) material mixed is transferred on twin screw plasticator plasticates, until it plasticates evenly;
(3) uniform material will be plasticated after water cooling bracing, carry out pelletizing;
(4) carry out drying by the particle cut importing drying machine, obtain this cable material afterwards.
Although illustrate and describe embodiments of the invention, those having ordinary skill in the art will appreciate that: do not departing under principle of the present invention and aim and can carry out multiple change, amendment, replacement and modification to these embodiments, scope of the present invention is by claim and equivalents thereof.
Claims (8)
1. the cable material of a polyvinyl chloride (PVC) RESINS nano environmental protection, it is characterized in that: represent with weight part, the main component of raw material comprises: polyvinyl chloride (PVC) RESINS 40-50, calcium zirconate 20-25, nano barium phthalate 10-15 part, Graphene 8-10 part, softening agent 12-18 part, linking agent 4-6 part, filler 35-45 part, melamine cyanurate 12-16 part, antimony sulfide 5-10 part, hypo-aluminum orthophosphate 5-8 part.
2. the cable material of a kind of polyvinyl chloride (PVC) RESINS nano environmental protection according to claim 1, is characterized in that: represent with weight part, and the composition of described raw material also comprises stablizer 4-6 part, lubricant 0.5-1.5 part, oxidation inhibitor 0.5-1.5 part.
3. the cable material of a kind of polyvinyl chloride (PVC) RESINS nano environmental protection according to claim 1 and 2, is characterized in that: described filler is mineral filler.
4. the cable material of a kind of polyvinyl chloride (PVC) RESINS nano environmental protection according to claim 3, is characterized in that: described mineral filler is calcium carbonate or calcium oxide.
5. the cable material of a kind of polyvinyl chloride (PVC) RESINS nano environmental protection according to claim 1 and 2, is characterized in that: described softening agent is adipic acid dioctyl ester.
6. the cable material of a kind of polyvinyl chloride (PVC) RESINS nano environmental protection according to claim 1 and 2, is characterized in that: described linking agent is Viscoat 295.
7. the cable material of a kind of polyvinyl chloride (PVC) RESINS nano environmental protection according to claim 2, it is characterized in that: described stablizer is zinc acetylacetonate, described lubricant is gama wax, and oxidation inhibitor is diphosphorous acid pentaerythritol stearic acid ester 2.
8. a preparation method for the cable material of polyvinyl chloride (PVC) RESINS nano environmental protection, is characterized in that: comprise the following steps:
(1) in high-speed mixer, add polyvinyl chloride (PVC) RESINS, calcium zirconate, nano barium phthalate, Graphene, melamine cyanurate, antimony sulfide, hypo-aluminum orthophosphate, softening agent, linking agent, filler successively respectively, mix under high-speed mixer effect;
(2) material mixed is transferred on twin screw plasticator plasticates, until it plasticates evenly;
(3) uniform material will be plasticated after water cooling bracing, carry out pelletizing;
(4) carry out drying by the particle cut importing drying machine, obtain this cable material afterwards.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510409108.0A CN104962006A (en) | 2015-07-14 | 2015-07-14 | Polyvinyl chloride resin nano environment-friendly cable material and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510409108.0A CN104962006A (en) | 2015-07-14 | 2015-07-14 | Polyvinyl chloride resin nano environment-friendly cable material and preparation method thereof |
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| CN104962006A true CN104962006A (en) | 2015-10-07 |
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| CN201510409108.0A Pending CN104962006A (en) | 2015-07-14 | 2015-07-14 | Polyvinyl chloride resin nano environment-friendly cable material and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110483921A (en) * | 2019-09-18 | 2019-11-22 | 天长市格瑞电缆材料有限公司 | A kind of low smoke and zero halogen photovoltaic irradiation cable material |
-
2015
- 2015-07-14 CN CN201510409108.0A patent/CN104962006A/en active Pending
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN110483921A (en) * | 2019-09-18 | 2019-11-22 | 天长市格瑞电缆材料有限公司 | A kind of low smoke and zero halogen photovoltaic irradiation cable material |
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Application publication date: 20151007 |