CN103766365A - Corn field weeding composition - Google Patents

Corn field weeding composition Download PDF

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Publication number
CN103766365A
CN103766365A CN201310666916.6A CN201310666916A CN103766365A CN 103766365 A CN103766365 A CN 103766365A CN 201310666916 A CN201310666916 A CN 201310666916A CN 103766365 A CN103766365 A CN 103766365A
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China
Prior art keywords
weeding composition
weed
fluroxypyr
nicosulfuron
pesticide
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CN201310666916.6A
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Chinese (zh)
Inventor
王礼文
刘鹏
陈佛祥
冷忠国
朱刚
张志伟
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Guangdong Zhongxun Agri Science Corp
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Guangdong Zhongxun Agri Science Corp
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Priority to CN201310666916.6A priority Critical patent/CN103766365A/en
Publication of CN103766365A publication Critical patent/CN103766365A/en
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Abstract

The invention relates to a corn field weeding composition which is composed of effective components A, B and C and proper amounts of pesticide adjuvants, wherein the effective component A is halosulfuron-methyl, B is nicosulfuron or rimsulfuron, and C is fluroxypyr or an ester compound thereof. The weeding composition is reasonable in components, has synergistic effect, overcomes the defects of incomplete weeding spectrum or lower activity for some weed and slow effect taking due to use of single weedicide, and lowers the risk in resistance due to use of single or two-element compounds. The weeding composition has obviously better preventing and treating effects than a single agent, lowers the consumption of the pesticide, and reduces the adverse effect of the pesticide on the ecological environment; and the weeding composition has important meanings for comprehensive treatment of weed resistance, and has huge economic benefit and social benefit.

Description

Cornfield weeding composition
Technical field
The invention belongs to technical field of pesticide, be specifically related to a kind of cornfield weeding composition of ternary built.
Background technology
Halosulfuronmethyl is absorption agricultural compound in sulfonylurea, can be plant stem-leaf and root absorption, and weeds first stop growing then withered, are mainly used in preventing and kill off annual broadleaf weed and sedge weed, and the rhizome of nutgrass flatsedge is had to special efficacy.
Fluroxypyr or its ester type compound are organic heterocyclic class selectivity inner sucting conduction type herbicide after seedling, after medicine, be absorbed by plants very soon, make sensitive plant occur the reaction of typical hormone herbicide, plant deformity, distortion, finally withered, can prevent and kill off the various broad leaved weeds such as dayflower, kitchen garden, chickweed.
Nicosulfuron is absorption agricultural compound in sulfonylurea, can be weeds cauline leaf and root absorption, in plant corpus, conduct subsequently, cause sensitive plant growth retardation, cauline leaf chlorisis, withered gradually, generally death in 20-25 days, but time that need be longer to some perennial weed in the situation that temperature is lower.Be mainly used in preventing and kill off corn field annual gramineous weed and part broad leaved weed, sedge weed is also had to certain preventive effect, dispenser good drug efficacy before 4 leaf phases after bud, when seedling is large, dispenser drug effect declines.
Rimsulfuron is sulfonylurea herbicide, branched-chain amino acid synthetic inhibitor, selective post-emergence herbicide.Be used for preventing and kill off corn field annual or perennial grass family and broad leaved weed, as creeping thistle, iron shepherd's purse, the rhizome of nutgrass flatsedge, curly dock, johnson grass, wild oat, hemostasis eleusine indica, barnyard grass, Annual Ryegrass, piemarker, Amaranthus retroflexus, clearvers, corn poppy, chickweed.Especially good to early application after annual weed bud.
The inventor conducts in-depth research the mixture of halosulfuronmethyl, nicosulfuron or rimsulfuron, fluroxypyr or its ester type compound, on the basis of a large amount of formula indoor screening tests and field medicine effect test, find that three's mixture has synergistic effect to green foxtail, eleusine indica, the rhizome of nutgrass flatsedge, field bindweed, unit or two yuan of combinations expand herbicide spectrum relatively, improve drug effect, compared with prior art there is novelty, creativeness and practicality.
Halosulfuronmethyl, nicosulfuron or rimsulfuron, fluroxypyr or its ester type compound composite without relevant report, the present invention does not lose novelty.
The present invention is expanding on the basis of herbicide spectrum, relatively unit or two yuan of compositions are remarkable to corn field main weeds and resistant weed green foxtail, eleusine indica, the rhizome of nutgrass flatsedge, field bindweed synergy, and then significantly reduced agricultural chemicals usage amount, reduce use cost and reduce carrying capacity of environment creative.
The present invention possesses the prospect of industrial applications, can excipient be that agricultural goes up conventional formulation as oil-suspending agent, suspending agent, water dispersible granules, wetting powder etc., possesses practicality.
Summary of the invention
The object of the invention is to solve the single or two yuan of deficiencies while using of weed killer herbicide, a kind of Herbicidal combinations that can effectively administer corn field weed is provided.Because said composition has significant synergies to corn field main weeds and resistant weed green foxtail, eleusine indica, the rhizome of nutgrass flatsedge, field bindweed; obviously reduce use cost; reduce agricultural chemicals usage amount and significantly reduce carrying capacity of environment simultaneously, there is positive effect for the corn field weed comprehensive regulation and environmental protection.
Technical scheme of the present invention is: a kind of cornfield weeding composition, and it comprises three kinds of active ingredients: effective constituents A, B, C, wherein active ingredient is that A is halosulfuronmethyl; B is the one in nicosulfuron or rimsulfuron; C is fluroxypyr or its ester type compound; The weight percentage of effective constituents A is 0.1%~20%, and the weight percentage of active ingredient B is 0.1%~30%, and the weight percentage of active ingredient C is 0.1%~40%, and surplus is the upper acceptable insecticides adjuvant of agricultural.
Described Herbicidal combinations can be according to well known to a person skilled in the art method, the application forms of the applicable agricultural uses such as preparation wetting powder, water dispersible granules, oil-suspending agent, microemulsion, suspending agent, suspension emulsion, aqueous emulsion.
Described Herbicidal combinations also contains acceptable insecticides adjuvant in the required agricultural of preparation pesticidal preparations, be selected from one or more in solvent, emulsifier, wetting agent, stabilizing agent, dispersant, bleeding agent, thickener, defoamer, antifreezing agent, disintegrant, binding agent, filler, carrier, medium, surfactant, be known substance, various auxiliary agents conventional in pesticidal preparations, can change to some extent according to different situations, be not particularly limited.
The production technology of the described various application forms of Herbicidal combinations all belongs to existing known technology, does not repeat them here.
Herbicidal combinations provided by the invention, is applicable to prevent and kill off corn field annual weed.
Herbicidal combinations provided by the invention, adopts cauline leaf spraying or directed spraying to use conventionally.
Herbicidal combinations provided by the invention has following beneficial effect:
1, Herbicidal combinations provided by the invention, shows obvious synergistic effect to corn field weed, and the control efficiency of composition is significantly improved than single dose, reduce the using dosage of agricultural chemicals, reduce medication number of times, reduced drug cost, reduced the adverse effect of agricultural chemicals to ecotope.
2, Herbicidal combinations provided by the invention, the combination of three kinds of active ingredients, has expanded herbicidal spectrum, and a drug can solve various weeds problems, has made up defect and limitation when single dose is used.
3, Herbicidal combinations provided by the invention, active ingredient mechanism of action is different, can overcome long-term single use and easily produce the shortcoming of resistance, extends the service life of medicament, to the comprehensive regulation important in inhibiting of Weed Resistance.
4, Herbicidal combinations provided by the invention, rapidly, the lasting period is long in drug effect performance, and use cost is low, easy to use, time saving and energy saving, and it applies huge economic benefit and social benefit.
Embodiment
In order to make object of the present invention, technical scheme and advantage more short and sweet, the present invention describes with following specific embodiment, but the present invention only limits to absolutely not these examples.The following stated is only the good embodiment of the present invention, only for describing the present invention, can not be interpreted as the restriction to scope of the present invention.It should be pointed out that all any modifications of making within the spirit and principles in the present invention, be equal to replacement and improvement etc., within all should being included in protection scope of the present invention.
Embodiment 1: halosulfuronmethyl, nicosulfuron, the different monooctyl ester of fluroxypyr and the composite Toxicity Determination to green foxtail, eleusine indica, the rhizome of nutgrass flatsedge, field bindweed thereof
Table one, halosulfuronmethyl, nicosulfuron, the different monooctyl ester of fluroxypyr and the composite Toxicity Determination result to green foxtail thereof.
Figure BDA0000433543970000041
Table two, halosulfuronmethyl, nicosulfuron, the different monooctyl ester of fluroxypyr and the composite Toxicity Determination result to eleusine indica thereof.
Figure BDA0000433543970000051
Table three, halosulfuronmethyl, nicosulfuron, the different monooctyl ester of fluroxypyr and the composite Toxicity Determination result to the rhizome of nutgrass flatsedge thereof.
Table four, halosulfuronmethyl, nicosulfuron, the different monooctyl ester of fluroxypyr and the composite Toxicity Determination result to field bindweed thereof
Figure BDA0000433543970000071
Evaluate weed killer herbicide associated form (NY/T 1155.7-2006) according to Colby method, its formula is as follows:
E 0 = A × B × C × · · · N 100 ( n - 1 )
In formula: A is halosulfuronmethyl fresh weight inhibiting rate to target weeds when alone with certain dosage;
B is nicosulfuron fresh weight inhibiting rate to target weeds when alone with certain dosage;
C is the different monooctyl ester of fluroxypyr fresh weight inhibiting rate to target weeds when alone with certain dosage;
N is the weed killer herbicide kind number of mixture;
E 0theoretical value to target weeds fresh weight inhibiting rate during for halosulfuronmethyl, nicosulfuron, three kinds of pharmacy mix of the different monooctyl ester of fluroxypyr;
It when E is halosulfuronmethyl, nicosulfuron, three kinds of pharmacy mix of the different monooctyl ester of fluroxypyr, is the measured value of contrast to target weeds fresh weight inhibiting rate.
Evaluation criterion: work as E 0when ﹣ E > 10%, be expressed as synergistic effect; As ﹣ 10%≤E 0when ﹣ E≤10%, show as summation action; Work as E 0when ﹣ E < ﹣ 10%, show as antagonism.
Evaluate weed killer herbicide associated form according to Colby method, table one, two, three, four data show, halosulfuronmethyl, nicosulfuron, the different monooctyl ester triple combination of fluroxypyr are remarkable to green foxtail, eleusine indica, the rhizome of nutgrass flatsedge, field bindweed synergistic effect, E 0-E value is all greater than 20%.
Embodiment 2: field control effectiveness test.
Table five, present composition field control effectiveness test result.
Figure BDA0000433543970000081
Known by test of pesticide effectiveness result, halosulfuronmethyl, nicosulfuron, the different monooctyl ester ternary built of fluroxypyr excipient are under water dispersible granules, oil-suspending agent, suspending agent routine dose, after medicine 15 days to the preventive effect of green foxtail, eleusine indica, the rhizome of nutgrass flatsedge, field thistle, field bindweed, acalypha copperleaf all more than 90%.
In sum, component of the present invention is reasonable, has remarkable synergistic effect, expands herbicide spectrum, and exploitation has good prospect for cornfield weeding.

Claims (4)

1. a cornfield weeding composition, is characterized in that comprising three kinds of active ingredients: effective constituents A, B, C, and wherein active ingredient is that A is halosulfuronmethyl; B is the one in nicosulfuron or rimsulfuron; C is fluroxypyr or its ester type compound.
2. a kind of cornfield weeding composition according to claim 1, it is characterized in that: the weight percentage of effective constituents A is 0.1%~20%, the weight percentage of active ingredient B is 0.1%~30%, the weight percentage of active ingredient C is 0.1%~40%, and surplus is the upper acceptable insecticides adjuvant of agricultural.
3. a kind of cornfield weeding composition according to claim 1 and 2, is characterized in that: the formulation of described Herbicidal combinations can be the one in wetting powder, water dispersible granules, oil-suspending agent, microemulsion, suspending agent, suspension emulsion, aqueous emulsion.
4. according to a kind of cornfield weeding composition described in claim 1-3 any one, it is characterized in that: be applicable to prevent and kill off corn field annual weed.
CN201310666916.6A 2013-12-09 2013-12-09 Corn field weeding composition Pending CN103766365A (en)

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104839184A (en) * 2015-04-18 2015-08-19 广东中迅农科股份有限公司 Pesticide composition containing halosulfuron-methyl, aminopyralid and nicosulfuron
CN104839185A (en) * 2015-04-18 2015-08-19 广东中迅农科股份有限公司 Weeding composition for controlling and removing annual weeds in corn fields
CN105557727A (en) * 2015-12-24 2016-05-11 安徽美兰农业发展股份有限公司 Nicosulfuron, atrazine and halosulfuron-methyl compound dispersible oil suspending agent and preparation method thereof
CN107047599A (en) * 2017-03-21 2017-08-18 佛山市盈辉作物科学有限公司 A kind of herbicidal composition for including halosulfuronmethyl, nicosulfuron and the different monooctyl ester of fluroxypyr
CN112120037A (en) * 2020-10-15 2020-12-25 安徽省农业科学院植物保护与农产品质量安全研究所 Weeding composition containing rimsulfuron, halosulfuron-methyl and flufenacet

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101066056A (en) * 2007-06-06 2007-11-07 赵邦斌 Re-compounded herbicide of nicosulfuron and fluroxypyr
CN102326572A (en) * 2011-06-18 2012-01-25 陕西韦尔奇作物保护有限公司 Weeding composition containing rimsulfuron and fluroxypyr
CN103300039A (en) * 2013-07-12 2013-09-18 安徽丰乐农化有限责任公司 Compounded herbicide for corn seedlings of postemergence

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101066056A (en) * 2007-06-06 2007-11-07 赵邦斌 Re-compounded herbicide of nicosulfuron and fluroxypyr
CN102326572A (en) * 2011-06-18 2012-01-25 陕西韦尔奇作物保护有限公司 Weeding composition containing rimsulfuron and fluroxypyr
CN103300039A (en) * 2013-07-12 2013-09-18 安徽丰乐农化有限责任公司 Compounded herbicide for corn seedlings of postemergence

Non-Patent Citations (1)

* Cited by examiner, † Cited by third party
Title
中华人民共和国农业部: "《中华人民共和国农业行业标准》", 10 July 2006 *

Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104839184A (en) * 2015-04-18 2015-08-19 广东中迅农科股份有限公司 Pesticide composition containing halosulfuron-methyl, aminopyralid and nicosulfuron
CN104839185A (en) * 2015-04-18 2015-08-19 广东中迅农科股份有限公司 Weeding composition for controlling and removing annual weeds in corn fields
CN105557727A (en) * 2015-12-24 2016-05-11 安徽美兰农业发展股份有限公司 Nicosulfuron, atrazine and halosulfuron-methyl compound dispersible oil suspending agent and preparation method thereof
CN107047599A (en) * 2017-03-21 2017-08-18 佛山市盈辉作物科学有限公司 A kind of herbicidal composition for including halosulfuronmethyl, nicosulfuron and the different monooctyl ester of fluroxypyr
CN112120037A (en) * 2020-10-15 2020-12-25 安徽省农业科学院植物保护与农产品质量安全研究所 Weeding composition containing rimsulfuron, halosulfuron-methyl and flufenacet

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