CN104663659A - Corn field herbicide composition containing 2,4-dichlorophenoxybutanoic and derivatives of 2,4-dichlorophenoxybutanoic - Google Patents
Corn field herbicide composition containing 2,4-dichlorophenoxybutanoic and derivatives of 2,4-dichlorophenoxybutanoic Download PDFInfo
- Publication number
- CN104663659A CN104663659A CN201510016471.6A CN201510016471A CN104663659A CN 104663659 A CN104663659 A CN 104663659A CN 201510016471 A CN201510016471 A CN 201510016471A CN 104663659 A CN104663659 A CN 104663659A
- Authority
- CN
- China
- Prior art keywords
- dichlorophenoxybutanoic
- active component
- herbicide composition
- corn field
- derivative
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Classifications
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N39/00—Biocides, pest repellants or attractants, or plant growth regulators containing aryloxy- or arylthio-aliphatic or cycloaliphatic compounds, containing the group or, e.g. phenoxyethylamine, phenylthio-acetonitrile, phenoxyacetone
- A01N39/02—Aryloxy-carboxylic acids; Derivatives thereof
-
- A—HUMAN NECESSITIES
- A01—AGRICULTURE; FORESTRY; ANIMAL HUSBANDRY; HUNTING; TRAPPING; FISHING
- A01N—PRESERVATION OF BODIES OF HUMANS OR ANIMALS OR PLANTS OR PARTS THEREOF; BIOCIDES, e.g. AS DISINFECTANTS, AS PESTICIDES OR AS HERBICIDES; PEST REPELLANTS OR ATTRACTANTS; PLANT GROWTH REGULATORS
- A01N47/00—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid
- A01N47/08—Biocides, pest repellants or attractants, or plant growth regulators containing organic compounds containing a carbon atom not being member of a ring and having no bond to a carbon or hydrogen atom, e.g. derivatives of carbonic acid the carbon atom having one or more single bonds to nitrogen atoms
- A01N47/28—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N<
- A01N47/36—Ureas or thioureas containing the groups >N—CO—N< or >N—CS—N< containing the group >N—CO—N< directly attached to at least one heterocyclic ring; Thio analogues thereof
Landscapes
- Life Sciences & Earth Sciences (AREA)
- Agronomy & Crop Science (AREA)
- Pest Control & Pesticides (AREA)
- Plant Pathology (AREA)
- Health & Medical Sciences (AREA)
- Engineering & Computer Science (AREA)
- Dentistry (AREA)
- General Health & Medical Sciences (AREA)
- Wood Science & Technology (AREA)
- Zoology (AREA)
- Environmental Sciences (AREA)
- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention discloses a corn field herbicide composition containing 2,4-dichlorophenoxybutanoic and derivatives of 2,4-dichlorophenoxybutanoic, and belongs to the field of pesticides. The corn field herbicide composition comprises an active ingredient A and an active ingredient B, wherein the active ingredient A is a 2,4-dichlorophenoxybutanoic compound; and the active ingredient B is selected from any one or more of alachlor, acetochlor, pretilachlor, butachlor, metolachlor, propisochlor, rimsulfuron, foramsulfuron, nicosulfuron, mesotrione, isoxaflutole, topramezone and atrazine. The corn field herbicide composition has a wide weeding spectrum, and is capable of preventing and treating grassy weeds, broadleaf weeds and nutgrass flatsedge; the active ingredient A is compounded with the active ingredient B, and the corn field herbicide composition has a synergistic effect. Compared with a single dosage, the corn field herbicide composition has an obvious synergistic effect, is high in weeding speed, good in safety on corn and long in lasting time; the weed damages can be avoided in the whole growth period by once application; and the pesticide application frequency and the pesticide application cost are effectively reduced.
Description
Technical field
The present invention relates to technical field of pesticide, particularly one contains the corn field herbicide composition of 2,4-Dichlorophenoxybutanoic and derivative thereof.
Background technology
Corn is one of world's staple food crop, produces throughout each continent except the South Pole.The cereal crops that China's corn is also main, China's maize sown area accounts for 1/6 of plant of grain crops area, and area is at about 300,000,000 mu.
Corn field weed kind is many, and according to statistics, the kind that can form Weed infestation has kind more than 200, wherein, the most generally, harm the most serious kind have kind more than 20.Main weeds have barnyard grass, eleusine indica, lady's-grass, green foxtail, field thistle, acalypha copperleaf, Amaranthus retroflexus, kitchen garden, the rhizome of nutgrass flatsedge etc.
Current corn field herbicide is mainly divided into herbicide before seedling stage as Acetochlor, butachlor, isopropyl methoxalamine etc.; Corn field herbicide after seedling is seldom selectable, mainly based on the sulfonylurea herbicide of nicosulfuron, rimsulfuron; HPPD inhibitor weed killer herbicide based on mesotrione; Atrazine, fluroxypyr, methoxone, 2,4-D butyl esters etc. use also very extensive in addition, mainly prevent and treat broad leaved weed.The weed killer herbicide of current control broad leaved weed is all very low to the safety of corn, is directed spraying during use substantially, and along with a large amount of uses of above-mentioned weed killer herbicide, Weed Resistance problem is more and more serious; Mix disposable solution corn field grass family broad leaved weed by composite or bucket and become active demand.
Summary of the invention
For making up above deficiency, the invention provides that a kind of herbicidal effect is good, instant effect, lasting period are long, the corn field herbicide composition containing 2,4-Dichlorophenoxybutanoic and derivative thereof of broad weed-killing spectrum.
The technical solution used in the present invention is:
A kind of corn field herbicide composition containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprise active component A and active component B, wherein, active component A is 2,4-Dichlorophenoxybutanoic compounds, and its general formula is:
or
Wherein, R is selected from hydrogen or saturated alkyl; M is selected from sodium ion, potassium ion, ammonium ion, dimethyl amine ion, isopropylamine ion;
Active component B be selected from alachlor, Acetochlor, the third careless amine, butachlor, isopropyl methoxalamine, propisochlor, rimsulfuron, foramsulfuron, nicosulfuron, mesotrione, isoxaflutole, benzene pyrazoles humulone, atrazine any one or a few.Lot of experiments proves: active component A is particularly suitable for broad leaved weed and the rhizome of nutgrass flatsedge such as field thistle, field bindweed, acalypha copperleaf, dayflower, meal bud grass that prevent and treat the more difficult control of other existing weed killer herbicides.
Preferably, in general formula, R is selected from hydrogen or methyl, ethyl, propyl group, butyl, 2-ethylhexyl.
Further, in general formula, R is selected from hydrogen or butyl, 2-ethylhexyl.
As preferably, M is selected from sodium ion, potassium ion, ammonium ion.
Preferably, the weight proportion of described active component A and active component B is 1-100:100-1.
Further, the weight proportion of described active component A and active component B is 1-20:20-1.
As preferably, the total amount of described active component A and active component B is the 1-99% of weed killer herbicide gross mass.
Further, the total amount of described active component A and active component B is the 20-60% of weed killer herbicide gross mass.
Preferably, described combination dosage form be wetting powder, missible oil, aqueous suspension agent, dispersible in oil-suspending agent, microemulsion, aqueous emulsion or water dispersible granules any one.
Beneficial effect of the present invention is:
The present invention has herbicide spectrum widely, can prevent and treat grassy weed, broad leaved weed and nutgrass flatsedge; Active component A and active component B composite, there is synergy, compared with single dose, there is obvious synergistic effect, and herbicide speed is fast, has good safety to corn.In addition, its lasting period is long, and a drug can ensure whole breeding time not by Weed infestation, effectively reduces spraying times and dispenser cost, economic benefit and social benefit obvious.Compensate for single dose to the anti-heterodyne of main weeds, take effect slow defect.
Embodiment
Different pesticide active ingredients is combined into mixture, is effective quick method of current development novel pesticide.After different component mixing, usually show three kinds of situations: summation action, antagonism and synergistic effect, its type of action needs lot of experiments to verify.
The invention discloses active component A and active component B composite and there is the weed killer herbicide of notable synergistic effect.
Table 1 and table 2 are involved active component A.
Active component A of the present invention is known substance, can prepare by the method for bibliographical information.J.Am.Chem.Chem.Soc. (1947) is shown in concrete operations, 69,718-723.
Table 1 R and active component A outward appearance and physical property
The outward appearance of table 2 M and active component A and physical property
Involved active component B:
(B1-1) alachlor: English name: Alachlor, CAS:15972-60-8;
(B1-2) Acetochlor: English name: acetochlor, CAS:34256-82-1;
(B1-3) the third careless amine: English name: Pretilachlor, CAS:51218-49-6;
(B1-4) butachlor: English name: Machette, CAS:23184-66-9;
(B1-5) isopropyl methoxalamine: English name: Metolachlor, CAS:51218-45-2;
(B1-6) propisochlor: English name: Propisochlor, CAS:86763-47-5;
(B2-1) rimsulfuron: English name: rimsulfuron, CAS:122931-48-0;
(B2-2) foramsulfuron: English name foramsulfuron, CAS:173159-57-4;
(B2-3) nicosulfuron: English name: Nicosulfuron, CAS:111991-09-4;
(B3-1) mesotrione: English name mesotrione, CAS:104206-82-82;
(B3-2) isoxaflutole: English name isoxaflutole, GAS:141112-29-0;
(B3-3) benzene pyrazoles humulone: English name Topramezone, CAS:210631-68-8;
(B4-1) atrazine: English name atrazine, CAS:102029-43-6.
Embodiment 1
A kind of corn field herbicide composition (missible oil) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: butachlor (B1-4) 20%;
Active ingredient: compound 3 40%;
Emulsifier: calcium dodecyl benzene sulfonate 9%;
Emulsifier: polyoxyethylene nonylphenol ether 9%;
Dimethylbenzene surplus.
Embodiment 2
A kind of corn field herbicide composition (missible oil) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: compound 6 40%;
Active ingredient: propisochlor (B1-6) 20%;
Emulsifier: calcium dodecyl benzene sulfonate 9%;
Emulsifier: polyoxyethylene nonylphenol ether 9%;
Dimethylbenzene surplus.
Embodiment 3:
A kind of corn field herbicide composition (wetting powder) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: rimsulfuron (B2-1) 2%;
Active ingredient: compound 1 40%;
Wetting agent: NNO 11%;
Dispersant: sodium lignin sulfonate 9%;
Kaolin surplus.
Embodiment 4:
A kind of corn field herbicide composition (aqueous suspension agent) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: isoxaflutole (B3-2) 4%;
Active ingredient: compound 8 20%;
Dispersant: sodium lignin sulfonate 3%;
Dispersant: phosphoric acid ester 3%
Thickener: xanthans 0.1%
Water surplus.
Embodiment 5:
A kind of corn field herbicide composition (missible oil) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: Acetochlor (B1-2) 20%;
Active ingredient: compound 3 40%;
Emulsifier: calcium dodecyl benzene sulfonate 9%;
Emulsifier: polyoxyethylene nonylphenol ether 9%;
Dimethylbenzene surplus.
Embodiment 6:
A kind of corn field herbicide composition (dispersibling oil-suspending agent) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: nicosulfuron (B2-3) 2%;
Active ingredient: compound 5 20%;
Emulsifier: calcium dodecyl benzene sulfonate 11%;
Emulsifier: castor oil polyoxyethylene ether 9%;
Methyl oleate surplus.
Embodiment 7:
A kind of corn field herbicide composition (dispersibling oil-suspending agent) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: compound 8 20%;
Active ingredient: mesotrione (B3-1) 5%;
Emulsifier: calcium dodecyl benzene sulfonate 11%;
Emulsifier: castor oil polyoxyethylene ether 9%;
Methyl oleate surplus.
Embodiment 8:
A kind of corn field herbicide composition (dispersibling oil-suspending agent) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: compound 3 20%;
Active ingredient: nicosulfuron (B2-3) 1%;
Active ingredient: rimsulfuron (B2-1) 0.5%;
Emulsifier: castor oil polyoxyethylene ether 9%
Emulsifier: calcium dodecyl benzene sulfonate 11%;
Methyl oleate surplus.
Embodiment 9:
A kind of corn field herbicide composition (wetting powder) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: compound 9 40%;
Active ingredient: foramsulfuron (B2-2) 2.5%;
Dispersant: sodium lignin sulfonate 9%;
Kaolin surplus.
Embodiment 10:
A kind of corn field herbicide composition (dispersibling oil-suspending agent) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: compound 8 20%;
Active ingredient: benzene pyrazoles humulone (B3-3) 0.75%;
Emulsifier: calcium dodecyl benzene sulfonate 11%;
Emulsifier: styryl APEO 9%;
Methyl oleate surplus.
Embodiment 11:
A kind of corn field herbicide composition (wetting powder) containing 2,4-Dichlorophenoxybutanoic and derivative thereof, comprising:
Active ingredient: compound 1 20%;
Active ingredient: nicosulfuron (B2-3) 2%;
Active ingredient: atrazine (B4-1) 20%;
Dispersant: sodium lignin sulfonate 9%;
Kaolin surplus.
The test of pesticide effectiveness 1: indoor greenhouse is tested
According to farm-chemical indoor determination criterion (weed killer herbicide-cauline leaf spray-on process), weeds adopt pot-culture method to cultivate, and in controlled greenhouse by solar heat, temperature controls at about 20 DEG C.Relative moisture is at 62%-81%.Treat that weeds grow to 2-4 sheet leaf, test nicosulfuron (B2-3) with 2, the composite indoor of 4-Embutox (compound 1) to lady's-grass, acalypha copperleaf, nutgrass flatsedge 20 days fresh weight preventive effect effects and and synergy effect between the two (GOWING method) process repetition 4 times, each process 3 basins.
Preventive effect calculates according to the following equation:
The result of the test of table 3 test of pesticide effectiveness 1
Result show, nicosulfuron and 2,4 Embutoxs under ratio 40+300 and 40+375 ratio, E-E
0be greater than 10, there is obvious synergistic effect.
The test of pesticide effectiveness 2: outdoor field experiment
Jinan City, Shandong Province, place
Determine 20%2,4-Embutox (compound 1) oil-suspending agent and 2,4-Embutox dimethylamine salt with 4% nicosulfuron (B2-3) oil-suspending agent, 2% rimsulfuron (B2-1) dispersible oil-suspending agent, 2.5% foramsulfuron (B2-2) dispersible the composite test of pesticide effectiveness to lady's-grass, acalypha copperleaf, nutgrass flatsedge of oil-suspending agent, community randomized arrangement, plot area 100m
2.Carry out cauline leaf spraying process, after medicine, 15d and 30d observes the strain fresh weight preventive effect of each medicament respectively.Result shows that 15 days, 30 days preventive effects to this several grass are all more than 85%, compared good synergistic effect with single dose.And the composite use of above-mentioned example does not affect the safety of field corn, and corn grows fine.Result is as follows:
The result of the test of table 4 test of pesticide effectiveness 2
Test of pesticide effectiveness 3:2,4-Dichlorophenoxybutanoic and part herbicide after seedling composite cauline leaf process field experiment
Test site is Jinan City, Shandong Province
The field corn 3-5 leaf phase, weeds 2-3 leaf, test medicine is preparation embodiment 3, 6, 7, 8, 9, 10, 11, all prepare according to above-mentioned example, be mixed with 20% 2 in addition, 4-Embutox (compound 1) dispersibles oil-suspending agent, nicosulfuron (B2-3) oil-suspending agent of 4%, the rimsulfuron (B2-1) of 2% dispersibles oil-suspending agent, benzene pyrazoles humulone (B3-3) oil-suspending agent of 1.5%, the mesotrione (B3-1) of 10% dispersibles oil-suspending agent, the foramsulfuron (B2-2) of 2.5% dispersibles oil-suspending agent, 2% nicosulfuron (B2-3)+1% rimsulfuron (B2-1) dispersibles oil-suspending agent and contrasts, test totally four process, each process three repetition, community randomized arrangement, plot area 100m
2.Carry out cauline leaf spraying process, after medicine, 15d and 30d observes the strain fresh weight preventive effect of each medicament respectively.Respondent is the green foxtail in field, lady's-grass, field thistle, field bindweed, the rhizome of nutgrass flatsedge, and visual test medicament occurs with or without poisoning field corn.
Preventive effect calculates according to the following equation:
。
Can obviously be found out by table 5, 2, 4-Embutox and derivative thereof and nicosulfuron, rimsulfuron, mesotrione, foramsulfuron, after the multiple combination of benzene pyrazoles humulone etc. is composite, each example is to green foxtail, lady's-grass, field thistle, field bindweed, the effect of the rhizome of nutgrass flatsedge all reaches more than 85%, with 2, 4-Embutox (compound 1) and nicosulfuron, rimsulfuron, mesotrione, foramsulfuron, alone and the nicosulfuron such as benzene pyrazoles humulone is compared with rimsulfuron mixture, there is obvious synergy and complementation, the preventive effect of the preparation 30d after composite is all improved than the preventive effect of 15d, illustrate that two components are composite and there is the good lasting period, and two component mixture compensate for the wideless shortcoming of alone herbicide spectrum, to broad leaved weed, grassy weed and the rhizome of nutgrass flatsedge all have preventive effect well, and in the concentration range that test is implemented, to corn safety.Can be used as corn field herbicide to use.
Table 5: the result of the test of the test of pesticide effectiveness 3
Claims (9)
1. one kind contains the corn field herbicide composition of 2,4-Dichlorophenoxybutanoic and derivative thereof, and it is characterized in that: comprise active component A and active component B, wherein, active component A is 2,4-Dichlorophenoxybutanoic compounds, and its general formula is:
or
Wherein, R is selected from hydrogen or saturated alkyl; M is selected from sodium ion, potassium ion, ammonium ion, dimethyl amine ion, isopropylamine ion;
Active component B be selected from alachlor, Acetochlor, the third careless amine, butachlor, isopropyl methoxalamine, propisochlor, rimsulfuron, foramsulfuron, nicosulfuron, mesotrione, isoxaflutole, benzene pyrazoles humulone, atrazine any one or a few.
2. contain the corn field herbicide composition of 2,4-Dichlorophenoxybutanoic and derivative thereof as claimed in claim 1, it is characterized in that: in general formula, R is selected from hydrogen or methyl, ethyl, propyl group, butyl, 2-ethylhexyl.
3. contain the corn field herbicide composition of 2,4-Dichlorophenoxybutanoic and derivative thereof as claimed in claim 2, it is characterized in that: in general formula, R is selected from hydrogen or butyl, 2-ethylhexyl.
4. contain the corn field herbicide composition of 2,4-Dichlorophenoxybutanoic and derivative thereof as claimed in claim 1, it is characterized in that: M is selected from sodium ion, potassium ion, ammonium ion.
5. contain the corn field herbicide composition of 2,4-Dichlorophenoxybutanoic and derivative thereof as claimed in claim 1, it is characterized in that: the weight proportion of described active component A and active component B is 1-100:100-1.
6. contain the corn field herbicide composition of 2,4-Dichlorophenoxybutanoic and derivative thereof as claimed in claim 5, it is characterized in that: the weight proportion of described active component A and active component B is 1-20:20-1.
7. contain the corn field herbicide composition of 2,4-Dichlorophenoxybutanoic and derivative thereof as claimed in claim 1, it is characterized in that: the total amount of described active component A and active component B is the 1-99% of weed killer herbicide gross mass.
8. contain the corn field herbicide composition of 2,4-Dichlorophenoxybutanoic and derivative thereof as claimed in claim 7, it is characterized in that: the total amount of described active component A and active component B is the 20-60% of weed killer herbicide gross mass.
9. as described in claim 7 or 8, contain 2, the corn field herbicide composition of 4-Dichlorophenoxybutanoic and derivative thereof, is characterized in that: described combination dosage form is wetting powder, missible oil, aqueous suspension agent, dispersible in oil-suspending agent, microemulsion, aqueous emulsion or water dispersible granules any one.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201510016471.6A CN104663659A (en) | 2014-01-26 | 2015-01-13 | Corn field herbicide composition containing 2,4-dichlorophenoxybutanoic and derivatives of 2,4-dichlorophenoxybutanoic |
Applications Claiming Priority (3)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN2014100373596 | 2014-01-26 | ||
| CN201410037359.6A CN104106584A (en) | 2014-01-26 | 2014-01-26 | Cornfield compounded herbicide composition |
| CN201510016471.6A CN104663659A (en) | 2014-01-26 | 2015-01-13 | Corn field herbicide composition containing 2,4-dichlorophenoxybutanoic and derivatives of 2,4-dichlorophenoxybutanoic |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN104663659A true CN104663659A (en) | 2015-06-03 |
Family
ID=51703729
Family Applications (3)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410037359.6A Pending CN104106584A (en) | 2014-01-26 | 2014-01-26 | Cornfield compounded herbicide composition |
| CN201510016306.0A Pending CN104672083A (en) | 2014-01-26 | 2015-01-13 | Cornfield herbicide compound and application thereof |
| CN201510016471.6A Pending CN104663659A (en) | 2014-01-26 | 2015-01-13 | Corn field herbicide composition containing 2,4-dichlorophenoxybutanoic and derivatives of 2,4-dichlorophenoxybutanoic |
Family Applications Before (2)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410037359.6A Pending CN104106584A (en) | 2014-01-26 | 2014-01-26 | Cornfield compounded herbicide composition |
| CN201510016306.0A Pending CN104672083A (en) | 2014-01-26 | 2015-01-13 | Cornfield herbicide compound and application thereof |
Country Status (2)
| Country | Link |
|---|---|
| CN (3) | CN104106584A (en) |
| WO (1) | WO2015109423A1 (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106259368A (en) * | 2016-08-16 | 2017-01-04 | 安徽丰乐农化有限责任公司 | A kind of corn field complex weedicide containing isoxazole oxadiazon |
| CN107960417A (en) * | 2016-10-20 | 2018-04-27 | 山东先达农化股份有限公司 | A kind of Herbicidal combinations and its application |
| CN110074126A (en) * | 2019-05-31 | 2019-08-02 | 江西鑫邦科技有限责任公司 | A kind of phenoxy carboxylic acid Herbicidal combinations of brassinolide-containing class compound |
Families Citing this family (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN111109305A (en) * | 2019-12-31 | 2020-05-08 | 潍坊友容实业有限公司 | Saline-alkali soil herbicide containing citrus extract and preparation method thereof |
| CN117481113B (en) * | 2023-12-21 | 2024-03-29 | 山东科赛基农生物工程有限公司 | Topramezone and clodinafop-propargyl dispersible oil suspending agent and application thereof |
Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031174A (en) * | 1987-08-10 | 1989-02-22 | 石原产业株式会社 | Herbicidal combinations |
| CN1398517A (en) * | 2001-07-27 | 2003-02-26 | 江苏省新沂中凯农用化工有限公司 | Herbicide composition containing nicosulfuron and its prepn and use |
| CN1411338A (en) * | 1999-11-15 | 2003-04-16 | 阿温提斯作物科学有限公司 | Herbicide composition with acylated amino phenyl sulfonyl carbamide |
| CN102334484A (en) * | 2011-11-07 | 2012-02-01 | 河北博嘉农业有限公司 | Herbicide composite |
| CN102986705A (en) * | 2012-11-30 | 2013-03-27 | 王学权 | Herbicide composition containing topramezone |
| CN103190414A (en) * | 2012-01-08 | 2013-07-10 | 山东滨农科技有限公司 | Herbicide composition containing topramezone and MCPA |
Family Cites Families (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| GB1097713A (en) * | 1963-03-28 | 1968-01-03 | May & Baker Ltd | Improvements in or relating to herbicidal compositions |
| AR206679A1 (en) * | 1971-11-19 | 1976-08-13 | Fisons Ltd | HERBICIDE COMPOSITION |
| JPS5675405A (en) * | 1979-11-26 | 1981-06-22 | Kumiai Chem Ind Co Ltd | Herbicidal composition |
| CN1142894A (en) * | 1996-07-03 | 1997-02-19 | 化学工业部沈阳化工研究院 | Sulfonylurea herbicide mixed agent and its use |
| CN1425297A (en) * | 2001-12-12 | 2003-06-25 | 马韵升 | Nicosulfuron herbicide composition |
| CN1428080A (en) * | 2001-12-27 | 2003-07-09 | 任立生 | Maize field stalk leaf weedicide composite and its preparation method |
| CN1537427A (en) * | 2003-10-22 | 2004-10-20 | 河北宣化农药有限责任公司 | Composite of herbicide |
| CN101530103A (en) * | 2009-04-27 | 2009-09-16 | 陕西上格之路生物科学有限公司 | Herbicide composition |
| CN103222470A (en) * | 2012-01-31 | 2013-07-31 | 胡登魁 | Leaves-removing herbicide after seedling emergence |
| CN102599181A (en) * | 2012-02-20 | 2012-07-25 | 王从爱 | Oil suspension agent composition containing nicosulfuron and 2,4-d isooctyl ester |
| CN104255728A (en) * | 2014-03-29 | 2015-01-07 | 潍坊先达化工有限公司 | Application of 2,4-dichlorophenoxybutyric acid and derivative of 2,4-dichlorophenoxybutyric acid |
-
2014
- 2014-01-26 CN CN201410037359.6A patent/CN104106584A/en active Pending
- 2014-03-03 WO PCT/CN2014/000190 patent/WO2015109423A1/en active Application Filing
-
2015
- 2015-01-13 CN CN201510016306.0A patent/CN104672083A/en active Pending
- 2015-01-13 CN CN201510016471.6A patent/CN104663659A/en active Pending
Patent Citations (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1031174A (en) * | 1987-08-10 | 1989-02-22 | 石原产业株式会社 | Herbicidal combinations |
| CN1411338A (en) * | 1999-11-15 | 2003-04-16 | 阿温提斯作物科学有限公司 | Herbicide composition with acylated amino phenyl sulfonyl carbamide |
| CN1398517A (en) * | 2001-07-27 | 2003-02-26 | 江苏省新沂中凯农用化工有限公司 | Herbicide composition containing nicosulfuron and its prepn and use |
| CN102334484A (en) * | 2011-11-07 | 2012-02-01 | 河北博嘉农业有限公司 | Herbicide composite |
| CN103190414A (en) * | 2012-01-08 | 2013-07-10 | 山东滨农科技有限公司 | Herbicide composition containing topramezone and MCPA |
| CN102986705A (en) * | 2012-11-30 | 2013-03-27 | 王学权 | Herbicide composition containing topramezone |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106259368A (en) * | 2016-08-16 | 2017-01-04 | 安徽丰乐农化有限责任公司 | A kind of corn field complex weedicide containing isoxazole oxadiazon |
| CN107960417A (en) * | 2016-10-20 | 2018-04-27 | 山东先达农化股份有限公司 | A kind of Herbicidal combinations and its application |
| CN110074126A (en) * | 2019-05-31 | 2019-08-02 | 江西鑫邦科技有限责任公司 | A kind of phenoxy carboxylic acid Herbicidal combinations of brassinolide-containing class compound |
Also Published As
| Publication number | Publication date |
|---|---|
| CN104672083A (en) | 2015-06-03 |
| CN104106584A (en) | 2014-10-22 |
| WO2015109423A1 (en) | 2015-07-30 |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103688994B (en) | Weeding composition with glufosinate and efficient haloxyfop-methyl, and preparation method of weeding composition | |
| CN101861867A (en) | Pesticide compound containing penoxsulam and cyhalofop-butyl and application thereof | |
| CN104663659A (en) | Corn field herbicide composition containing 2,4-dichlorophenoxybutanoic and derivatives of 2,4-dichlorophenoxybutanoic | |
| CN103271028A (en) | Compound herbicide | |
| CN105432644A (en) | Mixed herbicide containing halosulfuron-methyl and flufenacet | |
| CN104255728A (en) | Application of 2,4-dichlorophenoxybutyric acid and derivative of 2,4-dichlorophenoxybutyric acid | |
| CN102027981A (en) | Herbicidal composition containing nicosulfuron and clopyralid and application thereof | |
| CN105076200A (en) | Weeding composition containing glyphosate and florasulam | |
| CN103503899A (en) | Pesticide composition containing pyribenzoxim and halosulfuron-methyl | |
| CN103081944A (en) | Weeding composition and herbicide | |
| CN103271055B (en) | A kind of Synergistic herbicide compositions for preventing and kill off paddy field weed | |
| CN104106577A (en) | A weeding composition containing metazachlor and oxadiargyl | |
| CN103636650A (en) | Weeding composition containing fentrazamide and halosulfuron-methyl | |
| CN103798238A (en) | Pesticide composition with pyraflufen-ethyl and phenoxy carboxylic acid herbicide | |
| CN103493822A (en) | Herbicide with broad-spectrum weeding effect | |
| CN109452301B (en) | Ternary weeding composition containing propyrisulfuron | |
| CN103651479B (en) | A kind of Herbicidal combinations containing monosulfmeturon and N-alpha-chloroacetyl-N-isopropyl-o ethylaniline | |
| CN107912438A (en) | Herbicidal combinations and its application | |
| CN105432633A (en) | Rice-field weeding composition containing florasulam and cyhalofop-butyl | |
| CN105379742A (en) | Compound weeding composition containing clodinafop-propargyl and methabenzthiazuron and application thereof | |
| CN104396985A (en) | Sorghum field herbicide | |
| CN105360122A (en) | Compound weeding composition containing clodinafop-propargyl and methoxyphenone and application of compound weeding composition | |
| CN104285996A (en) | Herbicide composition for sorghum fields | |
| CN104585203A (en) | Post-emergence herbicide composition used in corn fields | |
| CN104012544A (en) | Weeding composition containing fenoxaprop-p-ethyl and bispyribac-sodium |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20150603 |
|
| RJ01 | Rejection of invention patent application after publication |