CN103757650A - Method for ultrasonic removal of carbon deposition - Google Patents

Method for ultrasonic removal of carbon deposition Download PDF

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Publication number
CN103757650A
CN103757650A CN201310517411.3A CN201310517411A CN103757650A CN 103757650 A CN103757650 A CN 103757650A CN 201310517411 A CN201310517411 A CN 201310517411A CN 103757650 A CN103757650 A CN 103757650A
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Prior art keywords
carbon
carbon deposition
piece surface
tank liquor
carbon remover
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CN201310517411.3A
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CN103757650B (en
Inventor
孙慧艳
张志成
杜兴盛
苑英志
周静
郭春光
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AECC Shenyang Liming Aero Engine Co Ltd
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Shenyang Liming Aero Engine Group Co Ltd
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Abstract

The invention relates to a method for ultrasonic removal of carbon deposition. According to the technical scheme of the invention, the method for ultrasonic removal of the carbon deposition comprises the following steps: deoiling parts, preparing a carbon deposition removing bath solution, carrying out ultrasonic removal of the carbon deposition, and carrying out hydrochloric acid corrosion. The method for ultrasonic removal of the carbon deposition utilizes the carbon deposition removing bath solution with a special formula, has the advantages of fast carbon deposition removing speed, high quality and easy implementation, and besides reduces the environmental pollution caused by using an ordinary chemical immersion method to remove the carbon deposition.

Description

A kind of ultrasonic wave carbon removing method
Technical field
The present invention relates to a kind of carbon removing method, particularly relate to a kind of ultrasonic wave carbon removing method.
Background technology
Carbon distribution is fuel and the product of lubricating oil under high temperature oxidation effect.In combustion chamber, oxygen supply is not enough, fuel and scurry into the lube stock of combustion chamber can not perfect combustion, and produce oil smoke and tar particles, after they and lubricating oil mix, be further oxidized into consistence colloidal liquid, stick to securely on nozzle, and under the continuous effect of high temperature, colloid aggregates into again more complicated polymkeric substance, i.e. carbon distribution.And engine temperature is higher, the carbon distribution of formation is also more firmly tightr, and participant belongs to bonding and closes firmly.Carbon distribution is as unclean in cleaning, will waste fuel oil, and have a strong impact on the work-ing life of engine.
What generally adopt in the market is chemical immersion method carbon remover.Utilize 1%~10% 741 washing composition, soak for a long time, more than generally all will being controlled at 24h.But for some obstinate carbon distributions, cannot thoroughly remove like this, can only lean on local mechanical polishing, but adopt this operation, easily damage again matrix, cause scrapping of part.
Summary of the invention
The invention provides a kind of ultrasonic wave carbon removing method, utilize the carbon remover tank liquor of special formulation, have advantages of that carbon remover speed is fast, quality is high, be easy to realize, reduced general chemistry infusion method carbon remover pollution on the environment simultaneously.
Technical scheme of the present invention is as follows:
A ultrasonic wave carbon removing method, comprises the steps:
(1) by part oil removing: employing acetone is degreaser, and part is immersed in degreaser, at room temperature soak oil removing 20~120 minutes, in air, dry or dry up; Put into 60~80 ℃ of alkali lye and carry out electrochemical deoiling, cleaning oil pollution is clean, then carry out hot water wash and cold wash, clean the alkali lye of piece surface remnants;
(2) make carbon remover tank liquor: carbon remover tank liquor formula is: potassium permanganate 10~35g/L, sodium hydroxide 25~50g/L, sodium dichromate 99 5~10g/L; With 40~60 ℃ of hot water, respectively described potassium permanganate, sodium hydroxide, sodium dichromate 99 are thoroughly dissolved, be placed in the groove with ultrasonic equipment, carbon remover tank liquor is stirred;
(3) ultrasonic wave carbon remover: the part after oil removing is put into described carbon remover tank liquor, control ultrasonic frequency at 20~30kHz, carbon remover tank liquor temperature at 40~60 ℃, every a part of 20~40min upset, until the thorough Ex-all of the carbon of piece surface black, piece surface part presents matrix metal gloss; Part is taken out, with hot water wash and cold wash, the alkali lye that piece surface is residual is thoroughly removed;
(4) hcl corrosion: can form oxide compound because alkali lye reacts with carbon distribution, be attached to piece surface, part is put into hydrochloric acid, the oxide compound of piece surface is removed, when part presents the matrix that has metalluster, the carbon on part is thoroughly cleaned out; Then with water blast gun, rinse part surfaces externally and internally, then put into hot water and clean, then make part rapid drying in air, finally with pressurized air, dry up.
Beneficial effect of the present invention:
1, carbon remover tank liquor formula of the present invention is: potassium permanganate 10~35g/L, sodium hydroxide 25~50g/L, sodium dichromate 99 5~10g/L; Wherein potassium permanganate 10~35g/L and sodium hydroxide 25~50g/L are used in conjunction with and can make the rigid structure generation of carbon surface loosening, and then it is inner to corrode carbon, improves carbon remover speed; Potassium permanganate is first for carbon remover tank liquor formula, carbon remover successful in this area.
2, in carbon remover tank liquor formula of the present invention, sodium dichromate 99 can play the effect of protection part metallic matrix, prevents part excessive erosion.
3, the present invention combines with pharmaceutical chemicals hyperacoustic cavitation effect to the solvency action of carbon distribution, reaches the object of thorough decarbonizing.The carbon on border can be removed or weaken to the high-speed micro-jet that the shock action that ultrasonic vibration produces in liquid and ultrasonic cavitation produce in solid and liquid surface, increase stirring action, accelerate the dissolving of carbon, the chemical dissolution effect of strengthening carbon remover tank liquor to carbon.
4, adopt above-mentioned processing method carbon remover, can be successfully applied to the repairing of engine fuel nozzle.After nozzle burner carbon distribution is removed, surperficial metal luster, nozzle opening air-flow is unobstructed, meets design requirement, can make it recover recycling, has saved production cost, increases work efficiency more than 8 times.
Embodiment
Embodiment 1
Figure DEST_PATH_GDA0000472499080000031
Adopt above technical recipe, by the technical process of nozzle burner carbon remover, carry out carbon remover, the carbon on nozzle burner surface is removed clean, presents the matrix that has metalluster, about 3h of carbon remover time.
Embodiment 2
Figure DEST_PATH_GDA0000472499080000041
Adopt above technical recipe, by the technical process of nozzle burner carbon remover, carry out carbon remover, the carbon on nozzle burner surface is removed clean, presents the matrix that has metalluster, about 1h of carbon remover time.
Embodiment 3
Figure DEST_PATH_GDA0000472499080000042
Adopt above technical recipe, by the technical process of nozzle burner carbon remover, carry out carbon remover, the carbon on nozzle burner surface is removed clean, presents the matrix that has metalluster, about 1h of carbon remover time.
Embodiment 4
Adopt above technical recipe, by the technical process of nozzle burner carbon remover, carry out carbon remover, the carbon on nozzle burner surface is removed clean, presents the matrix that has metalluster, about 1.5h of carbon remover time.

Claims (1)

1. a ultrasonic wave carbon removing method, is characterized in that, the method comprises the steps:
(1) by part oil removing: employing acetone is degreaser, and part is immersed in degreaser, at room temperature soak oil removing 20~120 minutes, in air, dry or dry up; Put into 60~80 ℃ of alkali lye and carry out electrochemical deoiling, cleaning oil pollution is clean, then carry out hot water wash and cold wash, clean the alkali lye of piece surface remnants;
(2) make carbon remover tank liquor: carbon remover tank liquor formula is: potassium permanganate 10~35g/L, sodium hydroxide 25~50g/L, sodium dichromate 99 5~10g/L; With 40~60 ℃ of hot water, respectively described potassium permanganate, sodium hydroxide, sodium dichromate 99 are thoroughly dissolved, be placed in the groove with ultrasonic equipment, carbon remover tank liquor is stirred;
(3) ultrasonic wave carbon remover: the part after oil removing is put into described carbon remover tank liquor, control ultrasonic frequency at 20~30kHz, carbon remover tank liquor temperature at 40~60 ℃, every a part of 20~40min upset, until the thorough Ex-all of the carbon of piece surface black, piece surface part presents matrix metal gloss; Part is taken out, with hot water wash and cold wash, the alkali lye that piece surface is residual is thoroughly removed;
(4) hcl corrosion: can form oxide compound because alkali lye reacts with carbon distribution, be attached to piece surface, part is put into hydrochloric acid, the oxide compound of piece surface is removed, when part presents the matrix that has metalluster, the carbon on part is thoroughly cleaned out; Then with water blast gun, rinse part surfaces externally and internally, then put into hot water and clean, then make part rapid drying in air, finally with pressurized air, dry up.
CN201310517411.3A 2013-10-25 2013-10-25 A kind of Method for ultrasonic removal of carbon deposition Expired - Fee Related CN103757650B (en)

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Cited By (11)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104060283A (en) * 2014-06-30 2014-09-24 湖北三江航天江河化工科技有限公司 Scrubbing agent for removing carbon deposition in artillery chamber and preparation method thereof
CN105297045A (en) * 2015-11-23 2016-02-03 佛山市高明俊品金属制品有限公司 Surface washing method for stainless steel pipes
CN105349281A (en) * 2015-11-19 2016-02-24 福州顺升科技有限公司 Gasoline deposited carbon remover, and preparation method and use method thereof
CN105436127A (en) * 2015-12-03 2016-03-30 中国南方航空工业(集团)有限公司 Deposited carbon removing method for fuel nozzle
CN107214152A (en) * 2017-07-11 2017-09-29 徐州东方热电有限公司 A kind of gas furnace burner noz(zle) cleaning and dipping device
CN107502905A (en) * 2017-10-25 2017-12-22 苏州华丰不锈钢紧固件有限公司 A kind of acid cleaning process for effectively removing thick oxide film
CN107716443A (en) * 2017-10-18 2018-02-23 源泰伟业汽车零部件有限公司 End-of-life engine ultrasonic cleaning process
CN108150288A (en) * 2017-12-18 2018-06-12 中国航发贵州黎阳航空动力有限公司 Engine duct carbon removing method
CN109234060A (en) * 2018-10-09 2019-01-18 宁波蒙曼生物科技有限公司 A kind of automobile carbon deposition detergent and its application method
CN110434120A (en) * 2019-08-30 2019-11-12 中国航发动力股份有限公司 A kind of fuel nozzle carbon cleaning method
CN112626528A (en) * 2020-11-27 2021-04-09 西安交通大学 Cleaning solution and cleaning method for renewable coke on inner surface of pipeline

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US5401325A (en) * 1993-07-29 1995-03-28 Drew Chemical Corporation Process for removing carbon deposits using microemulsion cleaners
US20030230324A1 (en) * 2002-03-15 2003-12-18 Institut Francais Du Petrole Process for the at least partial elimination of carbon deposits in a heat exchanger
CN101768749A (en) * 2008-12-30 2010-07-07 沈阳黎明航空发动机(集团)有限责任公司 Chemical carbon removing method of high-pressure turbine blade
CN101768748A (en) * 2008-12-30 2010-07-07 沈阳黎明航空发动机(集团)有限责任公司 Solution for chemically removing carbon deposition on high-pressure turbine blade
CN102107200A (en) * 2009-12-23 2011-06-29 沈阳黎明航空发动机(集团)有限责任公司 Out-groove energy-accumulating type supersonic cleaning process for accumulated carbon

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US20030230324A1 (en) * 2002-03-15 2003-12-18 Institut Francais Du Petrole Process for the at least partial elimination of carbon deposits in a heat exchanger
CN101768749A (en) * 2008-12-30 2010-07-07 沈阳黎明航空发动机(集团)有限责任公司 Chemical carbon removing method of high-pressure turbine blade
CN101768748A (en) * 2008-12-30 2010-07-07 沈阳黎明航空发动机(集团)有限责任公司 Solution for chemically removing carbon deposition on high-pressure turbine blade
CN102107200A (en) * 2009-12-23 2011-06-29 沈阳黎明航空发动机(集团)有限责任公司 Out-groove energy-accumulating type supersonic cleaning process for accumulated carbon

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Cited By (14)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104060283A (en) * 2014-06-30 2014-09-24 湖北三江航天江河化工科技有限公司 Scrubbing agent for removing carbon deposition in artillery chamber and preparation method thereof
CN105349281A (en) * 2015-11-19 2016-02-24 福州顺升科技有限公司 Gasoline deposited carbon remover, and preparation method and use method thereof
CN105297045A (en) * 2015-11-23 2016-02-03 佛山市高明俊品金属制品有限公司 Surface washing method for stainless steel pipes
CN105297045B (en) * 2015-11-23 2017-11-07 佛山市高明俊品金属制品有限公司 A kind of stainless steel pipe surface cleaning method
CN105436127A (en) * 2015-12-03 2016-03-30 中国南方航空工业(集团)有限公司 Deposited carbon removing method for fuel nozzle
CN107214152A (en) * 2017-07-11 2017-09-29 徐州东方热电有限公司 A kind of gas furnace burner noz(zle) cleaning and dipping device
CN107716443A (en) * 2017-10-18 2018-02-23 源泰伟业汽车零部件有限公司 End-of-life engine ultrasonic cleaning process
CN107502905A (en) * 2017-10-25 2017-12-22 苏州华丰不锈钢紧固件有限公司 A kind of acid cleaning process for effectively removing thick oxide film
CN108150288A (en) * 2017-12-18 2018-06-12 中国航发贵州黎阳航空动力有限公司 Engine duct carbon removing method
CN108150288B (en) * 2017-12-18 2020-06-19 中国航发贵州黎阳航空动力有限公司 Method for removing carbon deposition from engine conduit
CN109234060A (en) * 2018-10-09 2019-01-18 宁波蒙曼生物科技有限公司 A kind of automobile carbon deposition detergent and its application method
CN110434120A (en) * 2019-08-30 2019-11-12 中国航发动力股份有限公司 A kind of fuel nozzle carbon cleaning method
CN112626528A (en) * 2020-11-27 2021-04-09 西安交通大学 Cleaning solution and cleaning method for renewable coke on inner surface of pipeline
CN112626528B (en) * 2020-11-27 2022-06-07 西安交通大学 Cleaning solution and cleaning method for renewable coke on inner surface of pipeline

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Address after: 110043 Dong TA street, Dadong District, Shenyang, Liaoning Province, No. 6

Patentee after: Chinese Hangfa Shenyang Liming Aero engine limited liability company

Address before: 110043 Dong TA street, Dadong District, Shenyang, Liaoning Province, No. 6

Patentee before: Liming Aeroplane Engine (Group) Co., Ltd., Shenyang City

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