CN103756533A - Ultraviolet light polymerization water-based paint universal for metal and non-metal and preparation method thereof - Google Patents
Ultraviolet light polymerization water-based paint universal for metal and non-metal and preparation method thereof Download PDFInfo
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- CN103756533A CN103756533A CN201310743754.1A CN201310743754A CN103756533A CN 103756533 A CN103756533 A CN 103756533A CN 201310743754 A CN201310743754 A CN 201310743754A CN 103756533 A CN103756533 A CN 103756533A
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Abstract
The invention discloses ultraviolet light polymerization water-based paint universal for metal and non-metal and a preparation method of the paint. The ultraviolet light polymerization water-based paint universal for metal and non-metal comprises the following raw materials in parts by mass: 60-70 parts of vinyl ester resin, 38-46 parts of urethane acrylate, 1-2 parts of 2-hydroxy-2-methyl-1-phenylacetone, 0.5-1 part of bimercaptoacetic acid isooctyl di-n-octyltin, 35-40 parts of ethanol and 150-180 parts of water. The paint is short in curing time, that is, the curing time is 3 minutes and the adhesion capability to a substrate is of 1 grade, is good in stability and free of layering after being preserved for 6 months. The paint is simple in preparation method and applicable to popularization and application in a wide range.
Description
Technical field
The invention belongs to paint field, be specifically related to general ultraviolet solidified aqueous coating of a kind of metal and nonmetal and preparation method thereof.
Background technology
Ultraviolet-curing paint is paid close attention to because its good feature of environmental protection is more and more subject to people, but traditional photo-cured coating is generally kept away and unavoidably can be used human body volatile organic thing excitatory, therefore existing ultraviolet-curing paint has made water substitute pungency organic thinner, ultraviolet solidified aqueous coating has now enjoyed investigator to pay close attention to, but existing ultraviolet-curing paint still exists length, the not good deficiency of stability set time.
In sum, how to overcome the deficiencies in the prior art and become paint field problem demanding prompt solution.
Summary of the invention
The object of the invention is to overcome the deficiencies in the prior art and propose general ultraviolet solidified aqueous coating of a kind of metal and nonmetal and preparation method thereof, the paint solidification time of the present invention is shorter, and stability is better, and long storage time is difficult for layering.
Technical scheme of the present invention is as follows:
The general ultraviolet solidified aqueous coating of metal and nonmetal, comprises the following raw material according to mass fraction meter: vinyl ester resin 60-70 part, urethane acrylate 38-46 part, 2-hydroxy-2-methyl-1-phenyl-acetone 1-2 part, Imarcaptoacetate dioctyltin 0.5-1 part, ethanol 35-40 part, water 150-180 part.
The general ultraviolet solidified aqueous coating of described metal and nonmetal, comprises the following raw material according to mass fraction meter: 65 parts of vinyl ester resins, 40 parts of urethane acrylates, 1.5 parts of 2-hydroxy-2-methyl-1-phenyl-acetones, 0.7 part of Imarcaptoacetate dioctyltin, 37 parts of ethanol, 160 parts, water.
The preparation method of the described general ultraviolet solidified aqueous coating of metal and nonmetal, comprise the following steps: according to quality proportioning, by vinyl ester resin and urethane acrylate mixing and stirring, add 2-hydroxy-2-methyl-1-phenyl-acetone and Imarcaptoacetate dioctyltin to mix, drip the mixed solution of second alcohol and water, rate of addition control is 2mL/min, dropwises and stirs, and obtains the general ultraviolet solidified aqueous coating of metal and nonmetal.
beneficial effect:the paint solidification time of the present invention is shorter, and be 3min set time, to the sticking power of base material, is 1 grade, has good stability, and deposits after 6 months not stratified; Preparation method of the present invention is simple, is suitable for applying on a large scale.
Embodiment
Urethane acrylate of the present invention is purchased from Jiangmen City of Guangdong Province Heng Guang novel material company limited, and vinyl ester resin is purchased from Wuxi City A Erzi Chemical Co., Ltd., model ARZ3001.
Below in conjunction with embodiment, the present invention is described in further detail.
Embodiment 1
The general ultraviolet solidified aqueous coating of metal and nonmetal, comprises the following raw material according to mass fraction meter: 60 parts of vinyl ester resins, 38 parts of urethane acrylates, 1 part of 2-hydroxy-2-methyl-1-phenyl-acetone, 0.5 part of Imarcaptoacetate dioctyltin, 35 parts of ethanol, 150 parts, water.
The present embodiment preparation method: according to quality proportioning, by vinyl ester resin and urethane acrylate mixing and stirring, add 2-hydroxy-2-methyl-1-phenyl-acetone and Imarcaptoacetate dioctyltin to mix, drip the mixed solution of second alcohol and water, rate of addition control is 2mL/min, dropwise and stir, obtain the general ultraviolet solidified aqueous coating of metal and nonmetal.
This finished product is carried out to Performance Detection, and detected result is in Table 1.
Embodiment 2
The general ultraviolet solidified aqueous coating of metal and nonmetal, comprises the following raw material according to mass fraction meter: 70 parts of vinyl ester resins, 46 parts of urethane acrylates, 2 parts of 2-hydroxy-2-methyl-1-phenyl-acetones, 1 part of Imarcaptoacetate dioctyltin, 40 parts of ethanol, 180 parts, water.
The present embodiment preparation method, with embodiment 1, carries out Performance Detection by this finished product, and detected result is in Table 1.
Embodiment 3
The general ultraviolet solidified aqueous coating of metal and nonmetal, comprises the following raw material according to mass fraction meter: 65 parts of vinyl ester resins, 40 parts of urethane acrylates, 1.5 parts of 2-hydroxy-2-methyl-1-phenyl-acetones, 0.7 part of Imarcaptoacetate dioctyltin, 37 parts of ethanol, 160 parts, water.
The present embodiment preparation method, with embodiment 1, carries out Performance Detection by this finished product, and detected result is in Table 1.
Finished product prepared by embodiment 1-3 carries out performance test, the results are shown in Table 1:
Table 1 performance test data
| Performance | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| Set time, min | 3 | 2 | 3 |
| Sticking power (drawing circle method), level | 1 | 1 | 1 |
As seen from the above table, coating of the present invention has good sticking power, and set time is shorter.
Finished product stability of the present invention is good, deposits after 6 months not stratified.
Above-described embodiment is only the explanation to product of the present invention; not the present invention is made to any pro forma restriction; within not departing from technical scheme scope of the present invention, any equivalent that utilizes the technology contents of above-mentioned announcement to make simple transformation, all belongs to protection scope of the present invention.
Claims (3)
1. the general ultraviolet solidified aqueous coating of metal and nonmetal, it is characterized in that, comprise the following raw material according to mass fraction meter: vinyl ester resin 60-70 part, urethane acrylate 38-46 part, 2-hydroxy-2-methyl-1-phenyl-acetone 1-2 part, Imarcaptoacetate dioctyltin 0.5-1 part, ethanol 35-40 part, water 150-180 part.
2. the general ultraviolet solidified aqueous coating of metal and nonmetal according to claim 1, it is characterized in that, comprise the following raw material according to mass fraction meter: 65 parts of vinyl ester resins, 40 parts of urethane acrylates, 1.5 parts of 2-hydroxy-2-methyl-1-phenyl-acetones, 0.7 part of Imarcaptoacetate dioctyltin, 37 parts of ethanol, 160 parts, water.
3. the preparation method of the general ultraviolet solidified aqueous coating of metal and nonmetal claimed in claim 1, it is characterized in that, comprise the following steps: according to quality proportioning, by vinyl ester resin and urethane acrylate mixing and stirring, add 2-hydroxy-2-methyl-1-phenyl-acetone and Imarcaptoacetate dioctyltin to mix, drip the mixed solution of second alcohol and water, rate of addition control is 2mL/min, dropwise and stir, obtain the general ultraviolet solidified aqueous coating of metal and nonmetal.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310743754.1A CN103756533A (en) | 2013-12-30 | 2013-12-30 | Ultraviolet light polymerization water-based paint universal for metal and non-metal and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310743754.1A CN103756533A (en) | 2013-12-30 | 2013-12-30 | Ultraviolet light polymerization water-based paint universal for metal and non-metal and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103756533A true CN103756533A (en) | 2014-04-30 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310743754.1A Withdrawn CN103756533A (en) | 2013-12-30 | 2013-12-30 | Ultraviolet light polymerization water-based paint universal for metal and non-metal and preparation method thereof |
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| CN (1) | CN103756533A (en) |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105969102A (en) * | 2016-07-12 | 2016-09-28 | 无锡市华东电力设备有限公司 | Coating and preparation method thereof |
| CN106047094A (en) * | 2016-07-21 | 2016-10-26 | 苏州泰仑电子材料有限公司 | UV (Ultraviolet) cured protective film capable of reducing final viscosity and preparation method thereof |
| CN110506092A (en) * | 2017-04-14 | 2019-11-26 | 波林复合材料美国股份有限公司 | The method of adhesive compound and coating of objects |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006128875A1 (en) * | 2005-06-01 | 2006-12-07 | Akzo Nobel Coatings Internatioanl B.V. | Aqueous coating composition |
| CN101412861A (en) * | 2008-12-01 | 2009-04-22 | 中国海洋石油总公司 | Aqueous ultraviolet cured paint |
| CN101629050A (en) * | 2009-06-30 | 2010-01-20 | 广东华润涂料有限公司 | Urethane acrylate waterborne UV coating and preparation method thereof |
| CN102535245A (en) * | 2012-02-01 | 2012-07-04 | 苏州大学 | Ultraviolet (UV) curing alcohol water type nanometer hybridization paper glazing paint and preparation method thereof |
-
2013
- 2013-12-30 CN CN201310743754.1A patent/CN103756533A/en not_active Withdrawn
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2006128875A1 (en) * | 2005-06-01 | 2006-12-07 | Akzo Nobel Coatings Internatioanl B.V. | Aqueous coating composition |
| CN101412861A (en) * | 2008-12-01 | 2009-04-22 | 中国海洋石油总公司 | Aqueous ultraviolet cured paint |
| CN101629050A (en) * | 2009-06-30 | 2010-01-20 | 广东华润涂料有限公司 | Urethane acrylate waterborne UV coating and preparation method thereof |
| CN102535245A (en) * | 2012-02-01 | 2012-07-04 | 苏州大学 | Ultraviolet (UV) curing alcohol water type nanometer hybridization paper glazing paint and preparation method thereof |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105969102A (en) * | 2016-07-12 | 2016-09-28 | 无锡市华东电力设备有限公司 | Coating and preparation method thereof |
| CN106047094A (en) * | 2016-07-21 | 2016-10-26 | 苏州泰仑电子材料有限公司 | UV (Ultraviolet) cured protective film capable of reducing final viscosity and preparation method thereof |
| CN106047094B (en) * | 2016-07-21 | 2018-04-20 | 苏州泰仑电子材料有限公司 | Protective film for reducing final viscosity of UV curing types and preparation method thereof |
| CN110506092A (en) * | 2017-04-14 | 2019-11-26 | 波林复合材料美国股份有限公司 | The method of adhesive compound and coating of objects |
| CN110506092B (en) * | 2017-04-14 | 2023-03-14 | 波林复合材料美国股份有限公司 | Adhesive composition and method for coating objects |
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Application publication date: 20140430 |