CN103756400A - Quick cleaning fluid for writing brush - Google Patents

Abstract

The invention belongs to the field of a cleaning agent and relates to a cleaning fluid for cleaning ink of a writing brush, an oil painting brush and the like. The cleaning fluid is characterized by being prepared by the following steps: 1) adding 50 parts of sodium sulfanilate, 500 parts of water and 20 parts of hydrochloric acid into a reaction tank, stirring, cooling, and dropwise-adding 15 parts of sodium nitrite solution to obtain a diazotized liquid; adding and mixing 500 parts of water, 30 parts of sodium hydrogen sulfite and 45 parts of sodium hydroxide solution; adding and stirring the diazotized liquid; adding 100 parts of ethylene diamine tetraacetic acid, 20 parts of zinc powder, 55 parts of sulfonic acid and 10 parts of nonyl phenol polyoxyethylene (9), stirring and cooling to obtain sodium sulfonate phenylhydrazine hydrochloride; 2) adding 50 parts of aluminum trichloride, 15 parts of chlorobenzene and 20 parts of carbon disulfide solvent into a reaction pot, stirring, adding 100 parts of water for heating and refluxing, dropwise-adding 30 parts of acetic anhydride and stirring to obtain parachloroacetophenone, adding 25 parts of benzaldehyde into 20 parts of dioxane, mixing the benzaldehyde and the dioxane with the parachloroacetophenone for refluxing to obtain styryl parachloroacetophenone, and stirring the styryl parachloroacetophenone with the parasodium sulfonate phenylhydrazine hydrochloride to obtain the quick cleaning fluid for the writing brush.

Description

A kind of writing brush Rapid Cleaning liquid

Technical field

The invention belongs to clean-out system field, relate to a kind of prepared Chinese ink, pigment such as writing brush, oil painting brush of cleaning and clean special-purpose scavenging solution, specifically a kind of writing brush Rapid Cleaning liquid.

Background technology

Writing brush, oil painting brush are indispensable instruments in calligraphy and paintings.After using writing brush, oil painting brush, be often the pen milli of using cloth to wipe with, prepared Chinese ink or pigment are siphoned away, but also have prepared Chinese ink, pigment remains in pen milli.Because impurity and toughness are contained in prepared Chinese ink, pigment the inside, can make in the course of time pen milli gather a large amount of impurity, make pen lose toughness, pen milli also because containing prepared Chinese ink, pigment becomes black or other colors, and use is brought inconvenience, also bad to pen.General cleaning writing brush, oil painting brush all wash with water, can make pen milli follow the string and gloss, to pen infringement greatly but often wash with water.And washing can not be washed prepared Chinese ink, pigment off completely, also there will be the phenomenon of pen milli knotting, if knotting can not be made in order, whole pen is also just done for.Oil painting brush is more exquisite for cleaning, and an oil painting brush will dip multiple pigment conventionally, but can be residual in pen milli upper a kind of pigment, color is mixed in together, has greatly affected paintings.Therefore the pigment of, cleaning on writing brush, oil painting brush fast seems particularly important.

Summary of the invention

For addressing the above problem, the following solution that the present invention takes is:

A writing brush Rapid Cleaning liquid, this scavenging solution comprises that the preparation of sodium sulfonate hydrazinobenzene hydrochloride salt and styryl, to the preparation of chlorobenzene ketone, is characterized in that:

1) sodium sulfonate hydrazinobenzene hydrochloride salt preparation, in retort, add 50 parts of Sodium sulfanilates, 20 parts of 500 parts, water and hydrochloric acid, be uniformly mixed, be cooled to 2～3 ℃, further drip 15 parts of solution of Sodium Nitrite, obtain diazotization liquid, 500 parts of another water intakings, 45 parts of solution of 30 parts of sodium bisulfites and sodium hydroxide mix, in temperature, it is 80～85 ℃, pH value is under 6.2～6.7 condition, add described diazotization liquid, continue to stir 1.5～2.0h, add again 100 parts of tetrasodium ethylenediamine tetraacetates, 20 parts of zinc powders, 55 parts of sulfonic acid, 10 parts, Nonyl pheno (9) ether, continue to stir, stir 10～20min, be cooled to 15～25 ℃, sodium sulfonate hydrazinobenzene hydrochloride salt,

2) styryl is prepared chlorobenzene ketone, in reactor, add 50 parts of aluminum chlorides, 15 parts of chlorobenzenes and 20 parts of solvents of dithiocarbonic anhydride, be uniformly mixed, further add reflux in 100 parts of water, drip 30 parts of acetic anhydrides, continue to stir 1～2h, will obtain parachloroacetophenone, in 20 parts of another Qu dioxs, add 25 parts of phenyl aldehydes and described parachloroacetophenone to mix the 6～7h that refluxes, styryl to chlorobenzene ketone.

Styryl is stirred into mixed solution to chlorobenzene ketone and p-sulfonic acid sodium hydrazinobenzene hydrochloride salt, the bottled or packed writing brush Rapid Cleaning liquid that obtains of this mixed solution.

Described Sodium sulfanilate has another name called sodium paminobenzensulfonate, 4-sodium sulfanilate.The glossiness lobate crystallization of white.Species precipitate effect in this agent.

Described Sodium Nitrite pale yellow rhomboidal crystal.In this agent, be used as diazotization raw material.

Described sodium bisulfite has another name called sodium acid sulfite, Sodium Metabisulphate 65.White crystalline powder.Density 1.48g/cm ³.There is dioxide peroxide smell.In this agent, use used as stabilizers and bleaching and quickly penetrating agent.

Described aluminum chloride (anhydrous) is without dark color or white crystals and micro-yellowish crystallization or crystalline powder.There is strength hydrochloric acid smell.In this agent, be used as catalyzer.

Described chlorobenzene has another name called monochloro-benzene, Benzene Chloride.Colourless transparent liquid.In this agent, be used as solvent, intermediate.

Described acetic anhydride claims again diacetyl oxide, acetic anhydride, aceticanhydride.Colourless liquid.Density 1.083g/cm ³. fusing point-73.1 ℃.In this agent, be used as dispersion reaction raw materials.

Described tetrasodium ethylenediamine tetraacetate has another name called EDTA-4Na.White crystalline powder.In this agent, use detergent builder and complexing agent.

Described phenyl aldehyde has another name called benzaldehyde.Colourless or faint yellow strong refraction rate liquid.In this agent, be used as condensing agent.

Described hydrochloric acid claims again spirit of salt.Commodity concentrated hydrochloric acid is containing 37%～38% hydrogenchloride.In this agent, be used as acidizer.

Described dithiocarbonic anhydride achromatism and clarity, high refractive power, pourable liquid.Sterling has ether taste.There is very strong dissolving power.In this agent, be used as solvent.

Described diox has another name called Isosorbide-5-Nitrae-dioxane, epidioxy divinyl, epoxy two ethane, ethylene glycol diether.Colourless liquid.There is ethereal odor.Easily absorb oxygen and form superoxide.In this agent, be used as solvent and washing agent.

Described sodium hydroxide has another name called caustic soda, caustic alkali, caustic soda, caustic soda.White is deliquescence solid easily, has bulk, sheet, bar-shaped and granular.Reveal and to put in air easily moisture absorption and melt into viscous liquid gradually.Tool strong basicity.In this agent, be used as neutralizing agent.Be usually used in the gluey flocculation agent except the middle impurity that anhydrates.

The pearl opal metal of described zinc powder is glossy hexagon crystal lattice.Density 7.14g/cm ³.In this agent, be used as filler and luminous agent.

Described sulfonic acid sulphur (acid) base-SO ₃the general name of the compound that H is connected with alkyl or halogen atom etc.In this agent, be used as reodorant, clean-out system.

The light yellow ointment dress of described Nonyl pheno (9) ether material.There is the effects such as emulsification, decontamination, wetting, breakdown of emulsion, all very stable in wide pH value scope and wide temperature range.Anti-hard water is stronger, and mixes with negatively charged ion and cats product.In this agent, be used as washing composition, tensio-active agent.

Described water clear water.

During use, by writing brush Rapid Cleaning liquid and clear water mix and blend, ratio is generally 1:100 and carries out the pen milli stirring and washing to writing brush.

Benefit of the present invention is: the present invention can siphon away the prepared Chinese ink of writing brush, oil painting brush or pigment cleaning fast, can increase writing brush, oil painting brush elasticity and gloss, and easy to use, health etc.

Embodiment

Be below embodiment of the present invention preparation and formula constituent:

A writing brush Rapid Cleaning liquid, this scavenging solution comprises that the preparation of sodium sulfonate hydrazinobenzene hydrochloride salt and styryl, to the preparation of chlorobenzene ketone, is characterized in that:

1) sodium sulfonate hydrazinobenzene hydrochloride salt preparation, in retort, add 50 parts of Sodium sulfanilates, 20 parts of 500 parts, water and hydrochloric acid, be uniformly mixed, be cooled to 2～3 ℃, further drip 15 parts of solution of Sodium Nitrite, obtain diazotization liquid, 500 parts of another water intakings, 45 parts of solution of 30 parts of sodium bisulfites and sodium hydroxide mix, in temperature, it is 80～85 ℃, pH value is under 6.2～6.7 condition, add described diazotization liquid, continue to stir 1.5～2.0h, add again 100 parts of tetrasodium ethylenediamine tetraacetates, 20 parts of zinc powders, 55 parts of sulfonic acid, 10 parts, Nonyl pheno (9) ether, continue to stir, stir 10～20min, be cooled to 15～25 ℃, sodium sulfonate hydrazinobenzene hydrochloride salt,

2) styryl is prepared chlorobenzene ketone, in reactor, add 50 parts of aluminum chlorides, 15 parts of chlorobenzenes and 20 parts of solvents of dithiocarbonic anhydride, be uniformly mixed, further add reflux in 100 parts of water, drip 30 parts of acetic anhydrides, continue to stir 1～2h, will obtain parachloroacetophenone, in 20 parts of another Qu dioxs, add 25 parts of phenyl aldehydes and described parachloroacetophenone to mix the 6～7h that refluxes, styryl to chlorobenzene ketone.

Styryl is stirred into mixed solution to chlorobenzene ketone and p-sulfonic acid sodium hydrazinobenzene hydrochloride salt, the bottled or packed writing brush Rapid Cleaning liquid that obtains of this mixed solution.

Described sodium sulfonate hydrazinobenzene hydrochloride salt preparation has decomposition, gloss, bleaching action, described styryl has washing, soil-removing action to chlorobenzene ketone preparation, and two kinds are prepared and merge into scavenging solution and can effectively to rapid precipitation such as the gelatine of the main component of prepared Chinese ink and carbon black and additives, decompose and cleaning impurity.

During use, by writing brush Rapid Cleaning liquid and clear water mix and blend, ratio is generally 1:100 and carries out the pen milli stirring and washing to writing brush.

Claims (1)

1. a writing brush Rapid Cleaning liquid, comprises that prepared by sodium sulfonate hydrazinobenzene hydrochloride salt and styryl is prepared chlorobenzene ketone, it is characterized in that:

1) sodium sulfonate hydrazinobenzene hydrochloride salt preparation, in retort, add 50 parts of Sodium sulfanilates, 20 parts of 500 parts, water and hydrochloric acid, be uniformly mixed, be cooled to 2～3 ℃, further drip 15 parts of solution of Sodium Nitrite, obtain diazotization liquid, 500 parts of another water intakings, 45 parts of solution of 30 parts of sodium bisulfites and sodium hydroxide mix, in temperature, it is 80～85 ℃, pH value is under 6.2～6.7 condition, add described diazotization liquid, continue to stir 1.5～2.0h, add again 100 parts of tetrasodium ethylenediamine tetraacetates, 20 parts of zinc powders, 55 parts of sulfonic acid, 10 parts, Nonyl pheno (9) ether, continue to stir, stir 10～20min, be cooled to 15～25 ℃, sodium sulfonate hydrazinobenzene hydrochloride salt,

2) styryl is prepared chlorobenzene ketone; in reactor, add 50 parts of aluminum chlorides, 15 parts of chlorobenzenes and 20 parts of solvents of dithiocarbonic anhydride; be uniformly mixed; further add reflux in 100 parts of water; drip 30 parts of acetic anhydrides, continue to stir 1～2h, will obtain parachloroacetophenone; in 20 parts of another Qu dioxs, add 25 parts of phenyl aldehydes and described parachloroacetophenone to mix the 6～7h that refluxes, styryl to chlorobenzene ketone;

Styryl is stirred into mixed solution to chlorobenzene ketone and p-sulfonic acid sodium hydrazinobenzene hydrochloride salt, the bottled or packed writing brush Rapid Cleaning liquid that obtains of this mixed solution.