CN101845251A - Water-borne white board pen ink capable of being wiped dryly or with wiping agent and wiping agent thereof - Google Patents
Water-borne white board pen ink capable of being wiped dryly or with wiping agent and wiping agent thereof Download PDFInfo
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- CN101845251A CN101845251A CN 201010158764 CN201010158764A CN101845251A CN 101845251 A CN101845251 A CN 101845251A CN 201010158764 CN201010158764 CN 201010158764 CN 201010158764 A CN201010158764 A CN 201010158764A CN 101845251 A CN101845251 A CN 101845251A
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Abstract
The invention discloses a water-borne white board pen ink capable of being wiped dryly or with wiping agent and the wiping agent thereof. The ink mainly comprises distilled water, film-forming resin, flatting agent, sulfate, castor oil, interfacial agent, color-developing agent, drier and isothiazolinone. The ink is equipped with a special wiping agent. The white board ink uses water as solvent and colorant which reacts with reducer at normal temperature and voltage and is decolorized as the color-developing agent. The handwriting can be wiped dryly in a physical wiping manner and with the wiping agent in a chemical reaction wiping manner. The invention has the advantages of saving energy, environmental protection, no poison and pungent smell, easy writing and wiping, simple manufacture technology, low use cost and stable performance after long-term placement. The ink does not leak into the board face and cause pollution even after long-term use.
Description
Technical field
The present invention relates to a kind of writing ink and remover, but particularly be the xerotripsis of writing on a kind of dustless plate that is adapted at smoothly not absorbing water and the aqueous ink of white board pen and the wiping agent thereof of wet rubbing.
Background technology
What traditional teaching board used is the chalk of making as main raw material with gypsum, dust from flying in writing on the blackboard and when erasing the board, severe contamination classroom environment, harm teachers and students health.For solving above dust pollution question, multiple dust-free writing plate ink for writing on blackboard appears in the market, ink is injected supporting lettering pen, on supporting dust-free writing plate, write, can replace chalk to be used for teaching board, office account.These inks mainly contain three kinds, first kind is with the easy volatile organic solvent, face (dying) material and other auxiliary agent are the solvent-based inks of main component, for example " white board pen ink and manufacture method thereof (application number: CN200610098357.3) " just belongs to this type of ink, such ink is write on supporting clipboard, has easy-to-write and erasable, advantage such as dustless, available sponge or soft cloth blackboard eraser remove with the xerotripsis of physics wiping mode the writing on the blackboard writing are wiped totally, but the ink production technique is complicated, the cost height, volatile, organic solvent easily pollutes air ambient, write after for some time ink and slowly infiltrate the plate face and cause dirty plate, plate face routine maintenance is difficult.
Second kind of ink is to be the water-base ink of main component with water, pigment and other auxiliary agent, " aqueous ink of white board pen (application number: 200610012914.5) just belong to this type of ink; such ink is solvent with water; environmental protection, safety; write on supporting clipboard; have easy-to-write and erasable, advantage such as dustless; available sponge or soft cloth blackboard eraser remove with the xerotripsis of physics wiping mode the writing on the blackboard writing is wiped totally for example, but the ink production technique is complicated, package stability is poor, write after for some time ink and slowly infiltrate the plate face and cause dirty plate, plate face routine maintenance is difficult.
The third ink is to be the water-base ink of main component with water, dyestuff (or acid base indicator) and other auxiliary agent, for example " (application number: CN03114634.1) just belong to this type of ink; such ink is solvent with water; environmental protection, safety; write on supporting clipboard has easy-to-write and erasable, advantage such as dustless to hydrolysis ink for writing on blackboard constituent, and the writing on the blackboard writing can dip in water with the sponge blackboard eraser; remove the writing on the blackboard writing with chemical reaction mode wet rubbing, wipes totally to leave no trace.But remove the writing on the blackboard writing with chemical reaction mode wet rubbing, need after the wiping to wait for that the plate face can carry out the writing on the blackboard second time after dried substantially, some occasion use can be made troubles.
Summary of the invention
The present invention seeks to overcome deficiency in the prior art products, but the aqueous ink of white board pen and the wiping agent thereof of a kind of xerotripsis and wet rubbing are provided, this ink handwriting available physical wiping mode xerotripsis removes and chemical reaction wiping mode wet rubbing removes.Its prescription is simple, manufacture craft is easy, energy-conserving and environment-protective, buy property that resistance is stable for a long time, fluent writing, use cost be low, convenient and practical.
The technical solution used in the present invention is:
But provide the aqueous ink of white board pen of a kind of xerotripsis and wet rubbing, raw material by following weight part is made: 27～74 parts of distilled water, 2～4 parts of film-forming resins, 1～3 part of flow agent, 3～5 parts in vitriol, 2～5 parts of Viscotrol C, 5～8 parts of interfacial agents, 3～7 parts of developers, 10～40 parts of siccative, 0.05～0.1 part of isothiazolinone.
Aforesaid film-forming resin is selected from stabilized resins in water/mixed alkoxide solution, preferably polyethylene alcohol resin, Vltra tears or polyvinylpyrrolidone; The preferred non-ion fluorin carbon surface active agent of flow agent; Vitriol preferably sulfuric acid magnesium or zinc sulfate; The compound of the preferred propylene glycol of interfacial agent, polyoxyethylene glycol, polyoxyethylenated castor oil; Developer is selected from the dyestuff that can at normal temperatures and pressures reduction reaction take place with reductive agent in the matching stain and decolour, preferred acidic magenta, Methylene blue, acid green 3, acid green 5, methyl violet; One or more mixtures in siccative preferred alcohol, methyl alcohol, the propyl alcohol.
The preparation method of ink of the present invention:
Take by weighing each component according to the above ratio.Film-forming resin is added in 5 times of weight part distilled water, be heated to 90 ℃ and be stirred to resin and dissolve fully, under agitation add developer wiring solution-forming (1); Flow agent, Viscotrol C, interfacial agent, isothiazolinone are under agitation slowly joined wiring solution-forming in the siccative (2), then solution (1) and solution (2) are mixed, adding at last remains distilled water and vitriol, fully mixes to get product.
Be used to wipe a kind of special-purpose wiping agent of above-mentioned ink among the present invention, raw material by following weight part is made: 0.05～0.2 part of S-WAT, 0.1～0.3 part of disodium ethylene diamine tetraacetate, 0.2～1 part in alkyl diphenyl ether disulphonic acid sodium, 0.2～1 part in yellow soda ash, 0.2～1 part in Sulfothiorine, 0.01～0.05 part of Sodium Benzoate, 96～99.3 parts in water.
Preparation method: take by weighing each component according to the above ratio, mix and promptly get wiping agent solution.But with this wiping agent at normal temperatures and pressures Convenient scrubber remove above-mentioned aqueous ink of white board pen writing, wipe totally, leave no trace.
The present invention compared with prior art has following advantage:
1, preparation technology is easy, does not need special equipment, and prescription is simple, and the resistance of buying property for a long time is stable.
2, with water be solvent, energy-conserving and environment-protective, nontoxic having no irritating odor, fluent writing, easy-to-write and erasable, easy to use, cost is low.
3, ink handwriting method for deleting is various, inherited the accessibility of conventional white board board pen ink xerotripsis, simultaneously available wiping agent reaction wet rubbing removes, and solve the conventional white board board pen ink and write the disadvantage that easily causes the dirty plate of plate face after for some time, be the ideal substitute of conventional white board board pen ink.
Embodiment
Embodiment 1
Get distilled water 69.95g, polyvinyl alcohol resin 2g, non-ion fluorin carbon surface active agent 3g, sal epsom 5g, Viscotrol C 2g, propylene glycol 1g, polyoxyethylene glycol 2g, polyoxyethylenated castor oil 2g, acid green 53g, ethanol 10g, isothiazolinone 0.05g.
Preparation: polyvinyl alcohol resin is added in 5 times of weight part distilled water, be heated to 90 ℃ and be stirred to resin and dissolve fully, stop heating.Under agitation add acid green 5 wiring solution-formings (1).Non-ion fluorin carbon surface active agent, Viscotrol C, propylene glycol, polyoxyethylene glycol, polyoxyethylenated castor oil, isothiazolinone are under agitation slowly joined wiring solution-forming in the ethanol (2), then solution (1) and solution (2) are mixed, add residue distilled water and sal epsom at last, fully mix and promptly get green aqueous ink of white board pen.
Embodiment 2
Get distilled water 42.95g, Vltra tears 3g, non-ion fluorin carbon surface active agent 2g, sal epsom 4g, Viscotrol C 5g, propylene glycol 1g, polyoxyethylene glycol 4g, polyoxyethylenated castor oil 3g, C.I. 42685 5g, methyl alcohol 10g, ethanol 20g, isothiazolinone 0.05g.
Preparation: Vltra tears is added in 5 times of weight part distilled water, and stirring is dissolved it fully, under agitation adds C.I. 42685 wiring solution-forming (1).Non-ion fluorin carbon surface active agent, Viscotrol C, propylene glycol, polyoxyethylene glycol, polyoxyethylenated castor oil, isothiazolinone are under agitation slowly joined wiring solution-forming in ethanol, the methyl alcohol (2), then solution (1) and solution (2) are mixed, add residue distilled water and sal epsom at last, fully mix and promptly get red aqueous ink of white board pen.
Embodiment 3
Get distilled water 34.9g, polyvinylpyrrolidone 4g, non-ion fluorin carbon surface active agent 1g, zinc sulfate 3g, Viscotrol C 3g, propylene glycol 1g, polyoxyethylene glycol 3g, polyoxyethylenated castor oil 3g, methyl violet 7g, propyl alcohol 10g, ethanol 30g, isothiazolinone 0.1g.
Preparation: polyvinylpyrrolidone is added in 5 times of weight part distilled water, and stirring is dissolved it fully, under agitation adds methyl violet wiring solution-forming (1).Non-ion fluorin carbon surface active agent, Viscotrol C, propylene glycol, polyoxyethylene glycol, polyoxyethylenated castor oil, isothiazolinone are under agitation slowly joined wiring solution-forming in ethanol, the propyl alcohol (2), then solution (1) and solution (2) are mixed, add residue distilled water and zinc sulfate at last, fully mix and promptly get the purple aqueous ink of white board pen.
The preparation wiping agent
Embodiment 4
Get S-WAT 0.05g, disodium ethylene diamine tetraacetate 0.3g, alkyl diphenyl ether disulphonic acid sodium 1g, yellow soda ash 1g, Sulfothiorine 1g, Sodium Benzoate 0.01g, water 96.64g.
Preparation method: said components raw material mixing and stirring is promptly got wiping agent solution.
Embodiment 5
Get S-WAT 0.2g, disodium ethylene diamine tetraacetate 0.1g, alkyl diphenyl ether disulphonic acid sodium 0.2g, yellow soda ash 0.2g, Sulfothiorine 0.2g, Sodium Benzoate 0.05g, water 99.05g.
Preparation method: said components raw material mixing and stirring is promptly got wiping agent solution.
The performance test table:
Claims (8)
1. but the aqueous ink of white board pen of xerotripsis and wet rubbing, it is characterized in that making: 27～74 parts of distilled water by the raw material of following weight part, 2～4 parts of film-forming resins, 1～3 part of flow agent, 3～6 parts in vitriol, 2～5 parts of Viscotrol C, 5～8 parts of interfacial agents, 3～7 parts of developers, 10～40 parts of siccative, 0.05～0.1 part of isothiazolinone.
2. but the aqueous ink of white board pen of a kind of xerotripsis according to claim 1 and wet rubbing is characterized in that: described film-forming resin preferably polyethylene alcohol resin, Vltra tears or polyvinylpyrrolidone.
3. but the aqueous ink of white board pen of a kind of xerotripsis according to claim 1 and wet rubbing is characterized in that: the preferred non-ion fluorin carbon surface active agent of described flow agent.
4. but the aqueous ink of white board pen of a kind of xerotripsis according to claim 1 and wet rubbing is characterized in that: described vitriol preferably sulfuric acid magnesium or zinc sulfate.
5. but the aqueous ink of white board pen of a kind of xerotripsis according to claim 1 and wet rubbing is characterized in that: the compound of the preferred polyoxyethylenated castor oil of described interfacial agent, propylene glycol, polyoxyethylene glycol.
6. but the aqueous ink of white board pen of a kind of xerotripsis according to claim 1 and wet rubbing is characterized in that: described developer preferred acidic magenta, Methylene blue, acid green 3, acid green 5, methyl violet.
7. but the aqueous ink of white board pen of a kind of xerotripsis according to claim 1 and wet rubbing is characterized in that: one or more mixtures in described siccative preferred alcohol, methyl alcohol, the propyl alcohol.
8. but according to a kind of special-purpose wiping agent of described xerotripsis of claim 1 and wet rubbing aqueous ink of white board pen, it is characterized in that making: 0.05～0.2 part of S-WAT by the raw material of following weight part, 0.1～0.3 part of disodium ethylene diamine tetraacetate, 0.2～1 part in alkyl diphenyl ether disulphonic acid sodium, 0.2～1 part in yellow soda ash, 0.2～1 part in Sulfothiorine, 0.01～0.05 part of Sodium Benzoate, 96～99.3 parts in water.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 201010158764 CN101845251B (en) | 2010-04-28 | 2010-04-28 | Water-borne white board pen ink capable of being wiped dryly or with wiping agent and wiping agent thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN 201010158764 CN101845251B (en) | 2010-04-28 | 2010-04-28 | Water-borne white board pen ink capable of being wiped dryly or with wiping agent and wiping agent thereof |
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| CN101845251A true CN101845251A (en) | 2010-09-29 |
| CN101845251B CN101845251B (en) | 2012-09-26 |
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| CN 201010158764 Expired - Fee Related CN101845251B (en) | 2010-04-28 | 2010-04-28 | Water-borne white board pen ink capable of being wiped dryly or with wiping agent and wiping agent thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102514424A (en) * | 2011-12-23 | 2012-06-27 | 江门市盈江科技有限公司 | Whiteboard eraser structure with integrated functions of chemical erasure and physical erasure |
| CN102786843A (en) * | 2012-08-03 | 2012-11-21 | 济南蓝贝思特科技有限公司 | Environmental-friendly writing ink for white board pen |
| CN103448415A (en) * | 2013-09-13 | 2013-12-18 | 慈溪市匡堰盈兴竹制品厂 | Teaching pen convenient for erasing |
| CN103756400A (en) * | 2014-01-10 | 2014-04-30 | 戴新育 | Quick cleaning fluid for writing brush |
| CN105295526A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink capable of being hydrolyzed and used for fiber pen |
| CN105925067A (en) * | 2016-07-04 | 2016-09-07 | 湖北世安科技有限公司 | Color paste used for preparing whiteboard marker ink and preparation method thereof |
| CN106800830A (en) * | 2017-02-15 | 2017-06-06 | 山西大学 | The white board pen ink and its colour fading liquid of a kind of easy erasing |
| CN109535832A (en) * | 2018-12-16 | 2019-03-29 | 山西大学 | A kind of red fluorescence ink and its liquid that changes colour |
| CN109627847A (en) * | 2018-12-16 | 2019-04-16 | 山西大学 | A kind of red ink and its decolourant that can repeatedly develop the color |
| CN109651879A (en) * | 2018-12-16 | 2019-04-19 | 山西大学 | A kind of red fluorescence ink discoloration liquid |
| CN109651881A (en) * | 2018-12-16 | 2019-04-19 | 山西大学 | A kind of yellow ink and its erasing liquor |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182395A (en) * | 2007-12-17 | 2008-05-21 | 山西英可奥化工技术有限公司 | Dye-type alcohol-water ink used for white board marker and method for preparing the same |
| CN101550299A (en) * | 2008-04-02 | 2009-10-07 | 袁建新 | Alcohol-soluble ink for white board marker |
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2010
- 2010-04-28 CN CN 201010158764 patent/CN101845251B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101182395A (en) * | 2007-12-17 | 2008-05-21 | 山西英可奥化工技术有限公司 | Dye-type alcohol-water ink used for white board marker and method for preparing the same |
| CN101550299A (en) * | 2008-04-02 | 2009-10-07 | 袁建新 | Alcohol-soluble ink for white board marker |
Cited By (12)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102514424A (en) * | 2011-12-23 | 2012-06-27 | 江门市盈江科技有限公司 | Whiteboard eraser structure with integrated functions of chemical erasure and physical erasure |
| CN102786843A (en) * | 2012-08-03 | 2012-11-21 | 济南蓝贝思特科技有限公司 | Environmental-friendly writing ink for white board pen |
| CN103448415A (en) * | 2013-09-13 | 2013-12-18 | 慈溪市匡堰盈兴竹制品厂 | Teaching pen convenient for erasing |
| CN103448415B (en) * | 2013-09-13 | 2015-09-30 | 慈溪市匡堰盈兴竹制品厂 | A kind of Teaching pen being convenient to wipe |
| CN103756400A (en) * | 2014-01-10 | 2014-04-30 | 戴新育 | Quick cleaning fluid for writing brush |
| CN105295526A (en) * | 2015-10-26 | 2016-02-03 | 合肥瑞雪化工科技有限公司 | Ink capable of being hydrolyzed and used for fiber pen |
| CN105925067A (en) * | 2016-07-04 | 2016-09-07 | 湖北世安科技有限公司 | Color paste used for preparing whiteboard marker ink and preparation method thereof |
| CN106800830A (en) * | 2017-02-15 | 2017-06-06 | 山西大学 | The white board pen ink and its colour fading liquid of a kind of easy erasing |
| CN109535832A (en) * | 2018-12-16 | 2019-03-29 | 山西大学 | A kind of red fluorescence ink and its liquid that changes colour |
| CN109627847A (en) * | 2018-12-16 | 2019-04-16 | 山西大学 | A kind of red ink and its decolourant that can repeatedly develop the color |
| CN109651879A (en) * | 2018-12-16 | 2019-04-19 | 山西大学 | A kind of red fluorescence ink discoloration liquid |
| CN109651881A (en) * | 2018-12-16 | 2019-04-19 | 山西大学 | A kind of yellow ink and its erasing liquor |
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| CN101845251B (en) | 2012-09-26 |
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Granted publication date: 20120926 Termination date: 20180428 |