CN101054491B - Yellow fluorescence ink and erasing liquor thereof - Google Patents
Yellow fluorescence ink and erasing liquor thereof Download PDFInfo
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- CN101054491B CN101054491B CN 200710061867 CN200710061867A CN101054491B CN 101054491 B CN101054491 B CN 101054491B CN 200710061867 CN200710061867 CN 200710061867 CN 200710061867 A CN200710061867 A CN 200710061867A CN 101054491 B CN101054491 B CN 101054491B
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- yellow fluorescence
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Abstract
The invention provides a yellow fluorescence ink and its erasing liquid. The ink includes dye, pH regulator, dispersant, plasticiser, sodium citrate, ethanol and distilled water. The ink can be removed by a specific erasing liquid, which is composed of depigmenting agent, complexing agent, dispersant, anti-freeze agent, ethanol, essence and distilled water. The inventive ink has the properties of bright color, non-toxicity, insipidity, fluently writing, which can be used during writing, drawing or marking. It will not shield the existing character and the remarked characters are showed predominantly. The invention erasing liquid can quickly erase the content written by said ink.
Description
Technical field
The present invention relates to ink and erasing liquor thereof, specifically belong to be used to write, the Yellow fluorescence ink and the erasing liquor thereof of drawing or mark.
Background technology
When reading, study or drawing, used color inks is often made by colorant, solvent and other auxiliary reagent at present, and fluorescent ink is less.In case writing, most inks are difficult for revising.This class ink mainly contains two kinds, and a kind of is to be medium with the organic solvent, though it is clear with the organic solvent to be that the ink of medium is write, and cost height, volatile, its organic solvent contaminate environment.Another kind is a medium with water then, is that the water-base ink of medium is harmless because of it with water, is suitable for writing use.
Chinese patent application is number for CN87100224 discloses a kind of " erasable ink of aqueous solution type and preparation method ", and this invention is matrix with water, and is formulated in all proportions by water-soluble dye, tensio-active agent, tackiness agent and wetting agent.It provides a kind of novel aqueous solution type color inks of wiping, and this ink can be write in slick, does not absorb water, and on the smooth plate face, ink can be wiped with things such as brush, cloth after doing.This ink volatilization is slower, and nib is difficult for dry and hard, and fluent writing has no adverse effect to HUMAN HEALTH.This ink should not be used for writing on marker pen and the paper.
Chinese patent application number is 02142480.2 to disclose a kind of " fluorized marking tinting material and pen ", and this invention is the fluorized marking tinting material that is used for indicating object.But this fluorized marking tinting material can not fade, and solvent for use is ethanol, only is used for Item Mark.
Summary of the invention
The purpose of this invention is to provide a kind ofly can write, drawing or mark use with Yellow fluorescence ink and the erasing liquor thereof of water as solvent, this ink is when writing or paint, and is bright in colour bright; The Shi Buhui that makes marks hides existing literal, and it is outstanding to be labeled the literal demonstration.Erasing liquor of the present invention can wipe fast that this ink is write, the person's handwriting of drawing or mark.
A kind of Yellow fluorescence ink, components based on weight percentage comprises:
Dyestuff 0.05～5%
Acidity-basicity regulator 0.01～5%
Dispersion agent 0.01～3%
Connect material 0.1～5%
Softening agent 0.2～5%
Trisodium Citrate 0.01～1%
Ethanol 0.2～5%
Distilled water surplus
Described dyestuff is selected from one or more the arbitrary combination in fluorescein isothiocyanate, dichlorofluorescein and the fluorescein that can fade at normal temperatures and pressures by chemical process; Described acidity-basicity regulator is selected sodium hydroxide, Sodium phosphate dibasic-sodium phosphate or yellow soda ash-sodium bicarbonate for use; Described dispersion agent is selected from sodium stearate, Sodium dodecylbenzene sulfonate, sodium laurylsulfonate or sodium lauryl sulphate; Described connection material is polyoxyethylene glycol or Polyvinylpyrolidone (PVP); Described softening agent is glycol ether or glycerol.Can also comprise an amount of essence in this ink.
The preparation method of ink: take by weighing each component in proportion, will connect material earlier and join in half distilled water, heating makes and connects material dissolving fully, adds dyestuff then, adds ethanol again, stirs, and adds acidity-basicity regulator, continues to stir, and is made into dye solution; Dispersion agent is added second half distilled water, make it to dissolve fully, be poured into dye solution then, remaining component is added, fully stirring mixes solution, promptly gets Yellow fluorescence ink.
A kind of Yellow fluorescence ink erasing liquor, components based on weight percentage comprises:
Depigmenting agent 0.01～10%
Complexing agent 0.01～5%
Dispersion agent 0.01～5%
Antifreezing agent 0.1～4%
Sanitas 0.001～2%
Ethanol 1～5%
Distilled water surplus
Described depigmenting agent is phosphoric acid and saccharosonic acid, phosphoric acid and xitix or citric acid and saccharosonic acid.Described complexing agent is EDTA or CyDTA; Described dispersion agent is selected from one or more the arbitrary combination among fatty alcohol-polyoxyethylene ether AEO-8, fatty alcohol-polyoxyethylene ether AEO-9, fatty alcohol-polyoxyethylene ether AEO-10, fatty alcohol-polyoxyethylene ether AEO-15, dodecyl phenol polyethenoxy (12) ether, SOPE-10, OPE-10, tween20 and the tween80; Described antifreezing agent is ethylene glycol and/or glycerol; Can also comprise an amount of essence in this ink erasing liquor.This erasing liquor is specifically designed to wipes described fluorescent ink.
The preparation method of Yellow fluorescence ink erasing liquor: take by weighing each component in proportion, mix, stir, promptly get erasing liquor.
Compared with the prior art, the present invention fills a prescription simply, cost is lower, manufacture craft is easy, do not need special processing unit, can carry out at normal temperature and pressure; Make water as solvent in the prescription, product has nontoxic, non-stimulated smell; Prescription uses fluorescence dye, and writing is clear, does not put for a long time and can produce precipitation; Being suitable for the writing of daily study and learning, mark or drawing uses; Ink is furnished with special-purpose erasing liquor, is easy to wipe, and is convenient and practical.
Embodiment
Embodiment 1
A kind of prescription of Yellow fluorescence ink:
Fluorescein 1g
Fluorescein isothiocyanate 0.25g
Dichlorofluorescein 0.05g
Yellow soda ash 9.6g
Sodium bicarbonate 8g
Polyoxyethylene glycol 10g
Ethylene glycol 19g
Trisodium Citrate 2g
Ethanol 40g
Sodium stearate 0.1g
Distilled water 910ml
Take by weighing each component according to the above ratio, earlier polyoxyethylene glycol is joined in the 455ml distilled water, heating is dissolved polyoxyethylene glycol fully, add dyestuff then, add ethanol again, stir, add acidity-basicity regulator yellow soda ash and sodium bicarbonate, continue to stir, be made into dye solution; Sodium stearate is added in the 455ml distilled water, make it to dissolve fully, be poured into dye solution then, remaining component is added, fully stirring mixes solution, promptly gets yellow ink.
A kind of prescription of erasing liquor:
Phosphatase 11 0g
Xitix 7g
EDTA 4g
tween80 2g
Ethanol 22ml
Ethylene glycol 5ml
Distilled water 950ml
Take by weighing each component according to the above ratio, add each component of formula ratio, promptly get erasing liquor after fully mixing.
Embodiment 2
A kind of prescription of Yellow fluorescence ink:
Fluorescein 3.4g
Dichlorofluorescein 0.1g
Sodium hydroxide 2g
Polyvinylpyrolidone (PVP) 8g
Glycerol 15ml
Trisodium Citrate 2.5g
Ethanol 37ml
Sodium dodecylbenzene sulfonate 0.5g
Distilled water 930ml
Essence is an amount of
Take by weighing each component according to the above ratio, earlier Polyvinylpyrolidone (PVP) is joined in the 465ml distilled water, heating is dissolved Polyvinylpyrolidone (PVP) fully, add dyestuff then, add ethanol again, stir, add sodium hydroxide, continue to stir, be made into dye solution; Sodium dodecylbenzene sulfonate is added 465ml distilled water, make it to dissolve fully, be poured into dye solution then, remaining component is added, fully stirring mixes solution, promptly gets Yellow fluorescence ink.
A kind of prescription of erasing liquor:
Saccharosonic acid 15g
Citric acid 20.5g
CyDTA 3.5g
Tween20 1.5g
AEO-10 2.0
Ethanol 18ml
Ethylene glycol 10ml
Essence is an amount of
Distilled water 930ml
Take by weighing each component according to the above ratio, add each component of formula ratio, promptly get erasing liquor after fully mixing.
Embodiment 3
A kind of prescription of Yellow fluorescence ink:
Fluorescein 3.3g
Fluorescein isothiocyanate 0.1g
Sodium phosphate dibasic 7g
Sodium phosphate 8g
Polyoxyethylene glycol 25g
Glycerol 9ml
Trisodium Citrate 2g
Ethanol 45ml
Sodium laurylsulfonate 0.6g
Distilled water 900ml
Essence is an amount of
Take by weighing each component according to the above ratio, earlier polyoxyethylene glycol is joined in the 450ml distilled water, heating is dissolved polyoxyethylene glycol fully, adds dyestuff then, adds ethanol again, stirs, and adds Sodium phosphate dibasic and sodium phosphate, continues to stir; Be made into dye solution; Sodium laurylsulfonate is added 450ml distilled water, make it to dissolve fully, be poured into dye solution then, remaining component is added, fully stirring mixes solution, promptly gets Yellow fluorescence ink.
A kind of prescription of erasing liquor:
Phosphatase 11 0g
Saccharosonic acid 15g
EDTA 5g
OPE-10 1.5g
Dodecyl phenol polyethenoxy (12) ether 2.5g
Ethanol 20ml
Ethylene glycol 16ml
Essence is an amount of
Distilled water 930ml
Take by weighing each component according to the above ratio, add each component of formula ratio, promptly get erasing liquor after fully mixing.
The inks of embodiment 1,2 or 3 preparations are put for a long time and can not be produced precipitation, nontoxic, non-stimulated smell, write, when drawing or mark, and fluent writing, bright in colour bright, and be labeled literal and show outstandingly, the Shi Buhui that makes marks hides and has literal.With the erasing liquors of embodiment 1,2 or 3 preparations, all can wipe the person's handwriting of the writing of embodiment 1,2 or 3 prepared any inks, drawing or mark, convenient erasing is quick, shadow-free.
Claims (9)
1. Yellow fluorescence ink is characterized in that components based on weight percentage comprises:
Dyestuff 0.05～5%
Acidity-basicity regulator 0.01～5%
Dispersion agent 0.01～3%
Connect material 0.1～5%
Softening agent 0.2～5%
Trisodium Citrate 0.01～1%
Ethanol 0.2～5%
Distilled water surplus
Described dyestuff is selected from one or more the arbitrary combination in fluorescein isothiocyanate, dichlorofluorescein and the fluorescein.
2. Yellow fluorescence ink according to claim 1 is characterized in that described acidity-basicity regulator selects sodium hydroxide, Sodium phosphate dibasic-sodium phosphate or yellow soda ash-sodium bicarbonate for use.
3. Yellow fluorescence ink according to claim 1 is characterized in that described dispersion agent is selected from sodium stearate, Sodium dodecylbenzene sulfonate, sodium laurylsulfonate or sodium lauryl sulphate.
4. Yellow fluorescence ink according to claim 1 is characterized in that described connection material is polyoxyethylene glycol or Polyvinylpyrolidone (PVP).
5. Yellow fluorescence ink according to claim 1 is characterized in that described softening agent is glycol ether or glycerol.
6. Yellow fluorescence ink erasing liquor is characterized in that components based on weight percentage comprises:
Depigmenting agent 0.01～10%
Complexing agent 0.01～5%
Dispersion agent 0.01～5%
Antifreezing agent 0.1～4%
Ethanol 1～5%
Distilled water surplus
Described depigmenting agent is phosphoric acid and saccharosonic acid, phosphoric acid and xitix or citric acid and saccharosonic acid.
7. erasing liquor according to claim 6 is characterized in that described complexing agent is EDTA or CyDTA.
8. erasing liquor according to claim 6 is characterized in that described dispersion agent is selected from one or more the arbitrary combination among fatty alcohol-polyoxyethylene ether AEO-8, fatty alcohol-polyoxyethylene ether AEO-9, fatty alcohol-polyoxyethylene ether AEO-10, fatty alcohol-polyoxyethylene ether AEO-15, dodecyl phenol polyethenoxy (12) ether, SOPE-10, OPE-10, tween20 and the tween80.
9. erasing liquor according to claim 6 is characterized in that described antifreezing agent is ethylene glycol and/or glycerol.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710061867 CN101054491B (en) | 2007-04-30 | 2007-04-30 | Yellow fluorescence ink and erasing liquor thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN 200710061867 CN101054491B (en) | 2007-04-30 | 2007-04-30 | Yellow fluorescence ink and erasing liquor thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN101054491A CN101054491A (en) | 2007-10-17 |
| CN101054491B true CN101054491B (en) | 2010-05-19 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN 200710061867 Expired - Fee Related CN101054491B (en) | 2007-04-30 | 2007-04-30 | Yellow fluorescence ink and erasing liquor thereof |
Country Status (1)
| Country | Link |
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| CN (1) | CN101054491B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105968934A (en) * | 2016-05-18 | 2016-09-28 | 天津市净轩教育科技有限公司 | Writing board cleaning and maintaining solution and preparation method thereof |
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|---|---|---|---|---|
| CN101831216B (en) * | 2010-04-30 | 2012-05-23 | 山西大学 | Marker ink of glassware |
| CN102146233B (en) * | 2011-01-11 | 2013-07-31 | 山西大学 | Black writing liquid suitable for being written on matt board and erasing agent |
| CN102837532B (en) * | 2012-09-17 | 2015-03-04 | 山西大学 | Writing board coated with surface-modified paint and writing liquid matched with writing board |
| CN103396699B (en) * | 2013-07-30 | 2014-11-26 | 江西核工业兴中科技有限公司 | Environment-friendly fluorescent enhanced anti-counterfeiting ink and preparation method thereof |
| CN104087065B (en) * | 2014-07-02 | 2017-01-18 | 林格实业(深圳)有限公司 | Ink and preparation method thereof |
| CN105154243A (en) * | 2015-09-15 | 2015-12-16 | 王颖 | Illegal small ad cleaning fluid |
| CN105585901B (en) * | 2016-03-07 | 2018-09-04 | 上海晨光文具股份有限公司 | Color type fragrance fluorescent ink and preparation method thereof |
| CN105966122B (en) * | 2016-05-05 | 2017-12-15 | 中国科学院长春光学精密机械与物理研究所 | A kind of repeatable Writing method and writing system utilized of paper |
| CN106189481A (en) * | 2016-08-09 | 2016-12-07 | 丁玉琴 | A kind of preparation method of non-toxic quick-acting eradicator |
| CN109535832A (en) * | 2018-12-16 | 2019-03-29 | 山西大学 | A kind of red fluorescence ink and its liquid that changes colour |
| CN109627847A (en) * | 2018-12-16 | 2019-04-16 | 山西大学 | A kind of red ink and its decolourant that can repeatedly develop the color |
| CN109651881A (en) * | 2018-12-16 | 2019-04-19 | 山西大学 | A kind of yellow ink and its erasing liquor |
| CN109651879A (en) * | 2018-12-16 | 2019-04-19 | 山西大学 | A kind of red fluorescence ink discoloration liquid |
| CN110777545A (en) * | 2019-11-16 | 2020-02-11 | 山西大学 | Red clothes ink and fading powder thereof and corresponding preparation method |
| CN111548675A (en) * | 2020-05-08 | 2020-08-18 | 宁波佐图文化用品有限公司 | Self-luminous neutral ink for writing in dark room and preparation method thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN1088952A (en) * | 1992-12-26 | 1994-07-06 | 化工部北京化工研究院 | Emulsion type high-efficiency non-toxic ink remover |
| CN1478829A (en) * | 2003-04-03 | 2004-03-03 | 大连思创信息材料有限公司 | Multicolor composite ink used for inkjet printing machine |
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2007
- 2007-04-30 CN CN 200710061867 patent/CN101054491B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1088952A (en) * | 1992-12-26 | 1994-07-06 | 化工部北京化工研究院 | Emulsion type high-efficiency non-toxic ink remover |
| CN1478829A (en) * | 2003-04-03 | 2004-03-03 | 大连思创信息材料有限公司 | Multicolor composite ink used for inkjet printing machine |
Non-Patent Citations (2)
| Title |
|---|
| JP特开2000-7968A 2000.01.11 |
| 同上. |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN105968934A (en) * | 2016-05-18 | 2016-09-28 | 天津市净轩教育科技有限公司 | Writing board cleaning and maintaining solution and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN101054491A (en) | 2007-10-17 |
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Inventor after: Dong Chuan Inventor after: Li Ruijin Inventor after: Zhang Jiangang Inventor after: Song Shengmei Inventor after: Zhao Xiaohong Inventor after: Ju Dong Inventor after: Shuang Shaomin Inventor before: Song Shengmei Inventor before: Zhao Xiaohong Inventor before: Ju Dong Inventor before: Dong Chuan Inventor before: Shuang Shaomin |
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| COR | Change of bibliographic data |
Free format text: CORRECT: INVENTOR; FROM: SONG SHENGMEI ZHAO XIAOHONG JU DONG DONG CHUAN SHUANG SHAOMIN TO: DONG CHUAN LI RUIJIN ZHANG JIANGANG SONG SHENGMEI ZHAO XIAOHONG JU DONG SHUANG SHAOMIN |
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Granted publication date: 20100519 Termination date: 20130430 |