CN103756400B - Quick cleaning fluid for writing brush - Google Patents
Quick cleaning fluid for writing brush Download PDFInfo
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- CN103756400B CN103756400B CN201410011758.5A CN201410011758A CN103756400B CN 103756400 B CN103756400 B CN 103756400B CN 201410011758 A CN201410011758 A CN 201410011758A CN 103756400 B CN103756400 B CN 103756400B
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- styryl
- parachloroacetophenone
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- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The invention belongs to the field of a cleaning agent and relates to a cleaning fluid for cleaning ink of a writing brush, an oil painting brush and the like. The cleaning fluid is characterized by being prepared by the following steps: 1) adding 50 parts of sodium sulfanilate, 500 parts of water and 20 parts of hydrochloric acid into a reaction tank, stirring, cooling, and dropwise-adding 15 parts of sodium nitrite solution to obtain a diazotized liquid; adding and mixing 500 parts of water, 30 parts of sodium hydrogen sulfite and 45 parts of sodium hydroxide solution; adding and stirring the diazotized liquid; adding 100 parts of ethylene diamine tetraacetic acid, 20 parts of zinc powder, 55 parts of sulfonic acid and 10 parts of nonyl phenol polyoxyethylene (9), stirring and cooling to obtain sodium sulfonate phenylhydrazine hydrochloride; 2) adding 50 parts of aluminum trichloride, 15 parts of chlorobenzene and 20 parts of carbon disulfide solvent into a reaction pot, stirring, adding 100 parts of water for heating and refluxing, dropwise-adding 30 parts of acetic anhydride and stirring to obtain parachloroacetophenone, adding 25 parts of benzaldehyde into 20 parts of dioxane, mixing the benzaldehyde and the dioxane with the parachloroacetophenone for refluxing to obtain styryl parachloroacetophenone, and stirring the styryl parachloroacetophenone with the parasodium sulfonate phenylhydrazine hydrochloride to obtain the quick cleaning fluid for the writing brush.
Description
Technical field
The invention belongs to clean-out system field, relate to a kind ofly clean the prepared Chinese ink such as writing brush, oil painting brush, pigment cleans special scavenging solution, specifically a kind of writing brush Rapid Cleaning liquid.
Background technology
Writing brush, oil painting brush are indispensable instruments in calligraphy and paintings.After using writing brush, oil painting brush, be often use cloth to wipe with pen milli, prepared Chinese ink or pigment are siphoned away, but also have prepared Chinese ink, pigment remain in pen milli in.Because containing impurity and toughness inside prepared Chinese ink, pigment, pen milli can be made in the course of time to gather a large amount of impurity, make pen lose toughness, pen milli also because of containing prepared Chinese ink, pigment and become black or other colors, brings inconvenience to use, also bad to pen.General cleaning writing brush, oil painting brush all wash with water, but often wash with water pen milli can be made to follow the string and gloss, large to pen infringement.And washing can not be washed prepared Chinese ink, pigment off completely, also there will be the phenomenon of pen milli knotting, if knotting can not be made in order, whole pen is also just done for.Oil painting brush is more exquisite for cleaning, and an oil painting brush will dip multiple pigment usually, but can remain in pen milli and go up a kind of pigment, and color is mixed in together, greatly have impact on paintings.Therefore, the pigment cleaned on writing brush, oil painting brush seems particularly important fast.
Summary of the invention
For solving the problem, the following solution that the present invention takes is:
A kind of writing brush Rapid Cleaning liquid, this scavenging solution comprises the preparation of sodium sulfonate hydrazinobenzene hydrochloride salt and styryl is prepared chlorobenzene ketone, it is characterized in that:
1) sodium sulfonate hydrazinobenzene hydrochloride salt preparation, Sodium sulfanilate 50 parts is added in retort, 500 parts, water and hydrochloric acid 20 parts, be uniformly mixed, be cooled to 2 ~ 3 DEG C, further dropping Sodium Nitrite 15 parts of solution, obtain diazotization liquid, another water intaking 500 parts, sodium bisulfite 30 parts and sodium hydroxide 45 parts of solution mixing, it is 80 ~ 85 DEG C in temperature, pH value is under the condition of 6.2 ~ 6.7, add described diazotization liquid, continue stirring 1.5 ~ 2.0h, add tetrasodium ethylenediamine tetraacetate 100 parts again, zinc powder 20 parts, sulfonic acid 55 parts, 10 parts, Nonyl pheno (9) ether, continue to stir, stir 10 ~ 20min, be cooled to 15 ~ 25 DEG C, sodium sulfonate hydrazinobenzene hydrochloride salt,
2) styryl is prepared chlorobenzene ketone, aluminum chloride 50 parts, chlorobenzene 15 parts and dithiocarbonic anhydride 20 parts of solvents are added in reactor, be uniformly mixed, add reflux in 100 parts of water further, drip acetic anhydride 30 parts, continue stirring 1 ~ 2h, will parachloroacetophenone be obtained, add phenyl aldehyde 25 parts and described parachloroacetophenone mixing backflow 6 ~ 7h in another Qu diox 20 parts, styryl to chlorobenzene ketone.
Styryl is stirred into mixed solution to chlorobenzene ketone and p-sulfonic acid sodium hydrazinobenzene hydrochloride salt, and namely this mixed solution is bottled or packed obtains writing brush Rapid Cleaning liquid.
Described Sodium sulfanilate has another name called sodium paminobenzensulfonate, 4-sodium sulfanilate.The glossiness lobate crystallization of white.Species precipitate effect in this agent.
Described Sodium Nitrite pale yellow rhomboidal crystal.Diazotization raw material is used as in this agent.
Described sodium bisulfite has another name called sodium acid sulfite, Sodium Metabisulphate 65.White crystalline powder.Density 1.48g/cm
3.There is dioxide peroxide smell.With used as stabilizers and bleaching and quickly penetrating agent in this agent.
Described aluminum chloride (anhydrous) is without dark or white crystals and micro-yellowish crystallization or crystalline powder.There is strength hydrochloric acid smell.Catalyzer is used as in this agent.
Described chlorobenzene has another name called monochloro-benzene, Benzene Chloride.Colourless transparent liquid.Solvent, intermediate is used as in this agent.
Described acetic anhydride is also known as diacetyl oxide, acetic anhydride, aceticanhydride.Colourless liquid.Density 1.083g/cm
3. fusing point-73.1 DEG C.Be used as in this agent to disperse reaction raw materials.
Described tetrasodium ethylenediamine tetraacetate has another name called EDTA-4Na.White crystalline powder.With detergent builder and complexing agent in this agent.
Described phenyl aldehyde has another name called benzaldehyde.Colourless or faint yellow strong refraction rate liquid.Condensing agent is used as in this agent.
Described hydrochloric acid is also known as spirit of salt.Commodity concentrated hydrochloric acid is containing 37% ~ 38% hydrogenchloride.Acidizer is used as in this agent.
Described dithiocarbonic anhydride achromatism and clarity, high refractive power, pourable liquid.Sterling has ether taste.There is very strong dissolving power.Solvent is used as in this agent.
Described diox has another name called Isosorbide-5-Nitrae-dioxane, epidioxy divinyl, epoxy two ethane, ethylene glycol diether.Colourless liquid.There is ethereal odor.Easy absorption oxygen forms superoxide.Solvent and washing agent is used as in this agent.
Described sodium hydroxide has another name called caustic soda, caustic alkali, caustic soda, caustic soda.White easily deliquescence solid, has bulk, sheet, bar-shaped and granular.Dew puts easy moisture absorption in air and melt into viscous liquid gradually.Tool strong basicity.Neutralizing agent is used as in this agent.Be usually used in the gluey flocculation agent removing impurities in water.
The pearl opal metal of described zinc powder is glossy hexagon crystal lattice.Density 7.14g/cm
3.Filler and luminous agent is used as in this agent.
Described sulfonic acid sulphur (acid) base-SO
3the general name of the compound that H is connected with alkyl or halogen atom etc.Reodorant, clean-out system is used as in this agent.
Described Nonyl pheno (9) ether light yellow ointment dress material.There is the effects such as emulsification, decontamination, wetting, breakdown of emulsion, all very stable in wide pH value scope and wide temperature range.Anti-water hardness tolerance comparatively strong, and mix with negatively charged ion and cats product.Washing composition, tensio-active agent is used as in this agent.
Described water clear water.
During use, by writing brush Rapid Cleaning liquid and clear water mix and blend, ratio is generally 1:100 and carries out the pen of writing brush milli stirring and washing.
Benefit of the present invention is: the prepared Chinese ink of writing brush, oil painting brush or pigment cleaning can siphon away by the present invention fast, can increase writing brush, oil painting brush elasticity and gloss, and easy to use, health etc.
Embodiment
Be below embodiment of the present invention preparation and formula constituent:
A kind of writing brush Rapid Cleaning liquid, this scavenging solution comprises the preparation of sodium sulfonate hydrazinobenzene hydrochloride salt and styryl is prepared chlorobenzene ketone, it is characterized in that:
1) sodium sulfonate hydrazinobenzene hydrochloride salt preparation, Sodium sulfanilate 50 parts is added in retort, 500 parts, water and hydrochloric acid 20 parts, be uniformly mixed, be cooled to 2 ~ 3 DEG C, further dropping Sodium Nitrite 15 parts of solution, obtain diazotization liquid, another water intaking 500 parts, sodium bisulfite 30 parts and sodium hydroxide 45 parts of solution mixing, it is 80 ~ 85 DEG C in temperature, pH value is under the condition of 6.2 ~ 6.7, add described diazotization liquid, continue stirring 1.5 ~ 2.0h, add tetrasodium ethylenediamine tetraacetate 100 parts again, zinc powder 20 parts, sulfonic acid 55 parts, 10 parts, Nonyl pheno (9) ether, continue to stir, stir 10 ~ 20min, be cooled to 15 ~ 25 DEG C, sodium sulfonate hydrazinobenzene hydrochloride salt,
2) styryl is prepared chlorobenzene ketone, aluminum chloride 50 parts, chlorobenzene 15 parts and dithiocarbonic anhydride 20 parts of solvents are added in reactor, be uniformly mixed, add reflux in 100 parts of water further, drip acetic anhydride 30 parts, continue stirring 1 ~ 2h, will parachloroacetophenone be obtained, add phenyl aldehyde 25 parts and described parachloroacetophenone mixing backflow 6 ~ 7h in another Qu diox 20 parts, styryl to chlorobenzene ketone.
Styryl is stirred into mixed solution to chlorobenzene ketone and p-sulfonic acid sodium hydrazinobenzene hydrochloride salt, and namely this mixed solution is bottled or packed obtains writing brush Rapid Cleaning liquid.
Described sodium sulfonate hydrazinobenzene hydrochloride salt preparation has decomposition, gloss, bleaching action, described styryl has washing, soil-removing action to the preparation of chlorobenzene ketone, prepares to merge into two kinds scavenging solution and can effectively decompose the gelatine of the main component of prepared Chinese ink and the rapid precipitation such as carbon black and additive and clean impurity.
During use, by writing brush Rapid Cleaning liquid and clear water mix and blend, ratio is generally 1:100 and carries out the pen of writing brush milli stirring and washing.
Claims (1)
1. a writing brush scavenging solution, comprises the preparation of sodium sulfonate hydrazinobenzene hydrochloride salt and styryl is prepared chlorobenzene ketone, it is characterized in that:
1) sodium sulfonate hydrazinobenzene hydrochloride salt preparation, Sodium sulfanilate 50 parts is added in retort, 500 parts, water and hydrochloric acid 20 parts, be uniformly mixed, be cooled to 2 ~ 3 DEG C, further dropping sodium nitrite solution 15 parts, obtain diazotization liquid, another water intaking 500 parts, sodium bisulfite 30 parts and sodium hydroxide solution 45 parts mixing, it is 80 ~ 85 DEG C in temperature, pH value is under the condition of 6.2 ~ 6.7, add described diazotization liquid, continue stirring 1.5 ~ 2.0h, add tetrasodium ethylenediamine tetraacetate 100 parts again, zinc powder 20 parts, sulfonic acid 55 parts, 10 parts, Nonyl pheno (9) ether, continue to stir, stir 10 ~ 20min, be cooled to 15 ~ 25 DEG C, sodium sulfonate hydrazinobenzene hydrochloride salt,
2) styryl is prepared chlorobenzene ketone; aluminum chloride 50 parts, chlorobenzene 15 parts and carbon disulfide solvent 20 parts is added in reactor; be uniformly mixed; add 100 parts of water reflux further; drip acetic anhydride 30 parts, continue stirring 1 ~ 2h, will parachloroacetophenone be obtained; add phenyl aldehyde 25 parts and described parachloroacetophenone mixing backflow 6 ~ 7h in another Qu diox 20 parts, styryl to chlorobenzene ketone;
By above-mentioned steps 1) sodium sulfonate hydrazinobenzene hydrochloride salt and step 2) styryl stirs into mixed solution to chlorobenzene ketone, and namely this mixed solution is bottled or packed obtains writing brush scavenging solution.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011758.5A CN103756400B (en) | 2014-01-10 | 2014-01-10 | Quick cleaning fluid for writing brush |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410011758.5A CN103756400B (en) | 2014-01-10 | 2014-01-10 | Quick cleaning fluid for writing brush |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103756400A CN103756400A (en) | 2014-04-30 |
| CN103756400B true CN103756400B (en) | 2015-01-28 |
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ID=50523733
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201410011758.5A Expired - Fee Related CN103756400B (en) | 2014-01-10 | 2014-01-10 | Quick cleaning fluid for writing brush |
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| Country | Link |
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| CN (1) | CN103756400B (en) |
Families Citing this family (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107841190A (en) * | 2017-12-07 | 2018-03-27 | 大竹县第十小学 | A kind of writing brush cleaning fluid and preparation method thereof |
| CN109456844A (en) * | 2018-10-26 | 2019-03-12 | 安徽财经大学 | A kind of preparation and application of paintbrush brush cleaning solution and cleaning solution |
| CN109384657B (en) * | 2018-12-18 | 2021-08-31 | 苏州开元民生科技股份有限公司 | Synthetic method of p-hydroxyacetophenone |
Family Cites Families (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1186406C (en) * | 2003-03-18 | 2005-01-26 | 中国印钞造币总公司 | Water-soluble printing-ink detergent and preparation process |
| JP2007123775A (en) * | 2005-10-31 | 2007-05-17 | Tokyo Ohka Kogyo Co Ltd | Cleaning liquid and cleaning method |
| EP1837182B1 (en) * | 2006-03-22 | 2010-05-12 | FUJIFILM Corporation | Ink washing liquid and cleaning method |
| JP4841660B2 (en) * | 2009-06-26 | 2011-12-21 | ユニチカ株式会社 | Cleaning liquid for polyamide resin molded body and cleaning method using the same |
| CN101845251B (en) * | 2010-04-28 | 2012-09-26 | 方为 | Water-borne white board pen ink capable of being wiped dryly or with wiping agent and wiping agent thereof |
| CN102529542A (en) * | 2010-12-28 | 2012-07-04 | 上海市嘉定区南翔小学 | Method for washing writing brush |
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- 2014-01-10 CN CN201410011758.5A patent/CN103756400B/en not_active Expired - Fee Related
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| CN103756400A (en) | 2014-04-30 |
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