CN103747683B - Single container gravity-fed storage water purifier - Google Patents

Single container gravity-fed storage water purifier Download PDF

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Publication number
CN103747683B
CN103747683B CN201280024789.3A CN201280024789A CN103747683B CN 103747683 B CN103747683 B CN 103747683B CN 201280024789 A CN201280024789 A CN 201280024789A CN 103747683 B CN103747683 B CN 103747683B
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China
Prior art keywords
water
gravity
water purifier
feeding storage
storage water
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CN201280024789.3A
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CN103747683A (en
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T·普拉迪普
A·乔杜里
M·U·桑卡尔
安什普
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Indian Institutes of Technology
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Indian Institutes of Technology
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Priority claimed from PCT/IB2012/001237 external-priority patent/WO2012150506A2/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D29/00Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor
    • B01D29/60Filters with filtering elements stationary during filtration, e.g. pressure or suction filters, not covered by groups B01D24/00 - B01D27/00; Filtering elements therefor integrally combined with devices for controlling the filtration
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B01PHYSICAL OR CHEMICAL PROCESSES OR APPARATUS IN GENERAL
    • B01DSEPARATION
    • B01D15/00Separating processes involving the treatment of liquids with solid sorbents; Apparatus therefor
    • B01D15/08Selective adsorption, e.g. chromatography
    • B01D15/10Selective adsorption, e.g. chromatography characterised by constructional or operational features
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/001Processes for the treatment of water whereby the filtration technique is of importance
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/28Treatment of water, waste water, or sewage by sorption
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/42Treatment of water, waste water, or sewage by ion-exchange
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/44Treatment of water, waste water, or sewage by dialysis, osmosis or reverse osmosis
    • CCHEMISTRY; METALLURGY
    • C02TREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02FTREATMENT OF WATER, WASTE WATER, SEWAGE, OR SLUDGE
    • C02F1/00Treatment of water, waste water, or sewage
    • C02F1/50Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment
    • C02F1/505Treatment of water, waste water, or sewage by addition or application of a germicide or by oligodynamic treatment by oligodynamic treatment

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  • Chemical & Material Sciences (AREA)
  • Life Sciences & Earth Sciences (AREA)
  • Hydrology & Water Resources (AREA)
  • Engineering & Computer Science (AREA)
  • Environmental & Geological Engineering (AREA)
  • Water Supply & Treatment (AREA)
  • Organic Chemistry (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Analytical Chemistry (AREA)
  • Water Treatment By Sorption (AREA)

Abstract

A gravity-fed storage water purifier is provided. The gravity-fed water purifier includes a filtration unit for receiving water. The filtration unit includes a housing unit, a first membrane cloth layer, a second membrane cloth layer, and a granular biocidal composition layer disposed between the first and second membrane cloth layers. The first and second membrane cloth layers remove dirt, sand and sediments from the contaminated water, using a depth filtration mechanism. The granular biocidal composition layer removes bacteria and virus from the contaminated water, through fast leaching of silver ions into the water. A single storage container is provided that collects the water filtered by the virtue of filtration unit and gravity. An adsorbent composition is disposed between the storage container and an outlet tap of the storage container.

Description

Single container gravity feeding storage water purifier
Cross-Reference to Related Applications
This application claims the rights and interests of the India application number 1522/CHE/2011 submitting on May 2nd, 2011, this patent Shen Please be incorporated herein in its entirety by reference.
Background
Technical field
The present invention relates to Water warfare field, and it is specifically related to gravity feeding storage water purifier.
Technical background
The wide usability of the drinking water of cleaning is the great of the whole world (especially development neutralization less developed country) government Behave.Technically, the drinking water providing cleaning includes removing many pollutants from drinking water, including living species (for example, insecticide, volatility are organic for (for example, bacterium and virus), inorganic matter (for example, fluoride, arsenic, iron) and organic matter Thing).However, global some crowds continue due to the clean water that can not supply needed for daily life to bear related of disease The burden going out.Although many water treatment technologies are available for solving health problem.
In various known water treatment technologies, technology the most ancient includes the use of gravity filtration.For centuries, People remove visible dust and deposit using cloth from contaminated water.Even if in today, people continue to use this Item technology (for example, Reduction of cholera in Bangladeshi villages by simple Filtration, Colwell etc., PNAS, 2003,100,1051-1055).With various other filter mediums, for example, husky mistake Filter (Elimination of viruses, bacteria and protozoan oocysts by slow sand Filtration, Hijnen etc., Water Sci Technol., 2004,50 (1), 147-54), braiding and non-woven film cloth mistake Filter (Handbook of nonwoven filter media, I.M.Hutten, Elsevier, 2007) and milipore filter (Membranes in clean technologies:Theory and practice, Volume 1, Koltuniewicz etc., Wiley-VCH, 2008) use, physical filtering technology is developed.
The major advantage that gravity filtration technology removes microorganism is the low cost of Water warfare.However, along with Water warfare Inexpensive and next is to cannot ensure that microorganism is completely removed, because the water that gravity filtration technology carries out higher flow rate is net Change.Therefore, preferably filter for obtaining, flow rate should be extremely low.
Recently, one kind is referred to as the technology of " gravity feeding storage water purifier " because its manufacture is low with running cost, zero electric power Consume, without circulating water and effectively remove the microorganism in drinking water in operation and cause the very big concern of consumer.
Fig. 1 illustrates traditional gravity feeding storage water purifier.Traditional gravity feeding storage water purifier 100 includes First container 102 and second container 104.First container 102 stores raw water, such as contaminated water, and second container The water that 104 storages purify.Wall 106 by this two vessel isolation, to prevent raw water (as contaminated water) and to purify Water mixes.One or more Water warfare (porous) cylinders 108 are usually located between the first container 102 and second container 104.In typical case Use in, contaminated water is poured in the first container 102.Get dirty because the pressure caused by the head in the first container orders about The water of dye is entered in second container 104 by porous tube 108.Generally, the pollutant during water passes through porous tube 108, in water Contact with the adsorbent composition in porous tube 108, and remove from water.
Gravity feeding storage water purifier cylinder generally can as follows two parts characterizing:Based on ceramic candle part and carbon block Water warfare cylinder.The typical water purifier based on ceramic candle part is operated (i.e., with 1 l/h to 2 ls/h of flow rate The drinking water of 10 liters of purifications can be obtained within 5 to 10 hours).Pore in ceramic candle part is by thin dust particle from raw water Remove in (as contaminated water).As Bridges etc. U.S. Patent Application Publication 2008/0202992 (this patent application with Way of reference is integrally incorporated herein) in reported, sterilization composition can be filled in the hollow region of ceramic candle part, with true The water protecting output is microbial safety when edible.Similarly, Oyanedel-Craver etc. is in Sustainable Colloidal-Silver-Impregnated Ceramic Filter for Point-of-Use Water, Environ.Sci.Technol.2008, the ceramic filter having shown to impregnated of Nano silver grain in 42,927 933 can be from Bacterium is removed in drinking water.
(that is, 2 to 3 is little with 3 ls/h to 6 ls/h of flow rate operation for the typical water purifier based on carbon block When can obtain 10 liters purification drinking water)..Using carbon block remove from raw water (as contaminated water) reactive chlorine and Trace organic substance.As Bommi etc. in United States Patent (USP) 7,585,409 and Mistry etc. in PCT Publication application WO/2004/000732 Reported in (for reaching the purpose of open method for purifying water and technology, two above patent is all integrally incorporated herein with way of reference) Road, the bottom that sterilization composition may be combined in carbon block or can be placed on carbon block.
Although by using many filter mediums and by water purifier design some be improved to solve microorganism pollution Make multiple effort, but the cost of these solutions is still of a relatively high.The Affordability of clarifier is to improve people To cleaning drinking water acquisition key factor.Low cost has household water purifier and may improve whole world citizen's Play an important role in health.According to estimates, because each clarifier manufactures exemplary container using the plastics of about 2kg to 3kg, So container cost is about the 30% of water purifier price.Additionally, two containers cause to manufacture the extra cost of described device.
The different versions of twin containers gravity feeding storage water purifier have been reported (for example, the India of Adroja etc. U.S. of the PCT Publication application of patent application 1571/MUM/2008, Mistry etc., PCT Publication application 2004/000732, Bae etc. The PCT Publication application of state's patent 5,928,506, Bridges etc., PCT Publication application 2008/106276 and Frank The United States Patent (USP) 2,372,340 of Senyal), described patent is all integrally incorporated herein with way of reference.As described in reference to Fig. 1 Bright, the Basic Design of twin containers gravity feeding storage water purifier, described parameter bag is changed by changing many design parameters Include water (flow) direction (up/down), flow control valve include to prevent from overflowing, when the additional flow length of water is to increase contact Between etc..Described gravity feeding storage water purifier has been also carried out changing on size shape, for example, glass mould water purifier; The capacity of wherein top container is less than 3 liters.
Another shortcoming related to memory type water purifier is to need substantial amounts of plastics (for example, for two or more Individual container and cylinder shell).Therefore, the angle of the environmental disruption caused by from the cost reducing consumer and the impact reducing plastics For degree, the amount reducing the plastics used in water purifier is critically important.Further, since memory type water purifier has again Miscellaneous structure and needing removes, clean and integrated multiple part again, so the periodic maintenance of described memory type water purifier Expend more times.
In view of aforementioned, it is desirable to provide a kind of water purifier, which solve problems noted above and with prior art The relevant other shortcomings of water purification system.
General introduction
It is an object of the invention to provide a kind of single container gravity feeding storage water purifier, it designs simply, decreases and build Make required plastics quantity, comprising less part for Product Assembly and makes manufacture undertake low cost.
It is a further object to provide a kind of water purifier, it can be easily adapted to any Water warfare system System, including family, public and industrial system.
A further object of the present invention is to provide a kind of water purifier, and it delivers the water of microbial safety so that in water The concentration of antimicrobial maintains and is far below WHO (World Health Organization) limit.
On the one hand, there is provided a kind of gravity feeding storage water purifier.Described gravity enters feed water purifier and includes filtering Unit, it is used for receiving water, such as contaminated water.Described filter element include the first film layer of cloth, the second film layer of cloth and It is placed in the graininess sterilization composition layer between the first film layer of cloth and the second film layer of cloth.Provide a kind of single storage container, It collects the water by means of filter element and gravity filtration.
On the other hand, there is provided a kind of gravity feeding storage water purifier.Described gravity enters feed water purifier and included Filter unit, it is used for receiving water, such as raw water or contaminated water.Described filter element include the first film layer of cloth, second Film layer of cloth and be placed in sterilizing (for example, the graininess) composition layer between the first film layer of cloth and the second film layer of cloth.First film Layer of cloth and the second film layer of cloth can remove dust, sand and deposition using depth-type filtration mechanism from water (as contaminated water) Thing.Graininess sterilization composition layer can pass through the Rapid Leaching of one or more antimicrobial (such as silver ion) to water And eliminate or remove microorganism from contaminated water, such as bacterium and virus.Provide a kind of single storage container, its collection is borrowed Help the water of filter element and gravity filtration.Adsorbent composition can be placed in the outlet tap of storage container and storage container Between.
On the other hand, it is used filter element as independent water purification units, described filter element includes the first film cloth Layer, the second film layer of cloth and be placed in the graininess sterilization composition layer between the first film layer of cloth and the second film layer of cloth.In a side Face, this independent water purification units can be integrated with any commercially available water purifier.According to this aspect, non-purified Water (as contaminated water) independent water purification units can be passed through before entering water purifier.Independent water purification units Can be used by integrated with existing water purifier.On the one hand, this independent water purification units can by with disappear The available container of expense person integrated using.At described aspect, water (as contaminated water) passes through independent water purification units And it is collected in the available container of consumer.
On the one hand, graininess sterilization composition layer can comprise Nano silver grain, and described particle is immersed in (such as) to be had On machine Templated boehmite nanostructure (described composition and its purposes in water purification with this paper identical inventor PCT application PCT/IB2011/001551 described in).In multiple other sides, graininess sterilization composition layer comprises silver nanoparticle Particle, described particle is immersed in polyurethane;At least one oxidation in aluminium, zinc, manganese, copper, iron, titanium, zirconium, lanthanum, cerium and silicon In at least one in thing and/or oxyhydroxide.On the other hand, graininess sterilization composition can comprise nano grain of silver Son, described particle impregnates on the activated carbon and/or can impregnate on extra Nano silver grain on the activated carbon.
The additional aspect of the present invention and advantage are partly enumerated in detailed description and claim then, and portion Divide ground will draw from describe in detail, or can be learnt by putting into practice the present invention.Advantage discussed below will by under The key element that row 1-24 item (wherein the 1st and 24 is the technical scheme invented, and remaining is preferred technical scheme) is specifically noted To realize and to reach with combination.It should be understood that outlined above and described below be merely exemplary and explanatory, and do not limit institute The disclosed present invention.
1. a kind of gravity feeding storage water purifier, it includes:
Filter element, it is used for receiving raw water, and described filter element includes:
Outer cover unit;
First film layer of cloth;
Second film layer of cloth;And
Graininess sterilization composition layer, it is placed between described first film layer of cloth and described second film layer of cloth;And
Storage container, whereby by described first film layer of cloth and described second film layer of cloth, described graininess sterilization composition Layer and gravity are filtering described raw water, and whereby the water of described filtration are stored in described storage container.
2. the gravity feeding storage water purifier as described in above-mentioned 1, wherein said graininess sterilization composition layer comprises silver Nano-particle, described particle is immersed on the boehmite nanostructure of organic formwork.
3. the gravity feeding storage water purifier as described in above-mentioned 1, wherein said graininess sterilization composition layer comprises silver Nano-particle, described particle is immersed on the Nano silver grain on polyurethane.
4. the gravity feeding storage water purifier as described in above-mentioned 1, wherein said graininess sterilization composition layer comprises silver Nano-particle, described particle is immersed at least one oxide and hydroxyl in aluminium, zinc, manganese, iron, titanium, zirconium, lanthanum, cerium and silicon In at least one in base oxide.
5. the gravity feeding storage water purifier as described in above-mentioned 1, wherein said graininess sterilization composition layer comprises silver Nano-particle, described particle is immersed on dipping Nano silver grain on the activated carbon.
6. gravity feeding storage water purifier, wherein said first film layer of cloth and the described second film cloth as described in above-mentioned 1 Layer is dismountable, capable of washing, can adhere to or one or more of a combination thereof.
7. the gravity feeding storage water purifier as described in above-mentioned 1, the particle of wherein said graininess sterilization composition layer Size is about 0.3mm to about 1.5mm.
8. the gravity feeding storage water purifier as described in above-mentioned 1, the particle of wherein said graininess sterilization composition layer Size is about 0.5mm to about 1mm.
9. the gravity feeding storage water purifier as described in above-mentioned 1, wherein said raw water is with about 0.5L/min extremely The flow rate of about 5L/min is poured through described filter element.
10. the gravity feeding storage water purifier as described in above-mentioned 1, wherein said raw water is with about 1L/min to about The flow rate of 2L/min is poured through described filter element.
The 11. gravity feeding storage water purifiers as described in above-mentioned 1, wherein said filter element includes connecting to water source Water inlet.
The 12. gravity feeding storage water purifiers as described in above-mentioned 1, it further includes to be attached to described storage container Outlet tap, for exporting the water of described filtration.
The 13. gravity feeding storage water purifiers as described in above-mentioned 12, it further includes alarm mechanism, wherein said report Alert mechanism be configured to be provided for by the water of described filtration before being exported by described outlet tap in described storage container Middle holding predetermined time period.
The 14. gravity feeding storage water purifiers as described in above-mentioned 12, it further includes to be placed in described storage container Adsorbent composition and described outlet tap between.
15. as described in above-mentioned 12 gravity feeding storage water purifiers, wherein said adsorbent composition include activated carbon, At least one in activated alumina, silica, titanium dioxide, ion exchange resin and halogenated resins.
The 16. gravity feeding storage water purifiers as described in above-mentioned 1, wherein said storage container is by engineering plastics, stainless At least one in steel, copper, brass and potter's clay is made.
17. gravity feeding storage water purifier, wherein said first film layer of cloth and the described second film cloth as described in above-mentioned 1 Layer is made up of at least one in cellulose, polyester, nylon and polypropylene.
The 18. gravity feeding storage water purifiers as described in above-mentioned 1, wherein said water purifier further includes to float Valve, it adjusts the current leading to described water purifier.
19. as described in above-mentioned 1 gravity feeding storage water purifiers, wherein said water purifier connect to tubular type water source with Supply water to described water purifier.
The 20. gravity feeding storage water purifiers as described in above-mentioned 1, wherein said filter element is with acting on collecting container In the water of described filtration water filter unit.
The 21. gravity feedings as described in above-mentioned 18 store water purifiers, and wherein alarm mechanism is and described filter element collection Become.
The 22. gravity feeding storage water purifiers as described in above-mentioned 18, wherein said container includes bottle, tank, bucket, drum, glass Glass bottle, kettle, box, tumbler, water pitcher, canister, kettle or a combination thereof.
The 23. gravity feeding storage water purifiers as described in above-mentioned 18, wherein said filter element can be obtained with commercially available The water purifier obtaining is integrated.
A kind of 24. gravity feeding storage water purifiers, it includes:
Filter element, it is used for receiving water, and described filter element includes:
Outer cover unit;
First film layer of cloth;
Second film layer of cloth;And
Graininess sterilization composition layer, it is placed between the first film layer of cloth and the second film layer of cloth;
Storage container, whereby by described first film layer of cloth and described second film layer of cloth, described graininess sterilization composition Layer and gravity carry out filter water, and whereby the water of described filtration are stored in described storage container;
Adsorbent composition;And
Outlet tap, it is attached to described storage container, and the filter water of wherein said storage is by described adsorbent group Compound and exported by described outlet tap.
Brief description
It is incorporated to this specification and constitutes part thereof of accompanying drawing and illustrate some aspects, and use together with the description To explain the principle of the present invention.
Fig. 1 depicts traditional gravity feeding storage water purifier.
Fig. 2 depicts single container gravity feeding storage water purifier according to an aspect of the present invention.
Fig. 3 depicts single container gravity feeding storage water purifier according to a further aspect in the invention.
Fig. 4 depicts single container gravity feeding storage water purifier according to a further aspect in the invention.
Fig. 5 depicts single container gravity feeding storage water purifier according to another aspect of the invention.
It is net with the single container gravity feeding storage water without lid that Fig. 6 depicts having of the many aspects according to the present invention Change the top view of device.
Fig. 7 depict (a) of the many aspects according to the present invention as independent water purification units filter element (b) with The filter element being used in combination as the vial of storage container.
What Fig. 8 depicted the many aspects according to the present invention is based on activated carbon with commercially available water purifier such as (a) The water purifier Ji Yu film (counter-infiltration/ultrafiltration) for the water purifier (c) based on ceramic candle part for the water purifier (b) of block is integrated Filter element.
Fig. 9 depict the many aspects according to the present invention through single container gravity enter feed water purifier water volume with Drawing between corresponding count of bacteria.
Figure 10 depicts the volume of the water entering feed water purifier through single container gravity of the many aspects according to the present invention With the drawing between corresponding viral count.
Detailed Description Of The Invention
By reference to of the invention below describe in detail and including embodiment the present invention can be more easily understood.
Before the compound of the disclosure and description present invention, composition, article, system, device and/or method, Ying Li Solution, unless otherwise stated, they are not limited to specific synthetic method or concrete reagent, because they are it is of course possible to change. It should also be understood that term used herein only for description specific aspect and is not intended to limit the present invention.Although being similar to or waiting It is same as those described herein method and any method of material and material can also be used for putting into practice or tests the present invention, but retouch now State embodiment method and material.
The all announcements being mentioned above are herein incorporated by reference, so that disclosure and description are related to recited announcement Method and/or material.
Definition
Unless otherwise defined, otherwise all technology used herein and scientific terminology have general with of the art The identical meanings that logical technical staff is generally understood.Although any similar or equivalent to those described herein method and material Method and material can also be used for putting into practice or test the present invention, but presently describes embodiment method and material.
As used in this specification and claims, unless be in addition explicitly indicated, otherwise singulative " a kind of/ One " and " described/should " include multiple indicants.Thus, for example, mentioning the mixing that " metal " includes two or more metals Thing.
Herein, scope can be expressed as from " about " occurrence, and/or to " about " another occurrence.Work as table When reaching such a scope, on the other hand include from an occurrence and/or to another occurrence.Similarly, when value table When reaching for approximation, by using antecedent " about ", it will be understood that on the other hand described occurrence is formed.It is to be further understood that it is every The end points of individual scope is both significantly correlated with another end points, and independent of another end points.It should also be understood that disclosed herein is many be worth, And in addition to described value itself, there is disclosed herein each value is " about " that occurrence.For example, if disclosing value " 10 ", So " about 10 " are also disclosed.It should also be understood that each unit between two concrete units is also disclosed.For example, if open 10 and 15, then 11,12,13 and 14 be also disclosed.
As used herein, term " optional " or " optionally " mean the event subsequently describing or situation meeting or will not send out Raw, and this description includes described event or situation occurs example and the example not occurred.
As used herein, " raw water " and its similar terms refer to not purify using system as described herein Water.For example, raw water can be contaminated water.
On the one hand, the gravity feeding storage water purifier of the present invention can utilize following prerequisite:(i) sterilizing combination Thing, its have absorption pollutant rapid kinetics, enter water in the rapid kinetics of the desorption of bactericidal agent and from suction The swift electron of attached dose of surface to contaminant molecule that may be present one or more of shifts;And (ii) is from adsorbent In the case that composition discharges any active component, concentration should be in WHO in the limit of safe drinking water, thus avoiding providing The needs of second level clean unit.
The gravity feeding storage water purifier of the present invention includes film cloth, and it has ground floor and the second layer.On the one hand, Granular sterilization composition is placed between ground floor and the second layer.Film cloth (is such as subject to from raw water using depth-type filtration mechanism The water of pollution) in remove dust, sand and deposit.Graininess sterilization composition can be by leaching in water simultaneously silver ion And by absorption on the boehmite nanostructure of organic formwork for the virus or the chemical interaction with the silver ion leaching, To eliminate the bacterium in drinking water and virus.Print by propositions such as T.Pradeep before us for the exemplary sterilization composition It is described in degree patent application 947/CHE/2011 and 20070608, the full content of described patent application is with way of reference It is expressly incorporated herein.
On the one hand, the use of water purifier may need manually by water (as contaminated water) with 1 liter/min to 2 liters/ The typical flow rates of minute are poured on film layer of cloth.On the one hand, flow rate can be 0.1 liter/min to 5 liters/min. The water passing through can contact graininess sterilization composition, and wherein silver ion can be leached to water from sterilization composition.Through film After layer of cloth and sterilization composition, then water can be collected in storage container.The capacity of storage container can rise to 30 for 5 Rise, such as 10 liters or 15 liters.Typically require the time filling storage container of 5 minutes to 10 minutes.According to Environmental Protection Agency USA (US EPA) drinking water standard, water can stop in storage container and reach 1 hour to remove microorganism.By being arranged on outlet dragon Device at head controls the duration of a hour.Described device can discharge the principle work of brake according to time dependence Make, wherein provide knob on such devices to rotate to the position indicating one hour release time.After one hour, relieving mechanism It is activated and outlet tap can be opened.Therefore the water at outlet tap is safe to eat.
The advantage of gravity feeding storage water purifier is as follows:(i) due to only using single container, so reducing Water warfare The purchase cost of device.(ii) because the concentration of silver ion remaining in water is less than or is far below WHO limit, therefore do not need further Purified water.(iii) greatly improve effective duration of each circulation of Water warfare, thus promoting the net of supply consumer Change the faster availability of drinking water.
From prior art it is also known that the technology for purifying drinking water needs (Advances in of rational time of contact Water treatment by adsorption technology, Ali etc., Nature Protocols, 2006,1 (6), 2661).In the case of activated carbon, the absorption of pollutant may the needs air-land combat (EBCT) of 10 minutes (Predicting GAC performance with rapid small-scale column test, Crittenden etc., J.Am.Water Works Assoc.1991,83,77–87).Dechlorination is gone typically quickly by activated carbon, because it is alive Redox reaction between charcoal and chlorine for the property, and be not therefore adsorption process (Reduction of aqueous free Chlorine with granular activated carbon-pH and temperature effects, Suidan etc., Environ.Sci.Technol., 1977,11 (8), 785 789).Similarly, the activated carbon of immersion silver had been used for 30 seconds EBCT remove bacterium (Silver-embedded granular activated carbon as an from drinking water Antibacterial medium for water purification, Bandyopadhyaya etc., J.Chem.Technol.Biotechnol.,2008,83,1177–1180).Bridges etc. is in PCT Publication application 2008/ It has been reported that the sterilised medium based on chlorine and bromine needs the time of contact of 1 second to 3 seconds to kill microorganism in 106276.
Active sterilization agent generally can be leached in the microbicide composition from the water passing through, and containing active sterilization agent Water is kept the time of restriction.Generally, kill microorganism can complete in two ways:Relatively low time and high dose or higher when Between and low dosage.The second way is favourable, because preventing extra filtration step to remove excessive bactericidal agent from water Need.Mistry etc., in PCT Publication application PCT Publication application 2004/000732, for the sterilised medium based on chlorine, uses With the standing time implementing more than 30 minutes.
It is to come using described composition purifying drinking water by being filled in composition in film cloth, the EBCT of 0.1 second is available for For the contact between composition and water.The design of the water purification installation of our here reports is to be purified based on a kind of composition Water, described composition is boehmite nanometer framework (Ag-OTBN) of the organic formwork based on dipping Nano silver grain.Preparation side Method and its purposes in water purification have been described in detail in our earlier patents application 947/CHE/2011, described special Profit application is herein incorporated by reference.Although not wishing to be bound by theory, it is believed that the sterilizing activity mechanism of Nano silver grain It is the release due to silver ion in water.This silver ion releasing mechanism is used for the activity of sterilizing before.For Ag-OTBN, Have proven to the sustained release of the silver ion in the water more than 1,500 liters of volume capacities before.In water, the concentration of silver ion is usual It is about 20ppb, and the limit far below the 100ppb for safe drinking water defined for the WHO.
For avoiding using two containers it is necessary to store in a vessel purified water, and avoid in another container The needs of middle storage raw water (as contaminated water).At described aspect, raw water (as contaminated water) with go out Antimicrobial composition contacts in the porch of the container for storing purified water.Preferably, microbicide composition is filled in two-layer Between film cloth.
However, the key restriction factors of the use of microbicide composition in film cloth be microbicide composition with non-purified The contact of water (as contaminated water) is minimum.As illustrative embodiment, the Ag-OTBN particle of 20x60 sieve mesh can be clipped in two Between tunic cloth.The size of such a cylinder filter element is 10cm (D) × 10cm (H), and wherein Ag-OTBN accounts for 1cm's Depth.For the typical flow rate of 1L/min, EBCT is calculated as 0.1 second.Generally, in online water purifier, implement 2 seconds To the EBCT of 5 seconds.
Effectively the second aspect of sterilizing activity is to provide the standing time of feedwater when there is the bactericidal agent of leaching in water. This is all genuine in the nearly all bactericidal agent become known for drink water purifying.This is previously reported by (Mistry's etc. some PCT Publication application PCT Publication application 2004/000732;Antibacterial Activity and Mechanism of Action of the Silver Ion in Staphylococcus aureus and Escherichia coli, Jung Deng, Appl Environ Microbiol., 2008,74 (7), 2171;Observations on Halogens as Bathing Water Disinfectants, Brown etc., J.Appl.Microbiol., 1966,29,3,559) reported in Road.Higher with sterilizing agent concentration used in water, the standing time of needs is then fewer, and vice versa.However, using more The bactericidal agent of high concentration is probably unfavorable, because:(i) exceed the permission limit of drinking water concentration need additional step so that Remove bactericidal agent, and the sterilizing agent concentration of (ii) excess also can result in and the organic loading generally finding in drinking water Redox and/or other reaction.
Standing time can be realized by some modes, described mode depend primarily on required standing time lasting when Between and water purifier design complexity:(i) to consumer with regard to product simple notification, when illustrating to need fixing placement Between to kill microorganism completely, (ii) realizes the travel path of water, and wherein before reaching the outlet of water receptacle, water is in Water warfare Lentamente move in device, (iii) is arranged on to stop the device of water flowing at outlet tap, and wherein user is being filled with water appearance Connect described device after device, and described device cost regular time opens obstruction water being flow through to tap, and (iv) device being located in water purifier, described device is activated by hydraulic pressure and deactivates after the predetermined time period (described device may or may not be integrated into the obstruction that water flows through tap).In the concrete condition of the present invention, in outlet tap Above analogue means is installed, for controlling water standing time in a reservoir.The general structure of device is based on mechanical watch, example As described mechanical watch includes oscillator and control device, and wherein oscillator (being generally made up of pendulum or mechanical wheel) is with pre- Fixed frequency repeats to swing/vibration.Described oscillator can be supplied by the weight of spring or the rope being suspended from being looped around on pulley Energy.The forward movement of mechanical watch is to be caused by the movement of the gear teeth of escape wheel when swinging every time.For the machinery report wound up The commercially available acquisition of similar designs on alert device.
Fig. 2 depicts the single container gravity feeding storage water purifier 200 according to one embodiment of the invention.Dan Rong Think highly of power feeding storage water purifier 200 and include filter element 202, storage container 204 and outlet tap 206.Single container gravity The key component of feeding storage water purifier 200 is filter element 202, and it is arranged on the top of storage container 204.Filter element 202 can include covering 208, when clarifier not in use when, its be used for close water inlet.On the one hand, lid 208 is detachable 's.Lid 208 may also include configuration, is used for being directly connected to outside tap source (figure 3 illustrates and describe).Filter element 202 Also include shell 210, it accommodates raw water (as contaminated water) and passes water through filter element 202 to drive.Due to filling out The granular composition filling in filter element 202 provides negligible pressure drop, therefore shell 210 can have minimum altitude.? On the one hand, shell 210 is dismountable, and therefore user can easily be carried out.
There is provided two film layer of cloth the first film layer of cloths 212 and the second film layer of cloth 214 in the bottom of filter element 202.? On the one hand, the first film layer of cloth 212 and the second film layer of cloth 214 have identical filter efficiency and (put down with the micron rating of cloth or often The quality representation of Fang meter Bu).Graininess sterilization composition layer 216 is equably placed in the first film layer of cloth 212 and the second film layer of cloth Between 214.In one aspect of the invention, graininess sterilization composition layer includes Ag-OTBN particle.The particle of Ag-OTBN particle Size is in the range of 0.3mm to 5mm.At a preferred aspect, granular size is in the range of about 0.5mm to about 1.0mm.Wearing After crossing the first film layer of cloth 212, water is contacted with graininess sterilization composition, and wherein silver is leached in water in the form of an ion.In water The silver ion of leaching lead to kill any microorganism contained therein.Tap 206 facilitates and obtains storage from storage container 204 Filter water process.
On the one hand, water keeps at least about one hour in storage container 204.The duration of one hour is by being arranged on out Control device 218 at mouth leading 206 is adjusted.Described control device 218 is well known in the art, and can root Time dependence release principle work according to brake.There is provided the knob on control device 218 can be rotated to and indicate one hour The position of release time.After one hour, relieving mechanism can be activated and open outlet tap 206.Therefore, at outlet tap Water always can safe edible.
Will for it should be apparent to those skilled in the art that design water purification installation when, can be in single container gravity Place sterilization composition on the filter element 202 of feeding storage water purifier 200 and carry out multiple modifications, and do not significantly change this Bright efficiency or scope or spirit.On the one hand, granular adsorbent is used for removing multiple other pollutants from drinking water.? Grain can include activated carbon, activated alumina, silica, titanium dioxide, ion exchange resin, halogenated resins and combinations thereof.
Fig. 3 depicts single container gravity feeding storage water purifier 300 according to a further aspect in the invention.It should be noted that Single container gravity feeding storage water purifier 300 is structurally similar to the single container gravity feeding storage water purifier of Fig. 2 200.Additionally, porous adsorbent block 302 may be mounted between tap 206 and storage container 204.
On the one hand, porous adsorbent block 302 includes charcoal.Earlier patents application 2892/CHE/2010 (institute with reference to us The full content stating patent application is herein incorporated by reference) it should be noted that the pressure head in 0.5psi (feeds storage in gravity Generally can obtain in water purifier) under, by porous carbon block, the flow rate of 500ml/min to 600ml/min is (for 5.5cm Path for) be feasible.Guaranteed using activated carbon porous block 302 at outlet tap 206 or even connect organic impurities Also it is removed.Due to the reasonably high flow rate through porous carbon block 302, therefore user will be without in the face of being difficult to collect through dragon A difficult problem for the water of head.At output tap, the another advantage using porous carbon block 302 is, because the water without bacterium passes through charcoal Block, so will not occur the breeding of bacterium inside porous carbon block 302.Before it is reported that known activity carbon block serves as bacterium Breeding spot, and therefore, automatically solve the challenge preventing biological growth.Substitute activated carbon, can be situated between using other adsorbents Matter removing specific or a series of pollutant, such as fluoride, mercury, arsenic etc..
Fig. 4 depicts the container water purifier with substituting time marker.Filter element 202 may be located at removable Mechanical spring 404 on, described mechanical spring is connected to indicator color lock 405 and controls described indicator color lock.Filter single First 202 weight when filling water are transferred to mechanical spring 404, thus compressor mechanical spring 404 and allow indicator color Lock 405 moves from its initial position.Mechanical spring 404 spends a hour to return initial position.This position of mechanical spring 404 The change put is indicated by the color change of indicator color lock 405.Additionally, be internally formed bottom in filter element 202 having The chamber 402 of porous block 403.Chamber 402 can accommodate the water yield of 50mL to 100mL in filling, and spends a hour to lead to Cross porous block 403 to empty, thus providing a hours control period to mechanical spring 404.The water yield in chamber 402 determines to turn Move on to the weight of the filter element 202 on mechanical spring 404.Fig. 4 (i) is that indicator color lock 405 instruction one hours control Phase completes, thus showing that water prepares the state being eaten.Fig. 4 (ii) is that indicator color lock 405 instruction one hours control Phase well afoot and water are not yet ready for the state being eaten.It will be understood by those skilled in the art that being retouched above in association with Fig. 4 The version of the embodiment stated can also be used for designing the global function water purifier with time marker.
Fig. 5 depicts single container gravity feeding storage water purifier 500 according to another aspect of the invention.Single container weight Power feeding storage water purifier 500 is structurally similar to single container gravity feeding storage water purifier 200.Additionally, including pipe The accessory that formula water source 501, float trap 502 and pipeline connect 503 is integrated with water purifier 500.Tubular type water source 501 connect to Water purifier 500 and connected by pipeline and 503 extend to filter element 202.Pipeline connects 503 and passes through leakproof assembly parts (not Illustrate) it is connected with filter element 202.The junction point connecting 503 at tubular type water source 501 and pipeline provides float trap 502.Work as water When water level in clarifier 500 reaches predeterminated level, float trap 502 cuts out, and causes to lead to pipeline connection 503 and filter element 202 current are blocked.When the water level in water purifier 500 becomes lower than predeterminated level, float trap 502 is opened and is initiated Current connect 503 and filter element 202 by pipeline.
Fig. 6 depicts the Dan Rong and do not have with lid (reading figure A and figure B respectively) of the many aspects according to the present invention Think highly of the top view of power feeding storage water purifier.
Fig. 7 (a) depicts filter element 202 according to an aspect of the present invention as independent water purification units.Filter Unit 202 is integrated with the storage container of any types, shape, size, capacity or brand.Fig. 7 (b) depicts and holds with as storage The integrated filter element 202 of the vial 700 of device.Storage container can be bottle, tank, bucket, cylinder, vial, kettle, box, flat Cup, water pitcher, canister, kettle and one of case or its analog.The performance effects of filter element 202 are independent of storage container Property and described filter element can reuse several circulations.
Fig. 8 depicts the many aspects according to the present invention, integrated with commercially available water purifiers many in market Filter element 202.In general, water purifier is made up of prefilter, and described prefilter provides and is still subject to microorganism pollution Pre-filtered water to subsequent filter module.Caused the biofouling in filtering module by the water of microorganism pollution.Therefore, pre- mistake Filter is substituted or is combined with filter element 202, so that the water entering filtering module remains and sterilized.Illustrate and be based on The water purifier (Fig. 8 a) of activated carbon, the water purifier (Fig. 8 b) based on ceramic candle part and the water purifier (Fig. 8 c) based on film The example of integrated filter element 202.It should be noted that the advantage that filter element 202 is used in combination with other water purifiers is to filter The EBCT of unit 202 is extremely low;Therefore, with other filter mediums before integrated or integrated afterwards in, it does not provide any further Pressure drop.Therefore, if it is desirable to if, after filter element 202 can also be placed on the other filter medium of next-door neighbour.For example, mistake Filter unit 202 can with Fig. 8 a in based on integrated after the filter of activated carbon, produce the new design of water purifier.
Will for it should be apparent to those skilled in the art that design water purification installation when, can be to time marker Placement carries out multiple modifications, and does not significantly change efficiency or scope or the spirit of the present invention.On the one hand, time marker and mistake Filter unit is integrated, and in this case, described filter element can serve as independent water purification units.On the other hand, the time Indicator is integrated with storage container.On the other hand, time marker is integrated with adsorbent composition.
Referring now to Fig. 9, show that the feeding through gravity of many aspects describing according to the present invention stores water purifier 300 The volume of water and corresponding count of bacteria between drawing figure.It is observed that exceeding about 750 liters from figure In the passing through of volume, the performance of water purifier is intact (colibacillary challenge water concentration: 1 × 105CFU/mL).Trace A () and (b) represents input respectively and exports.Error bars shown in trace (a) are to be caused by the diurnal variation of bacterial concentration.
Figure 10 depicts the volume of the water feeding storage water purifier 300 through gravity of the many aspects according to the present invention With the drawing between corresponding viral count.As seen from Figure 10, in the passing through of the volume exceeding about 750 liters, water purifier Performance be intact (the challenge water concentration of MS2 coliphage:1×103PFU/ml).Trace (a) and (b) table respectively Show input and export.
Described aspect is the unrestricted present invention to illustrate the invention.It is therefore apparent that it is heretofore described Using the present invention principle without departing from any improvement of its spirit or essential characteristics, still fall within the scope of the present invention.Therefore, Design, method, structure, sequentially, the improvement of material and the like will be for those skilled in the art it is clear that but still fall within this In the range of invention.
Those skilled in the art will be evident that, the present invention can be made with multiple improvement and change, without deviating from the present invention Scope and spirit.From the thinking to this specification and the practice to invention disclosed herein, other enforcements of the present invention Scheme will be apparent for those skilled in the art.This specification and embodiment are intended to be considered exemplary only, the present invention True scope and spirit be to be indicated by following claims.

Claims (23)

1. a kind of gravity feeding storage water purifier, it includes:
Filter element, it is used for receiving raw water, and described filter element includes:
Outer cover unit;
First film layer of cloth;
Second film layer of cloth;And
Graininess sterilization composition layer, it comprises Nano silver grain, and described Nano silver grain is immersed in the Bo Mu of organic formwork On stone nanostructure, this graininess sterilization composition layer is placed between described first film layer of cloth and described second film layer of cloth;With And
Storage container, whereby by described first film layer of cloth and described second film layer of cloth, described graininess sterilization composition layer with And gravity is filtering described raw water, and whereby the water of filtration is stored in described storage container;
Adsorbent composition;And
Outlet tap, it is attached to described storage container, and the filter water of wherein said storage is by described adsorbent composition And exported by described outlet tap.
2. gravity feeding storage water purifier as claimed in claim 1, wherein said graininess sterilization composition layer also comprises It is immersed in the Nano silver grain on polyurethane.
3. gravity feeding storage water purifier as claimed in claim 1, wherein said graininess sterilization composition layer also comprises Nano silver grain, described particle be immersed at least one oxide in aluminium, zinc, manganese, iron, titanium, zirconium, lanthanum, cerium and silicon and In at least one in oxyhydroxide.
4. gravity feeding storage water purifier as claimed in claim 1, wherein said graininess sterilization composition layer also comprises Dipping Nano silver grain on the activated carbon.
5. gravity feeding storage water purifier as claimed in claim 1, wherein said first film layer of cloth and described second film cloth Layer is dismountable, capable of washing, can adhere to or one or more of a combination thereof.
6. gravity feeding storage water purifier as claimed in claim 1, the particle of wherein said graininess sterilization composition layer Size is 0.3mm to 1.5mm.
7. gravity feeding storage water purifier as claimed in claim 1, the particle of wherein said graininess sterilization composition layer Size is 0.5mm to 1mm.
8. gravity feeding storage water purifier as claimed in claim 1, wherein said raw water is with 0.5L/min to 5L/ The flow rate of min is poured through described filter element.
9. gravity feeding storage water purifier as claimed in claim 1, wherein said raw water is with 1L/min to 2L/ The flow rate of min is poured through described filter element.
10. gravity feeding storage water purifier as claimed in claim 1, wherein said filter element includes connecting to water source Water inlet.
11. gravity feeding storage water purifiers as claimed in claim 1, it further includes alarm mechanism, wherein said report Alert mechanism be configured to be provided for by the water of described filtration before being exported by described outlet tap in described storage container Middle holding predetermined time period.
12. gravity as claimed in claim 1 feeding storage water purifiers, wherein said adsorbent composition include activated carbon, At least one in activated alumina, silica, titanium dioxide, ion exchange resin and halogenated resins.
13. gravity as claimed in claim 1 feeding storage water purifiers, wherein said storage container is by engineering plastics, stainless At least one in steel, copper, brass and potter's clay is made.
14. gravity feeding storage water purifiers as claimed in claim 1, wherein said first film layer of cloth and described second film cloth Layer is made up of at least one in cellulose, polyester, nylon and polypropylene.
15. gravity feeding storage water purifiers as claimed in claim 1, wherein said water purifier further includes to float Valve, it adjusts the current leading to described water purifier.
16. gravity as claimed in claim 1 feeding storage water purifiers, wherein said water purifier connect to tubular type water source with Supply water to described water purifier.
17. gravity feeding storage water purifiers as claimed in claim 1, wherein said filter element also serves as and holds for collecting The water filter unit of the water of described filtration in device.
18. gravity feedings as claimed in claim 11 store water purifiers, and wherein alarm mechanism is and described filter element collection Become.
19. gravity as claimed in claim 15 feeding storage water purifiers, wherein said container include bottle, tank, bucket, cylinder, box, Tumbler, kettle or a combination thereof.
20. gravity feeding storage water purifiers as claimed in claim 19, wherein said bottle is vial.
21. gravity feeding storage water purifiers as claimed in claim 19, wherein said tank is water pitcher or canister.
22. gravity feeding storage water purifiers as claimed in claim 19, wherein said kettle is kettle.
23. gravity feeding storage water purifiers as claimed in claim 15, wherein said filter element can be obtained with commercially available The water purifier obtaining is integrated.
CN201280024789.3A 2012-06-22 2012-06-22 Single container gravity-fed storage water purifier Expired - Fee Related CN103747683B (en)

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KR20210132921A (en) 2020-04-28 2021-11-05 주식회사 아모그린텍 filter module for water-purifying device using gravity and water-purifying device including the same
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