CN103741230A - 一种交联橡胶纳米纤维材料及其制法和用途 - Google Patents
一种交联橡胶纳米纤维材料及其制法和用途 Download PDFInfo
- Publication number
- CN103741230A CN103741230A CN201410007686.7A CN201410007686A CN103741230A CN 103741230 A CN103741230 A CN 103741230A CN 201410007686 A CN201410007686 A CN 201410007686A CN 103741230 A CN103741230 A CN 103741230A
- Authority
- CN
- China
- Prior art keywords
- rubber
- fiber
- spinning
- preparation
- weight
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
- 229920001971 elastomer Polymers 0.000 title claims abstract description 109
- 239000005060 rubber Substances 0.000 title claims abstract description 109
- 239000000463 material Substances 0.000 title claims abstract description 87
- 239000002121 nanofiber Substances 0.000 title claims abstract description 79
- 238000004132 cross linking Methods 0.000 title claims abstract description 24
- 238000004519 manufacturing process Methods 0.000 title abstract description 6
- 239000000835 fiber Substances 0.000 claims abstract description 55
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 23
- 239000011248 coating agent Substances 0.000 claims abstract description 21
- 238000000576 coating method Methods 0.000 claims abstract description 21
- 239000002904 solvent Substances 0.000 claims abstract description 19
- 238000001523 electrospinning Methods 0.000 claims abstract description 8
- 239000002131 composite material Substances 0.000 claims abstract description 4
- 238000001514 detection method Methods 0.000 claims abstract description 4
- 239000012567 medical material Substances 0.000 claims abstract description 4
- 239000004753 textile Substances 0.000 claims abstract description 4
- 238000009987 spinning Methods 0.000 claims description 66
- 238000002360 preparation method Methods 0.000 claims description 23
- 238000004073 vulcanization Methods 0.000 claims description 22
- 239000002657 fibrous material Substances 0.000 claims description 20
- 238000000034 method Methods 0.000 claims description 17
- 238000005987 sulfurization reaction Methods 0.000 claims description 17
- HEDRZPFGACZZDS-UHFFFAOYSA-N Chloroform Chemical compound ClC(Cl)Cl HEDRZPFGACZZDS-UHFFFAOYSA-N 0.000 claims description 16
- 238000010041 electrostatic spinning Methods 0.000 claims description 16
- CSCPPACGZOOCGX-UHFFFAOYSA-N Acetone Chemical compound CC(C)=O CSCPPACGZOOCGX-UHFFFAOYSA-N 0.000 claims description 14
- 229920001195 polyisoprene Polymers 0.000 claims description 14
- 239000000203 mixture Substances 0.000 claims description 13
- 244000043261 Hevea brasiliensis Species 0.000 claims description 12
- ZMXDDKWLCZADIW-UHFFFAOYSA-N N,N-Dimethylformamide Chemical compound CN(C)C=O ZMXDDKWLCZADIW-UHFFFAOYSA-N 0.000 claims description 12
- 229920000459 Nitrile rubber Polymers 0.000 claims description 12
- MTAZNLWOLGHBHU-UHFFFAOYSA-N butadiene-styrene rubber Chemical compound C=CC=C.C=CC1=CC=CC=C1 MTAZNLWOLGHBHU-UHFFFAOYSA-N 0.000 claims description 12
- 229920003052 natural elastomer Polymers 0.000 claims description 12
- 229920001194 natural rubber Polymers 0.000 claims description 12
- 229920002857 polybutadiene Polymers 0.000 claims description 12
- 239000007788 liquid Substances 0.000 claims description 11
- 239000005062 Polybutadiene Substances 0.000 claims description 10
- -1 age resistor Substances 0.000 claims description 10
- YXFVVABEGXRONW-UHFFFAOYSA-N Toluene Chemical compound CC1=CC=CC=C1 YXFVVABEGXRONW-UHFFFAOYSA-N 0.000 claims description 9
- 239000013536 elastomeric material Substances 0.000 claims description 9
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 claims description 8
- 229910052799 carbon Inorganic materials 0.000 claims description 7
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 claims description 6
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 6
- OKKJLVBELUTLKV-UHFFFAOYSA-N Methanol Chemical compound OC OKKJLVBELUTLKV-UHFFFAOYSA-N 0.000 claims description 6
- 229910052717 sulfur Inorganic materials 0.000 claims description 6
- 239000011593 sulfur Substances 0.000 claims description 6
- 229920002472 Starch Polymers 0.000 claims description 5
- 239000008107 starch Substances 0.000 claims description 5
- 235000019698 starch Nutrition 0.000 claims description 5
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 5
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 4
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 4
- WYURNTSHIVDZCO-UHFFFAOYSA-N Tetrahydrofuran Chemical compound C1CCOC1 WYURNTSHIVDZCO-UHFFFAOYSA-N 0.000 claims description 4
- 230000003213 activating effect Effects 0.000 claims description 4
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 4
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 4
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 4
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 4
- MVPPADPHJFYWMZ-UHFFFAOYSA-N chlorobenzene Chemical compound ClC1=CC=CC=C1 MVPPADPHJFYWMZ-UHFFFAOYSA-N 0.000 claims description 4
- 229910052751 metal Inorganic materials 0.000 claims description 4
- 239000002184 metal Substances 0.000 claims description 4
- 150000001451 organic peroxides Chemical class 0.000 claims description 4
- 229920000036 polyvinylpyrrolidone Polymers 0.000 claims description 4
- 235000013855 polyvinylpyrrolidone Nutrition 0.000 claims description 4
- 239000012744 reinforcing agent Substances 0.000 claims description 4
- VZGDMQKNWNREIO-UHFFFAOYSA-N tetrachloromethane Chemical compound ClC(Cl)(Cl)Cl VZGDMQKNWNREIO-UHFFFAOYSA-N 0.000 claims description 4
- 108010010803 Gelatin Proteins 0.000 claims description 3
- 230000004888 barrier function Effects 0.000 claims description 3
- 229920005549 butyl rubber Polymers 0.000 claims description 3
- 125000002057 carboxymethyl group Chemical group [H]OC(=O)C([H])([H])[*] 0.000 claims description 3
- 229920000159 gelatin Polymers 0.000 claims description 3
- 239000008273 gelatin Substances 0.000 claims description 3
- 235000019322 gelatine Nutrition 0.000 claims description 3
- 235000011852 gelatine desserts Nutrition 0.000 claims description 3
- 229920002401 polyacrylamide Polymers 0.000 claims description 3
- 239000001267 polyvinylpyrrolidone Substances 0.000 claims description 3
- 229920002379 silicone rubber Polymers 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- 102000008186 Collagen Human genes 0.000 claims description 2
- 108010035532 Collagen Proteins 0.000 claims description 2
- XDTMQSROBMDMFD-UHFFFAOYSA-N Cyclohexane Chemical compound C1CCCCC1 XDTMQSROBMDMFD-UHFFFAOYSA-N 0.000 claims description 2
- 241000196324 Embryophyta Species 0.000 claims description 2
- 101100462438 Mus musculus Otulin gene Proteins 0.000 claims description 2
- IMNFDUFMRHMDMM-UHFFFAOYSA-N N-Heptane Chemical compound CCCCCCC IMNFDUFMRHMDMM-UHFFFAOYSA-N 0.000 claims description 2
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims description 2
- 239000002202 Polyethylene glycol Substances 0.000 claims description 2
- 239000005864 Sulphur Substances 0.000 claims description 2
- 150000001299 aldehydes Chemical class 0.000 claims description 2
- 239000000956 alloy Substances 0.000 claims description 2
- 229910045601 alloy Inorganic materials 0.000 claims description 2
- 150000001412 amines Chemical class 0.000 claims description 2
- 150000004945 aromatic hydrocarbons Chemical class 0.000 claims description 2
- 125000003118 aryl group Chemical class 0.000 claims description 2
- 229920001436 collagen Polymers 0.000 claims description 2
- 229920001577 copolymer Polymers 0.000 claims description 2
- 239000008367 deionised water Substances 0.000 claims description 2
- 229910021641 deionized water Inorganic materials 0.000 claims description 2
- 239000003480 eluent Substances 0.000 claims description 2
- 150000002148 esters Chemical class 0.000 claims description 2
- 150000002170 ethers Chemical class 0.000 claims description 2
- 239000000945 filler Substances 0.000 claims description 2
- 239000003292 glue Substances 0.000 claims description 2
- 229920000591 gum Polymers 0.000 claims description 2
- 150000002576 ketones Chemical class 0.000 claims description 2
- 229910044991 metal oxide Inorganic materials 0.000 claims description 2
- 150000004706 metal oxides Chemical class 0.000 claims description 2
- 229920001223 polyethylene glycol Polymers 0.000 claims description 2
- 150000004053 quinones Chemical class 0.000 claims description 2
- 239000012763 reinforcing filler Substances 0.000 claims description 2
- 238000005406 washing Methods 0.000 claims description 2
- 239000008096 xylene Substances 0.000 claims description 2
- 230000008901 benefit Effects 0.000 abstract description 8
- 238000005516 engineering process Methods 0.000 abstract description 6
- 239000000654 additive Substances 0.000 abstract 1
- 230000000996 additive effect Effects 0.000 abstract 1
- 230000000903 blocking effect Effects 0.000 abstract 1
- 239000011258 core-shell material Substances 0.000 abstract 1
- 238000001914 filtration Methods 0.000 abstract 1
- 239000011241 protective layer Substances 0.000 abstract 1
- 230000003014 reinforcing effect Effects 0.000 abstract 1
- 238000006557 surface reaction Methods 0.000 abstract 1
- 239000000243 solution Substances 0.000 description 34
- 239000004744 fabric Substances 0.000 description 26
- XLOMVQKBTHCTTD-UHFFFAOYSA-N Zinc monoxide Chemical compound [Zn]=O XLOMVQKBTHCTTD-UHFFFAOYSA-N 0.000 description 6
- 239000002059 nanofabric Substances 0.000 description 6
- 239000004745 nonwoven fabric Substances 0.000 description 6
- 230000001105 regulatory effect Effects 0.000 description 6
- 230000008569 process Effects 0.000 description 5
- 150000001875 compounds Chemical class 0.000 description 4
- 238000011161 development Methods 0.000 description 4
- 239000012046 mixed solvent Substances 0.000 description 4
- 229920000642 polymer Polymers 0.000 description 4
- 239000007921 spray Substances 0.000 description 4
- 238000012360 testing method Methods 0.000 description 4
- ZRMMVODKVLXCBB-UHFFFAOYSA-N 1-n-cyclohexyl-4-n-phenylbenzene-1,4-diamine Chemical compound C1CCCCC1NC(C=C1)=CC=C1NC1=CC=CC=C1 ZRMMVODKVLXCBB-UHFFFAOYSA-N 0.000 description 3
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 description 3
- 235000021355 Stearic acid Nutrition 0.000 description 3
- 230000003712 anti-aging effect Effects 0.000 description 3
- 238000001723 curing Methods 0.000 description 3
- 238000004090 dissolution Methods 0.000 description 3
- 238000002474 experimental method Methods 0.000 description 3
- QIQXTHQIDYTFRH-UHFFFAOYSA-N octadecanoic acid Chemical compound CCCCCCCCCCCCCCCCCC(O)=O QIQXTHQIDYTFRH-UHFFFAOYSA-N 0.000 description 3
- OQCDKBAXFALNLD-UHFFFAOYSA-N octadecanoic acid Natural products CCCCCCCC(C)CCCCCCCCC(O)=O OQCDKBAXFALNLD-UHFFFAOYSA-N 0.000 description 3
- 239000008117 stearic acid Substances 0.000 description 3
- 238000009281 ultraviolet germicidal irradiation Methods 0.000 description 3
- 239000011787 zinc oxide Substances 0.000 description 3
- XMNIXWIUMCBBBL-UHFFFAOYSA-N 2-(2-phenylpropan-2-ylperoxy)propan-2-ylbenzene Chemical compound C=1C=CC=CC=1C(C)(C)OOC(C)(C)C1=CC=CC=C1 XMNIXWIUMCBBBL-UHFFFAOYSA-N 0.000 description 2
- 239000007864 aqueous solution Substances 0.000 description 2
- 239000003431 cross linking reagent Substances 0.000 description 2
- 238000010586 diagram Methods 0.000 description 2
- 238000011065 in-situ storage Methods 0.000 description 2
- 229910052709 silver Inorganic materials 0.000 description 2
- 239000004332 silver Substances 0.000 description 2
- LSPHULWDVZXLIL-UHFFFAOYSA-N (+/-)-Camphoric acid Chemical class CC1(C)C(C(O)=O)CCC1(C)C(O)=O LSPHULWDVZXLIL-UHFFFAOYSA-N 0.000 description 1
- KOMNUTZXSVSERR-UHFFFAOYSA-N 1,3,5-tris(prop-2-enyl)-1,3,5-triazinane-2,4,6-trione Chemical compound C=CCN1C(=O)N(CC=C)C(=O)N(CC=C)C1=O KOMNUTZXSVSERR-UHFFFAOYSA-N 0.000 description 1
- 241000239290 Araneae Species 0.000 description 1
- 239000004135 Bone phosphate Substances 0.000 description 1
- 229920002943 EPDM rubber Polymers 0.000 description 1
- RRHGJUQNOFWUDK-UHFFFAOYSA-N Isoprene Chemical compound CC(=C)C=C RRHGJUQNOFWUDK-UHFFFAOYSA-N 0.000 description 1
- 229910002651 NO3 Inorganic materials 0.000 description 1
- NHNBFGGVMKEFGY-UHFFFAOYSA-N Nitrate Chemical compound [O-][N+]([O-])=O NHNBFGGVMKEFGY-UHFFFAOYSA-N 0.000 description 1
- 229920003171 Poly (ethylene oxide) Polymers 0.000 description 1
- 239000004952 Polyamide Substances 0.000 description 1
- 239000004698 Polyethylene Substances 0.000 description 1
- 239000004743 Polypropylene Substances 0.000 description 1
- 239000004793 Polystyrene Substances 0.000 description 1
- 239000004372 Polyvinyl alcohol Substances 0.000 description 1
- 239000012080 ambient air Substances 0.000 description 1
- 230000015572 biosynthetic process Effects 0.000 description 1
- NTXGQCSETZTARF-UHFFFAOYSA-N buta-1,3-diene;prop-2-enenitrile Chemical compound C=CC=C.C=CC#N NTXGQCSETZTARF-UHFFFAOYSA-N 0.000 description 1
- 239000006229 carbon black Substances 0.000 description 1
- 238000007796 conventional method Methods 0.000 description 1
- 230000000694 effects Effects 0.000 description 1
- 230000005684 electric field Effects 0.000 description 1
- 229940085805 fiberall Drugs 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 238000009472 formulation Methods 0.000 description 1
- 230000009477 glass transition Effects 0.000 description 1
- 238000013007 heat curing Methods 0.000 description 1
- 239000003999 initiator Substances 0.000 description 1
- 239000010977 jade Substances 0.000 description 1
- PIJPYDMVFNTHIP-UHFFFAOYSA-L lead sulfate Chemical compound [PbH4+2].[O-]S([O-])(=O)=O PIJPYDMVFNTHIP-UHFFFAOYSA-L 0.000 description 1
- 229920002521 macromolecule Polymers 0.000 description 1
- 238000005297 material degradation process Methods 0.000 description 1
- 239000012528 membrane Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 239000002105 nanoparticle Substances 0.000 description 1
- 239000003960 organic solvent Substances 0.000 description 1
- 238000000053 physical method Methods 0.000 description 1
- 229920003229 poly(methyl methacrylate) Polymers 0.000 description 1
- 229920002492 poly(sulfone) Polymers 0.000 description 1
- 229920002647 polyamide Polymers 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
- 229920005594 polymer fiber Polymers 0.000 description 1
- 239000004926 polymethyl methacrylate Substances 0.000 description 1
- 229920001155 polypropylene Polymers 0.000 description 1
- 229920002223 polystyrene Polymers 0.000 description 1
- 229920002635 polyurethane Polymers 0.000 description 1
- 239000004814 polyurethane Substances 0.000 description 1
- 229920002451 polyvinyl alcohol Polymers 0.000 description 1
- 229920000915 polyvinyl chloride Polymers 0.000 description 1
- 239000004800 polyvinyl chloride Substances 0.000 description 1
- 230000005855 radiation Effects 0.000 description 1
- 238000010092 rubber production Methods 0.000 description 1
- 230000003068 static effect Effects 0.000 description 1
- 238000005486 sulfidation Methods 0.000 description 1
- 229920003169 water-soluble polymer Polymers 0.000 description 1
Images
Landscapes
- Spinning Methods And Devices For Manufacturing Artificial Fibers (AREA)
- Artificial Filaments (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
Description
Claims (10)
Priority Applications (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410007686.7A CN103741230B (zh) | 2014-01-08 | 2014-01-08 | 一种交联橡胶纳米纤维材料及其制法和用途 |
Applications Claiming Priority (1)
Application Number | Priority Date | Filing Date | Title |
---|---|---|---|
CN201410007686.7A CN103741230B (zh) | 2014-01-08 | 2014-01-08 | 一种交联橡胶纳米纤维材料及其制法和用途 |
Publications (2)
Publication Number | Publication Date |
---|---|
CN103741230A true CN103741230A (zh) | 2014-04-23 |
CN103741230B CN103741230B (zh) | 2015-12-30 |
Family
ID=50498293
Family Applications (1)
Application Number | Title | Priority Date | Filing Date |
---|---|---|---|
CN201410007686.7A Active CN103741230B (zh) | 2014-01-08 | 2014-01-08 | 一种交联橡胶纳米纤维材料及其制法和用途 |
Country Status (1)
Country | Link |
---|---|
CN (1) | CN103741230B (zh) |
Cited By (14)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104804376A (zh) * | 2015-05-04 | 2015-07-29 | 芜湖市宝艺游乐科技设备有限公司 | 一种橡胶纳米纤维增韧的氧化石墨烯密胺树脂及其制备方法 |
CN105063774A (zh) * | 2015-09-01 | 2015-11-18 | 厦门理工学院 | 静电纺丝装置及其静电纺丝方法 |
CN105926156A (zh) * | 2016-01-27 | 2016-09-07 | 青岛科技大学 | 多孔的反式橡胶超细纤维无纺布及其制备方法和用途 |
CN106046631A (zh) * | 2016-05-26 | 2016-10-26 | 航天材料及工艺研究所 | 一种静电纺丝法填料规则排列的多层氟醚橡胶制备方法 |
CN106350897A (zh) * | 2016-08-30 | 2017-01-25 | 郑明耀 | 一种用于制鞋的纳米抗菌纤维材料 |
CN107663716A (zh) * | 2016-07-28 | 2018-02-06 | 中国地质大学(北京) | 一种溴化丁基橡胶的静电纺丝工艺 |
CN110539543A (zh) * | 2019-08-01 | 2019-12-06 | 陈小强 | 一种高强度绝热毡的制备方法 |
CN111549385A (zh) * | 2020-05-13 | 2020-08-18 | 青岛科技大学 | 一种导电纤维制备装置 |
CN111793847A (zh) * | 2020-07-31 | 2020-10-20 | 深圳市爱车屋汽车用品股份有限公司 | 一种透气吸湿性能好的新型纤维材料的制备方法 |
CN111826743A (zh) * | 2020-06-17 | 2020-10-27 | 界首市佳美棉业有限公司 | 一种橡胶复合纤维及其制备工艺 |
JP2020186486A (ja) * | 2019-05-13 | 2020-11-19 | 国立大学法人福井大学 | 繊維、不織布および繊維の製造方法 |
CN112176436A (zh) * | 2020-09-07 | 2021-01-05 | 江南大学 | 一种基于溶液喷射纺丝方法的顺丁橡胶微纳米纤维 |
CN112593296A (zh) * | 2020-12-03 | 2021-04-02 | 青岛科技大学 | 一种静电雾化纺丝混合橡胶湿法混炼方法及设备 |
WO2021246218A1 (ja) * | 2020-06-05 | 2021-12-09 | 株式会社バルカー | フッ素ゴム繊維、フッ素ゴム不織布およびフッ素ゴム繊維の製造方法 |
Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101089259A (zh) * | 2007-07-06 | 2007-12-19 | 东华大学 | 一种交联三维网状超细吸油纤维及其制备方法和应用 |
CN101100767A (zh) * | 2007-07-13 | 2008-01-09 | 东华大学 | 一种三元乙丙橡胶超细纤维及其制备方法和应用 |
WO2008022993A2 (de) * | 2006-08-21 | 2008-02-28 | Basf Se | Verfahren zur herstellung von nano- und mesofasern durch elektrospinnen von kolloidalen dispersionen |
CN101151403A (zh) * | 2005-02-24 | 2008-03-26 | 巴斯福股份公司 | 通过胶态分散体电纺丝制备纳米纤维和介纤维的方法 |
CN101456980A (zh) * | 2007-12-15 | 2009-06-17 | 固特异轮胎和橡胶公司 | 具有含聚合纳米纤维的元件的轮胎 |
CN101498057A (zh) * | 2009-03-06 | 2009-08-05 | 北京化工大学 | 一种橡胶纳米纤维的制备方法 |
US20120040581A1 (en) * | 2009-04-01 | 2012-02-16 | Centro De Estudios Investigaciones Tecnicas De Gipuzkoa | Template-supported method of forming patterns of nanofibers in the electrospinning process and uses of said nanofibers |
EP2557207A1 (en) * | 2011-08-10 | 2013-02-13 | Samsung Electronics Co., Ltd. | Stretchable conductive nanofibers, stretchable electrode using the same and method of producing the stretchable conductive nanofibers |
EP2607528A1 (de) * | 2011-12-22 | 2013-06-26 | Philipps-Universität Marburg | Haftoptimierung von durch Dispersionselektrospinnen hergestellten Fasern durch Variation des Erweichungspunktes des Latexpolymers |
-
2014
- 2014-01-08 CN CN201410007686.7A patent/CN103741230B/zh active Active
Patent Citations (9)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101151403A (zh) * | 2005-02-24 | 2008-03-26 | 巴斯福股份公司 | 通过胶态分散体电纺丝制备纳米纤维和介纤维的方法 |
WO2008022993A2 (de) * | 2006-08-21 | 2008-02-28 | Basf Se | Verfahren zur herstellung von nano- und mesofasern durch elektrospinnen von kolloidalen dispersionen |
CN101089259A (zh) * | 2007-07-06 | 2007-12-19 | 东华大学 | 一种交联三维网状超细吸油纤维及其制备方法和应用 |
CN101100767A (zh) * | 2007-07-13 | 2008-01-09 | 东华大学 | 一种三元乙丙橡胶超细纤维及其制备方法和应用 |
CN101456980A (zh) * | 2007-12-15 | 2009-06-17 | 固特异轮胎和橡胶公司 | 具有含聚合纳米纤维的元件的轮胎 |
CN101498057A (zh) * | 2009-03-06 | 2009-08-05 | 北京化工大学 | 一种橡胶纳米纤维的制备方法 |
US20120040581A1 (en) * | 2009-04-01 | 2012-02-16 | Centro De Estudios Investigaciones Tecnicas De Gipuzkoa | Template-supported method of forming patterns of nanofibers in the electrospinning process and uses of said nanofibers |
EP2557207A1 (en) * | 2011-08-10 | 2013-02-13 | Samsung Electronics Co., Ltd. | Stretchable conductive nanofibers, stretchable electrode using the same and method of producing the stretchable conductive nanofibers |
EP2607528A1 (de) * | 2011-12-22 | 2013-06-26 | Philipps-Universität Marburg | Haftoptimierung von durch Dispersionselektrospinnen hergestellten Fasern durch Variation des Erweichungspunktes des Latexpolymers |
Non-Patent Citations (1)
Title |
---|
张立群: "橡胶的纳米增强技术与理论", 《中日橡胶技术交流会论文集》 * |
Cited By (19)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104804376A (zh) * | 2015-05-04 | 2015-07-29 | 芜湖市宝艺游乐科技设备有限公司 | 一种橡胶纳米纤维增韧的氧化石墨烯密胺树脂及其制备方法 |
CN105063774A (zh) * | 2015-09-01 | 2015-11-18 | 厦门理工学院 | 静电纺丝装置及其静电纺丝方法 |
CN105926156A (zh) * | 2016-01-27 | 2016-09-07 | 青岛科技大学 | 多孔的反式橡胶超细纤维无纺布及其制备方法和用途 |
CN105926156B (zh) * | 2016-01-27 | 2018-05-01 | 青岛科技大学 | 多孔的反式橡胶超细纤维无纺布及其制备方法和用途 |
CN106046631A (zh) * | 2016-05-26 | 2016-10-26 | 航天材料及工艺研究所 | 一种静电纺丝法填料规则排列的多层氟醚橡胶制备方法 |
CN106046631B (zh) * | 2016-05-26 | 2018-03-09 | 航天材料及工艺研究所 | 一种静电纺丝法填料规则排列的多层氟醚橡胶制备方法 |
CN107663716A (zh) * | 2016-07-28 | 2018-02-06 | 中国地质大学(北京) | 一种溴化丁基橡胶的静电纺丝工艺 |
CN106350897A (zh) * | 2016-08-30 | 2017-01-25 | 郑明耀 | 一种用于制鞋的纳米抗菌纤维材料 |
JP2020186486A (ja) * | 2019-05-13 | 2020-11-19 | 国立大学法人福井大学 | 繊維、不織布および繊維の製造方法 |
JP7317312B2 (ja) | 2019-05-13 | 2023-07-31 | 国立大学法人福井大学 | 繊維、不織布および繊維の製造方法 |
CN110539543A (zh) * | 2019-08-01 | 2019-12-06 | 陈小强 | 一种高强度绝热毡的制备方法 |
CN111549385A (zh) * | 2020-05-13 | 2020-08-18 | 青岛科技大学 | 一种导电纤维制备装置 |
WO2021246218A1 (ja) * | 2020-06-05 | 2021-12-09 | 株式会社バルカー | フッ素ゴム繊維、フッ素ゴム不織布およびフッ素ゴム繊維の製造方法 |
CN111826743A (zh) * | 2020-06-17 | 2020-10-27 | 界首市佳美棉业有限公司 | 一种橡胶复合纤维及其制备工艺 |
CN111826743B (zh) * | 2020-06-17 | 2023-06-27 | 界首市佳美棉业有限公司 | 一种橡胶复合纤维及其制备工艺 |
CN111793847A (zh) * | 2020-07-31 | 2020-10-20 | 深圳市爱车屋汽车用品股份有限公司 | 一种透气吸湿性能好的新型纤维材料的制备方法 |
CN112176436A (zh) * | 2020-09-07 | 2021-01-05 | 江南大学 | 一种基于溶液喷射纺丝方法的顺丁橡胶微纳米纤维 |
CN112176436B (zh) * | 2020-09-07 | 2021-11-02 | 江南大学 | 一种基于溶液喷射纺丝方法的顺丁橡胶微纳米纤维 |
CN112593296A (zh) * | 2020-12-03 | 2021-04-02 | 青岛科技大学 | 一种静电雾化纺丝混合橡胶湿法混炼方法及设备 |
Also Published As
Publication number | Publication date |
---|---|
CN103741230B (zh) | 2015-12-30 |
Similar Documents
Publication | Publication Date | Title |
---|---|---|
CN103741230B (zh) | 一种交联橡胶纳米纤维材料及其制法和用途 | |
CN104790067B (zh) | 纳米导电高分子/石墨烯复合纤维及其制备方法和应用 | |
CN101748560B (zh) | 纳米级多孔静电纺复合材料的纺纱方法 | |
CN103981593B (zh) | 一种聚乙烯醇熔纺超细纤维的制备方法 | |
CN103088478B (zh) | 一种取向静电纺纳米纤维纱线连续制备装置 | |
CN104289042A (zh) | 一种静电纺纳米纤维驻极过滤材料及其制备方法 | |
CN105926156B (zh) | 多孔的反式橡胶超细纤维无纺布及其制备方法和用途 | |
CN104499089A (zh) | 一种改性丙纶纤维及其制备方法 | |
ATE459735T1 (de) | Verfahren zur herstellung eines endlosfilaments aus nanofaser | |
CN104213202A (zh) | 一种纺丝液及其制备抗菌空气过滤膜的方法 | |
CN103789874B (zh) | 平行电场诱导相分离法制备核壳结构天然聚电解质纳米纤维 | |
CN102277689A (zh) | 具有纳米结构的纤维素类纤维膜的制备装置及制备方法 | |
CN104451911A (zh) | 一种静电辅助溶液喷射纺丝装置及纺丝方法 | |
CN111020745A (zh) | 一种海藻酸钠和壳聚糖复合纳米纤维的制备方法 | |
CN105220361A (zh) | 一种茶多酚/醋酸纤维素纳米纤维膜的制备方法 | |
WO2022217952A1 (zh) | 一种直接在皮肤上纺丝制备纤维膜干电极的方法 | |
CN113413684B (zh) | 一种聚乳酸纳米双层纤维膜滤芯及其制备方法 | |
CN105332131A (zh) | 一种醋酸纳米纤维/涤纶长丝复合纱线的制备方法 | |
CN106350932A (zh) | 植绒蕾丝花边面料 | |
CN109730378A (zh) | 一种具有静电纺丝膜的pm2.5防护口罩及其制备方法 | |
CN103879120A (zh) | 基于废弃茧丝原料的丝蛋白纳米纤维雾霾防护产品 | |
CN113152090A (zh) | 一种抗菌抗病毒纤维素纳米纤维过滤防护膜及其制备方法 | |
CN113046925B (zh) | 一种聚偏氟乙烯超细纳米纤维膜及其制备方法 | |
CN103911766A (zh) | 反式橡胶纤维材料、其制备方法和用途 | |
KR101033278B1 (ko) | 전기방사를 이용한 개선된 폴리비닐알코올 나노섬유 멤브레인의 제조방법 |
Legal Events
Date | Code | Title | Description |
---|---|---|---|
C06 | Publication | ||
PB01 | Publication | ||
C10 | Entry into substantive examination | ||
SE01 | Entry into force of request for substantive examination | ||
ASS | Succession or assignment of patent right |
Owner name: ZHANG GUOJIE Free format text: FORMER OWNER: DONGYING GERUI NEW RUBBER + PLASTIC MATERIALS CO., LTD. Effective date: 20150316 |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20150316 Address after: 266042 rubber key laboratory, No. 51-1, Wuyang Road, Shandong, Qingdao Applicant after: Qingdao University of Science & Technology Applicant after: Zhang Guojie Address before: 266042 rubber key laboratory, No. 51-1, Wuyang Road, Shandong, Qingdao Applicant before: Qingdao University of Science & Technology Applicant before: Dongying Gerui Rubber Plastic New Materials Co., Ltd. |
|
C41 | Transfer of patent application or patent right or utility model | ||
TA01 | Transfer of patent application right |
Effective date of registration: 20150921 Address after: 266042 rubber key laboratory, No. 51-1, Wuyang Road, Shandong, Qingdao Applicant after: Qingdao University of Science & Technology Applicant after: SHANDONG HUAJU HIGH POLYMER MATERIAL CO., LTD. Address before: 266042 rubber key laboratory, No. 51-1, Wuyang Road, Shandong, Qingdao Applicant before: Qingdao University of Science & Technology Applicant before: Zhang Guojie |
|
C14 | Grant of patent or utility model | ||
GR01 | Patent grant |