(3) summary of the invention
The present invention in order to make up the deficiencies in the prior art, provide a kind of component rationally, viscosity-temperature characteristics energy and high temperature oil-film retention property is good, cleansing performance is good, the drain period is long, anti-oxidant nitrification ability is strong artificial fuel gas engine oil and preparation method thereof.
The present invention is achieved through the following technical solutions:
A kind of artificial fuel gas engine oil, the component comprising following weight percent is made: composite additive bag 5.8 ~ 11.5%, viscosity index improver 5.0 ~ 9.0%, oil soluble polyalkylene glycol 60 ~ 85%, oil based on surplus.
Described composite additive handbag draws together purification agent 3.0 ~ 5.0%, dispersion agent 2.0 ~ 4.0%, also comprises oxidation inhibitor 0.5 ~ 1.5% and/or oxidation and corrosion inhibitor 0.3 ~ 1.0%.
Described purification agent is sulfonate detergent or salicylate detergent (metal-salt is sodium, calcium, magnesium, zinc, barium etc.), carbon deposit, greasy filth in energy cleaned engine, there is very strong adsorption, cleaning function is played to the paint film on metalwork, carbon deposit etc., makes it be distributed in oil.
Described dispersion agent is ashless dispersant, its preferred dispersion agent is succimide, for maintaining the suspension of the insoluble substance because of high temperature oxidation, and dissolving has been deposited on greasy filth, carbon deposit etc. on metalwork, it is dispersed in oil with micella, can dissolve hydroxyl, carbonyl oxygenatedchemicals, containing nitro-compound and moisture etc., play the effect of solubilising.
Described oxidation inhibitor is ashless aromatic amine oxidation inhibitor or Hinered phenols antioxidant, and resistance of oxidation is strong, can suppress oxidation of lubricating oil, reduces the generation of precipitation, paint film and greasy filth, thus suppresses the growth of lubricating oil viscosity.
Described oxidation and corrosion inhibitor is organic sulfide oxidation and corrosion inhibitor, can suppress oxidation of lubricating oil, reduces the generation of precipitation, paint film and greasy filth, thus suppresses the growth of lubricating oil viscosity, can prevent the wearing and tearing of the corrosion of bearing and piston, cylinder, cam, tappet.
Described viscosity index improver is polymethacrylate or vinylbenzene and diene copolymer, can increase oil product viscosity, and improve viscosity index, low-temperature startup is good, reduces wearing and tearing, saves fuel oil, can all-season.
Traditional polyethers base oil is with oxyethane, propylene oxide, butylene oxide ring and tetrahydrofuran (THF) etc. for raw material, under catalyst action, and the simple linear polymer that open loop homopolymerization or copolymerization obtain.Oil soluble polyalkylene glycol of the present invention is not traditional oxyethane (EO) and propylene oxide (PO) homopolymerization copolymerized polymer, but pass through block polymerization, random copolymerization, the oil-soluble polymers that reverse block is obtained, have the following advantages: viscosity grade is extensive, viscosity index is high, high temperature performance is excellent, oil film strength is high, also there is outstanding depositional control and equipment cleaning, be not hydrolyzed, use safety, and in elastomer compatibility, there is outstanding behaviours the aspects such as water absorbability, particularly by alkoxylate chemical technology, improve a difficult problem for conventional polyether base oil and other base oil intermiscibility difference.Oil soluble polyalkylene glycol also has high biological degradation rate, is a kind of environmental protection base oil of high-quality.
Described base oil is synthesis hydrocarbon base oil or synthetic ester base oil, use composite with oil soluble polyalkylene glycol.
The preparation method of this artificial fuel gas engine oil, is characterized in that: comprise the steps:
(1) by oil soluble polyalkylene glycol and base oil mixing, heated and stirred, mixes to obtain mixing oil A at constant temperature 50 ~ 60 DEG C;
(2) in the obtained mixing oil A of step (1), add composite additive bag, viscosity index improver, continue stirring 1 ~ 2h under constant temperature 50 ~ 60 DEG C of conditions, obtained mixing oil B;
(3) the mixing oil B that step (2) is obtained is filtered under 0.1MPa ~ 0.2MPa pressure, obtain limpid transparent artificial fuel gas engine oil.
The beneficial effect of artificial fuel gas engine oil of the present invention and preparation method thereof is: component is reasonable, and viscosity-temperature characteristics can be good, and high temperature oil-film retention property is better; Few generation deposition, acid number change and viscosity change little, have obvious cleansing performance; Drain period is long, has good anti-oxidant nitrification ability, can suppress the generation of greasy filth, control piston and valve deposits during high temperature; The parts such as rational ash content can prevent component wear, protection engine, can meet the demand of different fuel and different ash product, at apical ring groove charcoal, platform charcoal, there is excellent performance the aspects such as piston, ring and cylinder sleeve scratch.
(4) embodiment
Below in conjunction with embodiment, the invention will be further described, but the present invention is not limited thereto, and the preparation method in embodiment is customary preparation methods, no longer describes in detail.
Embodiment 1:(is in double centner, as follows)
This composite additive bag, wherein calcic 1.09%, zinc 0.26%, nitrogen 0.86%, phosphorus 0.22%.
The preparation method of this artificial fuel gas engine oil, adopts following steps:
(1) oil soluble polyalkylene glycol of above-mentioned weight and synthetic ester base oil toothed gear pump are pumped in mediation Fu, heated and stirred, mixes to obtain mixing oil A at constant temperature 60 DEG C;
(2) in the obtained mixing oil A of step (1), add composite additive bag, the viscosity index improver (polymethacrylate) of above-mentioned weight, continue mechanical stirring 2h under constant temperature 60 DEG C of conditions, obtained mixing oil B;
(3) the mixing oil B that step (2) is obtained being filtered, under 0.2MPa pressure, through there being the metre filter of filter bag device, obtaining limpid transparent artificial fuel gas engine oil.
Embodiment 2:
This composite additive bag, wherein calcic 2.63%, zinc 1.26%, phosphorus 1.12%.
The preparation method of this artificial fuel gas engine oil, adopts following steps:
(1) oil soluble polyalkylene glycol of above-mentioned weight and synthetic ester base oil toothed gear pump are pumped in mediation Fu, heated and stirred, mixes to obtain mixing oil A at constant temperature 55 DEG C;
(2) in the obtained mixing oil A of step (1), add composite additive bag, the viscosity index improver (hydrogenated styrene isoprene copolymer) of above-mentioned weight, continue mechanical stirring 1.5h under constant temperature 55 DEG C of conditions, obtained mixing oil B;
(3) the mixing oil B that step (2) is obtained being filtered, under 0.15MPa pressure, through there being the metre filter of filter bag device, obtaining limpid transparent artificial fuel gas engine oil.
Embodiment 3:
This composite additive bag, wherein calcic 2.28%, zinc 1.07%, phosphorus 0.92%, sulphur 7.37%, molybdenum 0.19%.
The preparation method of this artificial fuel gas engine oil, adopts following steps:
(1) oil soluble of above-mentioned weight is gathered alkylene polyglycol and synthetic ester base oil toothed gear pump to pump into and be in harmonious proportion in Fu, heated and stirred, mixes to obtain mixing oil A at constant temperature 50 DEG C;
(2) in the obtained mixing oil A of step (1), add composite additive bag, the viscosity index improver (polymethacrylate) of above-mentioned weight, continue mechanical stirring 1h under constant temperature 50 DEG C of conditions, obtained mixing oil B;
(3) the mixing oil B that step (2) is obtained being filtered, under 0.1MPa pressure, through there being the metre filter of filter bag device, obtaining limpid transparent artificial fuel gas engine oil.
Embodiment 4:
This composite additive bag, wherein calcic 3.43%, zinc 1.66%, phosphorus 1.52%, nitrogen 0.99%.
The preparation method of this artificial fuel gas engine oil, adopts following steps:
(1) oil soluble polyalkylene glycol of above-mentioned weight and synthesis hydrocarbon base oil toothed gear pump are pumped in mediation Fu, heated and stirred, mixes to obtain mixing oil A at constant temperature 55 DEG C;
(2) in the obtained mixing oil A of step (1), add composite additive bag, the viscosity index improver (hydrogenated styrene isoprene copolymer) of above-mentioned weight, continue mechanical stirring 2h under constant temperature 55 DEG C of conditions, obtained mixing oil B;
(3) the mixing oil B that step (2) is obtained being filtered, under 0.15MPa pressure, through there being the metre filter of filter bag device, obtaining limpid transparent artificial fuel gas engine oil.
Embodiment 5:
This composite additive bag, wherein calcic 2.19%, zinc 0.96%, nitrogen 0.76%, phosphorus 0.88%.
The preparation method of this artificial fuel gas engine oil, adopts following steps:
(1) oil soluble polyalkylene glycol of above-mentioned weight and synthesis hydrocarbon base oil toothed gear pump are pumped in mediation Fu, heated and stirred, mixes to obtain mixing oil A at constant temperature 60 DEG C;
(2) in the obtained mixing oil A of step (1), add composite additive bag, the viscosity index improver (hydrogenated styrene isoprene copolymer) of above-mentioned weight, continue mechanical stirring 1.5h under constant temperature 60 DEG C of conditions, obtained mixing oil B;
(3) the mixing oil B that step (2) is obtained being filtered, under 0.2MPa pressure, through there being the metre filter of filter bag device, obtaining limpid transparent artificial fuel gas engine oil.
Compared with conventional gas engine oil, artificial fuel gas engine oil of the present invention has the following advantages:
A) pour point (experimental technique ASTMD97), the pour point of artificial fuel gas engine oil of the present invention is lower than conventional gas engine oil 15 ~ 30 DEG C, more adapts to extreme low temperature applied environment;
B) low temperature coefficient of dynamic viscosity (experimental technique ASTMD5293), artificial fuel gas engine oil of the present invention is under equal cold condition, and low temperature coefficient of dynamic viscosity reduces by 15 ~ 30%, more wipes surface lubrication near Bodhidharma, prevent wearing and tearing in cold start-up moment;
C) open flash point (experimental technique ASTMD92), artificial fuel gas engine oil flash of the present invention is than conventional gas engine innage 20 ~ 40 DEG C, and use safer, volatility is lower;
D) viscosity index (experimental technique ASTMD2270), artificial fuel gas engine oil of the present invention can improve 15 ~ 30, and viscosity-temperature characteristics can be better, and high-temperature viscosity rate of descent reduces by 15 ~ 30%, and high temperature oil-film retention property is better;
E) depositional control and cleansing performance (experimental technique ASTMD2893B), artificial fuel gas engine oil of the present invention seldom produces deposition, and acid number change and viscosity change little, have obvious cleansing performance;
F) vaporization losses (experimental technique ASTMD5800), the vaporization losses of artificial fuel gas engine oil of the present invention on average reduces by 15 ~ 30%, and in use, waste during high temperature is less;
G) endurance check (experimental technique ASTMD6681), artificial fuel gas engine oil of the present invention considers the characteristic of fuel gas, provides suitable ash content, and at apical ring groove charcoal, platform charcoal, there is excellent performance the aspects such as piston, ring and cylinder sleeve scratch;
H) oxidation stability (experimental technique ASTMD6984), artificial fuel gas engine oil of the present invention increases Be very effective in control at viscosity, and after long-time hot operation, viscosity change is very little;
I) overlength life cycle, the drain period of artificial fuel gas engine oil of the present invention is 1 ~ 5 times of conventional gas engine oil.