CN103734134A - Spinetoram and monosultap mixing oil suspension - Google Patents
Spinetoram and monosultap mixing oil suspension Download PDFInfo
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- CN103734134A CN103734134A CN201410038309.XA CN201410038309A CN103734134A CN 103734134 A CN103734134 A CN 103734134A CN 201410038309 A CN201410038309 A CN 201410038309A CN 103734134 A CN103734134 A CN 103734134A
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- ethyl pleocidin
- monosultap
- spinetoram
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Abstract
The invention relates to a spinetoram and monosultap mixing oil suspension which is prepared from the following raw materials in percentage by weight: 0.5-1.5 percent of spinetoram, 15-25 percent of monosultap, 7-9 percent of a surfactant, 2-4 percent of dibutyl adipate, 1-3 percent of carbomer resin, 0.1-0.3 percent of spermol, 0.2-0.4 percent of propylparaben and the balance of soybean oil. The spinetoram and monosultap mixing oil suspension disclosed by the invention is high in suspension rate, and the product is stable in performance. The spinetoram and monosultap mixing oil suspension is suitable for prevention and treatment of arthropod pests, in particular insecta, arachnoidea or nematode.
Description
Technical field
The present invention relates to a kind of ethyl pleocidin and the composite oil-suspending agent of desinsection list.
Background technology
Ethyl pleocidin, English name: Spinetoram, works code: XDE-175, registration number: 187166-40-1187166-15-0.Be the novel pleocidin insecticides of one of being produced by Dow AgroSciences, and receive first whole world registration, it can effectively control a kind of thorny primary pest on important insect pest, the especially fruit tree on fruit tree and nut---the stupid moth of apple.
Desinsection list, chemical name: 1. thiosulfonic acid sodium base 2. dimethylamino 3. thiosulfonic acid base propane, English name: Monosultap, CAS 29547-00-0.Be the analog of artificial synthetic nereistoxin, enter and in insect bodies, be converted into rapidly nereistoxin or Dihydronereistoxin element.This medicine is acetylcholine competitive inhibitor, have stronger tag, stomach toxicity and interior suction conduction, the larva of lepidoptera pest is had to good control efficiency.
Oil-suspending agent, is called for short oil suspending agent, refers to that one or more pesticide active ingredients (wherein have at least a kind of for the former medicine of solid) form high dispersive, stable suspension system in grease dispersion medium.Oil-suspending agent is generally rear for spraying with grease dilution, also can, without dilution, do ultra low volume spraying.
Summary of the invention
For solving the deficiencies in the prior art, technical problem to be solved by this invention is to provide a kind of ethyl pleocidin and the composite oil-suspending agent of desinsection list.Specifically by following technical proposals, be achieved:
Ethyl pleocidin and the composite oil-suspending agent of desinsection list, comprise the raw material of following weight percentage: ethyl pleocidin 0.5-1.5%; Desinsection list 15-25%.
Ethyl pleocidin and the composite oil-suspending agent of desinsection list, be comprised of following materials by weight percentage: ethyl pleocidin 0.5-1.5%; Desinsection list 15-25%; Surfactant 7-9%; Dibutyl adipate 2-4%; Carbomer 1-3%; Cetanol 0.1-0.3%; Propylben 0.2-0.4%; Surplus is soybean oil.
Described surfactant is poly-(Oxy-1, the 2-ethylidene) non-ionic surface active agent of cumene sodium sulfonate and/or α-[three (phenyl methyl) phenyl]-ω-hydroxyl.Preferably, described surfactant, by 30-70 weight portion cumene sodium sulfonate and poly-(Oxy-1,2-ethylidene) non-ionic surface active agent composition of 30-70 weight portion α-[three (phenyl methyl) phenyl]-ω-hydroxyl.
α-[three (phenyl methyl) phenyl]-ω-hydroxyl gathers (Oxy-1,2-ethylidene) non-ionic surface active agent, CAS:64422-66-8.Cumene sodium sulfonate, No. CAS: 28348-53-0.
The composite oil-suspending agent of ethyl pleocidin of the present invention and desinsection list can adopt the general method in this area to be prepared, as:
(1) in mixing kettle, add ethyl pleocidin, desinsection list, surfactant, dibutyl adipate, carbomer, cetanol, propylben and soybean oil, be uniformly mixed;
(2) be placed in sand mill and carry out ultramicro grinding, controlling average grain diameter is 3 μ m;
(3) check, qualified rear packing.
Ethyl pleocidin of the present invention and the composite oil-suspending agent of desinsection list have higher suspension rate, long-term stable storage.The present invention is applicable to prevent and treat arthropod, especially Insecta, arachnids or Nematoda.
Embodiment
Embodiment 1
(1) by corresponding embodiment 1 data of table 1, take each raw material;
(2) in mixing kettle, add ethyl pleocidin, desinsection list, surfactant, dibutyl adipate, carbomer, cetanol, propylben and soybean oil, be uniformly mixed;
(3) be placed in sand mill and carry out ultramicro grinding, controlling average grain diameter is 3 μ m;
(4) check, qualified rear packing.
Table 1: the oil-suspending agent formula table unit that ethyl pleocidin and desinsection list are composite: kilogram
Embodiment 2
By corresponding embodiment 2 data of table 1, take raw material, by the method for embodiment 1, be prepared.
Embodiment 3
By corresponding embodiment 3 data of table 1, take raw material, by the method for embodiment 1, be prepared.
Test case
High temperature storage 14 days under 14 days, 54 ℃ ± 2 ℃ conditions of room temperature storage respectively, adopt < < GB/T14825-2006 agricultural-chemical suspension rate assay method > > to survey suspensibility, concrete data see the following form 2.When suspensibility >85%, think that this product is certified products.
Table 2: agricultural-chemical suspension rate determination data list position: %
| ? | Embodiment 1 | Embodiment 2 | Embodiment 3 |
| After room temperature storage 14 days | 98.7 | 98.1 | 97.6 |
| After high temperature storage 14 days | 98.2 | 97.3 | 96.8 |
Suspension refers to that former powder of dispersion keeps the ability of suspension time length in suspension, represents with suspensibility conventionally.A good suspending agent, should have good storage stability, i.e. higher suspensibility.
Ethyl pleocidin of the present invention and the composite oil-suspending agent of desinsection list, suspensibility is high, plate-out ability and good penetrability, properties of product are stable.
α-[three (phenyl methyl) phenyl]-ω-hydroxyl gathers (Oxy-1,2-ethylidene) non-ionic surface active agent is mainly used in suppressing corrosion and the galvano-cautery in line cutting processing, sludge in softening working groove is used as rust-inhibiting additive in the silk thread of being careful cuts production process.In prior art, there is not any technology enlightenment of this raw material being played to dispersion moistening effect for agricultural chemicals reagent.In the present invention, in a creative way by poly-α-[three (phenyl methyl) phenyl]-ω-hydroxyl that is originally used for rust-inhibiting additive (Oxy-1,2-ethylidene) non-ionic surface active agent is diverted in insecticidal suspending agent, plays dispersion moistening effect.Especially, by composite to cumene sodium sulfonate and poly-(Oxy-1, the 2-ethylidene) non-ionic surface active agent of α-[three (phenyl methyl) phenyl]-ω-hydroxyl, Synergistic, effectively improves suspensibility.
Claims (4)
1. ethyl pleocidin and the composite oil-suspending agent of desinsection list, is characterized in that, comprises the raw material of following weight percentage: ethyl pleocidin 0.5-1.5%; Desinsection list 15-25%.
2. ethyl pleocidin and the composite oil-suspending agent of desinsection list, is characterized in that, consists of: ethyl pleocidin 0.5-1.5% following materials by weight percentage; Desinsection list 15-25%; Surfactant 7-9%; Dibutyl adipate 2-4%; Carbomer 1-3%; Cetanol 0.1-0.3%; Propylben 0.2-0.4%; Surplus is soybean oil.
3. ethyl pleocidin as claimed in claim 2 and the composite oil-suspending agent of desinsection list, it is characterized in that: described surfactant is poly-(Oxy-1, the 2-ethylidene) non-ionic surface active agent of cumene sodium sulfonate and/or α-[three (phenyl methyl) phenyl]-ω-hydroxyl.
4. ethyl pleocidin as claimed in claim 3 and the composite oil-suspending agent of desinsection list, it is characterized in that: described surfactant, by 30-70 weight portion cumene sodium sulfonate and poly-(Oxy-1,2-ethylidene) non-ionic surface active agent composition of 30-70 weight portion α-[three (phenyl methyl) phenyl]-ω-hydroxyl.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410038309.XA CN103734134B (en) | 2014-01-26 | 2014-01-26 | Ethyl pleocidin and the composite oil-suspending agent of Cupric sulfate |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201410038309.XA CN103734134B (en) | 2014-01-26 | 2014-01-26 | Ethyl pleocidin and the composite oil-suspending agent of Cupric sulfate |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103734134A true CN103734134A (en) | 2014-04-23 |
| CN103734134B CN103734134B (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201410038309.XA Active CN103734134B (en) | 2014-01-26 | 2014-01-26 | Ethyl pleocidin and the composite oil-suspending agent of Cupric sulfate |
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Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85108159A (en) * | 1984-11-14 | 1986-05-10 | 亨克尔两合股份公司 | Vaporization stopping agent |
| CN1984562A (en) * | 2004-07-15 | 2007-06-20 | 阿克佐诺贝尔股份有限公司 | Use of phosphated ALCANOLS as dispersants, emulsifiers, hydrotropes, wetting agents and compatability agents in agricultural compositions |
| CN103329902A (en) * | 2013-07-03 | 2013-10-02 | 江苏龙灯化学有限公司 | Insecticidal composition containing spinetoram and monosultap |
-
2014
- 2014-01-26 CN CN201410038309.XA patent/CN103734134B/en active Active
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN85108159A (en) * | 1984-11-14 | 1986-05-10 | 亨克尔两合股份公司 | Vaporization stopping agent |
| CN1984562A (en) * | 2004-07-15 | 2007-06-20 | 阿克佐诺贝尔股份有限公司 | Use of phosphated ALCANOLS as dispersants, emulsifiers, hydrotropes, wetting agents and compatability agents in agricultural compositions |
| CN103329902A (en) * | 2013-07-03 | 2013-10-02 | 江苏龙灯化学有限公司 | Insecticidal composition containing spinetoram and monosultap |
Non-Patent Citations (2)
| Title |
|---|
| 大岛龙吉: "《农药用表面活性剂》", 28 October 1986 * |
| 沈永嘉: "《精细化学品化学》", 30 June 2007, 高等教育出版社 * |
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| Publication number | Publication date |
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| CN103734134B (en) | 2016-04-20 |
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Inventor after: Gu Chunlei Inventor before: Chen Longdi |
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Effective date of registration: 20170908 Address after: 550000, Guiyang, Guiyang province National hi tech Industrial Development Zone (Baiyun District, 340 Baisha Road, 6-11 new green 8-18, Guizhou) Patentee after: Guizhou mission Biological Control Technology Co., Ltd. Address before: 201111 Shanghai city Minhang District Yuanjiang Road No. 5500 building first room E2128 Patentee before: Shanghai Yanzi Chemical Technology Co., Ltd. |
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