CN103709960B - A kind of nail-free glue and preparation method thereof - Google Patents
A kind of nail-free glue and preparation method thereof Download PDFInfo
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- CN103709960B CN103709960B CN201310726150.6A CN201310726150A CN103709960B CN 103709960 B CN103709960 B CN 103709960B CN 201310726150 A CN201310726150 A CN 201310726150A CN 103709960 B CN103709960 B CN 103709960B
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Abstract
The invention discloses a kind of nail-free glue and preparation method thereof, main component is synthetic rubber, thermoplastic styrene butadiene rubber, tackifying resin, flame-retarded resin, filler, antioxidant, fire retardant, organic solvent.Advantage of the present invention is: solid content is high, good environmental protection, not containing " triphen ", halogenated hydrocarbon noxious solvent; Bonding force and flame retardant properties high, formula optimization, adds efficient flame-retarding agent, adopts TRFR high flame retardant height tackifying resin to arrange in pairs or groups mutually with the good synthetic rubber of flame retardant resistance simultaneously, solves the problem adding tackiness agent self-adhesion after fire retardant, viscous force decline mutually; It is good that product executes 1 performance, both ensure that good application property, and give again nail-free glue good flame retardant resistance, easy to use, working efficiency improves greatly.
Description
Technical field
The present invention relates to adhesive area, specifically a kind of nail-free glue with anti-flaming function, and the preparation method of this tackiness agent.
Background technology
Along with the continuous progress of human society, the requirement of people to tackiness agent is also more and more higher, particularly environment protection aspect, and the tackiness agent with advantages such as large arch dam, low volatilization, low toxicities is more and more subject to the favor of people, nail-free glue just one of them.Nail-free glue, also known as liquid nail, there is the features such as adhering speed is fast, intensity is high, applied widely, solid content is high, the shelf lives is long, easy construction, alternative traditional nailing construction technology, easy to use, be widely used in the industries such as decorations, Furniture manufacture, advertisement art, cabinet, five metals.But in the practical applications such as construction and decoration, cabinet advertisement, have again special demand to the flame retardant resistance of tackiness agent, the nail-free glue circulated in the market does not then generally possess fire-retardant feature, have impact on it and promote.
Few about technical study disclosed in nail-free glue.A kind of nail-free glue for architectural decoration disclosed in CN101550320B, use styrene analog thermoplastic elastomer, modified rosin, petroleum resin, solvent, filler volatile organic content low, technique is simple, and bounding force is extremely strong, is applicable to most of building and ornament materials.But the materials such as styrene analog thermoplastic elastomer used all do not possess flame retardant resistance.
As can be seen here, develop a kind of nail-free glue with anti-flaming function and there is very large practicality and necessity.
Summary of the invention
The object of the invention is, in order to overcome technological deficiency recited above, to provide a kind of nail-free glue with anti-flaming function, also provide the preparation method of above-mentioned nail-free glue simultaneously.
A kind of nail-free glue of the present invention is achieved in that its formula proportioning is:
Described synthetic rubber is at least one in epichlorohydrin rubber, chlorosulfonated polyethylene, chloroprene rubber;
Described tackifying resin is at least one in ester gum, terpine resin, petroleum resin, staybelite;
Described flame-retarded resin is TRFR high flame retardant height tackifying resin;
Described filler is at least one in polynite, silicon-dioxide, calcium carbonate;
Described antioxidant is at least one in antioxidant 1010, antioxidant 264;
Described fire retardant is organic silicon fibre retardant HRJC-SFR100, DOW
fCA-107, SFRDC8008,
at least one of SFR-M-1201/1202, FRX-210/100;
Described fire retardant can also be expansion type flame retardant ExolitIFR-10, Exo1itIFR-11,
At least one in SpinflamMF82;
Described organic solvent is at least one in methylcyclopentane, industrial naptha, ethyl acetate, methylcarbonate, acetone.
The preparation method of described nail-free glue, comprises the following steps:
By formulation weight part proportioning, organic solvent is added in reactor, under whipped state, add synthetic rubber, thermoplastic styrene butadiene rubber, tackifying resin, flame-retarded resin, antioxidant, to dissolving completely, adding filler and fire retardant, stirring, obtaining nail-free glue.
A kind of nail-free glue tool of the present invention has the following advantages:
1. solid content is high, good environmental protection, not containing " triphen ", halogenated hydrocarbon noxious solvent;
2. bonding force and flame retardant properties high, formula optimization, adds efficient flame-retarding agent, adopts TRFR high flame retardant height tackifying resin to arrange in pairs or groups mutually with the good synthetic rubber of flame retardant resistance simultaneously, solves the problem adding tackiness agent self-adhesion after fire retardant, viscous force decline mutually;
3. product has good workability, and both ensure that good application property, and give again nail-free glue good flame retardant resistance, easy to use, working efficiency improves greatly.
Embodiment
The present invention will be described for following examples, but the present invention is not limited to these examples system.Modify to the specific embodiment of the present invention or carry out equivalent replacement to portion of techniques feature, and not departing from the spirit of the present invention program, it all should be encompassed in the middle of the technical scheme scope of request of the present invention protection.
Embodiment 1
1. by formulation weight part proportioning, methylcyclopentane 15 parts, ethyl acetate 10 parts, 5 parts, acetone are added in reactor, under whipped state, add epichlorohydrin rubber 2 parts, thermoplastic styrene butadiene rubber 25 parts, ester gum 10 parts, TRFR high flame retardant height tackifying resin 10 parts, antioxidant 1010 0.2 part, to dissolving completely, add polynite 30 parts and HRJC-SFR1000.5 part, stir, obtain nail-free glue.
Embodiment 2
By formulation weight part proportioning, industrial naptha 10 parts, ethyl acetate 5 parts, 5 parts, acetone are added in reactor, under whipped state, add chlorosulfonated polyethylene 10 parts, thermoplastic styrene butadiene rubber 15 parts, terpine resin 15 parts, TRFR high flame retardant height tackifying resin 8 parts, antioxidant 1010 1 part, to dissolving completely, add silicon-dioxide 20 parts and DOW
fCA-1071.5 part, stirs, and obtains nail-free glue.
Embodiment 3
By formulation weight part proportioning, industrial naptha 6 parts, methylcarbonate 2 parts, 2 parts, acetone are added in reactor, under whipped state, add chloroprene rubber 15 parts, thermoplastic styrene butadiene rubber 10 parts, petroleum resin 20 parts, TRFR high flame retardant height tackifying resin 5 parts, antioxidant 2641.8 parts, to dissolving completely, add 10 parts, calcium carbonate and SFRDC80082.5 part, stir, obtain nail-free glue.
Comparative example 4
By formulation weight part proportioning, methylcyclopentane 15 parts, methylcarbonate 10 parts, 5 parts, acetone are added in reactor, under whipped state, add thermoplastic styrene butadiene rubber 25 parts, petroleum resin 10 parts, antioxidant 2640.2 parts, to dissolving completely, add 30 parts, calcium carbonate, stir, obtain nail-free glue.
The correlated performance of the nail-free glue of embodiment 1 ~ 3, comparative example 4 adopts following methods test:
1. the mensuration of non-volatile content: measure according to the mensuration of standard GB/T2793-1995 tackiness agent non-volatile content.
2. the mensuration of initial adhesive strength and tensile shear strength: get 2.5cm × 2.5cm birch plate 2 pieces, take glue and be about 0.05g, is spread evenly across one end 2.5cm × 2.0cm of smooth front plate, another block is not coated with, after being overlapped by two boards, be placed in the fixture of fixation pressure, room temperature places 5min.Pressure relief, ambient temperatare sets to 0 .5h, carries out initial adhesive strength test with puller system; After sample is at room temperature placed 24h, carry out tensile shear strength test with puller system.
3. flame retardant resistance measures: measure according to the mensuration Using Horizontal Bridgman Method of standard GB/T2408-2008 Plastics Combustion performance and normal beam technique.
The correlated performance test result of a kind of nail-free glue of embodiment 1 ~ 3, comparative example 4 gained is as shown in table 1 below.
Table 1
As can be seen from the above table, a kind of nail-free glue of the present invention is compared with prior art (comparative example 4), and adhesiveproperties is good, excellent fireproof performance.
Main raw title, technical indicator
1. epichlorohydrin rubber, chlorosulfonated polyethylene, chloroprene rubber, thermoplastic styrene butadiene rubber, commercially available, technical grade;
2. ester gum, terpine resin, petroleum resin, staybelite, commercially available, technical grade;
3.TRFR high flame retardant height tackifying resin
Supplier: Qingdao Haijia Additives Co., Ltd.;
4. polynite, silicon-dioxide, calcium carbonate, commercially available, technical grade;
5. antioxidant 1010, antioxidant 264, commercially available, technical grade;
6.HRJC-SFR100
Supplier: the long-range Science and Technology Ltd. in Chinese and Western, Beijing;
7.DOW
FCA-107
Supplier: Dongguan City Su Bang plastic material company limited;
8.SFRDC8008、
SFR-M-1201／1202、FRX-210／100
Supplier: Shanghai Guang Bin trade Co., Ltd;
9.Ex01itIFR-10、Ex01itIFR-11
Supplier: HoeehstCe1anese company of the U.S.;
10.SpinflamMF82
Supplier: Italian Montef1uos company;
11. methylcyclopentanes, industrial naptha, ethyl acetate, methylcarbonate, acetone, commercially available, technical grade.
Claims (2)
1. a nail-free glue, is characterized in that, each component comprises by weight ratio:
Synthetic rubber 2 ~ 15 parts
Thermoplastic styrene butadiene rubber 10 ~ 25 parts
Tackifying resin 10 ~ 20 parts
Flame-retarded resin 5 ~ 10 parts
Filler 10 ~ 30 parts
Antioxidant 0.2 ~ 1.8 part
Fire retardant 0.5 ~ 2.5 part
Organic solvent 10 ~ 30 parts;
Wherein, synthetic rubber is at least one in epichlorohydrin rubber, chlorosulfonated polyethylene, chloroprene rubber; Tackifying resin is at least one in ester gum, terpine resin, petroleum resin, staybelite; Flame-retarded resin is TRFR high flame retardant height tackifying resin; Filler is at least one in polynite, silicon-dioxide, calcium carbonate; Antioxidant is at least one in antioxidant 1010, antioxidant 264; Fire retardant is at least one in organic silicon fibre retardant HRJC-SFR100, DOWCORNING FCA-107, SFRDC8008, Dymgard SFR-M-1201/1202, FRX-210/100, or is at least one in expansion type flame retardant ExolitIFR-10, ExolitIFR-11, SpinflamMF82; Organic solvent is at least one in methylcyclopentane, industrial naptha, ethyl acetate, methylcarbonate, acetone.
2. the preparation method of a kind of nail-free glue as claimed in claim 1, it is characterized in that, comprise the following steps: by formulation weight part proportioning, organic solvent is added in reactor, under whipped state, add synthetic rubber, thermoplastic styrene butadiene rubber, tackifying resin, flame-retarded resin, antioxidant, to dissolving completely, add filler and fire retardant, stir, obtain nail-free glue.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310726150.6A CN103709960B (en) | 2013-12-21 | 2013-12-21 | A kind of nail-free glue and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310726150.6A CN103709960B (en) | 2013-12-21 | 2013-12-21 | A kind of nail-free glue and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN103709960A CN103709960A (en) | 2014-04-09 |
| CN103709960B true CN103709960B (en) | 2015-11-25 |
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Families Citing this family (13)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104087200A (en) * | 2014-07-01 | 2014-10-08 | 中科院广州化学有限公司南雄材料生产基地 | Triphenyl-free chloroprene rubber adhesive and preparation method thereof |
| CN104178058A (en) * | 2014-09-05 | 2014-12-03 | 无锡欧易博阀业科技有限公司 | Environment-friendly adhesive |
| CN104449523B (en) * | 2014-12-31 | 2016-03-30 | 广州市白云化工实业有限公司 | Environment-friendly type nail-free glue and preparation method thereof |
| CN105238296A (en) * | 2015-09-21 | 2016-01-13 | 太仓市金锚新材料科技有限公司 | Novel environmentally-friendly all-purpose adhesive and preparation method thereof |
| CN106244103B (en) * | 2016-08-15 | 2018-02-06 | 广东三和化工科技有限公司 | A kind of glue spraying and preparation method thereof |
| CN108314976A (en) * | 2017-01-17 | 2018-07-24 | 南宝树脂化学工厂股份有限公司 | One kind low VOC nail-free glues for building and preparation method thereof |
| CN109702847A (en) * | 2017-10-26 | 2019-05-03 | 江苏凤凰木业有限公司 | A kind of flame retardant type composite wood |
| CN108192528A (en) * | 2017-11-23 | 2018-06-22 | 吉安迅达科技有限公司 | A kind of environmental protection one side glue and preparation method thereof |
| CN108424747A (en) * | 2018-04-08 | 2018-08-21 | 吴亚琴 | A kind of high preparation method for gluing low temperature resistant nail-free glue |
| CN112409958A (en) * | 2019-08-20 | 2021-02-26 | 广东顺德三和化工有限公司 | Aqueous flame-retardant liquid sealant and preparation method thereof |
| CN112409954A (en) * | 2019-08-20 | 2021-02-26 | 广东顺德三和化工有限公司 | Nail-free glue and preparation method thereof |
| CN112409955A (en) * | 2019-08-20 | 2021-02-26 | 广东顺德三和化工有限公司 | Nail-free glue and preparation method thereof |
| CN112409953A (en) * | 2019-08-20 | 2021-02-26 | 广东顺德三和化工有限公司 | Weather-resistant nail-free glue and preparation method thereof |
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| CN101402845A (en) * | 2008-11-11 | 2009-04-08 | 北京市化学工业研究院 | Process for producing flame-proof fluid sealant for construction |
| CN101550320A (en) * | 2009-05-21 | 2009-10-07 | 广州新展有机硅有限公司 | Nail-free glue for architectural decoration |
| CN102850964A (en) * | 2011-07-01 | 2013-01-02 | 上海渊信建筑材料有限公司 | Butyl sealant for flame-retardant hollow glass, and its preparation method |
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