CN103702959B - Can be used for building and the mixture based on volcanic rock granule decorated, laminated product and plate and preparation method thereof - Google Patents
Can be used for building and the mixture based on volcanic rock granule decorated, laminated product and plate and preparation method thereof Download PDFInfo
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- CN103702959B CN103702959B CN201180070191.3A CN201180070191A CN103702959B CN 103702959 B CN103702959 B CN 103702959B CN 201180070191 A CN201180070191 A CN 201180070191A CN 103702959 B CN103702959 B CN 103702959B
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- C—CHEMISTRY; METALLURGY
- C04—CEMENTS; CONCRETE; ARTIFICIAL STONE; CERAMICS; REFRACTORIES
- C04B—LIME, MAGNESIA; SLAG; CEMENTS; COMPOSITIONS THEREOF, e.g. MORTARS, CONCRETE OR LIKE BUILDING MATERIALS; ARTIFICIAL STONE; CERAMICS; REFRACTORIES; TREATMENT OF NATURAL STONE
- C04B26/00—Compositions of mortars, concrete or artificial stone, containing only organic binders, e.g. polymer or resin concrete
- C04B26/02—Macromolecular compounds
- C04B26/04—Macromolecular compounds obtained by reactions only involving carbon-to-carbon unsaturated bonds
- C04B26/06—Acrylates
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B7/00—Layered products characterised by the relation between layers; Layered products characterised by the relative orientation of features between layers, or by the relative values of a measurable parameter between layers, i.e. products comprising layers having different physical, chemical or physicochemical properties; Layered products characterised by the interconnection of layers
- B32B7/04—Interconnection of layers
- B32B7/12—Interconnection of layers using interposed adhesives or interposed materials with bonding properties
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/002—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising natural stone or artificial stone
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B9/00—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00
- B32B9/04—Layered products comprising a layer of a particular substance not covered by groups B32B11/00 - B32B29/00 comprising such particular substance as the main or only constituent of a layer, which is next to another layer of the same or of a different material
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D1/00—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances
- C09D1/02—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates
- C09D1/04—Coating compositions, e.g. paints, varnishes or lacquers, based on inorganic substances alkali metal silicates with organic additives
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D5/00—Coating compositions, e.g. paints, varnishes or lacquers, characterised by their physical nature or the effects produced; Filling pastes
- C09D5/02—Emulsion paints including aerosols
- C09D5/024—Emulsion paints including aerosols characterised by the additives
- C09D5/028—Pigments; Filters
-
- C—CHEMISTRY; METALLURGY
- C09—DYES; PAINTS; POLISHES; NATURAL RESINS; ADHESIVES; COMPOSITIONS NOT OTHERWISE PROVIDED FOR; APPLICATIONS OF MATERIALS NOT OTHERWISE PROVIDED FOR
- C09D—COATING COMPOSITIONS, e.g. PAINTS, VARNISHES OR LACQUERS; FILLING PASTES; CHEMICAL PAINT OR INK REMOVERS; INKS; CORRECTING FLUIDS; WOODSTAINS; PASTES OR SOLIDS FOR COLOURING OR PRINTING; USE OF MATERIALS THEREFOR
- C09D7/00—Features of coating compositions, not provided for in group C09D5/00; Processes for incorporating ingredients in coating compositions
- C09D7/40—Additives
- C09D7/60—Additives non-macromolecular
- C09D7/61—Additives non-macromolecular inorganic
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2307/00—Properties of the layers or laminate
- B32B2307/70—Other properties
- B32B2307/726—Permeability to liquids, absorption
- B32B2307/7265—Non-permeable
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2419/00—Buildings or parts thereof
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B32—LAYERED PRODUCTS
- B32B—LAYERED PRODUCTS, i.e. PRODUCTS BUILT-UP OF STRATA OF FLAT OR NON-FLAT, e.g. CELLULAR OR HONEYCOMB, FORM
- B32B2451/00—Decorative or ornamental articles
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Ceramic Engineering (AREA)
- Life Sciences & Earth Sciences (AREA)
- Wood Science & Technology (AREA)
- Inorganic Chemistry (AREA)
- Structural Engineering (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Dispersion Chemistry (AREA)
- Finishing Walls (AREA)
- Adhesives Or Adhesive Processes (AREA)
- Curing Cements, Concrete, And Artificial Stone (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The present invention relates to for the mixture that sliver is manufactured on solid substrate, for decorative purpose.This mixture includes the binding compositions of agglutinant, described agglutinant comprises volcanic rock granule and the polymeric blends that granular size is 1 micron to 5 microns, and the combined amount of described volcanic rock granule and polymeric blends be enough to play the effect of the binding agent of other compositions of flaggy；Present in an amount at least sufficient to the silicate compound stablizing described compositionss；With make compositionss moisten and fluidisation amount water.Described mixture can contain for forming the other compositions of flaggy or shape, and can be formed as can be used for building and the plate of decorative architecture thing or onboard formed, and described plate is made up of the sliver manufacturing and solid substrate with said mixture.The invention also discloses for preparing said mixture and can be used for building the method with the surface plate of decorative architecture.
Description
The technical field of the present invention
The present invention relates to technical field, the finishing especially with respect to building and the decoration of building and decoration, because it is
Sliver and the mixture of plate, can be used for building finishing and the decoration of surface and other objects.The invention still further relates to its manufacture method.
These products are obtained by volcanic rock granule.
Background of invention
Because it is very attractive in appearance and the fact that due to can easily be carved and be cut by people, volcanic rock (volcanic
Rocks) it is always the material of high value.This makes them, and supply falls short of demand, and its use in modern architecture has become
More expensive, hence in so that they become the luxury items being served only in luxurious building.These rocks are also referred to as igneous rock or broken
Bits igneous rock, for example, by the rock constituting from the fragment shape volcano product of volcanic eruption in Breakout events.
Mexican Soil erosion is partly due to stone pit exploitation and amounts to what 718,000,000 tons of volcanic rock caused, its
In border, caused environmental pollution (INEGI, the economic and ecological system more than 37,000,000 tons of useless solid residues
Meter, 2004).
Known several sheet material with natural stone appearance, but these are Counterfeit Item：Touch when us, smelling and observation
They when, the fact that they are not rocks become obvious.These slabstones are generally used for time in order to save installation and cost
In the building that the major part of purpose is made up of pre-cast building material.
In this classification, also there is aluminum, polystyrene and the other materials plate with natural rock covering, with respect to it
Weight and their plate of support, it is with limited acquiring size that described natural rock covers.These rocks are using the glue of synthesis
Stick adheres to onboard, therefore prepares their manufacture method and has very high cost, and limited by their overall dimensions
In the size of the rock obtaining them, so that described sheet material and manufacture method are restricted in terms of size and shape.
There is thousands of years in natural volcano rock beam, their most important shortcomings are their weight, thus are difficult to transport
With lay.It is generally relatively more frangible when the sheet material that natural volcanic rock obtains is in operation：Vibrations or collision can make it rupture.Due to this
Individual reason, they must be made and be thick enough that they can more firm and cracking resistance.When placing them on wall, this
A little sheet materials generally have huge weight, and this makes it difficult to or can not possibly be in the case of not causing its own or the damage of wall
Install.The wall that they are laid thereon must be solid enough and firm, the weight can support sheet material.Even if so, by
The constant impingement producing when laying, these sheet materials yet suffer from the risk rupturing.
Due to above-mentioned not convenient property, need to can be used for decoration and the improvement rock panel based on volcanic rock granule, and this
Invention now provided with these rock panel and its formula and manufacture method.
Summary of the invention
The present invention relates to various binding compositions and mixture, it is used for being formed as Architectural Construction or is used for Architectural Construction
In product.
In one embodiment, the present invention relates to being used for manufacturing the binding compositions of laminated product, it comprises agglutinant,
Described agglutinant comprises volcanic rock granule and the polymeric blends that granularity is 1 micron to 5 microns, and a combination thereof amount be enough to as use
Binding agent in the other compositions of laminated product；Present in an amount at least sufficient to the silicate compound stablizing described compositionss；With make described group
Compound moisten and fluidisation amount water.
In this binding compositions, volcanic rock granule is existed with 25% to 50% amount；Polymeric blends are with 10%
Amount to 40% exists；Existed with 1% to 10% amount with silicate, described amount is the weight based on dry composition.By water plus
Enter so that described compositionss can be combined with other materials to form the mixture for manufacturing laminated product.Described mixture
Comprise the implant of the solid particulate materials of described binding compositions and rock, plastics, glass, timber, metal or mineral.
Another embodiment relates to manufacture the preferred mixture of laminated product, and it comprises with higher than mixture 50%
Amount exist a diameter of 1 micron volcanic rock granule to 3mm；Agglutinant containing polymeric blends, described polymer mixes
The amount of compound is enough to act as the binding agent of rock particles；Present in an amount at least sufficient to the silicate compound stablizing described mixture；With make to mix
Compound moisten and fluidisation amount water.
Described rock particles is advantageously existed with about the 58% to 88% of mixture amount, and rock particles is with multiple
Different grain size level (size fraction) exists, including the granularity with 1 micron to 5 microns and with mixture weight
The first particle size fraction that 18% to 28% amount exists；There is the granularity and with mixture weight 10% of 0.25mm to 1.75mm
The second particle size fraction that amount to 20% exists；With the granularity with 2mm to 5mm and with the 30% to 40% of mixture weight
The 3rd particle size fraction that amount exists.
Described agglutinant is preferably emulsifying, and is existed with the 8% to 25% of mixture weight amount.This reagent comprises
Weight is than for 1: 4 to 3: 2, preferably 1: 1 to 2: 3 water dispersible block copolymer and polyvinyl.Water-dispersable polymeric
Thing powder comprises the block copolymer of the amount of the 4% to 10% of mixture weight；With the 4% to 15% of mixture weight amount
Polyvinyl.
Preferably block copolymer is butyl acrylate and styrol copolymer, and described ethylenic copolymer comprises with mixed
Vinyl acrylic copolymers (vinyl acrylic co-polymer) that the amount of about the 3% to 10% of polymer weight exists and
The combination of the polyvinyl acetate base ester resin being existed with about the 1% to 5% of mixture weight amount.
Described mixture also includes silicate compound to improve the stability of mixture.This compound is preferably mixture
The hydrated magnesium silicate of the amount of about the 1% to 5% of weight.Silicate compound can also be Kaolin, for example, Al2Si2O5
(OH)4.
The water that described mixture includes the amount to 30 weight % for about 15 weight % is beneficial to process and the mixing of composition.
The invention still further relates to by one of these mixture being formed desired shape and making the mixing of shaping
The product that thing is dried and prepares.Its form can include thering is the outer surface being polished to desired finish (finish)
Piece, plate, tile, post or bundle.The finished product of polishing can also be processed using sealant.Described product can include metal, glass, wood
Material or fibrous reinforcement, or can be provided on the matrix of plastics, timber, metal, inorganic mineral, pottery or concrete, described
Matrix optionally contains for fixing described product in ground or architectural adhesive.Described product can be prepared into building or
The internal or external structure member of other structures.
Another embodiment of the invention is related to prepare the method for mixture, including every kilogram of volcanic rock granule of offer about
Mixture is simultaneously homogenized by the water of 0.1 to 0.4 liter of amount.Agglutinant is preferably emulsifying, and described mixture with 500 to
Homogenize 30 to 120 minutes in the conventional mixer that 1000rpm runs.
The mixture homogenizing can be made various different products.The present invention includes forming the side of decoration rock product
Method, including forming desired shape by the mixture homogenizing and so that the mixture of shaping is dried.Can by casting or
The described mixture homogenizing is formed desired shape by molding.Generally, the mixture being dried is polished to desired essence
Whole degree, optionally subsequently applies sealant.The method also includes shaping the mixture homogenizing on matrix；Mixed by be dried
Compound is polished to desired finish；And optionally to matrix provide adhesive with by product be fixed on ground, wall or
On the side of structure.This material can be also used for forming those parts of structure.
Brief description
In the following description, and in form and accompanying drawing, clearly illustrate characterize for building and decoration based on fire
The mixture of mountain rock granule, sliver and plate, and the detailed content of the manufacture method of the present invention, wherein：
Fig. 1 is compared with commercially available prod, illustrates the figure of the weight of the plate of the present invention.
Fig. 2 illustrates the performance of the heat conductivity between the plate of the present invention and some commercially available prod.
Fig. 3 shows the plate of the present invention resistance to hydrochloric acid and some commercially available prod.
Fig. 4 illustrates the set-up time of the plate of the present invention compared with some other commercially available prod.
Detailed Description Of The Invention
The invention provides using the ornamental value attractive in appearance and high of volcanic rock (that is, igneous rock or chip igneous rock), and
The product that the waste that the volcanic rock deposit finding in the finite region in the world produces is obtained.When exploiting these deposits,
Due to 100% utilization the fact that the volcanic rock of taking-up, substantial amounts of volcanic rock waste can not be created, and formed from deposit
Big environmental pollution.
The present invention recycles this volcanic rock waste product now to form new He useful rock panel product.These produce
Product make use of and obtain the waste producing during bulk volcanic rock to form the artificial volcano having with natural volcano rock beam same characteristic features
Rock beam, thus these wastes are changed into the volcano rock beam replacing 100% natural volcano rock beam, and except specifically described herein
Beyond other attributes, also have the advantages that not producing and pollute and lighter.
The plate of the present invention has multiple desired features.They have and natural volcanic rock stone or large rock mass
(dimensional rock) identical outward appearance, quality, color and abnormal smells from the patient, but they are light at least 50% than natural volcano rock beam.
Due to employing the volcanic rock with this property, they go back acid rain resistant (hydrochloric acid, sulphuric acid and nitric acid).Their uvioresistants and
Can be used for shielding these rays in expectation.Described plate is functional, can be easily and quickly installed and make in advance any
Make or traditional element on.
The present invention relates to can be used for building and the mixture of the sliver in solid substrate decorated for preparation, described
Mixture is preferably by volcanic rock granule, ethylene-propylene acid copolymer, polyvinyl acetate base ester resin, butyl acrylate and benzene
Ethylene copolymer, hydrated magnesium silicate and water are formed.
The invention still further relates to by said mixture be obtained for ostentatious flag.Another embodiment is related to use
In the plate built and for decorative architecture thing, it includes above-mentioned Rock laminate and solid substrate.
Additionally, including i) mixing in a usual manner different volcanic rock for preparing the ad hoc approach of said mixture
Grain；Ii) with volcanic rock granule described in every 1 liter of water-wet of 4kg volcanic rock granule；Iii whole vinyl-acrylic) are added altogether
Polymers, polyvinyl acetate base ester resin, butyl acrylate and styrol copolymer, and hydrated magnesium silicate, and iv) with routine not
Rust steel reinforced concrete clutch prepared uniform mixture with 30 to 120 minutes under 500 to 1000rpm.
Present invention additionally comprises for the ad hoc approach preparing above-mentioned plate, methods described includes：I) delimit in solid substrate
The region that sliver will be laid, for this purpose it is proposed, provide perimeter edge in solid substrate；Ii) in an uniform manner by step 1,
2nd, the mixture described in 3 and 4 is added on the region of previous stage delimitation, until the region in perimeter edge is capped；
Iii mixture) is made to open wide the time being dried 24 to 72 hours；Iv) according to styles of dressing：Coarse or smooth, use diamond cup
(diamond cup) roughly grinds this plate；V) wash all residues of laminate, preferably pass through vacuum cleaned；Vi) on this piece
Apply one layer of waterproof seal agent and vii) make waterproof seal agent open wide dry 3 hours.In order to quickly solidify, it is possible to use
Heat or the energy of other forms, such as microwave, to be dried described material.
Embodiment
Following examples show the binding compositions how preparing the present invention and mixture to prepare various products.
The present invention is from the beginning of the volcanic rock granule available from waste, and is tested to find volcanic rock granule and coagulation
The best of breed of agent.Agglutinant is typically the copolymer of commercial distribution in the form of emulsion and resin.Also carry out moistening using water
Described granule, and the volume of mixture is supplied with the ratio of 1 liter of water of every 4 kilograms of granules.Result is shown in table 1.
As seen in Table 1, these tests show higher plasticity and shorter drying time by being given
With there is no obvious crack, the best of breed of agglutinant is butyl acrylate and styrene+polyvinyl acetate base ester resin+ethylene
The combination of base-acrylic copolymer.Find that acceptable drying time the shortest is 72 hours, because finding do not have agglutinant to provide
It is shorter than the drying time of 72 hours.
Table 1
Performance from the mixing of volcanic rock granule several different agglutinants
Plasticity is measured with the scoring of 0-10, and wherein highest value represents high-ductility.
Once finding the best of breed of agglutinant, then determine optimised quantity or the concentration of every kind of component by other test.
The experiment carrying out for this purpose uses different amounts of each component until determining optimal dose.The result of these tests is shown in
In table 2.
The water proofing property higher in order to give this mixture, adds other components, particularly alkaline hydrosilicate, such as
Hydrated magnesium silicate or Kaolin, to provide the colloidal mixt similar to slag, but have adhesion at room temperature and melt
Performance in any material, and having when being dried and natural volcanic rock identical physical features, therefore its can tolerate with
Natural large rock mass identical finishing.
When analyzing the dosage of different components of discussed mixture, find to combine when all copolymers of 10-40%
When silicate and water are used together, the granule/separation every square centimeter of significant quantity, optimum range is 1% to 10%, except water
(its corresponding scope is 1% to 20%).
By copolymer and hydrated magnesium silicate so that, during more than 40% use, the outward appearance of piece is undesirable, because those of excess add
Plus agent makes embossed (relief) of volcanic rock granule to disappear.These dosage are not preferred for decorative purpose, although gained
To plate present good hardness.These plates can be used in other application, such as expects wearability or wear resistence but does not need
In the case of decorative appearance.
Table 2
The performance of the various dose of constituents of a mixture is provided
The detached granule of PD-.Outward appearance based on 1 to 5 Scoring System, wherein higher value corresponds to more preferably outward appearance；Hardness
Based on 1 to 10 Scoring System.
It is found that copolymer can be mixed with water (referring to table 3), and contain available from the thin volcanic rock powder end of crushed rock
Inorganic bond (inorganic functional mineral), it, when being mixed with water and butyl acrylate and styrol copolymer, be there occurs
Change, this makes it have higher cohesiveness, adhesiveness and pliability.Using this combination, substrate plate can be with natural volcano
Rock stratum is pressed, but when they are dried, defines crack in piece, leads to this piece to have low wearability and water proofing property.Therefore, gather
When resin in vinyl-acetic ester emulsion is added together with ethylene-propylene acid copolymer, improve the stability of mixture,
Which thereby enhance its adhesiveness, wearability and water proofing property.Therefore, obtained plate does not present rupture or crack.
Table 3
The percentage ratio of the inorganic bond of different volcanic rock granules
As seen in table 3, find that the best of breed of volcanic rock granule is 1mm to 3mm or the group of 3mm+1mm+3 micron
Close.Additionally, the combination of 2mm+1mm+2 micron and+1 micron or 1mm to 5mm+0.25mm of 1mm+5 micron are to 1.75mm+2mm extremely
The combination of 5mm also shows that excellent result, is therefore also contemplated for these combinations in the present invention.However, it is specific for any one
Formula, adhesion to be considered and outward appearance are to determine optimum mixture.Generally, to obtain by using less granularity higher
Bonding, and be based on rupture or crack (evaporation of gas in mixture in solidification process) do not exist and obtained with
The similarity of undressed stone is judging outward appearance.It has to be noticed that too many little particle produces crack, and larger granular size is assigned
Give finished product with natural appearance.
Using preferred mixture disclosed herein, solid substrate is laminated, and carried out several test after,
Determine that following method is optimal：I) delimit, in solid substrate, the area boundary that sliver will be laid, for this purpose it is proposed, solid
Perimeter edge is provided on body substrate；Ii) in an uniform manner the mixture described in 1,2,3 and 4 was added in previous stage
On the region delimited, until the region in perimeter edge is capped；Iii mixture) is made to open wide the time being dried 24 to 72 hours；
Iv) according to desired styles of dressing：Coarse or smooth, roughly grind described plate with diamond cup；V) wash all residual of laminate
Stay thing, preferably pass through vacuum cleaned；Vi) one layer of waterproof seal agent and vii are applied on piece) make waterproof seal agent unlimited dry
Dry 3 hours.Described perimeter edge can be rigid strip or lath, and it depends highly on desired sliver thickness.
The method preparing the mixture for manufacturing the sliver with volcanic rock outward appearance comprises the following steps：
I) the variable grain mixing of the part of volcanic rock granule will be formed in a usual manner.
Ii) with volcanic rock granule part described in every 1 liter of water-wet of 4kg volcanic rock granule.
Iii) all of ethylene-propylene acid copolymer, polyvinyl acetate base ester resin, butyl acrylate and benzene second are added
Alkene copolymer, and hydrated magnesium silicate, and
Iv) with conventional stainless steel blender mixing, mix 30 to 120 minutes preferably under 500rpm to 1000rpm.
Those skilled in the art will know that these preferred conditions can be according to specific formula and end article to be prepared
To change as required.For example, it is possible to the speed homogenizing and time are changed according to the final component of mixture, and these
Composition can be dividedly in some parts according to the size of product to be prepared or disposably all add.Described agglutinant preferably with other
Carry out emulsifying before component mixing.Additionally, mixture set the drying of final curing condition or hardening time can be according to phase
The water yield of other constituents ratio interpolation is changed.
The mixture being obtained is substantially similar to cold slag, and it has adhesion and is melted in the spy in any material
Property.After drying, it has and natural volcanic rock identical hardness and physical features, and therefore we can apply identical to it and repair
Whole process.Importantly, the 90% of formula is derived from natural product.
Therefore, present invention additionally comprises can be used for the plate of decorative architecture surface and other body surfaces, wherein such stone
Plate includes the sliver being obtained with the mixture having been described above.
The plate that method shown in present patent application obtains is preferably in modern construction engineering using the solution of natural rock
Certainly method, due to its overall dimensions, weight and structure, the tradition that modern construction engineering always can not be obtained by natural volcanic rock
Plate cover because the weight of natural volcano rock beam and certain altitude place limiting factor.
This plate internal characteristicses become has the product neutralizing the many applications for decoration in building industry.This plate
There are all advantages (color never changes, and has outward appearance, abnormal smells from the patient and the quality of natural rock) of natural large rock mass, and do not have
Have the defect of weight aspect because it is light product (weight saving is up to 70%), and may serve as building,
The facade of shopping center, school, hospital and house.As decorative element, it can be used for indoor and outdoors metope, with
And it is used for ceiling rose.It can be used for an unbounded quantity of purpose, and its unique restriction is exactly to imagine.For being laminated described plate
Mixture allow us to apply colloidal mixture, rather than must using the net for adhesion, and when it is dried,
Rock is melted together with the material of plate used, forms the cohesion of uniqueness.Made it appear to as with diamond disk with diamond cup corase grind
Polished decoration large rock mass.
The kind of the lamination that onboard can obtain is natural equal to find in the different volcanic rock deposit in the whole world
The type of rock and the scope of color.
The advantage further describing plate described herein below along with accompanying drawing together, may certify that normal by any one
Rule product can not obtain such result.Especially, the weight of plate is lower by 70% than be obtained by individually natural volcanic rock.Outside it
Sight, quality, color and abnormal smells from the patient are identical with the plate being only obtained with natural rock.The plate of the present invention has pliability and provides absolutely
The ability that heat, acid-resisting, heat-resisting quantity, water proofing property, the effect of antibacterium, funguses and other moist associated biomolecules and uv-resistant are irradiated
(that is, its color never changes).This plate can be also used for providing sound insulation, and it provides in any kind of heavy or lightweight
Easily and rapidly installation on material.
These volcano rock stratum pressing plates just may serve as the building of building, shopping center, school, hospital and house
Face.As decorative element, it can be used for indoor and outdoors metope, and is used for ceiling rose.It can be used for infinitely
The purpose of amount, unique restriction is exactly to imagine.One of advantage of their maximums is to be easily installed, because they can be with identical
Simplicity is arranged on indoor and outdoors with by using the identical common skeleton and screw for installing plasterboard.For outdoor
Purposes, they can be easily installed as cement plate, and can use identical common skeleton and spiral shell for cement plate
Adjusting screw.In the case of soffit, they can be easily installed as common soffit and use identical to be used for its installation
Conventional system.
These plates have other advantages better than solid slabstone：They directly can be glued with screw, adhesive agent or mortar
Invest on metope rather than framework must be used.They can be also used for preparing furniture and decorative article, such as desk and workbench
Face.
It is important to emphasize that following facts：The mixture of as described before can apply to solid objects surface (e.g., container,
Bottle, box or any other surface of solids) to decorate them.In order to carry out this application, described surface must be simply clear
Clean mistake, then applies mixture by directly contact, and it then must be made to be dried and subsequently it be roughly ground.Washing institute from it
After the dust producing, add waterproof seal agent, and complete the decoration of object with rock laminated product.
Because final product and product are preferably rock building, they can act as load-bearing or structure in Architectural Construction
Element.As required mixture can be reinforced for these applications.Binding compositions disclosed herein can also be used
With the filler of other solid particulate materials in addition to rock, and remain able to prepare product and laminated product.Close
Suitable replacement packing material includes plastics, timber, glass, metal or mineral.These packing materials can be any selected big
Little, so that product or laminated product are provided with aesthetics or function outward appearance or structure.
Binding compositions are formed by the component that can combine to be maintained at described filler in the dense product of solid, institute
The dense product stating solid can form desired product as the succedaneum of rock laminated product specifically described herein.Especially
Ground, binding compositions make use of the volcanic rock granule of relatively small granularity with 1 to 5 micron and the group of polymeric blends
Close, the combined amount of the binding agent of its other component for use as laminate layers plays a role together.Based on dry adhesive composition
To determine the amount of these components, and volcanic rock granule is existed with 25% to 50% amount, and polymeric blends with 10% to
40% amount exists.Any polymeric blends for mixture specifically described herein can be used for adhesive composition
In.Another component of adhesive composition is the silicate of type specifically described herein, and to be used with 1% to 10% amount with
Stable adhesive compositions.By these components with so that compositionss is moistened and fluidisation the water of amount mix.Then, will glue
Mixture composite is combined together with packing material.Generally, by the binding agent of about 40 weight % to 60 weight % and about 40 weights
The filler of amount % to 60 weight % mixes to form mixture, and described mixture then can be with mixing with the rock of the present invention
Thing identical mode is used for forming laminated product or other products.
Obtained product can change according to the expectation of user, and they can make in a number of different manners
With.Mixture itself can be cast on the ground of structure, and so that it is dried, then polishing and sealing obtain final quality or
Finish.Can be by mixture be put on to form tile and panel on suitable matrix, described matrix includes timber, moulds
Material, steel, aluminum, cement, pottery or other can will be mobile for pouring section or transport to the support material of desired position
Any.The dorsal part of holder can include the adhesive for being fixed on tile on ground or metope.When using relatively
During thin panel, it is possible to use screw or bolt are fixing in structure by these.Can provide in the panel hole or hole with
In reception bolt or other installation hardware.Tile or panel can also be fixed on steel construction, it is used for construction and carries panel
Or the building of tile, thus provide the decorative cover of building.
By moulding or pouring into desired configuration, mixture can also be shaped as product.In this way it is possible to
Prepare various pieces, cube, bar or other shapes.The exposure of product can be repaired or be not polished by polishing, this
Depending on desired final quality and finish.After completing required finishing, the concrete of routine or pottery can be applied close
Envelope agent.
When mixture is formed product, it is possible to use various strengthening materials, including glass fibre, rod iron or lath, or can
To include the implant of timber, glass, pottery or other stone materials, this depends on the requirement of desired outward appearance and intensity.
Due to the multipurpose of described mixture be easy to apply, easily specific building products can be obtained, including wall
Face, block or metope element, fountain, pipe, window OR gate frame, or other heavy burdens or decoration element.These products are moistureproof, acidproof
Or acid rain, sea water resistance and other environmental conditions, simultaneously because its durable characteristic, its aesthetic property can keep for many years.
Claims (14)
1. a kind of mixture for manufacturing rock laminated product, it comprises：
Volcanic rock granule, its with the 58% to 88% of described mixture weight amount exist, wherein said volcanic rock granule so that
Few three particle size fractions exist, and exist including the granularity with 1 micron to 5 microns and with the 18% to 28% of mixture weight amount
The first particle size fraction, have 0.25mm to 1.75mm granularity and with the 10% to 20% of mixture weight amount exist second
Particle size fraction；And there is granularity the 3rd particle size fraction with the 30% to 40% of mixture weight amount presence of 2mm to 5mm；
Agglutinant, its amount of comprising be enough to play the polymeric blends of the binding agent effect of described volcanic rock granule；
Silicate compound, presents in an amount at least sufficient to and stablizes described mixture；With
Water, its content is used for making described mixture moisten and fluidizes.
2. the mixture described in claim 1, wherein said agglutinant is emulsifying, with the 8% to 25% of mixture weight
Amount exists and comprises weight ratio for 1:4 to 3:2 water dispersible block copolymer and polyvinyl.
3. the mixture described in claim 2, the described water dispersible block copolymer in wherein said agglutinant is with mixture
The amount of the 4% to 10% of weight exists, and described polyvinyl is existed with the 4% to 15% of mixture weight amount.
4. a kind of mixture for manufacturing rock laminated product, it comprises：
Volcanic rock granule, it is had 1 micron of diameter to 3mm and is existed with the amount higher than the 50% of mixture；
Agglutinant, it comprises the polymeric blends of the amount enough to the binding agent as described volcanic rock granule；And it is described poly-
Polymer mixtures comprise weight than for 1:4 to 3:2 water dispersible block copolymer and polyvinyl；Wherein said coagulation
Agent is emulsifying, is existed with the 8% to 25% of mixture weight amount；Wherein said water dispersible block copolymer is with mixture
The amount of the 4% to 10% of weight exists and described polyvinyl is existed with the 4% to 15% of mixture weight amount；
Wherein said block copolymer is butyl acrylate and styrol copolymer, and described polyvinyl comprise with
Vinyl acrylic copolymers that the amount of the 3% to 10% of mixture weight exists and with the 1% to 5% of mixture weight amount
The polyvinyl acetate base ester resin existing；
Silicate compound, presents in an amount at least sufficient to and stablizes described mixture；With
Water, its content is used for making described mixture moisten and fluidizes.
5. the mixture described in claim 1, wherein said silicate compound is the amount of the 1% to 5% of mixture weight
Hydrated magnesium silicate.
6. the mixture described in claim 1, wherein said water is existed with the 15% to 30% of mixture weight amount.
7. a kind of form desired shape and so that the mixture of described shaping is dried by making the mixture described in claim 1
And the product being obtained.
8. the product described in claim 7, it is the form of lamellar, tabular, tile, column or pencil, and it has and is polished to
The outer surface of desired finish.
9. the product described in claim 7, described product includes metal, glass, timber or fibrous reinforcement, or it passes through to mould
Supporting, described matrix optionally contains for described product is fixed on ground or architectural for material, the matrix of timber or metal
Adhesive.
10. a kind of mixture for manufacturing rock laminated product, it comprises：
Volcanic rock granule, it is had multiple different particle size fractions and is existed, wherein with the 58% to 88% of mixture weight amount
Described volcanic rock granule is existed with least three particle size fractions, including the granularity with 1 micron to 5 microns and with mixture weight
The first particle size fraction that 18% to 28% amount exists, have 0.25mm to 1.75mm granularity and with the 10% of mixture weight to
The second particle size fraction that 20% amount exists；And there is the granularity of 2mm to 5mm and with the 30% to 40% of mixture weight amount
The 3rd particle size fraction existing；
Agglutinant, its amount of comprising be enough to play the polymeric blends of the binding agent effect of described volcanic rock granule；Wherein said
Agglutinant is emulsifying, is existed with the 8% to 25% of mixture weight amount and comprises weight than for 1:4 to 3:2 moisture
Scattered property block copolymer and polyvinyl；
Silicate compound hydrated magnesium silicate, its content is the 1% to 5% of mixture weight, to stablize described mixture；With
Water, its content is the 15% to 30% of mixture weight, so that described mixture moistens and fluidizes；
Each constituent content sum of wherein said mixture is 100%.
Mixture described in 11. claim 10, the described water dispersible block copolymer in wherein said agglutinant is with described
The amount of the 4% to 10% of mixture weight exists；And described polyvinyl is with the 4% to 15% of described mixture weight
Amount exist.
Mixture described in 12. claim 11, wherein said block copolymer is butyl acrylate and styrol copolymer, and
And described polyvinyl comprise the vinyl acrylic copolymers that existed with the 3% to 10% of mixture weight amount and with
The polyvinyl acetate base ester resin that the amount of the 1% to 5% of mixture weight exists.
13. a kind of by make the mixture described in claim 4 formed desired shape and make described shaping mixture do
Dry and prepared product.
14. a kind of by make the mixture described in claim 10 formed desired shape and make described shaping mixture do
Dry and prepared product.
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| PCT/MX2011/000031 WO2012115497A1 (en) | 2011-02-21 | 2011-02-21 | Mixture, stone laminate and slab, based on volcanic rock particles, which can be used for construction and decoration, and production method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103702959A CN103702959A (en) | 2014-04-02 |
| CN103702959B true CN103702959B (en) | 2017-03-01 |
Family
ID=46721086
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201180070191.3A Expired - Fee Related CN103702959B (en) | 2011-02-21 | 2011-02-21 | Can be used for building and the mixture based on volcanic rock granule decorated, laminated product and plate and preparation method thereof |
Country Status (4)
| Country | Link |
|---|---|
| CN (1) | CN103702959B (en) |
| BR (1) | BR112013021356B1 (en) |
| MX (1) | MX345567B (en) |
| WO (1) | WO2012115497A1 (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| IT201800002939A1 (en) * | 2018-02-22 | 2019-08-22 | Alice Zantedeschi | Process for the manufacture of a membrane adapted for coupling to a fabric, and product thus obtained |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5514722A (en) * | 1994-08-12 | 1996-05-07 | Presidential Sports Systems, Inc. | Shock absorbingg underlayment for artificial playing surfaces |
| EP1932814A1 (en) * | 2006-12-05 | 2008-06-18 | Nicolas Fernando Tejada Juarez | Composition of polymeric concrete |
| EP2202056A1 (en) * | 2008-12-23 | 2010-06-30 | Unilin Industries, BVBA | Floor panel and methods for manufacturing floor panels |
-
2011
- 2011-02-21 BR BR112013021356-6A patent/BR112013021356B1/en not_active IP Right Cessation
- 2011-02-21 MX MX2011012453A patent/MX345567B/en active IP Right Grant
- 2011-02-21 CN CN201180070191.3A patent/CN103702959B/en not_active Expired - Fee Related
- 2011-02-21 WO PCT/MX2011/000031 patent/WO2012115497A1/en active Application Filing
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US5514722A (en) * | 1994-08-12 | 1996-05-07 | Presidential Sports Systems, Inc. | Shock absorbingg underlayment for artificial playing surfaces |
| EP1932814A1 (en) * | 2006-12-05 | 2008-06-18 | Nicolas Fernando Tejada Juarez | Composition of polymeric concrete |
| EP2202056A1 (en) * | 2008-12-23 | 2010-06-30 | Unilin Industries, BVBA | Floor panel and methods for manufacturing floor panels |
Also Published As
| Publication number | Publication date |
|---|---|
| MX345567B (en) | 2017-02-01 |
| BR112013021356B1 (en) | 2021-01-12 |
| CN103702959A (en) | 2014-04-02 |
| WO2012115497A1 (en) | 2012-08-30 |
| MX2011012453A (en) | 2013-02-07 |
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