CN103693747B - Be applied to biological floating bed Inorganic material carrier - Google Patents

Be applied to biological floating bed Inorganic material carrier Download PDF

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Publication number
CN103693747B
CN103693747B CN201310629855.6A CN201310629855A CN103693747B CN 103693747 B CN103693747 B CN 103693747B CN 201310629855 A CN201310629855 A CN 201310629855A CN 103693747 B CN103693747 B CN 103693747B
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China
Prior art keywords
parts
inorganic material
particle diameter
floating bed
material carrier
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Expired - Fee Related
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CN201310629855.6A
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CN103693747A (en
Inventor
杨喜田
刘芳
门路广
刘世亮
刘红恩
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HENAN SAN SAN AGRICULTURE SCIENCE AND TECHNOLOGY Co Ltd
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HENAN SAN SAN AGRICULTURE SCIENCE AND TECHNOLOGY Co Ltd
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Abstract

The present invention relates to and be a kind ofly applied to biological floating bed Inorganic material carrier.Be intended to solve existing floating bed carrier and easily cause secondary environmental pollution and potential safety hazard, technical problem that application cost is higher.Inorganic material carrier of the present invention is made up of the raw material of following weight parts: haydite 10 ~ 15 parts, expanded vermiculite 8 ~ 12 parts, float stone 8 ~ 15 parts, biomass charcoal 5 ~ 10 parts, attapulgite 3 ~ 8 parts, silicate cement 5 ~ 10 parts, 5 ~ 15 parts, diatomite, kaolin 5 ~ 10 parts, 5 ~ 10 parts, flyash, polypropylene fibre 0.5 ~ 1.5 part, water reducer 1 ~ 3 part.Inorganic material carrier of the present invention is environment friendly and pollution-free, and stable in physicochemical property, physical strength are high, long service life, and microorganism affinity is good, are conducive to microorganism growth, breeding, and improve microorganism colonization efficiency, water body purification is effective; Raw material sources are extensive, cheap, do not introduce pollution substance, and working service cost is low, is easy to promotion and implementation.

Description

Be applied to biological floating bed Inorganic material carrier
Technical field
The present invention relates to a plant growth carrier, be specifically related to a kind ofly be applied to biological floating bed Inorganic material carrier.
Background technology
In the last thirty years, along with socioeconomic fast development, a large amount of undressed industry and sanitary sewage are directly entered river, lake, cause the loads of nutrition in its water body water system sharply to increase, and eutrophication is abnormal serious.And the improvement in polluted river, lake is a very thorny and arm and a leg difficult problem in water pollution control, biological floating bed purification techniques based on higher plant has that efficiency is high, cost is low, easy care, landscape effect are good, can realize the feature such as in-situ immobilization and control polluted articles, and can the various depth of water be adapted to, also comparatively artificial wet land system is easy for the management of plant and results, is therefore applied to more and more and administers or repair eutrophication water.
At present, artificial floating rafts construction is in various forms, but the research of floating bed carrier application mainly contains three major types: the first kind is plant roots and stems carrier, this carrier just utilizes pleuston the earliest, after develop into gradually and directly in eutrophication water, plant emergent and submerged plant, achieve many achievements in research.But due to the easy excessive multiplication of waterplant and aging death, not easily, thus this technology fails to directly apply in the improvement of fairly large eutrophic lake for results and process, Equations of The Second Kind is organic polymer carrier (as polystyrene foam and material modified etc.), because the manufacture craft of organic polymer material is very ripe, cheap, install, transport and remodeling are conveniently, thus floating bed makes in material and occupies an leading position at home, but there is critical defect in this kind of material in application, floating bed resistance to corrosion is poor, easily aging, can not life-time service, inconvenient maintenance, more seriously these materials are easily lost under stress, break, run off and not easily to salvage in water, cause secondary environmental pollution and potential safety hazard on the contrary, become one of principal element of its spread of restriction, 3rd class is inorganic carrier, inorganic materials has obvious advantage compared with organic polymer material in environmental benefit and raw material sources, thus Inorganic material carrier will become the main trend of floating bed carrier development undoubtedly, but current in the majority with laboratory study, there is no can the actual achievement in research dropping into application.
Summary of the invention
The technical problem to be solved in the present invention is to provide and is a kind ofly applied to biological floating bed Inorganic material carrier, this carrier is environment friendly and pollution-free, there is stable physico-chemical property, higher physical strength and stronger microorganism affinity, and be beneficial to microorganism growth, breeding, improve microorganism colonization efficiency, and work-ing life is longer.
For solving the problems of the technologies described above, the technical solution used in the present invention is:
Design and be a kind ofly applied to biological floating bed Inorganic material carrier, be made up of the raw material of following weight parts:
Haydite 10 ~ 15 parts, expanded vermiculite 8 ~ 12 parts, float stone 8 ~ 15 parts, biomass charcoal 5 ~ 10 parts, attapulgite 3 ~ 8 parts, silicate cement 5 ~ 10 parts, 5 ~ 15 parts, diatomite, kaolin 5 ~ 10 parts, 5 ~ 10 parts, flyash, polypropylene fibre 0.5 ~ 1.5 part, water reducer 1 ~ 3 part.
The class materials such as the haydite in above-mentioned raw materials, expanded vermiculite, float stone, diatomite have vesicular structure, are suitable for microorganic adhesion and form microbial film, being conducive to pollution degradation material; Diatomite in raw material can improve intensity, extensibility, resistance to impact shock, tensile strength, the tear strength of carrier; Kaolin has good plasticity-and high cohesiveness; Attapulgite has unique dispersion, high temperature resistant, anti-good colloidal property and the higher adsorption bleaching ability such as saline and alkaline, and has certain plasticity-and cohesive force; Charcoal porous, surface is flourishing, and (specific surface area is at 300 ~ 400 m 2/ g), can air, nutrient in enrichment water body, suitable micro-organisms is perched, multiply; Described polypropylene fibre can improve carrier anti-fatigue performance, improve its weather resistance, improve carrier tolerance deformability, thus improve its toughness and shock resistance, use fiber can also play the effect of the tensile strength improving matrix, polypropylene fibre can select modified active polypropylene fibre, as selected through PP-g-MAH, OP-IO, PEG 200, PEG 1500, the surface-modifying agent such as PEPSO carries out hydrophilic polypropylene fibre, specifically can select 8wt%PP-g-MAH/PP, 4wt%PEG 200the modified active such as/PP, 2wt%PP-g-MAH/PP, 6wt%PEPSO/PP polypropylene fibre.
Above-mentioned raw materials preferable particle size scope: haydite 5 ~ 10 ㎜; Expanded vermiculite 2 ~ 8mm; Float stone 3 ~ 10mm; Biomass charcoal particle diameter is 40 ~ 100 orders; Attapulgite granularity is 100 ~ 200 orders; Diatomite particle diameter is 100 ~ 150 orders; Kaolin particle diameter is 80 ~ 150 orders, flyash particle diameter is 50 ~ 100 μm.
Described water reducer is at least one in sodium polyphosphate, sulfonated lignin.
The preparation method of above-mentioned Inorganic material carrier is as follows:
(1) prepare burden: configure each raw material by described proportioning;
(2) mix: the raw material configured is dry mixed 3 ~ 5min, then add wet mixing 5 ~ 10min after suitable quantity of water, obtain the mixing pug that water content reaches 15 ~ 25%;
(3) shaping: the shape upper step gained mixing pug being squeezed into needs;
(4) maintenance: maintenance 2 ~ 3 days under natural condition;
(5) dry: natural air drying.
The present invention has actively useful effect:
1. Inorganic material carrier of the present invention is environment friendly and pollution-free, has stable physico-chemical property, higher physical strength and stronger microorganism affinity, is conducive to microorganism growth, breeding, and improve microorganism colonization efficiency, water body purification is effective, and can life-time service.
2. low in raw material price selected by, wide material sources, do not introduce pollution substance, and working service cost is low, is easy to promotion and implementation.
Embodiment
The present invention is set forth further below in conjunction with specific embodiment.
Embodiment 1 one kinds is applied to biological floating bed Inorganic material carrier, is made up of the raw material of following weight parts: haydite (5 ~ 10 ㎜) 10 ~ 15 parts, expanded vermiculite (2 ~ 8mm) 8 ~ 12 parts, float stone (3 ~ 10mm) 8 ~ 15 parts, biomass charcoal (40 ~ 100 order) 5 ~ 10 parts, attapulgite (100 ~ 200 order) 3 ~ 8 parts, silicate cement 5 ~ 10 parts, 5 ~ 15 parts, diatomite (100 ~ 150 order), kaolin (80 ~ 150 order) 5 ~ 10 parts, 5 ~ 10 parts, flyash (50 ~ 100 μm), polypropylene fibre 0.5 ~ 1.5 part, water reducer 1 ~ 3 part.
The preparation method of above-mentioned Inorganic material carrier is as follows:
(1) prepare burden: configure each raw material by described proportioning;
(2) mix: the raw material configured is dry mixed 3 ~ 5min, then add wet mixing 5 ~ 10min after suitable quantity of water, obtain the mixing pug that water content reaches 15 ~ 25%;
(3) shaping: the shape upper step gained mixing pug being squeezed into needs;
(4) maintenance: maintenance 2 ~ 3 days under natural condition;
(5) dry: natural air drying, the performance index of shaping Inorganic material carrier are see table 1.
The physiochemical techniques index of the Inorganic material carrier that table 1 is biological floating bed
The floating bed system of above-mentioned structure is utilized to show the cleaning test that waste water of livestock poultry carries out: to the ideal purification effect of total nitrogen total phosphorus, reach 72% to nitrogen removal rate in eutrophic wastewater, total tp removal rate reaches 76%.
Although above the present invention is described in detail with a general description of the specific embodiments, on basis of the present invention, can make some modifications or improvements it, this will be apparent to those skilled in the art.Therefore, these modifications or improvements without departing from theon the basis of the spirit of the present invention, all belong to the scope of protection of present invention.

Claims (3)

1. be applied to a biological floating bed Inorganic material carrier, be made up of the raw material of following weight parts:
Particle diameter is the haydite 10 ~ 15 parts of 5 ~ 10mm, particle diameter is the expanded vermiculite 8 ~ 12 parts of 2 ~ 8mm, particle diameter is the float stone 8 ~ 15 parts of 3 ~ 10mm, particle diameter is 40 ~ 100 object biomass charcoal 5 ~ 10 parts, granularity is 100 ~ 200 object attapulgite 3 ~ 8 parts, silicate cement 5 ~ 10 parts, particle diameter is 5 ~ 15 parts, 100 ~ 150 order diatomite, particle diameter is 80 ~ 150 object kaolin 5 ~ 10 parts, particle diameter is 5 ~ 10 parts, the flyash of 50 ~ 100 μm, polypropylene fibre 0.5 ~ 1.5 part, water reducer 1 ~ 3 part.
2. be according to claim 1ly applied to biological floating bed Inorganic material carrier, it is characterized in that, described water reducer is at least one in sodium polyphosphate, sulfonated lignin.
3. be according to claim 1ly applied to biological floating bed Inorganic material carrier, it is characterized in that, the preparation method of described Inorganic material carrier is as follows:
(1) prepare burden: configure each raw material by described proportioning;
(2) mix: the raw material configured is dry mixed 3 ~ 5min, then add wet mixing 5 ~ 10min after suitable quantity of water, obtain the mixing pug that water content reaches 15 ~ 25%;
(3) shaping: the shape upper step gained mixing pug being squeezed into needs;
(4) maintenance: maintenance 2 ~ 3 days under natural condition;
(5) dry: natural air drying.
CN201310629855.6A 2013-12-02 2013-12-02 Be applied to biological floating bed Inorganic material carrier Expired - Fee Related CN103693747B (en)

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CN105692766A (en) * 2016-03-12 2016-06-22 云南圣清环保科技有限公司 Filler for sewage treatment
CN107792946A (en) * 2017-12-05 2018-03-13 郑州大学 Solid shore spats component of vegetation type for micro- polluted river strengthened denitrification and preparation method thereof
CN108849294B (en) * 2018-06-11 2020-11-24 中国科学院南京地理与湖泊研究所 Method for rapidly recovering submerged plants in lake with high organic matter sediments
CN109511515B (en) * 2018-11-15 2023-12-29 贵州省园艺研究所 Matrix for ecological vat landscaping and application thereof
CN111392972B (en) * 2020-04-09 2022-04-22 中冶华天工程技术有限公司 Preparation method of light bottom mud covering material and riverway bottom mud repairing method
CN112390368A (en) * 2020-10-09 2021-02-23 淮阴工学院 Novel bentonite composite active carbon ecological floating bed filler and preparation method thereof
CN113321385A (en) * 2021-06-30 2021-08-31 陈宁 Method for reducing tail water COD value in activated sludge process sewage treatment system
CN113321527A (en) * 2021-06-30 2021-08-31 陈宁 Novel composite ceramic and manufacturing method thereof

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CN100372787C (en) * 2006-05-11 2008-03-05 武汉大学 Method for constructing inorganic artificial article floating island
DE102011012346A1 (en) * 2011-02-24 2012-08-30 Wismut Gmbh Reactive material for stimulating microbial metabolic processes for the sustainable immobilization of inorganic pollutants in polluted waters
CN102583719B (en) * 2012-02-22 2014-04-09 广东绿园环境保护工程有限公司 Active composite suspended filler

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