CN103691571A - 一种能抑制磷辉石富集的浮选药剂 - Google Patents
一种能抑制磷辉石富集的浮选药剂 Download PDFInfo
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- CN103691571A CN103691571A CN201310714196.6A CN201310714196A CN103691571A CN 103691571 A CN103691571 A CN 103691571A CN 201310714196 A CN201310714196 A CN 201310714196A CN 103691571 A CN103691571 A CN 103691571A
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- acid
- phosphorus
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- 238000005188 flotation Methods 0.000 title abstract description 24
- 229910052586 apatite Inorganic materials 0.000 title abstract description 6
- VSIIXMUUUJUKCM-UHFFFAOYSA-D pentacalcium;fluoride;triphosphate Chemical compound [F-].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[Ca+2].[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O.[O-]P([O-])([O-])=O VSIIXMUUUJUKCM-UHFFFAOYSA-D 0.000 title abstract description 6
- 239000003153 chemical reaction reagent Substances 0.000 title abstract description 5
- 230000000452 restraining effect Effects 0.000 title abstract 2
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 53
- GCLGEJMYGQKIIW-UHFFFAOYSA-H sodium hexametaphosphate Chemical compound [Na]OP1(=O)OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])OP(=O)(O[Na])O1 GCLGEJMYGQKIIW-UHFFFAOYSA-H 0.000 claims abstract description 21
- 239000002253 acid Substances 0.000 claims abstract description 14
- 238000007667 floating Methods 0.000 claims description 37
- OAICVXFJPJFONN-UHFFFAOYSA-N Phosphorus Chemical compound [P] OAICVXFJPJFONN-UHFFFAOYSA-N 0.000 claims description 30
- 239000011574 phosphorus Substances 0.000 claims description 30
- 229910052698 phosphorus Inorganic materials 0.000 claims description 30
- 229910052611 pyroxene Inorganic materials 0.000 claims description 16
- YVURAEQQLUQPFO-UHFFFAOYSA-N phosphoric acid;styrene Chemical compound OP(O)(O)=O.C=CC1=CC=CC=C1 YVURAEQQLUQPFO-UHFFFAOYSA-N 0.000 claims description 9
- 125000002887 hydroxy group Chemical group [H]O* 0.000 claims description 3
- RTAQQCXQSZGOHL-UHFFFAOYSA-N Titanium Chemical compound [Ti] RTAQQCXQSZGOHL-UHFFFAOYSA-N 0.000 abstract description 10
- 239000010936 titanium Substances 0.000 abstract description 10
- 229910052719 titanium Inorganic materials 0.000 abstract description 10
- 231100000252 nontoxic Toxicity 0.000 abstract description 6
- 230000003000 nontoxic effect Effects 0.000 abstract description 6
- WRIDQFICGBMAFQ-UHFFFAOYSA-N (E)-8-Octadecenoic acid Natural products CCCCCCCCCC=CCCCCCCC(O)=O WRIDQFICGBMAFQ-UHFFFAOYSA-N 0.000 abstract description 5
- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 abstract description 5
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 abstract description 5
- 239000005642 Oleic acid Substances 0.000 abstract description 5
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 abstract description 5
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 abstract description 5
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 abstract description 5
- 229910001385 heavy metal Inorganic materials 0.000 abstract description 4
- 230000001988 toxicity Effects 0.000 abstract description 4
- 231100000419 toxicity Toxicity 0.000 abstract description 4
- SRIJLARXVRHZKD-UHFFFAOYSA-N OP(O)=O.C=CC1=CC=CC=C1 Chemical compound OP(O)=O.C=CC1=CC=CC=C1 SRIJLARXVRHZKD-UHFFFAOYSA-N 0.000 abstract 2
- BCKXLBQYZLBQEK-KVVVOXFISA-M Sodium oleate Chemical compound [Na+].CCCCCCCC\C=C/CCCCCCCC([O-])=O BCKXLBQYZLBQEK-KVVVOXFISA-M 0.000 abstract 2
- 230000003213 activating effect Effects 0.000 abstract 2
- 235000019982 sodium hexametaphosphate Nutrition 0.000 abstract 2
- 239000001577 tetrasodium phosphonato phosphate Substances 0.000 abstract 2
- 230000002195 synergetic effect Effects 0.000 abstract 1
- 239000012141 concentrate Substances 0.000 description 16
- YDZQQRWRVYGNER-UHFFFAOYSA-N iron;titanium;trihydrate Chemical compound O.O.O.[Ti].[Fe] YDZQQRWRVYGNER-UHFFFAOYSA-N 0.000 description 15
- 239000011575 calcium Substances 0.000 description 12
- 229910052500 inorganic mineral Inorganic materials 0.000 description 12
- 239000011707 mineral Substances 0.000 description 12
- 239000003814 drug Substances 0.000 description 11
- 241001460678 Napo <wasp> Species 0.000 description 9
- 230000000694 effects Effects 0.000 description 8
- SZVJSHCCFOBDDC-UHFFFAOYSA-N iron(II,III) oxide Inorganic materials O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 description 8
- 238000000034 method Methods 0.000 description 6
- 229910052720 vanadium Inorganic materials 0.000 description 6
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 description 6
- 238000005516 engineering process Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 230000008569 process Effects 0.000 description 5
- 150000003608 titanium Chemical class 0.000 description 5
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N titanium dioxide Inorganic materials O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 description 5
- 241000270666 Testudines Species 0.000 description 4
- 230000008901 benefit Effects 0.000 description 4
- 230000033228 biological regulation Effects 0.000 description 4
- 150000001875 compounds Chemical class 0.000 description 4
- 239000000243 solution Substances 0.000 description 4
- 230000007613 environmental effect Effects 0.000 description 3
- 238000012545 processing Methods 0.000 description 3
- 238000011084 recovery Methods 0.000 description 3
- 238000012360 testing method Methods 0.000 description 3
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 2
- NBIIXXVUZAFLBC-UHFFFAOYSA-N Phosphoric acid Chemical compound OP(O)(O)=O NBIIXXVUZAFLBC-UHFFFAOYSA-N 0.000 description 2
- NINIDFKCEFEMDL-UHFFFAOYSA-N Sulfur Chemical compound [S] NINIDFKCEFEMDL-UHFFFAOYSA-N 0.000 description 2
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 description 2
- 239000005864 Sulphur Substances 0.000 description 2
- 238000010521 absorption reaction Methods 0.000 description 2
- 239000012190 activator Substances 0.000 description 2
- 229910052791 calcium Inorganic materials 0.000 description 2
- 230000000536 complexating effect Effects 0.000 description 2
- 230000002079 cooperative effect Effects 0.000 description 2
- 235000014113 dietary fatty acids Nutrition 0.000 description 2
- 238000004090 dissolution Methods 0.000 description 2
- ZOOODBUHSVUZEM-UHFFFAOYSA-N ethoxymethanedithioic acid Chemical class CCOC(S)=S ZOOODBUHSVUZEM-UHFFFAOYSA-N 0.000 description 2
- 238000002474 experimental method Methods 0.000 description 2
- 239000000194 fatty acid Substances 0.000 description 2
- 229930195729 fatty acid Natural products 0.000 description 2
- 239000004088 foaming agent Substances 0.000 description 2
- 230000006872 improvement Effects 0.000 description 2
- 239000003112 inhibitor Substances 0.000 description 2
- 230000005764 inhibitory process Effects 0.000 description 2
- 229910021645 metal ion Inorganic materials 0.000 description 2
- 238000005065 mining Methods 0.000 description 2
- 229910052592 oxide mineral Inorganic materials 0.000 description 2
- 238000011020 pilot scale process Methods 0.000 description 2
- 231100000614 poison Toxicity 0.000 description 2
- 230000007096 poisonous effect Effects 0.000 description 2
- 238000011160 research Methods 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 description 2
- 239000002699 waste material Substances 0.000 description 2
- 102000040350 B family Human genes 0.000 description 1
- 108091072128 B family Proteins 0.000 description 1
- 229910021532 Calcite Inorganic materials 0.000 description 1
- 229910014472 Ca—O Inorganic materials 0.000 description 1
- HZCDANOFLILNSA-UHFFFAOYSA-N Dimethyl hydrogen phosphite Chemical compound COP(=O)OC HZCDANOFLILNSA-UHFFFAOYSA-N 0.000 description 1
- 229920000388 Polyphosphate Polymers 0.000 description 1
- 125000001931 aliphatic group Chemical group 0.000 description 1
- 150000003973 alkyl amines Chemical class 0.000 description 1
- 229910000147 aluminium phosphate Inorganic materials 0.000 description 1
- 150000001450 anions Chemical class 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 150000001768 cations Chemical class 0.000 description 1
- 230000000875 corresponding effect Effects 0.000 description 1
- 230000009849 deactivation Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 238000003795 desorption Methods 0.000 description 1
- 238000006477 desulfuration reaction Methods 0.000 description 1
- 230000023556 desulfurization Effects 0.000 description 1
- 238000011161 development Methods 0.000 description 1
- DNJIEGIFACGWOD-UHFFFAOYSA-N ethanethiol Chemical compound CCS DNJIEGIFACGWOD-UHFFFAOYSA-N 0.000 description 1
- 150000004665 fatty acids Chemical class 0.000 description 1
- 230000002349 favourable effect Effects 0.000 description 1
- -1 ferrous metal oxide Chemical class 0.000 description 1
- 239000008396 flotation agent Substances 0.000 description 1
- 230000005484 gravity Effects 0.000 description 1
- TVHALOSDPLTTSR-UHFFFAOYSA-H hexasodium;[oxido-[oxido(phosphonatooxy)phosphoryl]oxyphosphoryl] phosphate Chemical compound [Na+].[Na+].[Na+].[Na+].[Na+].[Na+].[O-]P([O-])(=O)OP([O-])(=O)OP([O-])(=O)OP([O-])([O-])=O TVHALOSDPLTTSR-UHFFFAOYSA-H 0.000 description 1
- BHEPBYXIRTUNPN-UHFFFAOYSA-N hydridophosphorus(.) (triplet) Chemical compound [PH] BHEPBYXIRTUNPN-UHFFFAOYSA-N 0.000 description 1
- 238000002329 infrared spectrum Methods 0.000 description 1
- 230000002401 inhibitory effect Effects 0.000 description 1
- 230000003993 interaction Effects 0.000 description 1
- 150000002500 ions Chemical class 0.000 description 1
- 229910052742 iron Inorganic materials 0.000 description 1
- 239000003446 ligand Substances 0.000 description 1
- 230000035800 maturation Effects 0.000 description 1
- 230000007246 mechanism Effects 0.000 description 1
- 229910044991 metal oxide Inorganic materials 0.000 description 1
- 238000005457 optimization Methods 0.000 description 1
- 239000001205 polyphosphate Substances 0.000 description 1
- 235000011176 polyphosphates Nutrition 0.000 description 1
- 238000003825 pressing Methods 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 230000004083 survival effect Effects 0.000 description 1
- 239000012991 xanthate Substances 0.000 description 1
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- Pharmaceuticals Containing Other Organic And Inorganic Compounds (AREA)
- Inorganic Compounds Of Heavy Metals (AREA)
Abstract
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CN201310714196.6A CN103691571B (zh) | 2013-12-23 | 2013-12-23 | 一种能抑制磷辉石富集的浮选药剂 |
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CN201310714196.6A CN103691571B (zh) | 2013-12-23 | 2013-12-23 | 一种能抑制磷辉石富集的浮选药剂 |
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CN103691571A true CN103691571A (zh) | 2014-04-02 |
CN103691571B CN103691571B (zh) | 2018-05-01 |
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Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113369020A (zh) * | 2021-06-11 | 2021-09-10 | 中南大学 | 一种提高钛铁矿与其脉石分离效率的浮选捕收剂、浮选药剂及浮选方法 |
Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB978110A (en) * | 1963-12-10 | 1964-12-16 | Akad Wissenschaften Ddr | Floatation process |
GB2108870A (en) * | 1981-11-04 | 1983-05-25 | Bergbau Und Huttenkombinat Alb | Flotation of oxidic tin ores |
US4421641A (en) * | 1981-01-05 | 1983-12-20 | Ceca S.A. | Enrichment process by flotation of phosphate-containing ores with carbonated and/or siliceous gangues, by amphoteric collecting agents |
CN101879479A (zh) * | 2010-06-08 | 2010-11-10 | 西北有色地质研究院 | 一种榴辉岩型金红石矿的选矿方法 |
CN102294305A (zh) * | 2011-06-20 | 2011-12-28 | 米建国 | 山东地区钛铁矿选矿浮选药品 |
-
2013
- 2013-12-23 CN CN201310714196.6A patent/CN103691571B/zh not_active Expired - Fee Related
Patent Citations (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
GB978110A (en) * | 1963-12-10 | 1964-12-16 | Akad Wissenschaften Ddr | Floatation process |
US4421641A (en) * | 1981-01-05 | 1983-12-20 | Ceca S.A. | Enrichment process by flotation of phosphate-containing ores with carbonated and/or siliceous gangues, by amphoteric collecting agents |
GB2108870A (en) * | 1981-11-04 | 1983-05-25 | Bergbau Und Huttenkombinat Alb | Flotation of oxidic tin ores |
CN101879479A (zh) * | 2010-06-08 | 2010-11-10 | 西北有色地质研究院 | 一种榴辉岩型金红石矿的选矿方法 |
CN102294305A (zh) * | 2011-06-20 | 2011-12-28 | 米建国 | 山东地区钛铁矿选矿浮选药品 |
Non-Patent Citations (1)
Title |
---|
罗溪梅: "云南玉溪钒钛磁铁矿的选矿试验研究", 《中国优秀硕士学位论文全文数据库(电子期刊)》 * |
Cited By (1)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN113369020A (zh) * | 2021-06-11 | 2021-09-10 | 中南大学 | 一种提高钛铁矿与其脉石分离效率的浮选捕收剂、浮选药剂及浮选方法 |
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Inventor after: Cai Weihua Inventor before: Yuan Jie |
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Effective date of registration: 20180330 Address after: 412300 Hunan city of Zhuzhou province Youxian Yau State Industrial Park Applicant after: Hunan Mingzhu ore dressing Pharmaceutical Co., Ltd. Address before: 402660 Chongqing Tongnan County catalpa dregs Street office, Liang Feng Ya Industrial Park A4-10/01 Applicant before: CHONGQING XINGTONG SCIENCE & TECHNOLOGY CO., LTD. |
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