CN103668956B - The anti-acarid method for sorting of anti-acarid finishing agent, fabric and anti-acarid fabric - Google Patents
The anti-acarid method for sorting of anti-acarid finishing agent, fabric and anti-acarid fabric Download PDFInfo
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Abstract
The invention discloses a kind of anti-acarid finishing agent, the anti-acarid method for sorting of fabric and anti-acarid fabric.Described anti-acarid finishing agent, be made up of the component of following weight parts: be made up of the component of following weight parts: 1,4-naphthridine-2,3-bis-base trithiocarbonate 2-6 part, phenyl 5,6-bis-chloro-2-trifluoro methyl benzimidazole base 1-carboxylic acid ester 0.5-2.5 part, 1-(4-fluorophenyl) biguanide hydrochloride 0.5-2.5 part, ethylene glycol 40-60 part, dodecyl carboxymethyl sodium form imidazoline acetate 10-20 part.The safety of the anti-acarid finishing agent of the present invention and effectively, use the anti-acarid finishing agent of the present invention through dipping or pad the obtained fabric of Final finishing, all have dirt mite, gamasid and trombiculid and good walk quickly and keep away performance, fabric and skin surface Long Term Contact, safe and non-stimulating, be the family life environment of people's Creating Comfort.
Description
Technical field
The present invention relates to a kind of anti-acarid finishing agent, the anti-acarid method for sorting of fabric and anti-acarid fabric.
Background technology
Global asthma control strategy (GINA) committee in 2003 proposes global asthma patient and estimates at 300,000,000, Chinese children asthma prevalence in 2000 is 0.5-3%, the state-owned asthmatic children of about 1,000 ten thousand according to a preliminary estimate, the whole nation has the asthma patient of about 2,500 ten thousand, and 2000 domestic in the comparatively nineteen ninety rising about 70% of 27 urban survey childhood asthma illness rates.Some big cities then rise more than one times.
A long time ago people will sneeze when contacting bookcase or suitcase room dirt, the situation such as rhinorrhea, know that room dirt can cause allergic reaction, but do not know what main allergen is always, until within 1969 years, just know that the main allergen in room dirt is dirt mite.Dirt mite is a kind of biology extremely harmful to health, and energy transmitted virus, bacterium, can cause the various diseases such as bronchial astehma, rhinitis, dermatitis, folliculitis, mange.According to data, have the asthma patient of 60% can produce allergic reaction to dirt mite, the childhood asthma of about 80% results from dust mite allergy.The asthma incidence of disease of China is very high, is second largest breathing problem.
According to relevant department's monitoring, in the city that the living standard such as Shanghai, Beijing is higher, at home, the distribution of dirt mite is maximum with carpet, secondly be cotton-wadded quilt, be thirdly mattress, pillow, floor, sofa etc., in such a case, the mite class can survived in room has 16 kinds more than.Investigation finds, is all flooded with dirt mite in the household of Taiwan 75%, and indoor every gram of dust under cover dirt mite of more than 10,000, far above the every gram of dust 100 to 1000 brought out required for irritated asthma to dust the concentration of mite.And the indoor total mite number distribution in house, Taiwan is maximum with carpet, next is cotton-wadded quilt, mattress, pillow, floor and sofa.
Household mite class in room dirt is distributed widely in the place having crowd to live, it is strong allergen, what cause is general allergic effect, comprises allergic asthma, allergia nose bulbar conjunctiva inflammation, AE/dermatitis, allergic urticaria etc., and mite property allergic effect is corresponding accounts for about 80% of respectively this disease kind.According to estimates, the asthma of 50%-80% is caused by dirt mite, and it can also cause many kinds of eczemas, hay fever, Hay Fever and other anaphylactia.Cause and breathe heavily the digestive juice that albumen is dirt mite enteroendocrine, its effect is very strong.The methods for the treatment of not good to this, can only prevent, and is exactly the quantity of necessary controlling dust mite.
Bed is an important recreating facility of people, and people has the time of 1/3rd in bed in life.Mattress in family is the largest source of dirt mite, because mattress is to provide warm, and the suitable environment of humidity and food source.The dirt mite of 10 ten thousand to 1,000 ten thousand is had in a common used mattress.The pillow to have used 2 years, 10% of its weight is the ight soil of dirt mite and the dirt mite die.
Along with improving constantly of people's living standard, people note the life staying idle at home environment of self living more, comprise the household articless such as mattress, bedcover, bed clothes.Use the textiles be made up of acarus-proof antibiotic and household articles, not only can press down mite, drive mite, effectively prevent dermopathic generation relevant to dirt mite, can also the breeding of antibacterial, anti-bacteria, thus the object obviously improving people's living environment can be reached.So develop anti-mite textiles just seem necessary.
Summary of the invention
For the deficiencies in the prior art, one of technical problem to be solved by this invention is to provide a kind of anti-acarid finishing agent.
Two of technical problem to be solved by this invention is to provide a kind of anti-acarid method for sorting of fabric.
Three of technical problem to be solved by this invention is to provide the anti-acarid method for sorting of another fabric
Four of technical problem to be solved by this invention is to provide a kind of anti-acarid fabric.
For solving the problems of the technologies described above, the present invention is achieved through the following technical solutions:
A kind of anti-acarid finishing agent, be made up of the component of following weight parts: 1,4-naphthridine-2,3-bis-base trithiocarbonate 2-6 part, phenyl 5,6-bis-chloro-2-trifluoro methyl benzimidazole base 1-carboxylic acid ester 0.5-2.5 part, 1-(4-fluorophenyl) biguanide hydrochloride 0.5-2.5 part, ethylene glycol 40-60 part, dodecyl carboxymethyl sodium form imidazoline acetate 10-20 part.
Above-mentioned each component is uniformly mixed, described anti-acarid finishing agent can be obtained.
Isosorbide-5-Nitrae-naphthridine-2,3-bis-base trithiocarbonate, No. CAS: 93-75-4.English name: 1,3-Dithiolo [4,5-b] quinoxaline-2-thione.
Phenyl 5,6-bis-chloro-2-trifluoro methyl benzimidazole base 1-carboxylic acid ester, English name: 1H-Benzimidazole-1-carboxylicacid, 5,6-dichloro-2-(trifluoromethyl)-, phenyl ester.No. CAS: 14255-88-0.
Dodecyl carboxymethyl sodium form imidazoline acetate, sodium laulyl carboxymethylimidazoline acetate, No. CAS: 64041-76-5.
1-(4-fluorophenyl) biguanide hydrochloride, No. CAS: 16018-83-0, English name: Imidodicarbonimidicdiamide, N-(4-fluorophenyl)-, hydrochloride (1:1).
An anti-acarid method for sorting for fabric, comprise and pad, dewater and baking step, described step of padding comprises:
(1) prepare anti-acarid dressing liquid: be dissolved in the water by described anti-acarid finishing agent, be mixed with anti-acarid dressing liquid, the mass concentration controlling anti-acarid finishing agent is 15 ~ 50g/l,
(2) fabric is padded by anti-acarid dressing liquid, pick-up 70-80%.
Described baking step is: by fabric drying at 90-110 DEG C of temperature.
An anti-acarid method for sorting for fabric, comprise dipping, dehydration and baking step, described impregnation steps comprises:
By fabric normal temperature dipping 15-20 minute, described anti-acarid finishing agent consumption is 1.0-3.0%o.w.f, and bath raio is 1:15-1:30.
Described baking step is: by fabric drying at 90-110 DEG C of temperature.
A kind of anti-acarid fabric, adopts above-mentioned method for sorting to be prepared from.
The advantage major embodiment of technical solution of the present invention is: the safety of the anti-acarid finishing agent of the present invention and effectively, use the anti-acarid finishing agent of the present invention through dipping or pad the obtained fabric of Final finishing, all have dirt mite, gamasid and trombiculid and good walk quickly and keep away performance, fabric and skin surface Long Term Contact, safe and non-stimulating, be the family life environment of people's Creating Comfort.
Detailed description of the invention
Embodiment 1
Each raw material is taken by embodiment corresponding to table 11 data.By 1,4-naphthridine-2,3-bis-base trithiocarbonate, phenyl 5,6-bis-chloro-2-trifluoro methyl benzimidazole base 1-carboxylic acid ester, 1-(4-fluorophenyl) biguanide hydrochloride, ethylene glycol and dodecyl carboxymethyl sodium form imidazoline acetate are uniformly mixed, sand milling is even, can obtain anti-acarid finishing agent of the present invention.
Embodiment 2
Each raw material is taken by embodiment corresponding to table 12 data.By method described in embodiment 1, anti-acarid finishing agent of the present invention can be obtained.
Embodiment 3
Each raw material is taken by embodiment corresponding to table 13 data.By method described in embodiment 1, anti-acarid finishing agent of the present invention can be obtained.
Table 1: anti-acarid finishing agent formula table unit: kilogram
| Embodiment 1 | Embodiment 2 | Embodiment 3 | |
| Isosorbide-5-Nitrae-naphthridine-2,3-bis-base trithiocarbonate | 2 | 6 | 4 |
| Phenyl 5,6-bis-chloro-2-trifluoro methyl benzimidazole base 1-carboxylic acid ester | 2.5 | 0.5 | 1.5 |
| 1-(4-fluorophenyl) biguanide hydrochloride | 0.5 | 2.5 | 1.5 |
| Dodecyl carboxymethyl sodium form imidazoline acetate | 20 | 10 | 10 |
| Ethylene glycol | 40 | 60 | 50 |
Embodiment 4
The anti-acarid of pure cotton fabric arranges: cotton yarn: 40s; 100 × 90/inch, fabric width 250cm
(1) prepare anti-acarid dressing liquid: be dissolved in the water by the anti-acarid finishing agent prepared by embodiment 3, be mixed with anti-acarid dressing liquid, the mass concentration controlling anti-acarid finishing agent is 30g/l.
(2) pure cotton fabric is padded by anti-acarid dressing liquid, pick-up 80%.
(3) dewater, by fabric drying at 100 DEG C of temperature, anti-acarid fabric of the present invention can be obtained.
Embodiment 5
The anti-acarid of pure cotton fabric arranges: cotton yarn: 40s; 100 × 90/inch, fabric width 250cm
(1) the anti-acarid finishing agent prepared by embodiment 3 is dissolved in the water, is mixed with anti-acarid dressing liquid.
(2) by pure cotton fabric normal temperature dipping anti-acarid dressing liquid 20 minutes, controlling anti-acarid finishing agent consumption is 2.0%o.w.f, and bath raio is 1:20.
(3) dewater, by fabric drying at 100 DEG C of temperature, anti-acarid fabric of the present invention can be obtained.
Test case 1
The plastic ware of 7 diameter 4cm, high 0.6cm is sticked on plate, about 3000 acarids are put in centre, around 6 plastic wares respectively on the lay of interval diameter be the insect-prevention treatment cloth specimen of 4cm and blank cloth specimen, and evenly put 0.05g powder feed (mite media) respectively on 6 cloth specimens.Put into saturated aqueous common salt in the lower floor of 27 × 13 × 8 (cm) food freshness-keeping box (or drier), then plate is put into the upper strata of antistaling box (or drier), 25 DEG C ± 1 DEG C, humidity 75%, constant temperature and humidity cultivates 24h.Powder feed punching on sample released by saline solution method of swimming, then wash collection, counting, is calculated as follows scattering ratio again:
Anti-mite performance test, test result is in table 2.
Wash resistant is tested, and test result is in table 2.
Table 2: anti-mite washing durability test chart
Test case 2
Anti-mite finishing agent toxicity test
(1) anti-mite finishing agent per os acute toxicity: in Example 4, mass concentration is that the anti-acarid finishing agent of 30g/l is to the disposable per os gavage of Kunming kind standard small white mouse of 40 empty stomach 16h, anti-mite agent dose, up to 10000mg/kg, observes the poisoning manifestations of animal every day.Terminate experiment after 7d, each group animal used as test is in whole experimentation kind, and without any poisoning manifestations, diet and motion are all normal, without 1 animal dead.According to acute toxicity grading criteria, this anti-acarid finishing agent belongs to innocuous substance.
(2) to skin irritation: cut respectively by 10 Japan's large ear tag quasi-experiment backbone diamond wools of rabbit, the anti-mite finishing agent being 30g/l by mass concentration in embodiment 4 is applied on gauze, apply ointment or plaster on the skin of right side exposure.Observing through 24h, all there is not the irritation such as erythema, oedema in application site skin.According to skin irritatin strength grading standard, this anti-mite antibacterial finishing agent application liquid belongs to non-stimulated material to skin.
(3) to eye irritation: be that the anti-acarid finishing agent of 30g/l directly instills the right eye of the large ear tag quasi-experiment of Japan with rabbit by mass concentration in embodiment 4, and compare with left eye; Passive closed 5s, then clean with normal saline flushing, observe after 24h, left and right eyes are all without exception again.According to eye irritation strength grading standard, this anti-acarid finishing agent belongs to non-stimulated material to eyes.
The safety of the anti-acarid finishing agent of the present invention and effectively, use the anti-acarid finishing agent of the present invention through dipping or pad the obtained fabric of Final finishing, all have dirt mite, gamasid and trombiculid and good walk quickly and keep away performance, fabric and skin surface Long Term Contact, safe and non-stimulating, be the family life environment of people's Creating Comfort.
Claims (1)
1. an anti-acarid finishing agent, it is characterized in that, be made up of the component of following weight parts: 1,4-naphthridine-2,3-bis-base trithiocarbonate 2-6 part, phenyl 5,6-bis-chloro-2-trifluoro methyl benzimidazole base 1-carboxylic acid ester 0.5-2.5 part, 1-(4-fluorophenyl) biguanide hydrochloride 0.5-2.5 part, ethylene glycol 40-60 part, dodecyl carboxymethyl sodium form imidazoline acetate 10-20 part.
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| CN105155258A (en) * | 2015-07-16 | 2015-12-16 | 广州立白企业集团有限公司 | Anti-mite fabric care composition and application method thereof |
| CN105568684A (en) * | 2016-03-11 | 2016-05-11 | 湖州宏鑫绸厂 | Anti-mite finishing method of wool fabric |
| CN106381596A (en) * | 2016-11-29 | 2017-02-08 | 魏健 | Cloth having anti-mite function and preparation method thereof |
| CN107139281A (en) * | 2017-06-29 | 2017-09-08 | 广东喜粤新材料科技有限公司 | It is a kind of can antibiosis anti-acarien worm laminated structure and preparation method |
| CN114481615A (en) * | 2022-01-07 | 2022-05-13 | 嵊州凯丽制衣有限公司 | Garment fabric and preparation process thereof |
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| CN1079126C (en) * | 1997-01-07 | 2002-02-13 | 李为学 | Antimicrobial finishing agent for textile and preparing process thereof |
| US20060257578A1 (en) * | 2003-04-09 | 2006-11-16 | Jun Zhang | Micronized wood preservative formulations comprising boron compounds |
| CN101503855B (en) * | 2008-02-04 | 2012-04-18 | 上海德桑精细化工有限公司 | Antibacterial anti-mite finishing agent for fabric |
| CN101660273A (en) * | 2008-08-28 | 2010-03-03 | 北京玉佳明三态离子科学研究院有限公司 | Method for manufacturing anti-mite and antibacterial fabric and series of multifunctional products thereof |
| MX2012007954A (en) * | 2010-01-07 | 2012-08-03 | Dow Agrosciences Llc | THIAZOLO[5,4-d] PYRIMIDINES AND THEIR USE AS AGROCHEMICALS. |
| JP2012051843A (en) * | 2010-09-02 | 2012-03-15 | Nissan Chem Ind Ltd | Composition for insecticide, mitecide, nematocide, molluscicide, germicide, or bactreiacide, and method of controlling pest |
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Effective date of registration: 20180903 Address after: 223600 south of Fu you road, Shuyang County Economic Development Zone, Suqian, Jiangsu Patentee after: Gongliu textile technology Shuyang Co. Ltd. Address before: 200137 1F79 14, 528 Yang Gao Bei Road, Pudong New Area, Shanghai. Patentee before: Shanghai Taohong Chemical Technology Co., Ltd. |