CN103664414A - Humic acid chelated with boron, magnesium and zinc medicine fertilizer and preparation method thereof - Google Patents
Humic acid chelated with boron, magnesium and zinc medicine fertilizer and preparation method thereof Download PDFInfo
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- CN103664414A CN103664414A CN201310682140.7A CN201310682140A CN103664414A CN 103664414 A CN103664414 A CN 103664414A CN 201310682140 A CN201310682140 A CN 201310682140A CN 103664414 A CN103664414 A CN 103664414A
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Abstract
The invention discloses a humic acid chelated with boron, magnesium and zinc medicine fertilizer and a preparation method thereof. The humic acid chelated with boron, magnesium and zinc medicine fertilizer is prepared from the following materials in parts by weight: 30-60 parts of majorelement fertilizers, 10-20 parts of humic acid, 5-8 parts of citric acid, 1-2 parts of ammonium borate, 5-6 parts of magnesium sulfate, 3-5 parts of zinc sulfate, 1-2 parts of chlorpyrifos, and 1-1.5 parts of clothianidin; the preparation method comprises the following steps: adding citric acid, ammonium borate, magnesium sulfate and zinc sulfate into a reaction kettle, adding water, and reacting at the temperature of 80-90 DEG C; then adding humic acid, reacting at the temperature of 80-90 DEG C, adding chlorpyrifos and clothianidin, and obtaining a mixed solution; introducing the majorelement fertilizers to a granulator, performing spraying granulation with the mixed solution to obtain the product. The humic acid chelated with boron, magnesium and zinc medicine fertilizer has the advantages of rich nutrition and one-step application; as the humic acid chelated with boron, magnesium and zinc medicine fertilizer supplies plant with necessary nutrition and also has the insecticidal function, labor and time are reduced, chelating effect is good, antagonism among microelements is effectively prevented, and the yield of crops is effectively improved.
Description
Technical field
The present invention relates to a kind of humic acid chelating boron magnesium zinc medicine fertilizer and preparation method thereof.
Background technology
Nitrogen phosphorus potassium macroelement is the required bioelement of crop growth, and in order to improve the output of farm crop, people relatively focus on using nitrogen phosphorus potassium macroelement fertilizer.Research shows, middle trace element, if boron, zinc and magnesium are also the necessary nutrition of crop growth, once lack, can affect the growth of farm crop equally, and therefore, when farmland planting, suitable using contains the attention that trace element fertilizer has caused people.
At present, the compound manure that contains middle trace element is that the inorganic salt of middle trace element or oxide compound are joined to mixed preparing in nitrogen-phosphorus-potassium compound fertilizer, and solidification and interionic antagonistic action due to soil, cause the utilization ratio of middle trace element low.
Agricultural chemicals energy kill pests prevents its growth that harms the crops, and improves crop yield, and giving crop spraying pesticide grown kill pests is one of requisite link of proportion of crop planting.But when proportion of crop planting, fertilizer and agricultural chemicals be separate administration often, to peasant, has increased work burden.
Summary of the invention
It is high that the technical problem to be solved in the present invention is to provide a kind of boron, magnesium, zinc microelement utilization ratio, alleviates peasant's labour intensity, humic acid chelating boron magnesium zinc medicine fertilizer of saving of work and time and preparation method thereof.
Technical solution of the present invention is:
A kind of humic acid chelating boron magnesium zinc medicine is fertile, counts by weight by following raw material and forms:
30 parts～60 parts of macroelement fertilizers;
10 parts～20 parts of humic acid;
5 parts～8 parts of citric acids;
1 part～2 parts of ammonium borates;
5 parts～6 parts, magnesium sulfate;
3 parts～5 parts, zinc sulfate;
1 part～2 parts of Chlorpyrifos 94;
1 part～1.5 parts of clothianidins.
Meter, contains the nitrogenous fertilizer of 10 parts～15 parts, phosphate fertilizer and 3 parts～10 parts potash fertilizer of 2 parts～5 parts in macroelement fertilizer by weight.
A preparation method for humic acid chelating boron magnesium zinc medicine fertilizer, its concrete steps are as follows:
1.1, according to parts by weight meter, 5 parts～8 parts citric acids, 1 part～2 parts ammonium borates, 5 parts～6 parts magnesium sulfate and 3 parts～5 parts zinc sulfate are added in reactor, add 200 parts of water, at 80 ℃～90 ℃ reaction 40min～60min, and then add 10 parts～20 parts humic acid, at 80 ℃～90 ℃ reaction 60min～90min, make middle trace element chelated fertilizer feed liquid;
1.2, according to parts by weight meter, 1 part～2 portions Chlorpyrifos 94 and 1 part～1.5 parts clothianidins are added in the middle trace element chelated fertilizer feed liquid that step 1.1 makes, obtain agricultural chemicals chelating fertilizer mixed solution;
1.3, according to parts by weight meter, 30 parts～60 parts macroelement fertilizers are put into tablets press, the agricultural chemicals chelating fertilizer mixed solution making by step 1.2 carries out mist projection granulating, obtains humic acid chelating boron magnesium zinc medicine fertile.
Meter, contains the nitrogenous fertilizer of 10 parts～15 parts, phosphate fertilizer and 3 parts～10 parts potash fertilizer of 2 parts～5 parts in macroelement fertilizer by weight.
Beneficial effect of the present invention:
1, utilize citric acid and humic acid as sequestrant, chelating is effective, and middle micronutrient can evenly and uniformly discharge, can effectively prevent antagonism between trace element, improved micro-utilization ratio, plant specific absorption improves more than 25%, and function nutrition group is extremely stable, in soil, be difficult for running off, in addition, humic acid also has improvement Soil structure, activating soil, strengthen the ability that crop root absorbs nutrition, thereby improve crop yield.
2, Chlorpyrifos 94 and clothianidin are carried out to composite synergistic function and the lasting effect of playing, make agricultural chemicals chelating fertilizer mixed solution with middle trace element chelated fertilizer, adopt the mode of mist projection granulating to mix with macroelement fertilizer, drug effect fertilizer efficiency discharges better, nutritious, disposable employed, can provide desired nutritional to plant, there is again insecticidal action, alleviate peasant's labour intensity, saving of work and time, can effectively improve the output of farm crop.
Embodiment
Embodiment 1
By following weight, take raw material: 20 kilograms, nitrogenous fertilizer, 4 kilograms, phosphate fertilizer, 6 kilograms, potash fertilizer, 20 kilograms of humic acid, 5 kilograms of citric acids, 2 kilograms of ammonium borates, 5 kilograms, magnesium sulfate, 5 kilograms, zinc sulfate, 1 kilogram of Chlorpyrifos 94,1.5 kilograms of clothianidins;
The fertile preparation process of this humic acid chelating boron magnesium zinc medicine is as follows:
1.1,5 kilograms of citric acids, 2 kilograms of ammonium borates, 5 kilograms of magnesium sulfate and 5 kilograms of zinc sulfate are added in reactor, add 200 kg of water, at 80 ℃ of reaction 60min, and then add 20 kilograms of humic acid, at 80 ℃ of reaction 90min, make middle trace element chelated fertilizer feed liquid;
1.2,1 kilogram of Chlorpyrifos 94 and 1.5 kilograms of clothianidins are added in the middle trace element chelated fertilizer feed liquid that step 1.1 makes, obtain agricultural chemicals chelating fertilizer mixed solution;
1.3,6 kilograms, 20 kilograms, nitrogenous fertilizer, 4 kilograms, phosphate fertilizer and potash fertilizer is put into tablets press, the agricultural chemicals chelating fertilizer mixed solution making by step 1.2 carries out mist projection granulating, obtains humic acid chelating boron magnesium zinc medicine fertile.
Embodiment 2
By following weight, take raw material: 30 kilograms, nitrogenous fertilizer, 10 kilograms, phosphate fertilizer, 10 kilograms, potash fertilizer, 10 kilograms of humic acid, 8 kilograms of citric acids, 1 kilogram of ammonium borate, 6 kilograms, magnesium sulfate, 3 kilograms, zinc sulfate, 2 kilograms of Chlorpyrifos 94,1 kilogram of clothianidin.
The fertile preparation process of this humic acid chelating boron magnesium zinc medicine is as follows:
1.1,8 kilograms of citric acids, 1 kilogram of ammonium borate, 6 kilograms of magnesium sulfate and 3 kilograms of zinc sulfate are added in reactor, add 200 kg of water, at 90 ℃ of reaction 40min, and then add 10 kilograms of humic acid, at 90 ℃ of reaction 60min, make middle trace element chelated fertilizer feed liquid;
1.2,2 kilograms of Chlorpyrifos 94 and 1 kilogram of clothianidin are added in the middle trace element chelated fertilizer feed liquid that step 1.1 makes, obtain agricultural chemicals chelating fertilizer mixed solution;
1.3,10 kilograms, 30 kilograms, nitrogenous fertilizer, 10 kilograms, phosphate fertilizer and potash fertilizer is put into tablets press, the agricultural chemicals chelating fertilizer mixed solution making by step 1.2 carries out mist projection granulating, obtains humic acid chelating boron magnesium zinc medicine fertile.
Embodiment 3
By following weight, take raw material: 30 kilograms, nitrogenous fertilizer, 10 kilograms, phosphate fertilizer, 20 kilograms, potash fertilizer, 15 kilograms of humic acid, 6 kilograms of citric acids, 1.5 kilograms of ammonium borates, 5.5 kilograms, magnesium sulfate, 4 kilograms, zinc sulfate, 1.5 kilograms of Chlorpyrifos 94,1.2 kilograms of clothianidins.
The fertile preparation process of this humic acid chelating boron magnesium zinc medicine is as follows:
1.1,6 kilograms of citric acids, 1.5 kilograms of ammonium borates, 5.5 kilograms of magnesium sulfate and 4 kilograms of zinc sulfate are added in reactor, add 200 kg of water, at 85 ℃ of reaction 50min, and then add 15 kilograms of humic acid, at 85 ℃ of reaction 75min, make middle trace element chelated fertilizer feed liquid;
1.2,1.5 kilograms of Chlorpyrifos 94 and 1.2 kilograms of clothianidins are added in the middle trace element chelated fertilizer feed liquid that step 1.1 makes, obtain agricultural chemicals chelating fertilizer mixed solution;
1.3,20 kilograms, 30 kilograms, nitrogenous fertilizer, 10 kilograms, phosphate fertilizer and potash fertilizer is put into tablets press, the agricultural chemicals chelating fertilizer mixed solution making by step 1.2 carries out mist projection granulating, obtains humic acid chelating boron magnesium zinc medicine fertile.
Comparative example 1
5 kilograms, 20 kilograms, nitrogenous fertilizer, 4 kilograms, phosphate fertilizer, 6 kilograms, potash fertilizer, 20 kilograms of humic acid, 2 kilograms of ammonium borates, 5 kilograms, magnesium sulfate and zinc sulfate mix, and are crushed to 80 orders, make boron magnesium zinc humic acid Chemical Mixed Fertilizer.
The boron magnesium zinc humic acid Chemical Mixed Fertilizer humic acid chelating boron magnesium zinc medicine of the embodiment of the present invention 1～embodiment 3 is fertile and comparative example 1 is applied in wheat paddock, 30 kgs/acre of amounts of application, use and between the field period of boron magnesium zinc humic acid Chemical Mixed Fertilizer, use separately Chlorpyrifos 94 and carry out desinsection, as shown in table 1 to the effect of farm crop.
Table 1
As can be seen from Table 1, the utilization ratio of the middle trace element of the boron of the embodiment of the present invention 1～embodiment 3, zinc, magnesium obviously improves, and can supplement the middle trace element of the needed boron of plant-growth, zinc, magnesium, also can supplement nitrogen phosphorus potassium.The humic acid chelating boron magnesium zinc medicine fertilizer of the embodiment of the present invention～embodiment 3 also has certain slow releasing function, and fertilizer efficiency, drug action time are long, and Chlorpyrifos 94 and clothianidin compound use, than using separately Chlorpyrifos 94 good drug efficacy.
Claims (4)
1. a humic acid chelating boron magnesium zinc medicine is fertile, it is characterized in that: count by weight by following raw material and form:
30 parts～60 parts of macroelement fertilizers;
10 parts～20 parts of humic acid;
5 parts～8 parts of citric acids;
1 part～2 parts of ammonium borates;
5 parts～6 parts, magnesium sulfate;
3 parts～5 parts, zinc sulfate;
1 part～2 parts of Chlorpyrifos 94;
1 part～1.5 parts of clothianidins.
2. humic acid chelating boron magnesium zinc medicine according to claim 1 is fertile, it is characterized in that: meter by weight, contains 10 parts～15 parts nitrogenous fertilizer, phosphate fertilizer and 3 parts～10 parts potash fertilizer of 2 parts～5 parts in macroelement fertilizer.
3. a preparation method for humic acid chelating boron magnesium zinc medicine fertilizer, is characterized in that: concrete steps are as follows:
1.1, according to parts by weight meter, 5 parts～8 parts citric acids, 1 part～2 parts ammonium borates, 5 parts～6 parts magnesium sulfate and 3 parts～5 parts zinc sulfate are added in reactor, add 200 parts of water, at 80 ℃～90 ℃ reaction 40min～60min, and then add 10 parts～20 parts humic acid, at 80 ℃～90 ℃ reaction 60min～90min, make middle trace element chelated fertilizer feed liquid;
1.2, according to parts by weight meter, 1 part～2 portions Chlorpyrifos 94 and 1 part～1.5 parts clothianidins are added in the middle trace element chelated fertilizer feed liquid that step 1.1 makes, obtain agricultural chemicals chelating fertilizer mixed solution;
1.3, according to parts by weight meter, 30 parts～60 parts macroelement fertilizers are put into tablets press, the agricultural chemicals chelating fertilizer mixed solution making by step 1.2 carries out mist projection granulating, obtains humic acid chelating boron magnesium zinc medicine fertile.
4. the preparation method of humic acid chelating boron magnesium zinc medicine fertilizer according to claim 3, is characterized in that: meter by weight, contains 10 parts～15 parts nitrogenous fertilizer, phosphate fertilizer and 3 parts～10 parts potash fertilizer of 2 parts～5 parts in macroelement fertilizer.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310682140.7A CN103664414A (en) | 2013-12-16 | 2013-12-16 | Humic acid chelated with boron, magnesium and zinc medicine fertilizer and preparation method thereof |
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| CN201310682140.7A CN103664414A (en) | 2013-12-16 | 2013-12-16 | Humic acid chelated with boron, magnesium and zinc medicine fertilizer and preparation method thereof |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591881A (en) * | 2014-12-31 | 2015-05-06 | 辽宁南洋肥业有限公司 | Preparation method of biological controlled-release drug fertilizer |
| CN105237277A (en) * | 2015-08-27 | 2016-01-13 | 辽宁省农业科学院 | Multifunctional boron-magnesium-zinc humic acid chelated ecological fertilizer |
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| CN101851128A (en) * | 2009-10-14 | 2010-10-06 | 李勇 | Plant compound fertilizer |
| CN101857472A (en) * | 2009-04-10 | 2010-10-13 | 董旭 | Foliar compound fertilizer and preparation method thereof |
| CN102531776A (en) * | 2011-12-23 | 2012-07-04 | 于永波 | Compound microbial fertilizer and method for producing same |
| CN103030474A (en) * | 2013-01-15 | 2013-04-10 | 广西汇丰生物科技有限公司 | Sugar cane pesticide fertilizer granule and preparation method thereof |
| CN103415214A (en) * | 2011-03-10 | 2013-11-27 | 迪帕克·普兰吉万达斯·沙阿 | An agrochemical composition comprising zinc, sulfur and a pesticidal active ingredient |
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2013
- 2013-12-16 CN CN201310682140.7A patent/CN103664414A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101857472A (en) * | 2009-04-10 | 2010-10-13 | 董旭 | Foliar compound fertilizer and preparation method thereof |
| CN101851128A (en) * | 2009-10-14 | 2010-10-06 | 李勇 | Plant compound fertilizer |
| CN103415214A (en) * | 2011-03-10 | 2013-11-27 | 迪帕克·普兰吉万达斯·沙阿 | An agrochemical composition comprising zinc, sulfur and a pesticidal active ingredient |
| CN102531776A (en) * | 2011-12-23 | 2012-07-04 | 于永波 | Compound microbial fertilizer and method for producing same |
| CN103030474A (en) * | 2013-01-15 | 2013-04-10 | 广西汇丰生物科技有限公司 | Sugar cane pesticide fertilizer granule and preparation method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104591881A (en) * | 2014-12-31 | 2015-05-06 | 辽宁南洋肥业有限公司 | Preparation method of biological controlled-release drug fertilizer |
| CN105237277A (en) * | 2015-08-27 | 2016-01-13 | 辽宁省农业科学院 | Multifunctional boron-magnesium-zinc humic acid chelated ecological fertilizer |
| CN105237277B (en) * | 2015-08-27 | 2018-11-13 | 辽宁省农业科学院 | A kind of multi-functional boron magnesium zinc humic acid chelating Eco-fertilizer |
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Application publication date: 20140326 |