CN103651384A - Suspoemulsion containing spinosad and tebufenpyrad and application of suspoemulsion - Google Patents
Suspoemulsion containing spinosad and tebufenpyrad and application of suspoemulsion Download PDFInfo
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- CN103651384A CN103651384A CN201310670127.XA CN201310670127A CN103651384A CN 103651384 A CN103651384 A CN 103651384A CN 201310670127 A CN201310670127 A CN 201310670127A CN 103651384 A CN103651384 A CN 103651384A
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- Prior art keywords
- tebufenpyrad
- multiple killing
- killing teichomycin
- suspension emulsion
- suspoemulsion
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- ZZYSLNWGKKDOML-UHFFFAOYSA-N tebufenpyrad Chemical compound CCC1=NN(C)C(C(=O)NCC=2C=CC(=CC=2)C(C)(C)C)=C1Cl ZZYSLNWGKKDOML-UHFFFAOYSA-N 0.000 title claims abstract description 53
- 239000005658 Tebufenpyrad Substances 0.000 title claims abstract description 52
- JFLRKDZMHNBDQS-UCQUSYKYSA-N CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C Chemical compound CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C(=C[C@H]3[C@@H]2CC(=O)O1)C)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C.CC[C@H]1CCC[C@@H]([C@H](C(=O)C2=C[C@H]3[C@@H]4C[C@@H](C[C@H]4C=C[C@H]3C2CC(=O)O1)O[C@H]5[C@@H]([C@@H]([C@H]([C@@H](O5)C)OC)OC)OC)C)O[C@H]6CC[C@@H]([C@H](O6)C)N(C)C JFLRKDZMHNBDQS-UCQUSYKYSA-N 0.000 title abstract description 6
- 239000005930 Spinosad Substances 0.000 title abstract description 6
- 229940014213 spinosad Drugs 0.000 title abstract description 6
- 239000004548 suspo-emulsion Substances 0.000 title abstract 5
- 108010053950 Teicoplanin Proteins 0.000 claims description 50
- BJNLLBUOHPVGFT-QRZIFLFXSA-N teichomycin Chemical compound CCCCCCCCCC(=O)N[C@@H]1[C@@H](O)[C@H](O)[C@@H](CO)O[C@H]1OC(C(=C1)OC=2C(=CC(=CC=2)[C@@H](O[C@H]2[C@@H]([C@@H](O)[C@H](O)[C@@H](CO)O2)NC(C)=O)[C@H]2C(N[C@H](C3=CC(O)=CC(O[C@@H]4[C@H]([C@@H](O)[C@H](O)[C@@H](CO)O4)O)=C3C=3C(O)=CC=C(C=3)[C@@H](NC3=O)C(=O)N2)C(O)=O)=O)Cl)=C(OC=2C(=CC(C[C@H](C(N4)=O)NC(=O)[C@H](N)C=5C=C(O6)C(O)=CC=5)=CC=2)Cl)C=C1[C@H]3NC(=O)[C@@H]4C1=CC6=CC(O)=C1 BJNLLBUOHPVGFT-QRZIFLFXSA-N 0.000 claims description 50
- 239000000839 emulsion Substances 0.000 claims description 14
- 239000000725 suspension Substances 0.000 claims description 13
- 241000488583 Panonychus ulmi Species 0.000 claims description 9
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 8
- QYYMDNHUJFIDDQ-UHFFFAOYSA-N 5-chloro-2-methyl-1,2-thiazol-3-one;2-methyl-1,2-thiazol-3-one Chemical compound CN1SC=CC1=O.CN1SC(Cl)=CC1=O QYYMDNHUJFIDDQ-UHFFFAOYSA-N 0.000 claims description 7
- 108010010803 Gelatin Proteins 0.000 claims description 7
- RCEAADKTGXTDOA-UHFFFAOYSA-N OS(O)(=O)=O.CCCCCCCCCCCC[Na] Chemical compound OS(O)(=O)=O.CCCCCCCCCCCC[Na] RCEAADKTGXTDOA-UHFFFAOYSA-N 0.000 claims description 7
- 210000000481 breast Anatomy 0.000 claims description 7
- MSJMDZAOKORVFC-UAIGNFCESA-L disodium maleate Chemical compound [Na+].[Na+].[O-]C(=O)\C=C/C([O-])=O MSJMDZAOKORVFC-UAIGNFCESA-L 0.000 claims description 7
- 229920000159 gelatin Polymers 0.000 claims description 7
- 239000008273 gelatin Substances 0.000 claims description 7
- 235000019322 gelatine Nutrition 0.000 claims description 7
- 235000011852 gelatine desserts Nutrition 0.000 claims description 7
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical class CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims description 7
- 239000002904 solvent Substances 0.000 claims description 7
- STCOOQWBFONSKY-UHFFFAOYSA-N tributyl phosphate Chemical compound CCCCOP(=O)(OCCCC)OCCCC STCOOQWBFONSKY-UHFFFAOYSA-N 0.000 claims description 7
- 239000004480 active ingredient Substances 0.000 claims description 5
- 241000488581 Panonychus citri Species 0.000 claims description 3
- 241000344246 Tetranychus cinnabarinus Species 0.000 claims description 3
- 239000000203 mixture Substances 0.000 abstract description 12
- 239000002917 insecticide Substances 0.000 abstract description 7
- 241000607479 Yersinia pestis Species 0.000 abstract description 6
- 230000007613 environmental effect Effects 0.000 abstract description 3
- 239000000575 pesticide Substances 0.000 abstract description 3
- 238000013329 compounding Methods 0.000 abstract 1
- 230000001681 protective effect Effects 0.000 abstract 1
- 239000003814 drug Substances 0.000 description 11
- 241000238631 Hexapoda Species 0.000 description 6
- 230000000694 effects Effects 0.000 description 6
- 150000001875 compounds Chemical class 0.000 description 5
- 238000000034 method Methods 0.000 description 5
- 230000002195 synergetic effect Effects 0.000 description 4
- 239000003905 agrochemical Substances 0.000 description 3
- 238000007796 conventional method Methods 0.000 description 3
- 238000010790 dilution Methods 0.000 description 3
- 239000012895 dilution Substances 0.000 description 3
- 238000002360 preparation method Methods 0.000 description 3
- 238000005507 spraying Methods 0.000 description 3
- 239000000375 suspending agent Substances 0.000 description 3
- 241000894006 Bacteria Species 0.000 description 2
- ZHNUHDYFZUAESO-UHFFFAOYSA-N Formamide Chemical compound NC=O ZHNUHDYFZUAESO-UHFFFAOYSA-N 0.000 description 2
- 241000868102 Saccharopolyspora spinosa Species 0.000 description 2
- 239000002131 composite material Substances 0.000 description 2
- 230000000749 insecticidal effect Effects 0.000 description 2
- 230000002045 lasting effect Effects 0.000 description 2
- SRJQTHAZUNRMPR-UHFFFAOYSA-N spinosyn A Natural products CC1C(=O)C2=CC3C4CC(OC5C(C(OC)C(OC)C(C)O5)OC)CC4C=CC3C2CC(=O)OC(CC)CCCC1OC1CCC(N(C)C)C(C)O1 SRJQTHAZUNRMPR-UHFFFAOYSA-N 0.000 description 2
- SRJQTHAZUNRMPR-UYQKXTDMSA-N spinosyn A Chemical compound O([C@H]1CCC[C@@H](OC(=O)C[C@H]2[C@@H]3C=C[C@@H]4C[C@H](C[C@H]4[C@@H]3C=C2C(=O)[C@@H]1C)O[C@H]1[C@@H]([C@H](OC)[C@@H](OC)[C@H](C)O1)OC)CC)[C@H]1CC[C@H](N(C)C)[C@@H](C)O1 SRJQTHAZUNRMPR-UYQKXTDMSA-N 0.000 description 2
- RDECBWLKMPEKPM-UHFFFAOYSA-N spinosyn D Natural products CC1C(=O)C2=CC3C4CC(OC5C(C(OC)C(OC)C(C)O5)OC)CC4C(C)=CC3C2CC(=O)OC(CC)CCCC1OC1CCC(N(C)C)C(C)O1 RDECBWLKMPEKPM-UHFFFAOYSA-N 0.000 description 2
- RDECBWLKMPEKPM-PSCJHHPTSA-N spinosyn D Chemical compound O([C@H]1CCC[C@@H](OC(=O)C[C@H]2[C@@H]3C=C(C)[C@@H]4C[C@H](C[C@H]4[C@@H]3C=C2C(=O)[C@@H]1C)O[C@H]1[C@@H]([C@H](OC)[C@@H](OC)[C@H](C)O1)OC)CC)[C@H]1CC[C@H](N(C)C)[C@@H](C)O1 RDECBWLKMPEKPM-PSCJHHPTSA-N 0.000 description 2
- SNICXCGAKADSCV-JTQLQIEISA-N (-)-Nicotine Chemical compound CN1CCC[C@H]1C1=CC=CN=C1 SNICXCGAKADSCV-JTQLQIEISA-N 0.000 description 1
- 241000186361 Actinobacteria <class> Species 0.000 description 1
- 241000254173 Coleoptera Species 0.000 description 1
- 241001517923 Douglasiidae Species 0.000 description 1
- 241000258937 Hemiptera Species 0.000 description 1
- 239000005906 Imidacloprid Substances 0.000 description 1
- 240000001307 Myosotis scorpioides Species 0.000 description 1
- 241000187560 Saccharopolyspora Species 0.000 description 1
- 241001414989 Thysanoptera Species 0.000 description 1
- 239000000642 acaricide Substances 0.000 description 1
- 230000004913 activation Effects 0.000 description 1
- 150000001298 alcohols Chemical class 0.000 description 1
- 150000001338 aliphatic hydrocarbons Chemical class 0.000 description 1
- 150000004945 aromatic hydrocarbons Chemical class 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 235000013399 edible fruits Nutrition 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002148 esters Chemical class 0.000 description 1
- 150000002170 ethers Chemical class 0.000 description 1
- 239000012530 fluid Substances 0.000 description 1
- 229960003692 gamma aminobutyric acid Drugs 0.000 description 1
- BTCSSZJGUNDROE-UHFFFAOYSA-N gamma-aminobutyric acid Chemical compound NCCCC(O)=O BTCSSZJGUNDROE-UHFFFAOYSA-N 0.000 description 1
- 238000010413 gardening Methods 0.000 description 1
- 150000008282 halocarbons Chemical class 0.000 description 1
- YWTYJOPNNQFBPC-UHFFFAOYSA-N imidacloprid Chemical compound [O-][N+](=O)\N=C1/NCCN1CC1=CC=C(Cl)N=C1 YWTYJOPNNQFBPC-UHFFFAOYSA-N 0.000 description 1
- 229940056881 imidacloprid Drugs 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000003120 macrolide antibiotic agent Substances 0.000 description 1
- 229940041033 macrolides Drugs 0.000 description 1
- 230000010534 mechanism of action Effects 0.000 description 1
- 229960002715 nicotine Drugs 0.000 description 1
- SNICXCGAKADSCV-UHFFFAOYSA-N nicotine Natural products CN1CCCC1C1=CC=CN=C1 SNICXCGAKADSCV-UHFFFAOYSA-N 0.000 description 1
- 230000003151 ovacidal effect Effects 0.000 description 1
- 239000002574 poison Substances 0.000 description 1
- 231100000614 poison Toxicity 0.000 description 1
- 231100000572 poisoning Toxicity 0.000 description 1
- 230000000607 poisoning effect Effects 0.000 description 1
- 230000003449 preventive effect Effects 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- 239000002689 soil Substances 0.000 description 1
- 238000001228 spectrum Methods 0.000 description 1
- 210000002784 stomach Anatomy 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 230000002459 sustained effect Effects 0.000 description 1
- 230000009885 systemic effect Effects 0.000 description 1
- 230000001988 toxicity Effects 0.000 description 1
- 231100000419 toxicity Toxicity 0.000 description 1
- 231100000820 toxicity test Toxicity 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
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- Agricultural Chemicals And Associated Chemicals (AREA)
Abstract
The invention belongs to the technical field of compounding pesticides, and specifically relates to a suspoemulsion containing spinosad and tebufenpyrad and an application of the suspoemulsion. The effective components of the suspoemulsions are spinosad and tebufenpyrad in a weight ratio of 5:1-15:1. The suspoemulsion containing spinosad and tebufenpyrad relieves the problem of existing pest resistance to insecticide to the maximum extent, so that the use level of pesticides is reduced, and the influence on the environment is further relieved, thereby satisfying the trend of environmental protection of the future society. The composition provided by the invention has the optimal crop protective effect.
Description
Technical field
The invention belongs to the composite technical field of agricultural chemical insecticide, be specially suspension emulsion and the application of a kind of multiple killing teichomycin and tebufenpyrad.
Background technology
Multiple killing teichomycin
It is a kind of macrolides Nuisanceless high-efficient biological insecticides that extract in thorn sugared many born of the same parents bacterium (Saccharopolyspora spinosa) zymotic fluid that multiple killing teichomycin has another name called pleocidin (Spinosad).Produce parent strain soil actinomycetes thorniness saccharopolyspora strain (the Saccharopolyspora spinosa Metrz & Yao) initial separation of pleocidin from one of Caribbean discarded wine brewing field.The researcher of The Dow Agrosciences, LLC. (Xian Wei Dow Agrosciences LLC) finds that this bacterium can produce the compound that insecticidal activity is very high, and practical product is the mixture of spinosyn A and spinosyn D, therefore be called spinosad.The mode of action of multiple killing teichomycin is novel, can sustained activation target insect acetylcholine nicotine receptor, but its binding site is different from nicotine and Imidacloprid.Multiple killing teichomycin also can affect GABA acceptor, but mechanism of action is unclear.At present also do not know whether have cross tolerance with the insecticide of other types.These compounds can cause that target plant-feed insect is as dead rapidly in caterpillar, leaf miner, thrips and leaf-feeding beetle, although administrative department's strong request is not used when resistance occurs, the moderate residual activity of this compound has reduced resistance and the raw possibility of mass-sending.When applying with 12-150g/hm, find no poisoning.
Fusing point (℃): Spinosyn A:84.0～99.5, Spinosyn D:161.5～170.
Solvability: water 235mg/L(PH=7); Can be miscible with arbitrary proportion and alcohols, aliphatic hydrocarbon, aromatic hydrocarbon, halogenated hydrocarbons, ester class, ethers and ketone.
Insect is had and tagged fast and stomach poison function, blade is had to stronger osmosis, can kill subepidermal insect, the longevity of residure is longer, and some insects are had to certain ovicidal action.Without systemic action.Be suitable for using on vegetables, fruit tree, gardening, crops, insecticidal effect be subject to rain affect less.Make insect generally to such medicament, produce very strong pesticide resistance, preventive effect is not equal to before.
Tebufenpyrad
English name: Tebufenpyrad
Molecular formula: C18H24CLN3O
CA registration number: 119168-77-3
Chemical name: N-(4-tertiary butyl benzyl) the chloro-3-ethyl-1-of-4-methylpyrazole-5-base formamide
Fusing point (℃): 61～62
Vapour pressure: 0.010787mPa (40 ℃)
Purposes:
This product belongs to amide-type miticide.Various mite classes and Semiptera, homoptera pest are had to tall and erect effect, and all have immediate effect with efficient the dawn each vegetative period to mite class, the lasting period is long.
But its action effect is also very single, after large-scale application, resistance risk is also very high.
Summary of the invention
The object of the present invention is to provide a kind of suspension emulsion and application thereof that has multiple killing teichomycin and tebufenpyrad; said composition active ingredient is multiple killing teichomycin and tebufenpyrad; wherein the weight ratio of multiple killing teichomycin and tebufenpyrad is; multiple killing teichomycin: tebufenpyrad=5:1-15:1; farthest alleviate the problem of current pest resistance to insecticide, thereby reduced the consumption of agricultural chemicals, also alleviated the impact for environment; the trend that meets future society environmental protection, composition of the present invention is received best crop protection effect.
Technical scheme of the present invention is:
A suspension emulsion for multiple killing teichomycin and tebufenpyrad, active ingredient is multiple killing teichomycin and tebufenpyrad, wherein the weight ratio of multiple killing teichomycin and tebufenpyrad is, multiple killing teichomycin: tebufenpyrad=5:1-15:1.
As preferably, the weight ratio of multiple killing teichomycin and tebufenpyrad is, multiple killing teichomycin: tebufenpyrad=8:1-12:1.
The suspension emulsion of multiple killing teichomycin of the present invention and tebufenpyrad, it consists of following component by weight percentage:
Multiple killing teichomycin 10-70%,
Tebufenpyrad 1-10%,
150# solvent naphtha 3-10%,
Lauryl sodium sulfate 1-3%,
Agriculture breast 400
#5-10%,
Propane diols 1-5%,
Maleic acid disodium salt 1-2%,
Tributyl phosphate 1-4%,
Gelatin 3-5%,
Kathon CG 0.5-1.5%,
Water surplus.
As preferably, the suspension emulsion of multiple killing teichomycin of the present invention and tebufenpyrad, it consists of following component by weight percentage:
Multiple killing teichomycin 20-50%,
Tebufenpyrad 2-6%,
150# solvent naphtha 3-10%,
Lauryl sodium sulfate 1-3%,
Agriculture breast 400
#5-10%,
Propane diols 1-5%,
Maleic acid disodium salt 1-2%,
Tributyl phosphate 1-4%,
Gelatin 3-5%,
Kathon CG 0.5-1.5%,
Water surplus.
Wherein, the total weight percentage of described active ingredient is 25-55%.
The suspension emulsion of multiple killing teichomycin of the present invention and tebufenpyrad, for preventing and treating citrus red mite, Tetranychus cinnabarinus, panonychus ulmi, is particularly useful for preventing and treating panonychus ulmi.
Beneficial effect of the present invention is:
Said composition is compound suspend emulsion composition, compare with single product, the feature with binary composition, strengthened significantly effect, delay the generation of pest resistance to insecticide, and expanded effective active control spectrum, and thering is speed fast, the lasting period is long, consumption is low, eco-friendly feature, the more important thing is, this compounded combination has effectively resisted the problem that pest resistance produces, farthest alleviated the problem of current pest resistance to insecticide, thereby reduced the consumption of agricultural chemicals, also alleviated the impact for environment, met the trend of future society environmental protection.The control efficiency of composition of the present invention is especially good to control panonychus ulmi, is mainly by the result of the synergistic function between each component.
To the compound synergic research of composition of the present invention, test adopts panonychus ulmi for test.
According to the abundant method of Sun Yun, calculate the toxicity index of medicament and mixed co-toxicity coefficient (CTC value).
The toxicity test result of the different proportion relations of table 1 to panonychus ulmi
| Process | Co-toxicity coefficient |
| Multiple killing teichomycin 5: tebufenpyrad 1 | 147.9 |
| Multiple killing teichomycin 8: tebufenpyrad 1 | 236.8 |
| Multiple killing teichomycin 12: tebufenpyrad 1 | 232.7 |
| Multiple killing teichomycin 15: tebufenpyrad 1 | 156.8 |
| Multiple killing teichomycin | ? |
| Tebufenpyrad | ? |
As can be seen from Table 1, multiple killing teichomycin and tebufenpyrad composite, have very high synergistic effect, especially multiple killing teichomycin: during tebufenpyrad=8:1-12:1, synergistic effect is more obvious, and the good results are evident to panonychus ulmi.
Embodiment
Below by specific embodiment, technical scheme of the present invention is described in detail.
Embodiment 1
The composition of 26% multiple killing teichomycin and tebufenpyrad
Multiple killing teichomycin 24%,
Tebufenpyrad 2%,
150# solvent naphtha 10%,
Lauryl sodium sulfate 3%,
Agriculture breast 400
#8%,
Propane diols 18%,
Maleic acid disodium salt 18%,
Tributyl phosphate 2%,
Gelatin 5%,
Kathon CG 0.5%,
Water surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to prevent and treat citrus red mite:
Co-toxicity coefficient is: 232.9;
By 3000 times of thin up sprayings, after medicine, 15 days control efficiency are that 96.2%, 24% 2000 times of multiple killing teichomycin suspending agent dilutions and 2% tebufenpyrad missible oil dilute 500 times, with same method, use respectively, after medicine 15 days, control efficiency was respectively 72.3% and 68.4%, significant difference.
Embodiment 2
The composition of 44% multiple killing teichomycin and tebufenpyrad
Multiple killing teichomycin 40%,
Tebufenpyrad 4%,
150# solvent naphtha 7%,
Lauryl sodium sulfate 1%,
Agriculture breast 400
#10%,
Propane diols 5%,
Maleic acid disodium salt 2%,
Tributyl phosphate 3%,
Gelatin 3%,
Kathon CG 1.5%,
Water surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to prevent and treat Tetranychus cinnabarinus:
Co-toxicity coefficient is: 246.2;
By 4000 times of thin up sprayings, after medicine, 15 days control efficiency are that 98.2%, 40% 3000 times of multiple killing teichomycin suspending agent dilutions and 4% tebufenpyrad missible oil dilute 200 times, with same method, use respectively, after medicine 15 days, control efficiency was respectively 71.8% and 72.5%, significant difference.
Embodiment 3
The composition of 54% multiple killing teichomycin and tebufenpyrad
Multiple killing teichomycin 48%,
Tebufenpyrad 6%,
150# solvent naphtha 3%,
Lauryl sodium sulfate 2%,
Agriculture breast 400
#52%,
Propane diols 4%,
Maleic acid disodium salt 1%,
Tributyl phosphate 4%,
Gelatin 4%,
Kathon CG 1%,
Water surplus.
Preparation method is the conventional method of this area.
This embodiment medicament is applied to prevent and treat panonychus ulmi:
Co-toxicity coefficient is: 232.9;
By 4000 times of thin up sprayings, after medicine, 15 days control efficiency are that 99.0%, 48% 3000 times of multiple killing teichomycin suspending agent dilutions and 6% tebufenpyrad missible oil dilute 500 times, with same method, use respectively, after medicine 15 days, control efficiency was respectively 78.5% and 70.1%, significant difference.
Claims (6)
1. a suspension emulsion for multiple killing teichomycin and tebufenpyrad, active ingredient is multiple killing teichomycin and tebufenpyrad, wherein the weight ratio of multiple killing teichomycin and tebufenpyrad is, multiple killing teichomycin: tebufenpyrad=5:1-15:1.
2. the suspension emulsion of multiple killing teichomycin according to claim 1 and tebufenpyrad, is characterized in that, the weight ratio of multiple killing teichomycin and tebufenpyrad is, multiple killing teichomycin: tebufenpyrad=8:1-12:1.
3. the suspension emulsion of multiple killing teichomycin according to claim 1 and 2 and tebufenpyrad, is characterized in that, it consists of following component by weight percentage:
Multiple killing teichomycin 10-70%,
Tebufenpyrad 1-10%,
150# solvent naphtha 3-10%,
Lauryl sodium sulfate 1-3%,
Agriculture breast 400
#5-10%,
Propane diols 1-5%,
Maleic acid disodium salt 1-2%,
Tributyl phosphate 1-4%,
Gelatin 3-5%,
Kathon CG 0.5-1.5%,
Water surplus.
4. the suspension emulsion of multiple killing teichomycin according to claim 3 and tebufenpyrad, is characterized in that, it consists of following component by weight percentage:
Multiple killing teichomycin 20-50%,
Tebufenpyrad 2-6%,
150# solvent naphtha 3-10%,
Lauryl sodium sulfate 1-3%,
Agriculture breast 400
#5-10%,
Propane diols 1-5%,
Maleic acid disodium salt 1-2%,
Tributyl phosphate 1-4%,
Gelatin 3-5%,
Kathon CG 0.5-1.5%,
Water surplus.
5. according to the multiple killing teichomycin described in the arbitrary claim of claim 1-4 and the suspension emulsion of tebufenpyrad, it is characterized in that, the total weight percentage of described active ingredient is 25-55%.
6. the suspension emulsion of multiple killing teichomycin according to claim 5 and tebufenpyrad, for preventing and treating citrus red mite, Tetranychus cinnabarinus, panonychus ulmi, is particularly useful for preventing and treating panonychus ulmi.
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| EP2363023A1 (en) * | 2010-03-04 | 2011-09-07 | Basf Se | Synergistic fungicidal and insecticidal mixtures |
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| WO2000002453A1 (en) * | 1998-07-07 | 2000-01-20 | Novartis Ag | Pesticidal composition comprising emamectin |
| CN101018482A (en) * | 2004-07-20 | 2007-08-15 | 拜尔农作物科学股份公司 | Insecticidal agents based on selected insecticides and safeners |
| JP2006213664A (en) * | 2005-02-04 | 2006-08-17 | Mitsui Chemicals Inc | Plant disease control composition and its control method |
| EP2363023A1 (en) * | 2010-03-04 | 2011-09-07 | Basf Se | Synergistic fungicidal and insecticidal mixtures |
| WO2011144593A1 (en) * | 2010-05-18 | 2011-11-24 | Basf Se | Pesticidal mixtures comprising insecticides and pyraclostrobin |
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