CN103642285A - Acrylic resin paint for vehicles and preparation method therefor - Google Patents
Acrylic resin paint for vehicles and preparation method therefor Download PDFInfo
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- CN103642285A CN103642285A CN201310413145.XA CN201310413145A CN103642285A CN 103642285 A CN103642285 A CN 103642285A CN 201310413145 A CN201310413145 A CN 201310413145A CN 103642285 A CN103642285 A CN 103642285A
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Abstract
The invention provides an acrylic resin paint for vehicles and a preparation method therefor. The paint is prepared from the following raw materials, by weight, 70-75 parts of thermoplastic acrylic resins, 2-3 parts of glacial acetic acid, 3-4 parts of sulfonated oil, 2-3 parts of Turkey red oil, 4-5 parts of morpholine, 3-5 parts of p-benzoquinone, 3-5 parts of methyl trichlorosilane, 12-15 parts of acrylonitrile, 1-2 parts of fatty alcohol polyoxyethylene ether phosphate ester, 6-8 parts of maleic anhydride, 9-12 parts of N,N-diethyl divinyl triamine, 15-18 parts of ethyl acetate, 8-10 parts of xylene and 3-4 parts of film forming auxiliary agents. The raw materials are nontoxic, so the paint has minimal poison to human body during production and usage processes and has low pollution to the environment. In the recipe, film forming resins are added, compatibility of each component is raised, and the film forming effect is raised greatly. The obtained paint film has excellent water resistance and corrosion resistance, firm bonding strength and excellent alkali resistance and high temperature resistance.
Description
Technical field
The present invention relates to metal rust preventing technical field, be specifically related to a kind of automobile-used acrylic resin paint and preparation method thereof.
Background technology
Metallic corrosion is the very serious problem that people face.The metal that scrap because of metallic corrosion every year in the whole world reaches more than several hundred million tons, and financial loss accounts for 1.5%～2.5% of total value of production in national economy.Metal rusting is the most general, loss is maximum a kind of corrosion.Antirust work is always one of great scientific research task both domestic and external, and people work out the corrosion that many kinds of measures prevented and suppressed metal, and antirust with coating is a kind of effective means.
Summary of the invention
The object of this invention is to provide a kind of automobile-used acrylic resin paint and preparation method thereof, various metals is had to antirust function.
Technical scheme of the present invention is as follows:
An automobile-used acrylic resin paint, is characterized in that, its feed composition by following weight part is prepared from:
Thermoplastic acrylic resin 70-75, Glacial acetic acid 2-3, sulphonated oil 3-4, alizarin assistant 2-3, morpholine 4-5, para benzoquinone 3-5, METHYL TRICHLORO SILANE 3-5, vinyl cyanide 12-15, aliphatic alcohol polyoxyvinethene phosphate 1-2, MALEIC ANHYDRIDE 6-8, N, N-diethyl divinyl triamine 9-12, ethyl acetate 15-18, dimethylbenzene 8-10, film coalescence aid 3-4.
Described automobile-used acrylic resin paint, is characterized in that: described film coalescence aid is prepared from by the raw material of following weight part:
Alcohol ester 12 10-12, nano-sized carbon 0.1-0.2, ricinolic acid 1-2, aluminum nitride powder 2-3,2-amino-2-methyl-1-propanol 2-3, silane resin acceptor kh-550 1-2, diatomite in powder 0.3-0.5, tributyl citrate 3-4, ethyl acetate 4-5, Oil of Eucalyptus 1-2, methylethyl ketone peroxide 1-2;
Preparation method: nano-sized carbon, ricinolic acid, aluminum nitride powder, 2-amino-2-methyl-1-propanol, tributyl citrate, ethyl acetate are mixed, dispersed with stirring, then, add again methylethyl ketone peroxide, stirring reaction 40-60 minute, then, is heated to 75-80 ℃, add Oil of Eucalyptus, alcohol ester 12, continue to stir 30-40 minute, be cooled to 60-65 ℃, add other remaining component, 1200-1400 rev/min of stirring reaction 1-2 hour, obtains.
The preparation method of described automobile-used acrylic resin paint, is characterized in that, comprises the following steps:
Dimethylbenzene, sulphonated oil, alizarin assistant, Glacial acetic acid are joined in reactor, stir after 10-15 minute, again by thermoplastic acrylic resin, MALEIC ANHYDRIDE, N, N-diethyl divinyl triamine, vinyl cyanide add wherein, stir after 30-40 minute, finally the rest materials such as the morpholine in formula, para benzoquinone, METHYL TRICHLORO SILANE, aliphatic alcohol polyoxyvinethene phosphate, film coalescence aid, ethyl acetate are joined in reactor together, stir together 20-30 minute, 400 order filter-cloth filterings for mixed slurry, obtain finished product of the present invention.
Beneficial effect of the present invention:
Advantages of nontoxic raw materials of the present invention, therefore production and use procedure are little to human body murder by poisoning, and environmental pollution is low, adds film coalescence aid in formula, has improved the consistency of each composition, has greatly improved film-formation result.The paint film of gained is water-fast, antiseptic property is excellent, and resistance to elevated temperatures is good, and bonding strength is firm, alkaline-resisting, water tolerance is all good.
Embodiment:
Embodiment
An automobile-used acrylic resin paint, its feed composition by following weight (kg) is prepared from:
Thermoplastic acrylic resin 73, Glacial acetic acid 2, sulphonated oil 4, alizarin assistant 3, morpholine 5, para benzoquinone 4, METHYL TRICHLORO SILANE 4, vinyl cyanide 13, aliphatic alcohol polyoxyvinethene phosphate 1, MALEIC ANHYDRIDE 7, N, N-diethyl divinyl triamine 10, ethyl acetate 16, dimethylbenzene 9, film coalescence aid 4;
Concrete preparation method, comprises the following steps:
1, the preparation of film coalescence aid:
(kg) takes alcohol ester 12 by weight, nano-sized carbon 0.1, ricinolic acid 1, aluminum nitride powder 2, 2-amino-2-methyl-1-propanol 3, silane resin acceptor kh-550 1, diatomite in powder 0.4, tributyl citrate 3, ethyl acetate 4, Oil of Eucalyptus 2, methylethyl ketone peroxide 2, by nano-sized carbon, ricinolic acid, aluminum nitride powder, 2-amino-2-methyl-1-propanol, tributyl citrate, ethyl acetate is mixed, dispersed with stirring, then, add again methylethyl ketone peroxide, stirring reaction 40-60 minute, then, be heated to 75-80 ℃, add Oil of Eucalyptus, alcohol ester 12, continue to stir 30-40 minute, be cooled to 60-65 ℃, add other remaining component, 1200-1400 rev/min stirring reaction 1-2 hour and get final product.
2, the preparation of automobile-used acrylic resin paint, make according to the following steps:
Dimethylbenzene, sulphonated oil, alizarin assistant, Glacial acetic acid are joined in reactor, stir after 10-15 minute, again by thermoplastic acrylic resin, MALEIC ANHYDRIDE, N, N-diethyl divinyl triamine, vinyl cyanide add wherein, stir after 30-40 minute, finally the rest materials such as the morpholine in formula, para benzoquinone, METHYL TRICHLORO SILANE, aliphatic alcohol polyoxyvinethene phosphate, film coalescence aid, ethyl acetate are joined in reactor together, stir together 20-30 minute, 400 order filter-cloth filterings for mixed slurry, obtain finished product of the present invention.
Testing data
Rust proof paint prepared by above-described embodiment is according to standard: HG/T2244-1991 < < lathe priming paint > > tests, and result is as following table 1.
The detected result of the performance of table 1 rust proof paint
Claims (3)
1. an automobile-used acrylic resin paint, is characterized in that, its feed composition by following weight part is prepared from:
Thermoplastic acrylic resin 70-75, Glacial acetic acid 2-3, sulphonated oil 3-4, alizarin assistant 2-3, morpholine 4-5, para benzoquinone 3-5, METHYL TRICHLORO SILANE 3-5, vinyl cyanide 12-15, aliphatic alcohol polyoxyvinethene phosphate 1-2, MALEIC ANHYDRIDE 6-8, N, N-diethyl divinyl triamine 9-12, ethyl acetate 15-18, dimethylbenzene 8-10, film coalescence aid 3-4.
2. automobile-used acrylic resin paint according to claim 1, is characterized in that: described film coalescence aid is prepared from by the raw material of following weight part:
Alcohol ester 12 10-12, nano-sized carbon 0.1-0.2, ricinolic acid 1-2, aluminum nitride powder 2-3,2-amino-2-methyl-1-propyl alcohol 2-3, silane resin acceptor kh-550 1-2, diatomite in powder 0.3-0.5, tributyl citrate 3-4, ethyl acetate 4-5, Oil of Eucalyptus 1-2, methylethyl ketone peroxide 1-2;
Preparation method: nano-sized carbon, ricinolic acid, aluminum nitride powder, 2-amino-2-methyl-1-propyl alcohol, tributyl citrate, ethyl acetate are mixed, dispersed with stirring, then, add again methylethyl ketone peroxide, stirring reaction 40-60 minute, then, is heated to 75-80 ℃, add Oil of Eucalyptus, alcohol ester 12, continue to stir 30-40 minute, be cooled to 60-65 ℃, add other remaining component, 1200-1400 rev/min of stirring reaction 1-2 hour, obtains.
3. the preparation method of automobile-used acrylic resin paint according to claim 1, is characterized in that, comprises the following steps:
Dimethylbenzene, sulphonated oil, alizarin assistant, Glacial acetic acid are joined in reactor, stir after 10-15 minute, again by thermoplastic acrylic resin, MALEIC ANHYDRIDE, N, N-diethyl divinyl triamine, vinyl cyanide add wherein, stir after 30-40 minute, finally the rest materials such as the morpholine in formula, para benzoquinone, METHYL TRICHLORO SILANE, aliphatic alcohol polyoxyvinethene phosphate, film coalescence aid, ethyl acetate are joined in reactor together, stir together 20-30 minute, 400 order filter-cloth filterings for mixed slurry, obtain finished product of the present invention.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310413145.XA CN103642285B (en) | 2013-09-10 | 2013-09-10 | A kind of automobile-used acrylic resin paint and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310413145.XA CN103642285B (en) | 2013-09-10 | 2013-09-10 | A kind of automobile-used acrylic resin paint and preparation method thereof |
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| Publication Number | Publication Date |
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| CN103642285A true CN103642285A (en) | 2014-03-19 |
| CN103642285B CN103642285B (en) | 2016-08-10 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310413145.XA Active CN103642285B (en) | 2013-09-10 | 2013-09-10 | A kind of automobile-used acrylic resin paint and preparation method thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018223411A1 (en) * | 2017-06-07 | 2018-12-13 | 南通加隆塑胶有限公司 | Weather resistant paint for automobile outside rearview mirror and preparation method therefor |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61174273A (en) * | 1985-01-28 | 1986-08-05 | Nichirin Rubber Kogyo Kk | Antifouling paint |
| CN102382537A (en) * | 2011-10-17 | 2012-03-21 | 张家港市永法涂料有限公司 | On rust and anti-rust paint emulsion and preparation method thereof |
| CN102417783A (en) * | 2011-10-10 | 2012-04-18 | 漳州市奈特新型建材有限责任公司 | Waterproof/sealing paint with aqueous resin as main body |
| CN102993810A (en) * | 2012-11-28 | 2013-03-27 | 天长市开林化工有限公司 | General water-based quick-drying anti-rust paint and preparation method thereof |
-
2013
- 2013-09-10 CN CN201310413145.XA patent/CN103642285B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JPS61174273A (en) * | 1985-01-28 | 1986-08-05 | Nichirin Rubber Kogyo Kk | Antifouling paint |
| CN102417783A (en) * | 2011-10-10 | 2012-04-18 | 漳州市奈特新型建材有限责任公司 | Waterproof/sealing paint with aqueous resin as main body |
| CN102382537A (en) * | 2011-10-17 | 2012-03-21 | 张家港市永法涂料有限公司 | On rust and anti-rust paint emulsion and preparation method thereof |
| CN102993810A (en) * | 2012-11-28 | 2013-03-27 | 天长市开林化工有限公司 | General water-based quick-drying anti-rust paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| WO2018223411A1 (en) * | 2017-06-07 | 2018-12-13 | 南通加隆塑胶有限公司 | Weather resistant paint for automobile outside rearview mirror and preparation method therefor |
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| CN103642285B (en) | 2016-08-10 |
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Inventor after: Luo Hongguang Inventor before: Kong Huaying |
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| TR01 | Transfer of patent right |
Effective date of registration: 20170315 Address after: 510000 Guangzhou, Baiyun District, Guangdong Huang Park Road, No. 129 (2), Room 401 Patentee after: Guangzhou Jinwei Chemical Co., Ltd. Address before: 244031 Tongling, Anhui Province Economic Development Zone, Lion Rock Road, No. 3636 Patentee before: TONGLING SIDE TECHNOLOGY CO., LTD. |