CN103642203B - A kind of anticorrosion sponge and preparation method thereof - Google Patents
A kind of anticorrosion sponge and preparation method thereof Download PDFInfo
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- CN103642203B CN103642203B CN201310566853.7A CN201310566853A CN103642203B CN 103642203 B CN103642203 B CN 103642203B CN 201310566853 A CN201310566853 A CN 201310566853A CN 103642203 B CN103642203 B CN 103642203B
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- weight portion
- sponge
- water
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- modifier
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- 238000002360 preparation method Methods 0.000 title claims abstract description 12
- PEDCQBHIVMGVHV-UHFFFAOYSA-N Glycerine Chemical compound OCC(O)CO PEDCQBHIVMGVHV-UHFFFAOYSA-N 0.000 claims abstract description 14
- 239000003607 modifier Substances 0.000 claims abstract description 11
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims abstract description 11
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005058 Isophorone diisocyanate Substances 0.000 claims abstract description 7
- 239000004721 Polyphenylene oxide Substances 0.000 claims abstract description 7
- 229940008099 dimethicone Drugs 0.000 claims abstract description 7
- 239000004205 dimethyl polysiloxane Substances 0.000 claims abstract description 7
- 235000013870 dimethyl polysiloxane Nutrition 0.000 claims abstract description 7
- 235000011187 glycerol Nutrition 0.000 claims abstract description 7
- NIMLQBUJDJZYEJ-UHFFFAOYSA-N isophorone diisocyanate Chemical compound CC1(C)CC(N=C=O)CC(C)(CN=C=O)C1 NIMLQBUJDJZYEJ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000435 poly(dimethylsiloxane) Polymers 0.000 claims abstract description 7
- 229920000570 polyether Polymers 0.000 claims abstract description 7
- GWEVSGVZZGPLCZ-UHFFFAOYSA-N Titan oxide Chemical compound O=[Ti]=O GWEVSGVZZGPLCZ-UHFFFAOYSA-N 0.000 claims abstract description 6
- OGIDPMRJRNCKJF-UHFFFAOYSA-N titanium oxide Inorganic materials [Ti]=O OGIDPMRJRNCKJF-UHFFFAOYSA-N 0.000 claims abstract description 6
- 239000000463 material Substances 0.000 claims abstract description 5
- 235000019270 ammonium chloride Nutrition 0.000 claims abstract description 4
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 4
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 4
- 235000010299 hexamethylene tetramine Nutrition 0.000 claims abstract description 4
- VKYKSIONXSXAKP-UHFFFAOYSA-N hexamethylenetetramine Chemical compound C1N(C2)CN3CN1CN2C3 VKYKSIONXSXAKP-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229960004011 methenamine Drugs 0.000 claims abstract description 4
- UKODFQOELJFMII-UHFFFAOYSA-N pentamethyldiethylenetriamine Chemical compound CN(C)CCN(C)CCN(C)C UKODFQOELJFMII-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- YCIMNLLNPGFGHC-UHFFFAOYSA-N catechol Chemical compound OC1=CC=CC=C1O YCIMNLLNPGFGHC-UHFFFAOYSA-N 0.000 claims description 6
- CHQMHPLRPQMAMX-UHFFFAOYSA-L sodium persulfate Chemical compound [Na+].[Na+].[O-]S(=O)(=O)OOS([O-])(=O)=O CHQMHPLRPQMAMX-UHFFFAOYSA-L 0.000 claims description 6
- YNAVUWVOSKDBBP-UHFFFAOYSA-N Morpholine Chemical compound C1COCCN1 YNAVUWVOSKDBBP-UHFFFAOYSA-N 0.000 claims description 4
- SMZOUWXMTYCWNB-UHFFFAOYSA-N 2-(2-methoxy-5-methylphenyl)ethanamine Chemical compound COC1=CC=C(C)C=C1CCN SMZOUWXMTYCWNB-UHFFFAOYSA-N 0.000 claims description 3
- NIXOWILDQLNWCW-UHFFFAOYSA-N 2-Propenoic acid Natural products OC(=O)C=C NIXOWILDQLNWCW-UHFFFAOYSA-N 0.000 claims description 3
- 229920002134 Carboxymethyl cellulose Polymers 0.000 claims description 3
- 239000001768 carboxy methyl cellulose Substances 0.000 claims description 3
- 235000010948 carboxy methyl cellulose Nutrition 0.000 claims description 3
- 239000008112 carboxymethyl-cellulose Substances 0.000 claims description 3
- 239000012467 final product Substances 0.000 claims description 3
- 238000005187 foaming Methods 0.000 claims description 3
- JPMIIZHYYWMHDT-UHFFFAOYSA-N octhilinone Chemical compound CCCCCCCCN1SC=CC1=O JPMIIZHYYWMHDT-UHFFFAOYSA-N 0.000 claims description 3
- HGWOWDFNMKCVLG-UHFFFAOYSA-N [O--].[O--].[Ti+4].[Ti+4] Chemical compound [O--].[O--].[Ti+4].[Ti+4] HGWOWDFNMKCVLG-UHFFFAOYSA-N 0.000 claims description 2
- 230000007797 corrosion Effects 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 3
- 230000000844 anti-bacterial effect Effects 0.000 abstract description 2
- 238000004140 cleaning Methods 0.000 abstract description 2
- 230000001590 oxidative effect Effects 0.000 abstract description 2
- PWWSSIYVTQUJQQ-UHFFFAOYSA-N distearyl thiodipropionate Chemical compound CCCCCCCCCCCCCCCCCCOC(=O)CCSCCC(=O)OCCCCCCCCCCCCCCCCCC PWWSSIYVTQUJQQ-UHFFFAOYSA-N 0.000 abstract 1
- 239000004814 polyurethane Substances 0.000 description 3
- 229920002635 polyurethane Polymers 0.000 description 3
- 239000000047 product Substances 0.000 description 2
- 241000894006 Bacteria Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000007613 environmental effect Effects 0.000 description 1
- 150000002780 morpholines Chemical class 0.000 description 1
- 229910021392 nanocarbon Inorganic materials 0.000 description 1
- 239000002994 raw material Substances 0.000 description 1
- 239000003643 water by type Substances 0.000 description 1
Landscapes
- Lubricants (AREA)
- Polyurethanes Or Polyureas (AREA)
- Manufacture Of Porous Articles, And Recovery And Treatment Of Waste Products (AREA)
Abstract
The invention discloses a kind of anticorrosion sponge and preparation method thereof, does is the weight portion of its constitutive material: a kind of anticorrosion sponge, is characterized in that the weight portion of its constitutive material is: glycerine atactic polyether GPE-3000? 78-85, IPDI 30-35, nano titanium oxide 1-3, methenamine 4.0-6.0, pentamethyl-diethylenetriamine 1-3, ammonium chloride 0.5-0.8, antioxidant DSTP? 0.6-0.7, organotin 0.1-0.2, dimethicone 2-3, modifier 1-2 and water 5.0-6.5; The present invention has the feature of good flexibility, elasticity, antistatic, resistance to water, and antibacterial, the automatically cleaning of nano titanium oxide energy, the present invention has good wetability, acidproof, high temperature resistant and corrosion resistance, density is low, higher than performance, without creep, superhigh temperature resistant under non-oxidizing atmosphere, fatigue durability is good, postpones the service life of sponge.
Description
Technical field
The present invention relates to the preparation method of a kind of sponge, be specifically related to a kind of anticorrosion sponge and preparation method thereof.
Background technology
Sponge product is universal gradually in people's life, wherein there are the household objects such as seat, sofa, mattress that sponge makes, PPG is the primary raw material of producing polyurethane sponge, existing polyurethane sponge is produced the general PPG adopting and is conventionally adopted petroleum-type PPG, but the stabilized polyurethane that petroleum-type PPG is made is high, under nature, be difficult to decompose; Make it not have degradability, be unfavorable for environmental protection and sustainable development, along with the expansion of the application of sponge product, a large amount of sponge of market demand is supplied with, and because existing sponge exists a lot of performance deficiencies, uses sponge just to have potential safety hazard.
Summary of the invention
The object of the present invention is to provide a kind of anticorrosion sponge and preparation method thereof.
The present invention adopts following technical scheme to achieve these goals:
A kind of anticorrosion sponge, is characterized in that the weight portion of its constitutive material is: glycerine atactic polyether GPE-300078-85, IPDI 30-35, nano titanium oxide 1-3, methenamine 4.0-6.0, pentamethyl-diethylenetriamine 1-3, ammonium chloride 0.5-0.8, antioxidant DSTP0.6-0.7, organotin 0.1-0.2, dimethicone 2-3, modifier 1-2 and water 5.0-6.5;
The preparation method of described modifier is: 25-30 weight parts water is added to reaction vessel, be heated to 80-90 DEG C; Getting carboxymethyl cellulose 2-3 weight portion is added to the water, stirring and dissolving, add again 0.1-0.15 weight portion nanometer titanium dioxide titanium valve, 1.2-1.3 weight portion morpholine, 1-1.2 weight portion APEO, 1-2 parts by weight of acrylic acid, stir, be cooled to 20-30 DEG C, add the sodium peroxydisulfate of 0.2-0.3 weight portion, stir, reaction 30-45 minute, then, add again 1-2 weight portion catechol, 0.1-0.2 weight portion Kathon, continue stirring reaction 45-60 minute, to obtain final product.
The preparation method of described anticorrosion sponge, it is characterized in that first the glycerine atactic polyether GPE-3000 of above-mentioned formula ratio, IPDI, dimethicone, modifier being dropped in blender and being mixed, stir, and be heated to 35-40 DEG C, again other residual components of above-mentioned formula ratio is dropped in blender and mixed, after pouring mould after high-speed stirred 2-4 minute into and foaming and solidify, obtain anticorrosion sponge.
Modifier of the present invention can increase corrosion-resistant, go mouldy raw bacterium performance and flexibility and the resilience of sponge.
Beneficial effect of the present invention:
The present invention has the feature of good flexibility, elasticity, antistatic, resistance to water, and antibacterial, the automatically cleaning of nano titanium oxide energy, the present invention has good wetability, acidproof, high temperature resistant and corrosion resistance, density is low, higher than performance, without creep, superhigh temperature resistant under non-oxidizing atmosphere, fatigue durability is good, postpones the service life of sponge.
Detailed description of the invention
Embodiment 1: anticorrosion sponge, the weight portion (kg) of its constitutive material is: glycerine atactic polyether GPE-300078, IPDI 30, nano titanium oxide 1, methenamine 4.0, pentamethyl-diethylenetriamine 3, ammonium chloride 0.8, antioxidant DSTP0.7, organotin 0.2, dimethicone 3, modifier 2 and water 6.5;
The preparation method of described modifier is: 25 weight parts waters are added to reaction vessel, be heated to 80-90 DEG C; Getting carboxymethyl cellulose 2 weight portions is added to the water, stirring and dissolving, then add 0.1 weight portion nano-carbon powder, 1.2 weight portion morpholines, 1 weight portion APEO, 1 parts by weight of acrylic acid, stir, be cooled to 20-30 DEG C, the sodium peroxydisulfate that adds 0.3 weight portion, stirs, reaction 30-45 minute, then, add again 1 weight portion catechol, 0.2 weight portion Kathon, continue stirring reaction 45-60 minute, to obtain final product.
The preparation method of described anticorrosion sponge, it is characterized in that first the glycerine atactic polyether GPE-3000 of above-mentioned formula ratio, IPDI, dimethicone, modifier being dropped in blender and being mixed, stir, and be heated to 35-40 DEG C, again other residual components of above-mentioned formula ratio is dropped in blender and mixed, after pouring mould after high-speed stirred 2-4 minute into and foaming and solidify, obtain anticorrosion sponge.
The sponge performance data making by above-described embodiment 1 is as follows: hardness 45Kpa, resilience 36%.
Claims (2)
1. an anticorrosion sponge, is characterized in that the weight portion of its constitutive material is: glycerine atactic polyether GPE-300078-85, IPDI 30-35, nano titanium oxide 1-3, methenamine 4.0-6.0, pentamethyl-diethylenetriamine 1-3, ammonium chloride 0.5-0.8, antioxidant DSTP0.6-0.7, organotin 0.1-0.2, dimethicone 2-3, modifier 1-2 and water 5.0-6.5;
The preparation method of described modifier is: 25-30 weight parts water is added to reaction vessel, be heated to 80-90 DEG C; Getting carboxymethyl cellulose 2-3 weight portion is added to the water, stirring and dissolving, add again 0.1-0.15 weight portion nanometer titanium dioxide titanium valve, 1.2-1.3 weight portion morpholine, 1-1.2 weight portion APEO, 1-2 parts by weight of acrylic acid, stir, be cooled to 20-30 DEG C, add the sodium peroxydisulfate of 0.2-0.3 weight portion, stir, reaction 30-45 minute, then, add again 1-2 weight portion catechol, 0.1-0.2 weight portion Kathon, continue stirring reaction 45-60 minute, to obtain final product.
2. the preparation method of an anticorrosion sponge as claimed in claim 1, it is characterized in that first the glycerine atactic polyether GPE-3000 of above-mentioned formula ratio, IPDI, dimethicone, modifier being dropped in blender and being mixed, stir, and be heated to 35-40 DEG C, again other residual components of above-mentioned formula ratio is dropped in blender and mixed, after pouring mould after high-speed stirred 2-4 minute into and foaming and solidify, obtain anticorrosion sponge.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310566853.7A CN103642203B (en) | 2013-11-13 | 2013-11-13 | A kind of anticorrosion sponge and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310566853.7A CN103642203B (en) | 2013-11-13 | 2013-11-13 | A kind of anticorrosion sponge and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103642203A CN103642203A (en) | 2014-03-19 |
| CN103642203B true CN103642203B (en) | 2016-05-11 |
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| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310566853.7A Expired - Fee Related CN103642203B (en) | 2013-11-13 | 2013-11-13 | A kind of anticorrosion sponge and preparation method thereof |
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| Country | Link |
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| CN (1) | CN103642203B (en) |
Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107125187A (en) * | 2017-07-13 | 2017-09-05 | 浙江海洋大学 | A kind of Portunus Trituberculatus transport case |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995089A (en) * | 2006-12-22 | 2007-07-11 | 淮安康维化工科技有限公司 | Photo-catalytic antibiotic sponge and its pillow and mat product |
| CN102190882A (en) * | 2010-03-10 | 2011-09-21 | 华中科技大学 | Inorganic nanoparticles-modified polyurethane sponge mask material, and preparation method and application thereof |
-
2013
- 2013-11-13 CN CN201310566853.7A patent/CN103642203B/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1995089A (en) * | 2006-12-22 | 2007-07-11 | 淮安康维化工科技有限公司 | Photo-catalytic antibiotic sponge and its pillow and mat product |
| CN102190882A (en) * | 2010-03-10 | 2011-09-21 | 华中科技大学 | Inorganic nanoparticles-modified polyurethane sponge mask material, and preparation method and application thereof |
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| Publication number | Publication date |
|---|---|
| CN103642203A (en) | 2014-03-19 |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
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| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information | ||
| CB03 | Change of inventor or designer information |
Inventor after: Shi Shengfa Inventor before: Jing Yuanxiang |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170424 Address after: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: Day 238100 Anhui city of Ma'anshan Province Gu Lu, Hanshan County Economic Development Zone No. 18 Patentee before: ANHUI JINMA SPONGE Co.,Ltd. Effective date of registration: 20170424 Address after: 523000 Guangdong city of Dongguan province Dongcheng District Liuhua Road No. 63 building Xiakou 3 floor Patentee after: DONGGUAN JIALONG BEDDING Co.,Ltd. Address before: 510000 unit 2414-2416, building, No. five, No. 371, Tianhe District, Guangdong, China Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20191204 Address after: 233000 Room 1402, Ziyang Building, Pearl Plaza, Huaishang District, Bengbu City, Anhui Province Patentee after: Bengbu HRABERO Intellectual Property Service Co.,Ltd. Address before: 523000 Guangdong city of Dongguan province Dongcheng District Liuhua Road No. 63 building Xiakou 3 floor Patentee before: DONGGUAN JIALONG BEDDING Co.,Ltd. |
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| TR01 | Transfer of patent right | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20200925 Address after: Hongqi Zhen Tang Li Cun, Ganjingzi District, Dalian City, Liaoning Province Patentee after: Dalian Jinlida foam Co.,Ltd. Address before: 233000 Room 1402, Ziyang Building, Pearl Plaza, Huaishang District, Bengbu City, Anhui Province Patentee before: Bengbu HRABERO Intellectual Property Service Co.,Ltd. |
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| CF01 | Termination of patent right due to non-payment of annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160511 Termination date: 20211113 |