CN103641988A - Static resistance sponge and production method thereof - Google Patents
Static resistance sponge and production method thereof Download PDFInfo
- Publication number
- CN103641988A CN103641988A CN201310566798.1A CN201310566798A CN103641988A CN 103641988 A CN103641988 A CN 103641988A CN 201310566798 A CN201310566798 A CN 201310566798A CN 103641988 A CN103641988 A CN 103641988A
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- sponge
- static
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/70—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the isocyanates or isothiocyanates used
- C08G18/72—Polyisocyanates or polyisothiocyanates
- C08G18/74—Polyisocyanates or polyisothiocyanates cyclic
- C08G18/75—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic
- C08G18/751—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring
- C08G18/752—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group
- C08G18/753—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group
- C08G18/755—Polyisocyanates or polyisothiocyanates cyclic cycloaliphatic containing only one cycloaliphatic ring containing at least one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group containing one isocyanate or isothiocyanate group linked to the cycloaliphatic ring by means of an aliphatic group having a primary carbon atom next to the isocyanate or isothiocyanate group and at least one isocyanate or isothiocyanate group linked to a secondary carbon atom of the cycloaliphatic ring, e.g. isophorone diisocyanate
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- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G18/00—Polymeric products of isocyanates or isothiocyanates
- C08G18/06—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen
- C08G18/28—Polymeric products of isocyanates or isothiocyanates with compounds having active hydrogen characterised by the compounds used containing active hydrogen
- C08G18/40—High-molecular-weight compounds
- C08G18/48—Polyethers
- C08G18/4825—Polyethers containing two hydroxy groups
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K13/00—Use of mixtures of ingredients not covered by one single of the preceding main groups, each of these compounds being essential
- C08K13/04—Ingredients characterised by their shape and organic or inorganic ingredients
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/34—Silicon-containing compounds
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K7/00—Use of ingredients characterised by shape
- C08K7/02—Fibres or whiskers
- C08K7/04—Fibres or whiskers inorganic
- C08K7/06—Elements
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08G—MACROMOLECULAR COMPOUNDS OBTAINED OTHERWISE THAN BY REACTIONS ONLY INVOLVING UNSATURATED CARBON-TO-CARBON BONDS
- C08G2110/00—Foam properties
- C08G2110/0083—Foam properties prepared using water as the sole blowing agent
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/001—Conductive additives
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/011—Nanostructured additives
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- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Polyurethanes Or Polyureas (AREA)
Abstract
The invention discloses a static resistance sponge and a production method, and the sponge comprises the following raw materials by weight: 100-120 parts of polypropylene oxide glycol, 40-45 parts of isophorone diisocyanate, 7.5-8.5 parts of attapulgite nanoocomposites, 2.0-3.0 parts of conductive carbon fiber, 0.3-0.6 parts of triethylene diamine, 0.7-0.9 parts of amine oxide, 0.5-0.7 parts of stannous octoate, 1-2 parts of modifier and 4.5-6.5 parts of water. The static resistance sponge has the characteristics of softness, elasticity, static resistance and water resistance. The attapulgite nanoocomposites have excellent wettability, acid resistance, high temperature resistance and corrosion resistance, the conductive carbon fiber forms a conductive layer in the sponge, so that generation of static can be effectively prevented.
Description
Technical field
The preparation method who the present invention relates to a kind of sponge, is specifically related to a kind of Anti-static sponge and preparation method thereof.
Background technology
Sponge product is universal gradually in people life, wherein has the household objects such as seat that sponge makes, sofa, mattress.People, except the household objects of making of sponge, also utilize sponge to be used as cleaning appliance, as by the clean household of sponge product, with the clean bowls and chopsticks of sponge product, with sponge product, have a bath etc.
Existing sponge production method technique is single, and product performance index can not meet market demand completely, and an urgent demand is studied from different aspects.
Summary of the invention
The object of the present invention is to provide a kind of Anti-static sponge and preparation method thereof.
The present invention adopts following technical scheme to achieve these goals:
An Anti-static sponge, is characterized in that the weight part of its constitutive material is: polyoxypropyleneglycol 100-120, isophorone diisocyanate 40-45, nano-attapulgite 7.5-8.5, conductive carbon fibre 2.0-3.0, triethylene diamine 0.3-0.6, ammonium oxide 0.7-0.9, stannous octoate 0.5-0.7, properties-correcting agent 1-2 and water 4.5-6.5.
The preparation method of described properties-correcting agent is: 25-30 weight parts water is added to reaction vessel, be heated to 80-90 ℃; Getting carboxymethyl cellulose 2-3 weight part is added to the water, stirring and dissolving, then add 0.1-0.15 weight part nano-carbon powder, 1.2-1.3 weight part morpholine, 1-1.2 weight part Soxylat A 25-7,1-2 parts by weight of acrylic acid, stir, be cooled to 20-30 ℃, the Sodium Persulfate that adds 0.2-0.3 weight part, stirs, reaction 30-45 minute, then, add again 1-2 weight part catechol, 0.1-0.2 weight part Kathon, continue stirring reaction 45-60 minute, obtain.
The preparation method of described Anti-static sponge, it is characterized in that first the polyoxypropyleneglycol of above-mentioned formula ratio, isophorone diisocyanate, properties-correcting agent being dropped in mixing tank and being mixed, stir, and be heated to 30-45 ℃, again other remaining component of above-mentioned formula ratio is dropped in mixing tank and mixed, high-speed stirring 10-30 pours mould into and foams and solidify after second after, obtain Anti-static sponge.
Properties-correcting agent of the present invention can increase corrosion-resistant, go mouldy raw bacterium performance and flexibility and the rebound resilience of sponge.
Beneficial effect of the present invention:
The present invention has the feature of good flexibility, elasticity, anti-electrostatic, water tolerance, and nano-attapulgite has good wettability, acidproof, high temperature resistant and corrosion resistance, and conductive carbon fibre forms conductive layer in sponge, effectively prevents generation of static electricity.
Embodiment
Embodiment 1: Anti-static sponge, the weight part of its constitutive material (kg) is: polyoxypropyleneglycol 100, isophorone diisocyanate 40, nano-attapulgite 7.5, conductive carbon fibre 2.0, triethylene diamine 0.3, ammonium oxide 0.7, stannous octoate 0.5, properties-correcting agent 1 and water 4.5.
The preparation method of described properties-correcting agent is: 25 weight parts waters are added to reaction vessel, be heated to 80-90 ℃; Getting carboxymethyl cellulose 2 weight parts is added to the water, stirring and dissolving, then add 0.1 weight part nano-carbon powder, 1.2 weight part morpholines, 1 weight part Soxylat A 25-7,1 parts by weight of acrylic acid, stir, be cooled to 20-30 ℃, the Sodium Persulfate that adds 0.3 weight part, stirs, reaction 30-45 minute, then, add again 1 weight part catechol, 0.2 weight part Kathon, continue stirring reaction 45-60 minute, obtain.
The preparation method of Anti-static sponge, it is characterized in that first the polyoxypropyleneglycol of above-mentioned formula ratio, isophorone diisocyanate, properties-correcting agent being dropped in mixing tank and being mixed, stir, and be heated to 30-45 ℃, again other remaining component of above-mentioned formula ratio is dropped in mixing tank and mixed, high-speed stirring 10-30 pours mould into and foams and solidify after second after, obtain Anti-static sponge.
The sponge performance data making by above-described embodiment 1 is as follows: hardness 50Kpa, resilience 40%.
Claims (2)
1. an Anti-static sponge, is characterized in that the weight part of its constitutive material is: polyoxypropyleneglycol 100-120, isophorone diisocyanate 40-45, nano-attapulgite 7.5-8.5, conductive carbon fibre 2.0-3.0, triethylene diamine 0.3-0.6, ammonium oxide 0.7-0.9, stannous octoate 0.5-0.7, properties-correcting agent 1-2 and water 4.5-6.5;
The preparation method of described properties-correcting agent is: 25-30 weight parts water is added to reaction vessel, be heated to 80-90 ℃; Getting carboxymethyl cellulose 2-3 weight part is added to the water, stirring and dissolving, then add 0.1-0.15 weight part nano-carbon powder, 1.2-1.3 weight part morpholine, 1-1.2 weight part Soxylat A 25-7,1-2 parts by weight of acrylic acid, stir, be cooled to 20-30 ℃, the Sodium Persulfate that adds 0.2-0.3 weight part, stirs, reaction 30-45 minute, then, add again 1-2 weight part catechol, 0.1-0.2 weight part Kathon, continue stirring reaction 45-60 minute, obtain.
2. the preparation method of an Anti-static sponge as claimed in claim 1, it is characterized in that first the polyoxypropyleneglycol of above-mentioned formula ratio, isophorone diisocyanate, properties-correcting agent being dropped in mixing tank and being mixed, stir, and be heated to 30-45 ℃, again other remaining component of above-mentioned formula ratio is dropped in mixing tank and mixed, high-speed stirring 10-30 pours mould into and foams and solidify after second after, obtain Anti-static sponge.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310566798.1A CN103641988B (en) | 2013-11-13 | 2013-11-13 | A kind of Anti-static sponge and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310566798.1A CN103641988B (en) | 2013-11-13 | 2013-11-13 | A kind of Anti-static sponge and preparation method thereof |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103641988A true CN103641988A (en) | 2014-03-19 |
| CN103641988B CN103641988B (en) | 2016-02-24 |
Family
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310566798.1A Expired - Fee Related CN103641988B (en) | 2013-11-13 | 2013-11-13 | A kind of Anti-static sponge and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103641988B (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832177A (en) * | 2017-02-24 | 2017-06-13 | 耿佃勇 | polyurethane electronic sponge and preparation method thereof |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134302A (en) * | 2010-01-21 | 2011-07-27 | 东莞市源聚德实业有限公司 | Anti-static sponge |
| CN102336885A (en) * | 2011-07-02 | 2012-02-01 | 胡志刚 | Polyurethane sponge with excellent environmental tolerance |
| CN102773963A (en) * | 2012-08-01 | 2012-11-14 | 张加兵 | Production process of anti-static sponge |
| CN202774453U (en) * | 2012-07-12 | 2013-03-13 | 温州安腾劳保用品有限公司 | Anti-static safety shoe |
| CN103275364A (en) * | 2013-06-18 | 2013-09-04 | 际华三五三七制鞋有限责任公司 | Anti-static bacteriostatic disulfide sponge sizing material, and preparation method and application thereof |
-
2013
- 2013-11-13 CN CN201310566798.1A patent/CN103641988B/en not_active Expired - Fee Related
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102134302A (en) * | 2010-01-21 | 2011-07-27 | 东莞市源聚德实业有限公司 | Anti-static sponge |
| CN102336885A (en) * | 2011-07-02 | 2012-02-01 | 胡志刚 | Polyurethane sponge with excellent environmental tolerance |
| CN202774453U (en) * | 2012-07-12 | 2013-03-13 | 温州安腾劳保用品有限公司 | Anti-static safety shoe |
| CN102773963A (en) * | 2012-08-01 | 2012-11-14 | 张加兵 | Production process of anti-static sponge |
| CN103275364A (en) * | 2013-06-18 | 2013-09-04 | 际华三五三七制鞋有限责任公司 | Anti-static bacteriostatic disulfide sponge sizing material, and preparation method and application thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106832177A (en) * | 2017-02-24 | 2017-06-13 | 耿佃勇 | polyurethane electronic sponge and preparation method thereof |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103641988B (en) | 2016-02-24 |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| CB03 | Change of inventor or designer information |
Inventor after: Xu Chenmei Inventor before: Jing Yuanxiang |
|
| CB03 | Change of inventor or designer information | ||
| TR01 | Transfer of patent right |
Effective date of registration: 20170427 Address after: 519000 Zhuhai, Xiangzhou, the former mountain road, Chung Chung Road, No. 36 Patentee after: Zhuhai Ding Ding Technology Co.,Ltd. Address before: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee before: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Effective date of registration: 20170427 Address after: Tianhe District Tong East Road Guangzhou city Guangdong province 510665 B-101 No. 5, room B-118 Patentee after: GUANGDONG GAOHANG INTELLECTUAL PROPERTY OPERATION Co.,Ltd. Address before: Day 238100 Anhui city of Ma'anshan Province Gu Lu, Hanshan County Economic Development Zone No. 18 Patentee before: ANHUI JINMA SPONGE Co.,Ltd. |
|
| TR01 | Transfer of patent right | ||
| CF01 | Termination of patent right due to non-payment of annual fee |
Granted publication date: 20160224 Termination date: 20191113 |
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| CF01 | Termination of patent right due to non-payment of annual fee |