CN103637930A - Aqueous scrubbing cleaning cosmetic product - Google Patents
Aqueous scrubbing cleaning cosmetic product Download PDFInfo
- Publication number
- CN103637930A CN103637930A CN201310729397.3A CN201310729397A CN103637930A CN 103637930 A CN103637930 A CN 103637930A CN 201310729397 A CN201310729397 A CN 201310729397A CN 103637930 A CN103637930 A CN 103637930A
- Authority
- CN
- China
- Prior art keywords
- cosmetic preparation
- aqueous
- surfactant
- fatty acid
- quality
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Granted
Links
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- 238000004140 cleaning Methods 0.000 title abstract description 29
- 238000005201 scrubbing Methods 0.000 title abstract 5
- -1 polyoxyethylene Polymers 0.000 claims abstract description 59
- 239000000194 fatty acid Substances 0.000 claims abstract description 45
- 235000014113 dietary fatty acids Nutrition 0.000 claims abstract description 43
- 229930195729 fatty acid Natural products 0.000 claims abstract description 43
- 229920003171 Poly (ethylene oxide) Polymers 0.000 claims abstract description 37
- 150000005846 sugar alcohols Polymers 0.000 claims abstract description 13
- 229960003237 betaine Drugs 0.000 claims abstract description 9
- 238000002360 preparation method Methods 0.000 claims description 74
- 239000000203 mixture Substances 0.000 claims description 48
- 239000002280 amphoteric surfactant Substances 0.000 claims description 25
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 claims description 18
- 150000004665 fatty acids Chemical class 0.000 claims description 13
- 239000003945 anionic surfactant Substances 0.000 claims description 12
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- 239000003093 cationic surfactant Substances 0.000 claims description 9
- 239000011159 matrix material Substances 0.000 claims description 9
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 5
- 229910052799 carbon Inorganic materials 0.000 claims description 5
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- 150000002500 ions Chemical class 0.000 abstract 2
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- XDOFQFKRPWOURC-UHFFFAOYSA-N 16-methylheptadecanoic acid Chemical compound CC(C)CCCCCCCCCCCCCCC(O)=O XDOFQFKRPWOURC-UHFFFAOYSA-N 0.000 description 3
- OQRYWJHKYLPGOZ-UHFFFAOYSA-M C(CCCCCCCCCCC)C(=C(OC)OC)[N+](C)(C)C.[OH-] Chemical compound C(CCCCCCCCCCC)C(=C(OC)OC)[N+](C)(C)C.[OH-] OQRYWJHKYLPGOZ-UHFFFAOYSA-M 0.000 description 3
- LYCAIKOWRPUZTN-UHFFFAOYSA-N Ethylene glycol Chemical compound OCCO LYCAIKOWRPUZTN-UHFFFAOYSA-N 0.000 description 3
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- 238000011010 flushing procedure Methods 0.000 description 3
- 230000036541 health Effects 0.000 description 3
- RAXXELZNTBOGNW-UHFFFAOYSA-N imidazole Natural products C1=CNC=N1 RAXXELZNTBOGNW-UHFFFAOYSA-N 0.000 description 3
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- LQJBNNIYVWPHFW-UHFFFAOYSA-N 20:1omega9c fatty acid Natural products CCCCCCCCCCC=CCCCCCCCC(O)=O LQJBNNIYVWPHFW-UHFFFAOYSA-N 0.000 description 2
- QSBYPNXLFMSGKH-UHFFFAOYSA-N 9-Heptadecensaeure Natural products CCCCCCCC=CCCCCCCCC(O)=O QSBYPNXLFMSGKH-UHFFFAOYSA-N 0.000 description 2
- DHMQDGOQFOQNFH-UHFFFAOYSA-N Glycine Chemical compound NCC(O)=O DHMQDGOQFOQNFH-UHFFFAOYSA-N 0.000 description 2
- 239000005642 Oleic acid Substances 0.000 description 2
- ZQPPMHVWECSIRJ-UHFFFAOYSA-N Oleic acid Natural products CCCCCCCCC=CCCCCCCCC(O)=O ZQPPMHVWECSIRJ-UHFFFAOYSA-N 0.000 description 2
- 239000002202 Polyethylene glycol Substances 0.000 description 2
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- 230000003213 activating effect Effects 0.000 description 2
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- 150000001413 amino acids Chemical class 0.000 description 2
- 230000000844 anti-bacterial effect Effects 0.000 description 2
- 238000013459 approach Methods 0.000 description 2
- MRUAUOIMASANKQ-UHFFFAOYSA-N cocamidopropyl betaine Chemical compound CCCCCCCCCCCC(=O)NCCC[N+](C)(C)CC([O-])=O MRUAUOIMASANKQ-UHFFFAOYSA-N 0.000 description 2
- 239000003599 detergent Substances 0.000 description 2
- 150000005690 diesters Chemical class 0.000 description 2
- POULHZVOKOAJMA-UHFFFAOYSA-N dodecanoic acid Chemical compound CCCCCCCCCCCC(O)=O POULHZVOKOAJMA-UHFFFAOYSA-N 0.000 description 2
- 125000004435 hydrogen atom Chemical group [H]* 0.000 description 2
- 125000002887 hydroxy group Chemical group [H]O* 0.000 description 2
- QXJSBBXBKPUZAA-UHFFFAOYSA-N isooleic acid Natural products CCCCCCCC=CCCCCCCCCC(O)=O QXJSBBXBKPUZAA-UHFFFAOYSA-N 0.000 description 2
- 238000004519 manufacturing process Methods 0.000 description 2
- ZQPPMHVWECSIRJ-KTKRTIGZSA-N oleic acid Chemical compound CCCCCCCC\C=C/CCCCCCCC(O)=O ZQPPMHVWECSIRJ-KTKRTIGZSA-N 0.000 description 2
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- BDOYKFSQFYNPKF-UHFFFAOYSA-N 2-[2-[bis(carboxymethyl)amino]ethyl-(carboxymethyl)amino]acetic acid;sodium Chemical compound [Na].[Na].OC(=O)CN(CC(O)=O)CCN(CC(O)=O)CC(O)=O BDOYKFSQFYNPKF-UHFFFAOYSA-N 0.000 description 1
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- UIVPNOBLHXUKDX-UHFFFAOYSA-N 3,5,5-trimethylhexyl 3,5,5-trimethylhexanoate Chemical compound CC(C)(C)CC(C)CCOC(=O)CC(C)CC(C)(C)C UIVPNOBLHXUKDX-UHFFFAOYSA-N 0.000 description 1
- FBPFZTCFMRRESA-FSIIMWSLSA-N D-Glucitol Natural products OC[C@H](O)[C@H](O)[C@@H](O)[C@H](O)CO FBPFZTCFMRRESA-FSIIMWSLSA-N 0.000 description 1
- 206010013786 Dry skin Diseases 0.000 description 1
- ZGTMUACCHSMWAC-UHFFFAOYSA-L EDTA disodium salt (anhydrous) Chemical compound [Na+].[Na+].OC(=O)CN(CC([O-])=O)CCN(CC(O)=O)CC([O-])=O ZGTMUACCHSMWAC-UHFFFAOYSA-L 0.000 description 1
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Landscapes
- Cosmetics (AREA)
Abstract
The invention provides an aqueous scrubbing cleaning cosmetic product used for removing cosmetics and a scrubbing cosmetic slice formed by immersing the cosmetic product in basis material and used for removing the cosmetics, wherein the aqueous scrubbing cleaning cosmetic product has excellent cleaning effect, low irritation, no foam residuary, and excellent usability and conservation stability. In the aqueous scrubbing cleaning cosmetic product used for removing cosmetics, the content of polyoxyethylene fatty acid glyceride such as polyoxyethylene (octanoic acid / capric acid)glyceride (A) is set 3 to 10 percent by mass, the content of ampholytic surfactant such as lauryl glycine betaine (B) is set as 0.005 to 2 percent by mass, and the polyhydric alcohols such as propylene glycol (C) is set in a proportion of 1 to 12 percent by mass, and all the ingredients are adjusted substantially without negative ion surfactant and positive ion surfactant. A crubbing cosmetic slice can be produced by immersing the cleaning cosmetic product in the basis material.
Description
Technical field
The present invention relates to a kind of novel aqueous wiped clean cosmetic preparation, more specifically, relate to a kind of aqueous wiped clean cosmetic preparation that contains nonionic surfactant and amphoteric surfactant.
Background technology
At present, the color make-up cosmetic preparation that contains oil content as removal lipstick, foundation cream, mascara, eye shadow etc. clean makeup material, the material that has the such oil preparation of liquid paraffin or contain nonionic surfactant is proposed.Wherein, employing used oil preparation clean makeup material time, for the oils and fats dirt of color make-up etc., remove effect excellence, yet, but there is following problem: after wiping or after rinsing, oil preparation also can be residual and produce sticky sense, must be again with facial abluent, clean, cause excessive defat and produce pachylosis.On the other hand, adopt containing oil preparation, do not used nonionic surfactant clean makeup material time, easily wiping or flushing, however but there is the not necessarily abundant such problem of effect of removing to the oils and fats dirt of color make-up etc.
Therefore, in recent years, having attempted in the situation that not using oil preparation improving the effect of removing to oils and fats dirt, is that the watersoluble cleaning cosmetic preparation of polyoxyethylene fatty acid glyceride has also proposed various schemes for containing hydrophilic non-ionic surfactant.For example; in patent documentation 1; the watersoluble cleaning cosmetic preparation that contains polyoxyethylene fatty acid glyceride, polyhydric alcohol and N-Oleum Cocois fatty acyl group-L-arginine ethyl ester pyrrolidone carboxylic acid salt has been proposed; as the typical example of polyoxyethylene fatty acid glyceride, recorded polyoxyethylene (caprylic/capric) glyceride.In addition, in patent documentation 2, a kind of watersoluble cleaning cosmetic preparation that contains polyoxyethylene (caprylic/capric) glyceride, polyoxyethylene coco-nut oil fatty acid glyceride and polyhydric alcohol has been proposed.
These watersoluble cleaning cosmetic preparations are wiping color make-up cosmetic preparation easily, can suppress the sticky sense after using.But, with regard to polyoxyethylene fatty acid glyceride, once temperature uprises, the dissolubility in water reduces, therefore, there is following problem: product easy variation because of temperature in preservation produces separates out, as the appearance damage that cleans makeup material, moreover, also cause the reduction of cleaning function.
On the other hand, a kind of aqueous skin cleaner that contains polyoxyethylene fatty acid glyceride and amphoteric surfactant and/or semi-polarity surfactant is disclosed in patent documentation 3.And record: with regard to the usage rate of two compositions, the former/the latter's (mass ratio) is 2/1～1/8, preferably 1/1～1/8 (0015 section of reference), by be used in combination both within the scope of this, can obtain in makeup removing function and foaming function aspects excellence, and the skin after using be given to the skin cleaner (with reference to 0033 section) of salubrious sense.But, if will utilize the skin cleaner of such foaming function as the different wiped clean cosmetic preparation of using method, can follow the foaming in use and cause foam residual, therefore, use difficulty, and, because the use level of amphoteric surfactant or semi-polarity surfactant is many, therefore, there is the such problem of low irritant hardly.
In addition, in patent documentation 4, a kind of contained the such addition of polyoxyethylene (caprylic/capric) the glyceride fatty glyceride of ethylene oxide and aqueous cleansing cosmetic of polyhydric alcohol proposed.And record: except above-mentioned composition, can coordinate anionic surfactant, cationic surfactant, amphoteric surfactant or nonionic surfactant (with reference to 0017 section).But, this aqueous cleansing cosmetic be also with patent documentation 3 in the cosmetics that propose use after similarly making blister.Therefore, as concrete coordinating example, only recorded except above-mentioned fatty glyceride, also coordinated the composition of a large amount of other surfactants.In the situation that containing as mentioned above exhibiting high surface activating agent, even if use polyoxyethylene (caprylic/capric) glyceride as nonionic surfactant, be also suitable as hardly wiped clean cosmetic preparation.
In addition, in patent documentation 5～7, recorded contain (A) polyoxyethylene (7) coco-nut oil fatty acid glyceride 6 quality %, (B) lauroylamidopropyl betaine 1 quality % and water plate detergent as embodiment.Particularly in patent documentation 7, recorded this plate detergent for wiping.In addition, in patent documentation 5 and 6, recorded oxyneurine type amphoteric surfactantes such as can utilizing lauryl dimethyl oxyneurine as amphoteric surfactant.In addition, in patent documentation 8, recorded and be impregnated in the wipe-off type using in sheet material and clean in makeup material, with the ratio of 2 quality %, used propylene glycol.
But the cleaning agent proposing in patent documentation 5 is to take the sterilizing cleaning agent compositions for skin that specific fatty acid amine salt is bactericidal active ingredient, does not wherein record aqueous wiped clean cosmetic preparation.In addition, coordinating example shown in embodiment is owing to containing fatty acid amine salt (it is also anionic surfactant), therefore, storage stability is insufficient, in addition, contain in a large number the oiliness compositions such as Jojoba oil, Squalene, dimethyl polysiloxane, isononyl isononanoate, cannot eliminate the problem of the cleaning agent of above-mentioned use oil preparation.And, also contain the polyhydric alcohol of 20 quality %, aspect sticky sense, also having problems.
In addition, the cleaning agent proposing in patent documentation 6 is the cosmetic preparation that contains special nebulousurine agent, does not wherein record aqueous wiped clean cosmetic preparation.In addition, the surfactant using is recited as any of anionic surfactant, cationic surfactant, nonionic surfactant, amphoteric surfactant, semi-polarity surfactant, is not particularly limited.And, similarly contain a large amount of oiliness compositions and the polyhydric alcohol of 20 quality % with patent documentation 5.
Moreover the cleaning agent proposing in patent documentation 7 is to contain Pu Luluonike type surfactant as the Irrigation of surfactant flaking makeup material.In the document, the compositions shown in embodiment also contains a large amount of oiliness compositions and the polyhydric alcohol of 20 quality %.Also recorded in addition: can be used in combination Pu Luluonike type surfactant and polyoxyethylene fatty acid glyceride as surfactant, but in the situation that using polyoxyethylene fatty acid glyceride separately, storage stability and color make-up removability become insufficient.
In patent documentation 8, disclose a kind of wipe-off type using in being impregnated in sheet material and cleaned makeup material, wherein, (C) ratio of polyhydric alcohol is 0.1～8 quality %.But, the document discloses a kind of health and has cleaned articles for use, it is that more than 20ml cleaning agent is impregnated in specific matrix material and obtains by making foam number under rated condition, as the surfactant using, recorded the good anion surfactant that particularly preferably bubbles (with reference to 0029 section).In fact, (the cleaning composition 2) of patent documentation 8 and (cleaning composition 3) are all contained a large amount of anion surfactants.And, in the situation that coordinated polyoxyethylene (7) the coco-nut oil fatty acid glyceride (cleaning composition 2) as non-ionic surface active agent, its use level is only 2 quality %, in this coordinating example, after all, the main component of surfactant is anion surfactant.
Moreover, in patent documentation 9, recorded and a kind ofly wiped away clearly medicinal liquid for humidity strip (claim 1), make this medicinal liquid be impregnated in matrix material and obtain wipe away clearly humidity strip (claim 3), the described humidity strip of wiping away clearly contains with medicinal liquid: containing amino organo-silicon compound (a), water-soluble amino acid or derivatives thereof (b), amide betaine type amphoteric surfactant (c), water-soluble polyol (d) and acrylic polymer (e), and having recorded this, to wipe away clearly humidity strip be wet tissue, for facial film, body film (body sheet) etc.Wherein, facial film is in face this point and is common for removing the wiping cosmetic sheet of color make-up cosmetic preparation at application site.But, wipe away clearly humidity strip and use for the people's of wiping baby or health inconvenience health dirt, so-called completely different from the object of wiping dirt with cosmetic sheet for the wiping of removing ornaments and formal dress.
In addition, the above-mentioned humidity strip of wiping away clearly contains amide betaine type amphoteric surfactant (c) and water-soluble polyol (d) with medicinal liquid, using specific (a) composition as oil content, containing amino organo-silicon compound as essential composition, this medicinal liquid cannot be made watersoluble cleaning cosmetic preparation.
Prior art document
Patent documentation
Patent documentation 1 TOHKEMY 2008-56609 communique
Patent documentation 2 TOHKEMY 2010-70521 communiques
Patent documentation 3 Japanese kokai publication hei 7-215841 communiques
Patent documentation 4 TOHKEMY 2010-222323 communiques
Patent documentation 5 TOHKEMY 2006-206582 communiques
Patent documentation 6 TOHKEMY 2003-073221 communiques
Patent documentation 7 TOHKEMY 2004-203794 communiques
Patent documentation 8 TOHKEMY 2002-363063 communiques
Patent documentation 9 Japan are public table 2008-123115 communique again
Summary of the invention
Invent technical problem to be solved
The present invention take such situation to complete as background, its object is, provide a kind of for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, it not only has abrasive power, and there is no sticky sense, low stimulation and do not have foam residual after just wiping, and can not separate out with separated for a long time excellent storage stability.
For solving the technical scheme of problem
The inventor etc. conduct in-depth research for the performance improvement of the aqueous wiped clean cosmetic preparation that contains hydrophilic non-ionic surfactant, found that, take polyoxyethylene fatty acid glyceride while containing a small amount of amphoteric surfactant in cleaning the system of composition, can obtain clean power excellence, low irritant and not have foam residual, the aqueous wiped clean cosmetic preparation of usability and excellent storage stability, so that completed the present invention.
Therefore, according to the present invention, can provide a kind of for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, it contains:
(A) the polyoxyethylene fatty acid glyceride of 3～10 quality %,
(B) amphoteric surfactant of 0.005～2 quality % and
(C) polyhydric alcohol of 1～12 quality %,
And in fact not containing anionic surfactant and cationic surfactant.In addition, as other invention, also provide a kind of for removing the wiping cosmetic sheet of color make-up cosmetic preparation, it obtains by making above-mentioned aqueous wiped clean cosmetic preparation be impregnated in matrix material.
Invention effect
Of the present invention not only have abrasive power for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, and do not have sticky sense after firm wiping, to the stimulation of skin less, do not have foam residual, also can because of temperature Change, not separate out surfactant, storage stability also excellent.In addition, wiping of the present invention cleans makeup material with sheet owing to containing in matrix material, therefore, only with this sheet material wiping, can lay down color make-up cosmetic preparation, and then, owing to being lamellar, therefore, be easy to carry to destination or the Reiseziel of going out.
The specific embodiment
Aqueous wiped clean cosmetic preparation of the present invention is to contain (A) polyoxyethylene fatty acid glyceride, (B) amphoteric surfactant and (C) polyhydric alcohol, but in fact not containing the Water-borne modification makeup material of anionic surfactant and cationic surfactant.
(A) composition using is the ester of the ehter bond that has fatty acid, consist of Polyethylene Glycol and glycerol, by following formula (1), is represented.
[Chemical formula 1]
Wherein, R
1, R
2r
3for the acyl group from fatty acid or hydrogen atom, R
1, R
2and R
3in at least one is the acyl group that is derived from fatty acid.In addition, x, y and z are 0 or integer.
As R
1, R
2and R
3in acyl group basic fatty acid, be R
1-OH, R
2-OH or R
3fatty acid shown in-OH is as long as consider the dissolubility in water and the zest of skin suitably selected to the saturated or undersaturated fatty acid that normally carbon number is 8～22.As its concrete example, such as can illustration: sad, capric acid, lauric acid, myristic acid, Palmic acid, stearic acid, isostearic acid, oleic acid, linoleic acid, linolenic acid, coco-nut oil fatty acid etc.Wherein, from clean power, dissolubility water and consider aspect the low irritant of skin, can preferably use carbon number is 8～14 straight chain fatty acid, the branched chain fatty acid of carbon number 16～22 and the unsaturated fatty acid of carbon number 16～22.
Polyoxyethylene fatty acid glyceride can be any of monoesters body, diester body, three ester bodies, from the deliquescent viewpoint water, considers, preferably monoesters body and diester body, particularly preferably used monoesters body.In addition, from the acyl group (R of fatty acid
1, R
2or R
3) can form ester with the hydroxyl of glycerol, also can be via oxygen ethylidene chain formation ester.
Form (A) composition polyoxyethylene portion ethylene oxide addition molal quantity, be that x, y in formula (1) and the total of z are generally 4～10, be preferably 5～8.If addition molal quantity is too small, the dissolubility in water is not enough, if much, shows the tendency that effect reduces of removing of cosmetic dirt.In addition, so long as have the material of polyoxyethylene portion, any of x, y and z can be 0, in addition, and R
1, R
2and R
3in one or two can be hydrogen atom, but be preferably 0 or 1 from the hydroxyl value of glycerol.
(A) composition can directly be used as the raw material of cosmetic use and the commercially available product of selling.For example can enumerate: at INCI (International Nomenclature Cosmetic Ingredient labeling names, the name of international cosmetic raw material) called after PEG-7CAPRYLIC/CAPRIC GLYCERIDES in, it is the material of PEG-7 (caprylic/capric) glyceride, the material of called after PEG-4 (caprylic/capric) glyceride, the material of called after PEG-6 (caprylic/capric) glyceride, the material of called after PEG-8 (caprylic/capric) glyceride, the material of called after coco-nut oil fatty acid PEG-7 glyceride, the material of called after isostearic acid PEG-6 glyceride, the material of called after oleic acid PEG-5 glyceride etc.
These compositions can be distinguished use separately, also can use two or more by proper combination.As particularly preferred (A) composition, from the viewpoint of cleaning effect excellence, consider, can enumerate: polyoxyethylene (caprylic/capric) glyceride and polyoxyethylene coco-nut oil fatty acid glyceride.
In the present invention, (A) composition be take and coordinated as 3～10 quality %, the content that is preferably 4～8 quality % with respect to aqueous wiped clean cosmetic preparation total amount.If lower than 3 quality %, cleaning effect is not enough, if surpass 10 quality %, worries that excessive defat produces and stimulates skin.
In addition, (A) part for composition can be replaced with other nonionic surfactant.But, if the ratio of polyoxyethylene fatty acid glyceride tails off, effect of the present invention reduces, therefore, in the total amount of other nonionic surfactant and polyoxyethylene fatty acid glyceride, the ratio of other nonionic surfactant is necessary for below 20 quality %, preferably below 10 quality %.Particularly preferably in mismatching in other the situation of nonionic surfactant, only by polyoxyethylene fatty acid glyceride, form (A) composition.
As the concrete example of other nonionic surfactant using, can enumerate: polyoxyethylene sorbitan fatty acid ester, Polyoxyethylene Sorbitol Fatty Acid Esters, polyoxyethylene fatty acid ester, alkyl androstanediol, polyoxyethylene alkyl ether, polyoxyethylene polyoxy-propylene, sucrose fatty acid ester, polyglyceryl fatty acid ester, polyoxyethylene hardened castor oil etc.
As the second composition in the present invention, be (B) amphoteric surfactant, can enumerate:
The oxyneurine type amphoteric surfactantes such as lauryl dimethyl oxyneurine, Oleum Cocois alkyl dimethyl oxyneurine, stearyl dimethylaminoethyl acid betanin, stearyl dihydroxy ethyl betanin;
The glycine type amphotericss such as alkyl glycinate, carboxyl methylglycine salt, N-acyl amino ethyl-N-2-hydroxyethyl glycinate;
The aminopropan acid type amphoteric surfactantes such as alkyl aminopropionic acid salt, alkyl imino dipropionate;
The amido propyl betaine type amphoteric surfactantes such as Oleum Cocois fattyamidopropyl betaine, Petiolus Trachycarpi oil fat amido propyl betaine, lauroylamidopropyl betaine, Oleum Ricini amido propyl betaine;
N-alkyl-N, N-Dimethyl Ammonium-N-propyl sulfonic acid salt, N-alkyl-N, N-Dimethyl Ammonium-N-(2-hydroxypropyl) sulfonate, N-fatty acid amide propyl group-N, the sulfobetaines type amphoteric surfactantes such as N-Dimethyl Ammonium-N-(2-hydroxypropyl) sulfonate;
The imidazole type betaine type amphoteric surfac-tants such as 2-alkyl-N-carboxyl methyl-N-hydroxyethyl imidazoles betanin, undecyl hydroxyethyl imidazoles betanin sodium, undecyl-N-hydroxyethyl-N-carboxyl Methylimidazole. betanin etc.
Wherein, from the viewpoint of separating out control and low irritant of (A) composition, consider, LAURYL BETAIN/ lauryl betaine) and Oleum Cocois alkyl dimethyl oxyneurine (INCI name: COCO-BETAIN/ coco betaine) preferred oxyneurine type amphoteric surfactant, more preferably lauryl dimethyl oxyneurine (INCI name:.
(B) content of composition is 0.005～2 quality %, is preferably 0.05～1 quality %.If lower than 0.005 quality %, (A) composition separate out inhibition deficiency, if surpass 2 quality %, worry the zest to skin, and produce in use the residual problem of foam.
Watersoluble cleaning cosmetic preparation of the present invention can be by coordinating each above-mentioned preparation that becomes to assign in water.The water using is as long as be to be the water that can be used as cosmetic preparation raw material, and there is no particular limitation, but conventionally use pure water.In watersoluble cleaning cosmetic preparation, the shared ratio of water is generally 70～95 quality %, is preferably 80～90 quality %.
In the present invention, except (A) composition, (B) composition, also add (C) polyhydric alcohol as the 3rd composition.Concrete example as (C) polyhydric alcohol, for example can illustration: ethylene glycol, diethylene glycol, triethylene glycol, Polyethylene Glycol, propylene glycol, dipropylene glycol, Isopropanediol, 1, ammediol, 1,3-butanediol, 1,2-butanediol, 1,2-pentanediol, 1,2-hexanediol, 1,2-ethohexadiol, 1, the glycolss such as 2-decanediol;
The glycerols such as glycerol, concentrated glycerin, two glycerol, polyglycereol etc.These compositions can be used separately a kind, also can appropriately combined use two or more.Wherein, while using propylene glycol and 1,3 butylene glycol, can make sticky sense few clean makeup material.
(C) the preferred content of composition is 1～12 quality %, more preferably 3～10 quality %.If lower than 1 quality %, moist feeling is easily not enough, if surpass 12 quality %, feels sticky.
In watersoluble cleaning cosmetic preparation of the present invention, do not contain in fact anionic surfactant and cationic surfactant.If there is anionic surfactant or cationic surfactant, produce foaming characteristic, therefore, in the situation that containing them, their content is below the content of amphoteric surfactant, and below 0.2 quality % of cosmetic preparation total amount.Be particularly preferably below 0.1 quality %.In addition, preferably in fact containing ethanol, by not containing ethanol, though after use, do not utilize the flushing of warm water or use after wash one's face, to the stimulation of skin, also can reduce.In addition, " in fact not containing ethanol " in the present invention refers to " can not make it by other approach, contain ethanol ", and micro-ethanol contained in each gradation composition is not included in " ethanol containing by other approach " scope.
As long as can not destroy in the scope of effect of the present invention, except above-mentioned essential composition, in aqueous wiped clean cosmetic preparation of the present invention, can also coordinate moisturizing composition, plant extract, vitamins, antiseptic, antibacterial, UV absorbent, antioxidant, stabilization agent, pH adjusting agent, spice, the pigments etc. such as viscosity modifier, aminoacid such as additive, anionic property polymer, nonionic polymer, cation property copolymer for cleaning agent of existing use.
Aqueous wiped clean cosmetic preparation of the present invention, because the oils and fats of the generations such as the sebum to facial or cosmetic removes effect excellence, therefore, can be preferably used as the remover of color make-up.In addition, as its using method, the viewpoint of the tight sense of skin and suppress to form the viewpoint consideration of dry skin because of excessive defat from suppress using, washes one's face preferably do not utilize the flushing of warm water or use after use after.As preferred using method, can illustration: make watersoluble cleaning cosmetic preparation be impregnated in cotton or non-woven fabrics etc. and for the method for application site or watersoluble cleaning cosmetic preparation is used in after application site, by method of the wipings such as cotton or non-woven fabrics etc.
Aqueous wiped clean cosmetic preparation of the present invention is conventionally put into the suitable containers such as glass system, plastics and is preserved, and also can make as required to clean makeup material and be impregnated in matrix material in advance and make the form of sheet for wiping.As long as matrix material is for abundant impregnation cleans the material of makeup material, and there is no particular limitation, such as can illustration: paper, non-woven fabrics, gauze, absorbent cotton, urethane film, sponge thin slice etc.Wherein, particularly preferably himself there is the adsorbing non-woven fabrics of oiliness composition.In addition, the impregnation ratio of cosmetic preparation is preferably the maximum in the scope that liquid can not drip down, and its amount depends on material, therefore, can easily confirm by preliminary experiment.
Therefore, impregnation clean the sheet material of makeup material and reinstate seal packaged form high and light weight with unnecessary a little cosmetic preparation one and pack.The preferred concrete example of such packaged form is laminated film having on aluminium lamination and polyethylene terephthalate layer etc.These packaging material can implement to prevent the surface treatments such as ultraviolet according to hope.In addition, the size of this matrix material needs only suitable selection, is generally the scope of 10cm * 10cm～30cm * 30cm.The shape of matrix material is also not particularly limited, and preferably long limit is minor face 1.5～2 times, and the length of the minor face rectangle that is 10～15cm.
[embodiment]
Below, based on embodiment, the present invention is described in further detail, but the present invention is not subject to any restriction of these embodiment.In addition, the evaluation methodology of the aqueous wiped clean cosmetic preparation in embodiment and comparative example is as described below, and the use level of each composition represents " quality % " unless otherwise specified.
(evaluation methodology 1: the evaluation of cosmetic soil release effect)
Woman, evaluate after the face coating oiliness foundation cream of panel (20), with impregnation clean makeup material cotton wiping implemented the part of cosmetic, according to following metewand, the effect of removing of oiliness foundation cream is carried out to sensory evaluation.
The metewand > of < cosmetic soil release effect
◎: in 20 16 above answer cosmetic dirts remove effect excellence
What in zero: 20,11～15 were answered cosmetic dirts removes effect excellence
△: what in 20,6～10 were answered cosmetic dirts removes effect excellence
*: in 20 5 following answer cosmetic dirts remove effect excellence
(evaluation methodology 2: the evaluation of use sense)
According to following metewand to the excitement after just having cleaned in above-mentioned evaluation methodology 1 and foam is residual carries out sensory evaluation.In addition, so-called excitement refers to from just cleaning the temporary transient sensation of pricking of feeling in the scope of 10 minutes.
The metewand > of < excitement
◎: in 20,16 above answers do not have excitement
In zero: 20,11～15 answers do not have excitement
△: in 20,6～10 answers do not have excitement
*: in 20,5 following answers do not have excitement
The metewand > that < foam is residual
◎: in 20,16 above answers do not have foam residual
In zero: 20,11～15 answers do not have foam residual
△: in 20,6～10 answers do not have foam residual
*: in 20,5 do not have foam residual below
(evaluation methodology 3: the evaluation of storage stability)
By sample keeping 30 days in the temperature chamber of 50 ℃, perusal surfactant have or not separate out and and have or not and be separated, according to following benchmark evaluation storage stability.
The metewand > of < storage stability
Zero: even if 30 days surfactants of keeping can not separated out yet, also can not produce and be separated
△: after 30 days, surfactant is separated out, and find to be separated
*: watersoluble cleaning cosmetic preparation has just been prepared rear surface activating agent and has been separated out, and generation is separated
Embodiment 1 and comparative example 1～3
According to the cooperation shown in table 1, by following step, mix each composition and prepare watersoluble cleaning cosmetic preparation.In addition, in table 1, the composition shown in abbreviation refers to following compound.
EDTA-2Na: ethylenediaminetetraacetic acid disodium dihydrogen
PG: propylene glycol
BG:1,3-butanediol
(caprylic/capric) PEG-6 glyceride: the polyoxyethylene fatty acid glyceride that ethylene oxide addition molal quantity is 6, fatty acid part is the fatty acid mixed of sad and capric acid (trade name: Softigen767, Sasol company manufacture)
(manufacturing step)
(1) constituent of the A phase shown in table 1 mixed and be heated to 80 ℃.
(2) then, the composition of B phase is joined A mutually in and mix homogeneously.
(3) mixture obtaining is cooled to after 40 ℃ while stirring, adds C phase mix homogeneously.
To the watersoluble cleaning cosmetic preparation evaluation cosmetic dirt as above obtaining remove effect, excitement, foam is residual and storage stability.Show the result in table 1.
[table 1] (%)
As shown in Table 1, a small amount of interpolation is compared excellent storage stability as the system (embodiment 1) of the lauryl betaine of amphoteric surfactant with the system (comparative example 1) of not adding lauryl betaine.On the other hand, the storage stability of the system (comparative example 3) of known interpolation anionic surfactant's system (comparative example 2) and interpolation cationic surfactant does not only improve, and worsens.
Embodiment 2～6
Except becoming the cooperation shown in table 2, prepare similarly to Example 1 watersoluble cleaning cosmetic preparation, its performance is evaluated.Show the result in table 2.
[table 2] (%)
As shown in Table 2, if coordinate polyoxyethylene fatty acid glyceride and a small amount of amphoteric surfactant (lauryl betaine) simultaneously, can obtain not producing excitement, can not produce the makeup material that cleans of the residual and excellent storage stability of foam.In addition, if the content of amphoteric surfactant is 1.75 quality %, there is a little the residual sense of foam (with reference to embodiment 6).
Comparative example 4～8
Except becoming the cooperation shown in table 3, prepare similarly to Example 1 watersoluble cleaning cosmetic preparation, its performance is evaluated.Show the result in table 3.
[table 3] (%)
Known in amphoteric surfactant surpasses the comparative example 4 of 2 quality %, produce foam residual, at amphoteric surfactant, surpass in the comparative example 5 of 4 quality %, foam-expelling is residual become strong beyond, excitement grow.In addition, as shown in comparative example 4 and comparative example 5, even if the gross mass % of nonionic surfactant and amphoteric surfactant is certain, follow the addition of amphoteric surfactant to increase, also can produce excitement, produce foam residual.
In addition, as shown in comparative example 6 and comparative example 7, even if the content of amphoteric surfactant is below 2 quality %, in the situation that the use level of polyoxyethylene fatty acid glyceride is lower than 3 quality %, storage stability also can be very poor, make up hardly to remove effect abundant.In addition, as shown in comparative example 8, if the use level of polyoxyethylene fatty acid glyceride is too much, produce excitement, produce foam residual.
[industrial utilize probability]
According to the present invention, can provide a kind of for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, it not only has abrasive power, and there is no sticky sense, the low stimulation after firm wiping and do not have foam residual, do not separate out and be separated for a long time, excellent storage stability.In addition, can provide a kind of can be used as carry with clean makeup material for removing the wiping cosmetic sheet of color make-up cosmetic preparation.
Claims (8)
1. for removing an aqueous wiped clean cosmetic preparation for color make-up cosmetic preparation, it contains:
(A) the polyoxyethylene fatty acid glyceride of 3～10 quality %,
(B) amphoteric surfactant of 0.005～2 quality % and
(C) polyhydric alcohol of 1～12 quality %,
And in fact not containing anionic surfactant and cationic surfactant.
2. as claimed in claim 1 for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, it is not in fact containing ethanol.
3. as claimed in claim 1 or 2 for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, wherein, the fatty acid of described (A) composition is that carbon number is 8～22 fatty acid.
4. as claimed in claim 1 or 2 for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, wherein, the addition molal quantity of the ethylene oxide of described (A) composition is 4～10.
5. as claimed in claim 1 or 2 for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, wherein, described (B) composition is oxyneurine type amphoteric surfactant.
6. as claimed in claim 1 or 2 for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, wherein, not containing anionic surfactant and cationic surfactant, or,
In the situation that containing them, their content is below the content of (B) composition and below 0.1 quality % of total amount.
7. as claimed in claim 1 or 2 for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation, wherein, the content of described (B) composition is 0.05～1 quality %.
8. for removing a wiping cosmetic sheet for color make-up cosmetic preparation, it makes in claim 1～7 being impregnated in matrix material and obtaining for removing the aqueous wiped clean cosmetic preparation of color make-up cosmetic preparation described in any one.
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| JP2013-080203 | 2013-04-08 | ||
| JP2013080203A JP5427970B1 (en) | 2013-04-08 | 2013-04-08 | Aqueous wipe cleansing cosmetic |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108096061A (en) * | 2016-11-25 | 2018-06-01 | 株式会社芳珂 | Cosmetic preparation composition |
| CN113105953A (en) * | 2020-01-10 | 2021-07-13 | 花王株式会社 | Cleaning agent composition, hard surface cleaning sheet, and hard surface cleaning method |
| CN113317999A (en) * | 2020-02-28 | 2021-08-31 | 北京龙和隆盛生物技术股份有限公司 | Liquid composition for wiping |
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| JP2021178795A (en) | 2020-05-14 | 2021-11-18 | 株式会社 資生堂 | Detergent composition |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003073221A (en) * | 2001-08-31 | 2003-03-12 | Lion Corp | Clouding agent-containing cosmetic |
| JP2006206582A (en) * | 2004-12-27 | 2006-08-10 | Lion Corp | Detergent composition for sterilization of skin and sterilization method |
| CN102961268A (en) * | 2011-08-31 | 2013-03-13 | 花王株式会社 | Skin cleanser composition |
| CN102961289A (en) * | 2012-12-08 | 2013-03-13 | 大连创达技术交易市场有限公司 | Skin-whitening and moisture-preserving wet tissue |
-
2013
- 2013-04-08 JP JP2013080203A patent/JP5427970B1/en active Active
- 2013-12-26 CN CN201310729397.3A patent/CN103637930B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2003073221A (en) * | 2001-08-31 | 2003-03-12 | Lion Corp | Clouding agent-containing cosmetic |
| JP2006206582A (en) * | 2004-12-27 | 2006-08-10 | Lion Corp | Detergent composition for sterilization of skin and sterilization method |
| CN102961268A (en) * | 2011-08-31 | 2013-03-13 | 花王株式会社 | Skin cleanser composition |
| CN102961289A (en) * | 2012-12-08 | 2013-03-13 | 大连创达技术交易市场有限公司 | Skin-whitening and moisture-preserving wet tissue |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN108096061A (en) * | 2016-11-25 | 2018-06-01 | 株式会社芳珂 | Cosmetic preparation composition |
| CN108096061B (en) * | 2016-11-25 | 2022-04-08 | 株式会社芳珂 | Cosmetic composition |
| CN113105953A (en) * | 2020-01-10 | 2021-07-13 | 花王株式会社 | Cleaning agent composition, hard surface cleaning sheet, and hard surface cleaning method |
| CN113317999A (en) * | 2020-02-28 | 2021-08-31 | 北京龙和隆盛生物技术股份有限公司 | Liquid composition for wiping |
Also Published As
| Publication number | Publication date |
|---|---|
| CN103637930B (en) | 2015-01-28 |
| JP2014201561A (en) | 2014-10-27 |
| JP5427970B1 (en) | 2014-02-26 |
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Address after: 100044 10D1, D3A, 3 building, 1 West Gate Street, Xicheng District, Beijing. Patentee after: Beijing Longhe Longsheng Biotechnology Co.,Ltd. Address before: 100044 10D1, D3A, 3 building, 1 West Gate Street, Xicheng District, Beijing. Patentee before: Beijing Longhe Longsheng Biotechnology Development Co.,Ltd. |