CN103626207B - 一种从含锂盐湖卤水中提取锂盐的方法和装置 - Google Patents
一种从含锂盐湖卤水中提取锂盐的方法和装置 Download PDFInfo
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- CN103626207B CN103626207B CN201210295828.5A CN201210295828A CN103626207B CN 103626207 B CN103626207 B CN 103626207B CN 201210295828 A CN201210295828 A CN 201210295828A CN 103626207 B CN103626207 B CN 103626207B
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- bittern
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- salt
- lithium salts
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- 241001131796 Botaurus stellaris Species 0.000 title claims abstract description 106
- 229910003002 lithium salt Inorganic materials 0.000 title claims abstract description 59
- 159000000002 lithium salts Chemical class 0.000 title claims abstract description 59
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 title claims abstract description 58
- 238000000034 method Methods 0.000 title claims abstract description 53
- 239000012528 membrane Substances 0.000 claims abstract description 73
- 238000005188 flotation Methods 0.000 claims abstract description 51
- 150000003839 salts Chemical class 0.000 claims abstract description 43
- 239000000463 material Substances 0.000 claims abstract description 27
- 230000002209 hydrophobic effect Effects 0.000 claims abstract description 24
- 159000000003 magnesium salts Chemical class 0.000 claims abstract description 20
- 239000012982 microporous membrane Substances 0.000 claims abstract description 20
- 239000012043 crude product Substances 0.000 claims abstract description 19
- 159000000000 sodium salts Chemical class 0.000 claims abstract description 17
- 238000010438 heat treatment Methods 0.000 claims abstract description 10
- 210000004379 membrane Anatomy 0.000 claims description 77
- 238000007667 floating Methods 0.000 claims description 25
- 239000003795 chemical substances by application Substances 0.000 claims description 23
- 239000004743 Polypropylene Substances 0.000 claims description 16
- 229920001155 polypropylene Polymers 0.000 claims description 16
- 239000012466 permeate Substances 0.000 claims description 15
- -1 polytetrafluoroethylene Polymers 0.000 claims description 15
- 230000008569 process Effects 0.000 claims description 15
- 238000007599 discharging Methods 0.000 claims description 13
- 239000011833 salt mixture Substances 0.000 claims description 11
- 239000003814 drug Substances 0.000 claims description 10
- 238000000227 grinding Methods 0.000 claims description 10
- 229920001343 polytetrafluoroethylene Polymers 0.000 claims description 10
- 239000004810 polytetrafluoroethylene Substances 0.000 claims description 10
- 239000008187 granular material Substances 0.000 claims description 9
- 239000002131 composite material Substances 0.000 claims description 8
- ZSIAUFGUXNUGDI-UHFFFAOYSA-N hexan-1-ol Chemical compound CCCCCCO ZSIAUFGUXNUGDI-UHFFFAOYSA-N 0.000 claims description 8
- 150000001335 aliphatic alkanes Chemical class 0.000 claims description 7
- 239000004809 Teflon Substances 0.000 claims description 6
- 229920006362 Teflon® Polymers 0.000 claims description 6
- 239000000284 extract Substances 0.000 claims description 6
- 125000002496 methyl group Chemical group [H]C([H])([H])* 0.000 claims description 6
- WVYWICLMDOOCFB-UHFFFAOYSA-N 4-methyl-2-pentanol Chemical compound CC(C)CC(C)O WVYWICLMDOOCFB-UHFFFAOYSA-N 0.000 claims description 5
- 239000002033 PVDF binder Substances 0.000 claims description 4
- SJWFXCIHNDVPSH-UHFFFAOYSA-N octan-2-ol Chemical compound CCCCCCC(C)O SJWFXCIHNDVPSH-UHFFFAOYSA-N 0.000 claims description 4
- 229920002981 polyvinylidene fluoride Polymers 0.000 claims description 4
- 239000012267 brine Substances 0.000 claims description 3
- 230000008595 infiltration Effects 0.000 claims description 3
- 238000001764 infiltration Methods 0.000 claims description 3
- 239000011777 magnesium Substances 0.000 claims description 3
- 238000005096 rolling process Methods 0.000 claims description 3
- HPALAKNZSZLMCH-UHFFFAOYSA-M sodium;chloride;hydrate Chemical compound O.[Na+].[Cl-] HPALAKNZSZLMCH-UHFFFAOYSA-M 0.000 claims description 3
- 235000012489 doughnuts Nutrition 0.000 claims 1
- 230000007613 environmental effect Effects 0.000 abstract description 5
- 230000008901 benefit Effects 0.000 abstract description 4
- 238000009776 industrial production Methods 0.000 abstract description 2
- 229910052744 lithium Inorganic materials 0.000 description 22
- WHXSMMKQMYFTQS-UHFFFAOYSA-N Lithium Chemical compound [Li] WHXSMMKQMYFTQS-UHFFFAOYSA-N 0.000 description 21
- 239000000126 substance Substances 0.000 description 13
- 229910052500 inorganic mineral Inorganic materials 0.000 description 11
- 239000011707 mineral Substances 0.000 description 11
- 239000013505 freshwater Substances 0.000 description 10
- 229910052736 halogen Inorganic materials 0.000 description 6
- 150000002367 halogens Chemical class 0.000 description 6
- 239000002245 particle Substances 0.000 description 6
- 238000010926 purge Methods 0.000 description 6
- 230000004888 barrier function Effects 0.000 description 5
- 238000009833 condensation Methods 0.000 description 5
- 230000005494 condensation Effects 0.000 description 5
- 238000004821 distillation Methods 0.000 description 5
- 238000005516 engineering process Methods 0.000 description 5
- 238000004519 manufacturing process Methods 0.000 description 5
- 239000012452 mother liquor Substances 0.000 description 5
- 239000000047 product Substances 0.000 description 5
- XEEYBQQBJWHFJM-UHFFFAOYSA-N Iron Chemical compound [Fe] XEEYBQQBJWHFJM-UHFFFAOYSA-N 0.000 description 4
- 238000004140 cleaning Methods 0.000 description 4
- 239000004744 fabric Substances 0.000 description 4
- 238000002156 mixing Methods 0.000 description 4
- 238000011084 recovery Methods 0.000 description 4
- VEXZGXHMUGYJMC-UHFFFAOYSA-M Chloride anion Chemical compound [Cl-] VEXZGXHMUGYJMC-UHFFFAOYSA-M 0.000 description 3
- 239000012141 concentrate Substances 0.000 description 3
- 239000007788 liquid Substances 0.000 description 3
- CHBCHAGCVIMDKI-UHFFFAOYSA-N [F].C=C Chemical compound [F].C=C CHBCHAGCVIMDKI-UHFFFAOYSA-N 0.000 description 2
- 238000007796 conventional method Methods 0.000 description 2
- 230000000694 effects Effects 0.000 description 2
- 239000007789 gas Substances 0.000 description 2
- 239000012510 hollow fiber Substances 0.000 description 2
- 229910052742 iron Inorganic materials 0.000 description 2
- XGZVUEUWXADBQD-UHFFFAOYSA-L lithium carbonate Chemical compound [Li+].[Li+].[O-]C([O-])=O XGZVUEUWXADBQD-UHFFFAOYSA-L 0.000 description 2
- 229910052808 lithium carbonate Inorganic materials 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 238000012986 modification Methods 0.000 description 2
- 230000004048 modification Effects 0.000 description 2
- 238000001556 precipitation Methods 0.000 description 2
- 239000000243 solution Substances 0.000 description 2
- 238000012546 transfer Methods 0.000 description 2
- KRHYYFGTRYWZRS-UHFFFAOYSA-M Fluoride anion Chemical compound [F-] KRHYYFGTRYWZRS-UHFFFAOYSA-M 0.000 description 1
- FYYHWMGAXLPEAU-UHFFFAOYSA-N Magnesium Chemical compound [Mg] FYYHWMGAXLPEAU-UHFFFAOYSA-N 0.000 description 1
- 206010054949 Metaplasia Diseases 0.000 description 1
- 229910000831 Steel Inorganic materials 0.000 description 1
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 description 1
- 238000004220 aggregation Methods 0.000 description 1
- 230000002776 aggregation Effects 0.000 description 1
- 238000004458 analytical method Methods 0.000 description 1
- 239000007864 aqueous solution Substances 0.000 description 1
- 238000001354 calcination Methods 0.000 description 1
- 229910052799 carbon Inorganic materials 0.000 description 1
- 150000001721 carbon Chemical group 0.000 description 1
- 239000003054 catalyst Substances 0.000 description 1
- 239000000919 ceramic Substances 0.000 description 1
- 238000006243 chemical reaction Methods 0.000 description 1
- 150000001875 compounds Chemical class 0.000 description 1
- 238000001816 cooling Methods 0.000 description 1
- 238000002425 crystallisation Methods 0.000 description 1
- 230000008025 crystallization Effects 0.000 description 1
- 230000007547 defect Effects 0.000 description 1
- 230000006735 deficit Effects 0.000 description 1
- 238000001704 evaporation Methods 0.000 description 1
- 230000008020 evaporation Effects 0.000 description 1
- 238000002474 experimental method Methods 0.000 description 1
- 238000000605 extraction Methods 0.000 description 1
- 238000009291 froth flotation Methods 0.000 description 1
- 230000003760 hair shine Effects 0.000 description 1
- 238000005342 ion exchange Methods 0.000 description 1
- 238000002386 leaching Methods 0.000 description 1
- 239000007791 liquid phase Substances 0.000 description 1
- 229910052749 magnesium Inorganic materials 0.000 description 1
- 230000015689 metaplastic ossification Effects 0.000 description 1
- 239000003595 mist Substances 0.000 description 1
- 239000000178 monomer Substances 0.000 description 1
- 239000011148 porous material Substances 0.000 description 1
- 239000010453 quartz Substances 0.000 description 1
- 230000009467 reduction Effects 0.000 description 1
- 238000005185 salting out Methods 0.000 description 1
- 239000004065 semiconductor Substances 0.000 description 1
- 238000000926 separation method Methods 0.000 description 1
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N silicon dioxide Inorganic materials O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 description 1
- 239000002002 slurry Substances 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 238000000638 solvent extraction Methods 0.000 description 1
- 238000001179 sorption measurement Methods 0.000 description 1
- 239000010959 steel Substances 0.000 description 1
- 238000003756 stirring Methods 0.000 description 1
- 239000002918 waste heat Substances 0.000 description 1
- 230000010148 water-pollination Effects 0.000 description 1
Classifications
-
- Y—GENERAL TAGGING OF NEW TECHNOLOGICAL DEVELOPMENTS; GENERAL TAGGING OF CROSS-SECTIONAL TECHNOLOGIES SPANNING OVER SEVERAL SECTIONS OF THE IPC; TECHNICAL SUBJECTS COVERED BY FORMER USPC CROSS-REFERENCE ART COLLECTIONS [XRACs] AND DIGESTS
- Y02—TECHNOLOGIES OR APPLICATIONS FOR MITIGATION OR ADAPTATION AGAINST CLIMATE CHANGE
- Y02P—CLIMATE CHANGE MITIGATION TECHNOLOGIES IN THE PRODUCTION OR PROCESSING OF GOODS
- Y02P20/00—Technologies relating to chemical industry
- Y02P20/10—Process efficiency
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- Separation Using Semi-Permeable Membranes (AREA)
Abstract
Description
Claims (12)
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CN201210295828.5A CN103626207B (zh) | 2012-08-20 | 2012-08-20 | 一种从含锂盐湖卤水中提取锂盐的方法和装置 |
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CN201210295828.5A CN103626207B (zh) | 2012-08-20 | 2012-08-20 | 一种从含锂盐湖卤水中提取锂盐的方法和装置 |
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CN103626207A CN103626207A (zh) | 2014-03-12 |
CN103626207B true CN103626207B (zh) | 2017-03-29 |
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Families Citing this family (2)
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CN106241839B (zh) * | 2016-07-20 | 2018-01-30 | 青海大学 | 一种从盐湖老卤中分离镁、降低镁锂比的方法 |
CN117695872A (zh) * | 2024-01-04 | 2024-03-15 | 中国海洋大学 | 一种用于膜萃取-膜反萃的复合膜组及其制备方法和应用 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101928023A (zh) * | 2010-09-03 | 2010-12-29 | 山西大学 | 利用太阳能从卤水中制取碳酸锂的装置和方法 |
CN102139891A (zh) * | 2011-01-27 | 2011-08-03 | 山西大学 | 钾盐矿快速制取工业盐的方法和装置 |
CN102154563A (zh) * | 2010-12-09 | 2011-08-17 | 江南大学 | 一种从盐湖卤水中富集锂的浮选方法 |
CN102433434A (zh) * | 2010-09-29 | 2012-05-02 | 王辉 | 用水作为循环工作物质(水洗循环法)以提高含锂卤水膜法分离锂的回收率的方法 |
-
2012
- 2012-08-20 CN CN201210295828.5A patent/CN103626207B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN101928023A (zh) * | 2010-09-03 | 2010-12-29 | 山西大学 | 利用太阳能从卤水中制取碳酸锂的装置和方法 |
CN102433434A (zh) * | 2010-09-29 | 2012-05-02 | 王辉 | 用水作为循环工作物质(水洗循环法)以提高含锂卤水膜法分离锂的回收率的方法 |
CN102154563A (zh) * | 2010-12-09 | 2011-08-17 | 江南大学 | 一种从盐湖卤水中富集锂的浮选方法 |
CN102139891A (zh) * | 2011-01-27 | 2011-08-03 | 山西大学 | 钾盐矿快速制取工业盐的方法和装置 |
Non-Patent Citations (1)
Title |
---|
直接接触式膜蒸馏脱盐过程与热量回收研究;李蕾;《中国优秀硕士学位论文全文数据库 基础科学辑》;20090415;A010-19 * |
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Effective date of registration: 20231012 Address after: 523888 building 6, No. 5, Weifeng Road, Dongcheng Street, Dongguan City, Guangdong Province Patentee after: GUANGDONG TAIQUAN ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. Address before: Room 101, Building 6, No. 5, Weifeng Road, Dongcheng Street, Dongguan City, Guangdong Province, 523015 Patentee before: Guangdong Songquan Environmental Protection Equipment Co.,Ltd. |
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Address after: 523888 building 6, No. 5, Weifeng Road, Dongcheng Street, Dongguan City, Guangdong Province Patentee after: Guangdong Taiquan Technology Co.,Ltd. Country or region after: China Address before: 523888 building 6, No. 5, Weifeng Road, Dongcheng Street, Dongguan City, Guangdong Province Patentee before: GUANGDONG TAIQUAN ENVIRONMENTAL PROTECTION TECHNOLOGY Co.,Ltd. Country or region before: China |
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