CN103613850B - A kind of Filament for vermin-proof plastic woven bag - Google Patents

A kind of Filament for vermin-proof plastic woven bag Download PDF

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Publication number
CN103613850B
CN103613850B CN201310617633.2A CN201310617633A CN103613850B CN 103613850 B CN103613850 B CN 103613850B CN 201310617633 A CN201310617633 A CN 201310617633A CN 103613850 B CN103613850 B CN 103613850B
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China
Prior art keywords
auxiliary agent
filament
vermin
ferrocene
woven bag
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CN201310617633.2A
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Chinese (zh)
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CN103613850A (en
Inventor
戴之青
汤毅
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ANHUI ANYUAN PLASTIC Co Ltd
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ANHUI ANYUAN PLASTIC Co Ltd
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Priority to CN201310617633.2A priority Critical patent/CN103613850B/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/10Homopolymers or copolymers of propene
    • C08L23/12Polypropene
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F1/00General methods for the manufacture of artificial filaments or the like
    • D01F1/02Addition of substances to the spinning solution or to the melt
    • D01F1/10Other agents for modifying properties
    • DTEXTILES; PAPER
    • D01NATURAL OR MAN-MADE THREADS OR FIBRES; SPINNING
    • D01FCHEMICAL FEATURES IN THE MANUFACTURE OF ARTIFICIAL FILAMENTS, THREADS, FIBRES, BRISTLES OR RIBBONS; APPARATUS SPECIALLY ADAPTED FOR THE MANUFACTURE OF CARBON FILAMENTS
    • D01F6/00Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof
    • D01F6/44Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds
    • D01F6/46Monocomponent artificial filaments or the like of synthetic polymers; Manufacture thereof from mixtures of polymers obtained by reactions only involving carbon-to-carbon unsaturated bonds as major constituent with other polymers or low-molecular-weight compounds of polyolefins
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/12Applications used for fibers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Engineering & Computer Science (AREA)
  • General Chemical & Material Sciences (AREA)
  • Textile Engineering (AREA)
  • Health & Medical Sciences (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Manufacturing & Machinery (AREA)
  • Agricultural Chemicals And Associated Chemicals (AREA)
  • Artificial Filaments (AREA)

Abstract

The invention discloses a kind of Filament for vermin-proof plastic woven bag, it is characterized in that, be made up by operations such as batching, melting, filtration, extruding membrane, water-cooled, sub-wire, wire drawing, rollings of the raw material of following weight part: polypropylene 100, metallocene linear-low density polyethylene 4-6, pyrethroid 0.2-0.4, Mono-n-butyltin 0.4-0.6, acrylate 3.2-3.6, chlorinatedpolyethylene 2-4, ferrocene 1-1.5, methyl ethyl diketone selenium 0.1-0.2, auxiliary agent 3-3.5; The present invention adds auxiliary agent, can be effectively anti-aging, anti-Exposure to Sunlight, and rationally, cost is low for formula, and the Polywoven Bag made can effective anti-insect bite, adds work-ing life and the use range of packing bag, is applicable to long-distance transport and article and preserves and use.

Description

A kind of Filament for vermin-proof plastic woven bag
Technical field
The present invention relates to chemical technology field, particularly a kind of Filament for vermin-proof plastic woven bag.
Background technology
Polywoven Bag is divided into Polypropylene Bag, polyethylene bag by main raw formation; Bag at the bottom of seam end bag, tape edge is divided into by method of sewing.Be widely used in a kind of wrapping material of the article such as fertilizer, Chemicals at present.Its main production utilizes plastic raw materials to be flat filament through extrusion film, cutting, unilateral stretching, through obtaining product through knitting device, is commonly referred to as woven bag.The packing bag of the polypropylene flat-filament establishment that conventional art is produced, weathering resistance is poor, easily occur hardening at north of china in winter, embrittlement, demoulding, peeling, the problem such as fracture, in south because summer temperature is high, illumination strong, ultraviolet penetration power is strong, easily cause that woven bag is aging, the problem such as burn into poor toughness, intensity low work-ing life is short, not only wasted resource but also contaminate environment.
Summary of the invention
The object of this invention is to provide a kind of Filament for vermin-proof plastic woven bag.
In order to realize object of the present invention, the present invention is by following scheme implementation:
A kind of Filament for vermin-proof plastic woven bag, is made up by operations such as batching, melting, filtration, extruding membrane, water-cooled, sub-wire, wire drawing, rollings of the raw material of following weight part: polypropylene 100, metallocene linear-low density polyethylene 4-6, pyrethroid 0.2-0.4, Mono-n-butyltin 0.4-0.6, acrylate 3.2-3.6, chlorinatedpolyethylene 2-4, ferrocene 1-1.5, methyl ethyl diketone selenium 0.1-0.2, auxiliary agent 3-3.5;
Described auxiliary agent is made up of the raw material of following weight part: clay 20-24, alum 5-6, altax 2-3, linking agent TAC2-3, antioxidant 1010 1-2, Tremoliteor Tremoliteasbestos 3-4, ferrocene 2-3, morpholine 1-2,1,6 hexanediyl ester 5-7, phthalic ester 35-40, Tenox PG 3-4, green tea powder 1-2, coix seed oil 2-3, vanadium diboride 2-3, l-Epicatechol 1-2; Clay, Tremoliteor Tremoliteasbestos are sent in calcining furnace and calcine 2-3 hour at 720-740 DEG C by preparation method, then, take out, send in the hydrochloric acid soln of 10-15% and soak 2-3 hour, filter, obtain filter residue, clean, dry, grind to form 400-600 order powder with clear water; Gained powder mixes with other remaining component, is heated to 60-70 DEG C, stirring reaction 40-50 minute, and cooling, grinds to form slurry, to obtain final product.
Excellent effect of the present invention is: the present invention adds auxiliary agent, can be effectively anti-aging, anti-Exposure to Sunlight, rationally, cost is low for formula, and the Polywoven Bag made can effective anti-insect bite, add work-ing life and the use range of packing bag, be applicable to long-distance transport and article preservation use.
Embodiment
Below by specific examples, the present invention is described in detail.
A kind of Filament for vermin-proof plastic woven bag, is made up by operations such as batching, melting, filtration, extruding membrane, water-cooled, sub-wire, wire drawing, rollings of the raw material of following weight part (kilogram): polypropylene 100, metallocene linear-low density polyethylene 4, pyrethroid 0.2, Mono-n-butyltin 0.4, acrylate 3.2, chlorinatedpolyethylene 2, ferrocene 1, methyl ethyl diketone selenium 0.1, auxiliary agent 3;
Described auxiliary agent is made up of the raw material of following weight part (kilogram): described auxiliary agent is made up of the raw material of following weight part (kilogram): clay 20, alum 5, altax 3, linking agent TAC2, antioxidant 1010 1, Tremoliteor Tremoliteasbestos 3, ferrocene 2, morpholine 1,1,6 hexanediyl ester 5, phthalic ester 35, Tenox PG 3, green tea powder 1, coix seed oil 2, vanadium diboride 3, l-Epicatechol 1; Clay, Tremoliteor Tremoliteasbestos are sent in calcining furnace and calcine 2-3 hour at 720-740 DEG C by preparation method, then, take out, send in the hydrochloric acid soln of 10-15% and soak 2-3 hour, filter, obtain filter residue, clean, dry, grind to form 400-600 order powder with clear water; Gained powder mixes with other remaining component, is heated to 60-70 DEG C, stirring reaction 40-50 minute, and cooling, grinds to form slurry, to obtain final product.
After tested, the radial pull-off force of the flat filament that the present invention produces and broadwise pull-off force are all greater than 790N/50mm, substantially increase the tensile strength of flat filament, have stopped the fracture of wire problem in braiding process.

Claims (1)

1. a Filament for vermin-proof plastic woven bag, it is characterized in that, be made up by operations such as batching, melting, filtration, extruding membrane, water-cooled, sub-wire, wire drawing, rollings of the raw material of following weight part: polypropylene 100, metallocene linear-low density polyethylene 4-6, pyrethroid 0.2-0.4, Mono-n-butyltin 0.4-0.6, acrylate 3.2-3.6, chlorinatedpolyethylene 2-4, ferrocene 1-1.5, methyl ethyl diketone selenium 0.1-0.2, auxiliary agent 3-3.5;
Described auxiliary agent is made up of the raw material of following weight part: clay 20-24, alum 5-6, altax 2-3, linking agent TAC2-3, antioxidant 1010 1-2, Tremoliteor Tremoliteasbestos 3-4, ferrocene 2-3, morpholine 1-2,1,6 hexanediyl ester 5-7, phthalic ester 35-40, Tenox PG 3-4, green tea powder 1-2, coix seed oil 2-3, vanadium diboride 2-3, l-Epicatechol 1-2; Clay, Tremoliteor Tremoliteasbestos are sent in calcining furnace and calcine 2-3 hour at 720-740 DEG C by preparation method, then, take out, send in the hydrochloric acid soln of 10-15% and soak 2-3 hour, filter, obtain filter residue, clean, dry, grind to form 400-600 order powder with clear water; Gained powder mixes with other remaining component, is heated to 60-70 DEG C, stirring reaction 40-50 minute, and cooling, grinds to form slurry, to obtain final product.
CN201310617633.2A 2013-11-28 2013-11-28 A kind of Filament for vermin-proof plastic woven bag Active CN103613850B (en)

Priority Applications (1)

Application Number Priority Date Filing Date Title
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Application Number Priority Date Filing Date Title
CN201310617633.2A CN103613850B (en) 2013-11-28 2013-11-28 A kind of Filament for vermin-proof plastic woven bag

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CN103613850A CN103613850A (en) 2014-03-05
CN103613850B true CN103613850B (en) 2016-02-03

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Families Citing this family (7)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104562237B (en) * 2014-12-29 2017-01-04 中国水产科学研究院东海水产研究所 The Grouper cultivating head rope processing manufacture method of circle silk
CN105400072A (en) * 2015-12-01 2016-03-16 潜山县恒源塑业有限责任公司 Material for damp-proof plastic woven bag
CN106046552A (en) * 2016-07-19 2016-10-26 金寨县凯歌塑业有限公司 Silk for producing insect bite-proof woven bags
CN106221010A (en) * 2016-08-23 2016-12-14 天津市旭辉恒远塑料包装股份有限公司 A kind of insect protected durable plastic material woven bag silk
CN107805343A (en) * 2017-10-31 2018-03-16 遵义宏龙塑料有限责任公司 Auxiliary agent for insect-proof plastic woven bag
CN107805344A (en) * 2017-10-31 2018-03-16 遵义宏龙塑料有限责任公司 Novel plastic woven bag
CN107815016A (en) * 2017-10-31 2018-03-20 遵义宏龙塑料有限责任公司 Method for manufacturing novel plastic woven bag

Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1148061A (en) * 1995-06-21 1997-04-23 Fmc有限公司 Pyrethroid-containing crop protection bags
CN102731914A (en) * 2012-07-23 2012-10-17 安徽安远塑胶股份有限公司 Novel composition used for preparing anti-aging plastic woven products

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1148061A (en) * 1995-06-21 1997-04-23 Fmc有限公司 Pyrethroid-containing crop protection bags
CN102731914A (en) * 2012-07-23 2012-10-17 安徽安远塑胶股份有限公司 Novel composition used for preparing anti-aging plastic woven products

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Denomination of invention: A type of silk for insect resistant plastic woven bags

Effective date of registration: 20230630

Granted publication date: 20160203

Pledgee: China Co. truction Bank Corp Dingyuan branch

Pledgor: ANHUI ANYUAN PLASTICS Inc.

Registration number: Y2023980047007