CN107805343A - Auxiliary agent for insect-proof plastic woven bag - Google Patents
Auxiliary agent for insect-proof plastic woven bag Download PDFInfo
- Publication number
- CN107805343A CN107805343A CN201711049179.XA CN201711049179A CN107805343A CN 107805343 A CN107805343 A CN 107805343A CN 201711049179 A CN201711049179 A CN 201711049179A CN 107805343 A CN107805343 A CN 107805343A
- Authority
- CN
- China
- Prior art keywords
- auxiliary agent
- parts
- woven bag
- moth
- eating
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
- 239000012752 auxiliary agent Substances 0.000 title claims abstract description 16
- 239000004927 clay Substances 0.000 claims abstract description 7
- 229910052891 actinolite Inorganic materials 0.000 claims abstract description 6
- 229940037003 alum Drugs 0.000 claims abstract description 4
- 239000003431 cross linking reagent Substances 0.000 claims abstract description 4
- KTWOOEGAPBSYNW-UHFFFAOYSA-N ferrocene Chemical compound [Fe+2].C=1C=C[CH-]C=1.C=1C=C[CH-]C=1 KTWOOEGAPBSYNW-UHFFFAOYSA-N 0.000 claims abstract description 4
- 229910052720 vanadium Inorganic materials 0.000 claims abstract description 4
- LEONUFNNVUYDNQ-UHFFFAOYSA-N vanadium atom Chemical compound [V] LEONUFNNVUYDNQ-UHFFFAOYSA-N 0.000 claims abstract description 4
- -1 Phthalic acid ester Chemical class 0.000 claims description 13
- QAOWNCQODCNURD-UHFFFAOYSA-N Sulfuric acid Chemical compound OS(O)(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-N 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- 238000001816 cooling Methods 0.000 claims description 5
- 239000000203 mixture Substances 0.000 claims description 5
- 238000002360 preparation method Methods 0.000 claims description 5
- 238000000034 method Methods 0.000 claims description 4
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- 238000001354 calcination Methods 0.000 claims description 3
- XNGIFLGASWRNHJ-UHFFFAOYSA-N o-dicarboxybenzene Natural products OC(=O)C1=CC=CC=C1C(O)=O XNGIFLGASWRNHJ-UHFFFAOYSA-N 0.000 claims description 3
- 239000002002 slurry Substances 0.000 claims description 3
- 238000003756 stirring Methods 0.000 claims description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 3
- AFZSMODLJJCVPP-UHFFFAOYSA-N dibenzothiazol-2-yl disulfide Chemical compound C1=CC=C2SC(SSC=3SC4=CC=CC=C4N=3)=NC2=C1 AFZSMODLJJCVPP-UHFFFAOYSA-N 0.000 claims 1
- 239000004575 stone Substances 0.000 claims 1
- VOBUAPTXJKMNCT-UHFFFAOYSA-N 1-prop-2-enoyloxyhexyl prop-2-enoate Chemical compound CCCCCC(OC(=O)C=C)OC(=O)C=C VOBUAPTXJKMNCT-UHFFFAOYSA-N 0.000 abstract 1
- 239000003963 antioxidant agent Substances 0.000 abstract 1
- 230000003078 antioxidant effect Effects 0.000 abstract 1
- XNGIFLGASWRNHJ-UHFFFAOYSA-L phthalate(2-) Chemical compound [O-]C(=O)C1=CC=CC=C1C([O-])=O XNGIFLGASWRNHJ-UHFFFAOYSA-L 0.000 abstract 1
- 239000004744 fabric Substances 0.000 description 10
- 239000011248 coating agent Substances 0.000 description 6
- 238000000576 coating method Methods 0.000 description 6
- 239000004743 Polypropylene Substances 0.000 description 5
- 229920001155 polypropylene Polymers 0.000 description 5
- 235000019738 Limestone Nutrition 0.000 description 4
- 239000004594 Masterbatch (MB) Substances 0.000 description 4
- 239000004793 Polystyrene Substances 0.000 description 4
- WHHGLZMJPXIBIX-UHFFFAOYSA-N decabromodiphenyl ether Chemical compound BrC1=C(Br)C(Br)=C(Br)C(Br)=C1OC1=C(Br)C(Br)=C(Br)C(Br)=C1Br WHHGLZMJPXIBIX-UHFFFAOYSA-N 0.000 description 4
- 239000003822 epoxy resin Substances 0.000 description 4
- 239000006028 limestone Substances 0.000 description 4
- 229920000092 linear low density polyethylene Polymers 0.000 description 4
- 239000004707 linear low-density polyethylene Substances 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- 229920000647 polyepoxide Polymers 0.000 description 4
- 229920002223 polystyrene Polymers 0.000 description 4
- 238000009958 sewing Methods 0.000 description 3
- 150000001335 aliphatic alkanes Chemical class 0.000 description 2
- 239000003795 chemical substances by application Substances 0.000 description 2
- 238000005520 cutting process Methods 0.000 description 2
- 238000005516 engineering process Methods 0.000 description 2
- 239000003337 fertilizer Substances 0.000 description 2
- 238000009940 knitting Methods 0.000 description 2
- 238000002156 mixing Methods 0.000 description 2
- KOVKEDGZABFDPF-UHFFFAOYSA-N n-(triethoxysilylmethyl)aniline Chemical compound CCO[Si](OCC)(OCC)CNC1=CC=CC=C1 KOVKEDGZABFDPF-UHFFFAOYSA-N 0.000 description 2
- 239000005022 packaging material Substances 0.000 description 2
- 239000002994 raw material Substances 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- 208000006877 Insect Bites and Stings Diseases 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 238000011068 loading method Methods 0.000 description 1
- 239000000463 material Substances 0.000 description 1
- 238000012986 modification Methods 0.000 description 1
- 230000004048 modification Effects 0.000 description 1
- 229920000573 polyethylene Polymers 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/10—Homopolymers or copolymers of propene
- C08L23/12—Polypropene
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/001—Combinations of extrusion moulding with other shaping operations
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C48/00—Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
- B29C48/25—Component parts, details or accessories; Auxiliary operations
- B29C48/92—Measuring, controlling or regulating
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C2948/00—Indexing scheme relating to extrusion moulding
- B29C2948/92—Measuring, controlling or regulating
- B29C2948/92504—Controlled parameter
- B29C2948/92704—Temperature
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29L—INDEXING SCHEME ASSOCIATED WITH SUBCLASS B29C, RELATING TO PARTICULAR ARTICLES
- B29L2031/00—Other particular articles
- B29L2031/712—Containers; Packaging elements or accessories, Packages
- B29L2031/7128—Bags, sacks, sachets
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K3/00—Use of inorganic substances as compounding ingredients
- C08K3/18—Oxygen-containing compounds, e.g. metal carbonyls
- C08K3/24—Acids; Salts thereof
- C08K3/26—Carbonates; Bicarbonates
- C08K2003/265—Calcium, strontium or barium carbonate
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Engineering & Computer Science (AREA)
- Mechanical Engineering (AREA)
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Nonwoven Fabrics (AREA)
- Artificial Filaments (AREA)
Abstract
The invention provides an auxiliary agent for a mothproof plastic woven bag, which comprises the following components: 40% of phthalate, 20% of clay, 15% of alum, 5% of accelerator DM, 5% of hexanediol diacrylate, 5% of crosslinking agent TAC, 10104% of antioxidant, 4% of actinolite, 3% of ferrocene and 2% of vanadium diboride.
Description
Technical field
The present invention relates to a kind of auxiliary agent of Anti-moth-eating Polywoven Bag.
Background technology
Polywoven Bag is configured to Polypropylene Bag, Polythene Bag by main material；It is divided into seam bottom bag, tape edge by method of sewing
Bottom bag.It is now widely used for a kind of packaging material of fertilizer, chemical products and other items.It is now widely used for fertilizer, chemical industry
A kind of packaging material of product and other items.It is deposited in storehouse and is easy to be broken by insect bite and caused content to spill.
The content of the invention
In view of the deficienciess of the prior art, it is an object of the present invention to provide a kind of auxiliary agent of Anti-moth-eating Polywoven Bag, with
Solve the problems, such as to propose in above-mentioned background technology.
The present invention solves its technical problem and is achieved through the following technical solutions：
A kind of Anti-moth-eating Polywoven Bag, including 100 parts of polypropylene, 50 parts of LLDPE, polystyrene 20
Part, 10 parts of anilinomethyl triethoxysilane, 5 parts of lime stone, 2 parts of epoxy resin, 0.5 part of deca-BDE, 5 parts of auxiliary agent, add
Add 5 parts of masterbatch.
The preparation method of the Anti-moth-eating Polywoven Bag is specific as follows：
Ith, by 100 parts of polypropylene, 50 parts of LLDPE, 20 parts of polystyrene, anilinomethyl triethoxysilicane
5 parts 10 parts of alkane, 5 parts of lime stone, 2 parts of epoxy resin, 0.5 part of deca-BDE, 5 parts of auxiliary agent, addition of masterbatch sequentially add mixing
In machine, it is well mixed at being 79 DEG C in temperature, obtains mixture；
IIth, mixture is added in extruder with 100kg/min charging rate and extruded, is then cooled and shaped,
Obtain producing the coating woven cloth of woven bag；
IIIth, first by the preheating temperature of preheating roller tube to 85 DEG C, the temperature of cooling stick is adjusted to 25 DEG C, then with membrana oralis to life
The coating woven cloth for the production woven bag that step II obtains is put into screw rod for 120mm and squeezed by the coating woven cloth gap of production woven bag
Go out in machine and extruded, obtain the flat filament of woven bag coated cloth；
IVth, the flat filament for the woven bag coated cloth that step III obtains is compiled using flat die technique using cylindrical knitting machine
Knit, then in turn through cutting, severing and sewing, that is, obtain Polywoven Bag.
The auxiliary agent is made from the following raw materials in parts by weight：Phthalic acid ester 40%, clay 20%, alum 15%, rush
Enter agent DM 5%, hexanediyl ester 5%, crosslinking agent TAC5%, antioxidant 1010 4%, actinolite 4%, ferrocene
3%th, vanadium diboride 2%
The auxiliary agent preparation method is to be sent into calcining furnace and calcine 2.5 hours at 735 DEG C clay, actinolite, then,
Take out, be sent into 20% sulfuric acid solution and soak 1.5 hours, filter, obtain filter residue, cleaned with clear water, dry, be ground into 350 mesh
Powder；Gained powder mixes with other residual components, is heated to 65 DEG C, stirring reaction 40-50 minutes, cooling, is ground into slurry,
Produce.
The present invention has the beneficial effect that：
The present invention extends the service life of woven bag and improves tensile property, can effectively prevent and treat and damage by worms, woven bag is not easy always
Change, service life length, tensile force is high so that the article of loading is not likely to produce putrid and deteriorated, and cracky, does not extend making for woven bag
With the life-span and improve tensile property.
Embodiment
The present invention will be described in detail below.
Embodiment：
A kind of Anti-moth-eating Polywoven Bag, including 100 parts of polypropylene, 50 parts of LLDPE, polystyrene 20
Part, 10 parts of anilinomethyl triethoxysilane, 5 parts of lime stone, 2 parts of epoxy resin, 0.5 part of deca-BDE, 5 parts of auxiliary agent, add
Add 5 parts of masterbatch.
The preparation method of the Anti-moth-eating Polywoven Bag is specific as follows：
Ith, by 100 parts of polypropylene, 50 parts of LLDPE, 20 parts of polystyrene, anilinomethyl triethoxysilicane
5 parts 10 parts of alkane, 5 parts of lime stone, 2 parts of epoxy resin, 0.5 part of deca-BDE, 5 parts of auxiliary agent, addition of masterbatch sequentially add mixing
In machine, it is well mixed at being 79 DEG C in temperature, obtains mixture；
IIth, mixture is added in extruder with 100kg/min charging rate and extruded, is then cooled and shaped,
Obtain producing the coating woven cloth of woven bag；
IIIth, first by the preheating temperature of preheating roller tube to 85 DEG C, the temperature of cooling stick is adjusted to 25 DEG C, then with membrana oralis to life
The coating woven cloth for the production woven bag that step II obtains is put into screw rod for 120mm and squeezed by the coating woven cloth gap of production woven bag
Go out in machine and extruded, obtain the flat filament of woven bag coated cloth；
IVth, the flat filament for the woven bag coated cloth that step III obtains is compiled using flat die technique using cylindrical knitting machine
Knit, then in turn through cutting, severing and sewing, that is, obtain Polywoven Bag.
The auxiliary agent is made from the following raw materials in parts by weight：Phthalic acid ester 40%, clay 20%, alum 15%, rush
Enter agent DM 5%, hexanediyl ester 5%, crosslinking agent TAC5%, antioxidant 1010 4%, actinolite 4%, ferrocene
3%th, vanadium diboride 2%.
The auxiliary agent preparation method is to be sent into calcining furnace and calcine 2.5 hours at 735 DEG C clay, actinolite, then,
Take out, be sent into 20% sulfuric acid solution and soak 1.5 hours, filter, obtain filter residue, cleaned with clear water, dry, be ground into 350 mesh
Powder；Gained powder mixes with other residual components, is heated to 65 DEG C, stirring reaction 40-50 minutes, cooling, is ground into slurry,
Produce.
Although disclosing embodiments of the invention for the purpose of illustration, it will be appreciated by those skilled in the art that：Not
Depart from the present invention and spirit and scope of the appended claims in, it is various replace, change and modifications all be it is possible, therefore, this
The scope of invention is not limited to embodiment disclosure of that.
Claims (2)
1. a kind of auxiliary agent of Anti-moth-eating Polywoven Bag, it is characterised in that including following：Phthalic acid ester 40%, clay
20%th, alum 15%, altax 5%, hexanediyl ester 5%, crosslinking agent TAC5%, antioxidant 1010 4%, sun
Play stone 4%, ferrocene 3%, vanadium diboride 2%.
A kind of 2. auxiliary agent of Anti-moth-eating Polywoven Bag according to claim 1, it is characterised in that the preparation of the auxiliary agent
Method is that clay, actinolite are sent into calcining furnace to calcine at 735 DEG C 2.5 hours, then, takes out, is sent into 20% sulfuric acid
Soaked 1.5 hours in solution, filter, obtain filter residue, cleaned with clear water, dry, be ground into 350 mesh powders；Gained powder with it is other
Residual components mix, and are heated to 65 DEG C, stirring reaction 40-50 minutes, cooling, are ground into slurry, produce.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711049179.XA CN107805343A (en) | 2017-10-31 | 2017-10-31 | Auxiliary agent for insect-proof plastic woven bag |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201711049179.XA CN107805343A (en) | 2017-10-31 | 2017-10-31 | Auxiliary agent for insect-proof plastic woven bag |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN107805343A true CN107805343A (en) | 2018-03-16 |
Family
ID=61583091
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201711049179.XA Pending CN107805343A (en) | 2017-10-31 | 2017-10-31 | Auxiliary agent for insect-proof plastic woven bag |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN107805343A (en) |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0159102A1 (en) * | 1984-01-04 | 1985-10-23 | Mobil Oil Corporation | Blends of LLDPE, PP and EPDM or EPR for films of improved stiffness, tear and impact strength |
| CN103613850A (en) * | 2013-11-28 | 2014-03-05 | 安徽安远塑胶股份有限公司 | Filament for vermin-proof plastic woven bag |
-
2017
- 2017-10-31 CN CN201711049179.XA patent/CN107805343A/en active Pending
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP0159102A1 (en) * | 1984-01-04 | 1985-10-23 | Mobil Oil Corporation | Blends of LLDPE, PP and EPDM or EPR for films of improved stiffness, tear and impact strength |
| CN103613850A (en) * | 2013-11-28 | 2014-03-05 | 安徽安远塑胶股份有限公司 | Filament for vermin-proof plastic woven bag |
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| Date | Code | Title | Description |
|---|---|---|---|
| PB01 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| WD01 | Invention patent application deemed withdrawn after publication | ||
| WD01 | Invention patent application deemed withdrawn after publication |
Application publication date: 20180316 |