CN103589266A - Preparation method and application of oily anti-fouling agent - Google Patents
Preparation method and application of oily anti-fouling agent Download PDFInfo
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- CN103589266A CN103589266A CN201310568762.7A CN201310568762A CN103589266A CN 103589266 A CN103589266 A CN 103589266A CN 201310568762 A CN201310568762 A CN 201310568762A CN 103589266 A CN103589266 A CN 103589266A
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Abstract
The invention discloses a preparation method and an application of an oily anti-fouling agent. 50-90 parts of isopropanol by mass is added into a reaction kettle, the temperature is kept at 20-30 DEG C, the isopropanol is stirred at the stirring speed of 100-1200rpm after the temperature is controlled, then 3-10 parts of dodecyltriethoxysilane by mass, 5-30 parts of fluorosilicon copolymer resin by mass, 2-10 parts of reactive polysiloxane by mass, 0.1-0.5 parts of an aluminum-titanium compound coupling agent by mass and 0.1-0.5 parts of a biuret curing agent by mass are sequentially added into the reaction kettle, stirring is continued during adding, the stirring is continued at the speed of 200-2000rpm for 5-20min after adding, and a prepared colorless transparent liquid is the oily anti-fouling agent. According to the oily anti-fouling agent, the raw materials are cheap and easy to obtain, the preparation method is simple, and the prepared anti-fouling agent is simple to use, capable of being sprayed at the normal temperature, lasting in effect, repellent to water contamination and oil contamination and obvious in anti-fouling effect.
Description
Technical field
The invention belongs to stain control agent preparing technical field, particularly a kind of preparation method of oiliness stain control agent and application thereof.This stain control agent is processed for the soiling protective of artificial stone-like material's finished product, comprises that the surface soiling of artificial hilllock stone, quartzite, entity plane materiel class artificial stone-like material table top, metope, bathroom sink etc. is processed.
Background technology
Artificial stone-like material because its performance good, have beautiful in colour, highly polished, color even is consistent, anti-pressure and abrasion-proof, good toughness, compact structure, sturdy and durable, light specific gravity, do not absorb water, resistance to erosion weathering, the advantage such as aberration is little, colour-fast, radioactivity is low.The advantage with comprehensive utilization of resources has immeasurable effect aspect environmental protection and energy saving, is also genuine building materials Green Product.Become the finishing material of modern architecture first-selection.But artificial stone-like material is as decoration plane material, there is at present a persistence for very large its appearance effect of problems affect, that is exactly easily to pollute, especially entity plane materiel class rostone product, for life, be easy to be subject to some life food, daily necessities, dust, sewage etc. to pollute dirty, affect its lasting decorative effect.
The present invention is directed to the characteristics such as artificial stone-like material's resin base, water-intake rate be low, a kind of artificial stone-like material of special preparation uses oiliness stain control agent, select film-forming resin, collocation such as hydrophobic and oil repellent fluorine silicon materials that surface tension is little, prepare a kind of film-forming type stain control agent, be used for being sprayed at artificial stone-like material surface, neither affect decorative effect, can effectively isolate again various stains and infect.
Summary of the invention
The object of this invention is to provide a kind of preparation method and application thereof of oiliness stain control agent.
Preparation method's concrete steps of oiliness stain control agent are:
The Virahol of 50 ~ 90 mass parts is added in reactor, maintain the temperature at 20 ℃ ~ 30 ℃, after temperature is controlled, beginning is stirred with the stir speed (S.S.) of 100 ~ 1200 revs/min, then successively by the dodecyl triethoxyl silane of 3 ~ 10 mass parts, the fluorine-silicon copolymer resin of 5 ~ 30 mass parts, the reactive polysiloxane of 2 ~ 10 mass parts, 0.1 ~ 0.5 mass parts aluminium titanium composite coupler and 0.1 ~ 0.5 mass parts diisocyanate biuret curing agent add in reactor, between charge period, keep whipped state, rotating speed with 200 ~ 2000 revs/min after reinforced continues to be uniformly mixed 5 ~ 20 minutes, make colourless transparent liquid and be oiliness stain control agent.
The prepared oiliness stain control agent of the present invention is applied to the surface soiling conservation treatment of artificial stone-like material's finished product.
Advantage of the present invention is as follows:
(1) the present invention's raw material used is cheaply easy to get, and preparation method is simple.
(2) the oiliness stain control agent using method that the present invention makes is simple, cold spraying, and effect is lasting, and greasy dirt is hated in hydrophobic dirt, and anti-fouling effect is obvious.
(3) the oiliness stain control agent that the present invention makes is special for artificial stone-like material's characteristic specially, more practical than the protective agent of other lithotome on market.
Embodiment
embodiment 1:
The main raw material that the present embodiment is prepared oiliness stain control agent is Virahol (technical grade), dodecyl triethoxyl silane (technical grade), fluorine-silicon copolymer resin (technical grade), reactive polysiloxane (technical grade), diisocyanate biuret curing agent (technical grade) and aluminium titanium composite coupler (technical grade).
The concrete steps of preparation oiliness stain control agent are:
The Virahol of 70 kilograms is added in reactor, keep 25 ℃ of temperature, after temperature is controlled, beginning is stirred with the stir speed (S.S.) of 800 revs/min, then successively the dodecyl triethoxyl silane of 5 kilograms, the fluorine-silicon copolymer resin of 20 kilograms, reactive polysiloxane, 0.4 kg aluminium titanium composite coupler and 0.3 kilogram of diisocyanate biuret curing agent of 4.3 kilograms are added in reactor, between charge period, keep whipped state, the reinforced complete rotating speed with 1200 revs/min continues to be uniformly mixed 10 minutes, makes colourless transparent liquid and is oiliness stain control agent.
The application of the oiliness stain control agent that the present embodiment is prepared:
The oiliness stain control agent of preparation is applied to stone surface, artificial hilllock, after normal temperature spontaneous curing in 24 hours, these stains that can pollute untreated rostone generation such as soy sauce, tomato-sauce, ink, red wine, water-based big end pen, oiliness big end pen are spilt in its surface, after 24 hours, clear water cleans, and noresidue stain, lotus leaf effect produce.By the antifouling rank in GB/T3810.14-1999, from original 2 grades, bring up to more than 5 grades.
embodiment 2:
The main raw material that the present embodiment is prepared oiliness stain control agent is Virahol (technical grade), dodecyl triethoxyl silane (technical grade), fluorine-silicon copolymer resin (technical grade), reactive polysiloxane (technical grade), diisocyanate biuret curing agent (technical grade) and aluminium titanium composite coupler (technical grade).
The concrete steps of preparation oiliness stain control agent are:
The Virahol of 80 kilograms is added in reactor, keep 25 ℃ of temperature, after temperature is controlled, beginning is stirred with the stir speed (S.S.) of 600 revs/min, then successively the dodecyl triethoxyl silane of 5 kilograms, the fluorine-silicon copolymer resin of 10 kilograms, reactive polysiloxane, 0.4 kg aluminium titanium composite coupler and 0.4 kilogram of diisocyanate biuret curing agent of 4.2 kilograms are added in reactor, between charge period, keep whipped state, the reinforced complete rotating speed with 1000 revs/min continues to be uniformly mixed 15 minutes, makes colourless transparent liquid and is oiliness stain control agent.
The application of the oiliness stain control agent that the present embodiment is prepared:
The oiliness stain control agent of preparation is coated with for artificial quartz in lump surface, after normal temperature spontaneous curing in 24 hours, these stains that can pollute untreated rostone generation such as soy sauce, tomato-sauce, ink, red wine, water-based big end pen, oiliness big end pen are spilt in its surface, after 24 hours, clear water cleans, and noresidue stain, lotus leaf effect produce.By the antifouling rank in GB/T3810.14-1999, from original 2 grades, bring up to more than 5 grades.
Claims (2)
1. a preparation method for oiliness stain control agent, is characterized in that concrete steps are:
The Virahol of 50 ~ 90 mass parts is added in reactor, maintain the temperature at 20 ℃ ~ 30 ℃, after temperature is controlled, beginning is stirred with the stir speed (S.S.) of 100 ~ 1200 revs/min, then successively by the dodecyl triethoxyl silane of 3 ~ 10 mass parts, the fluorine-silicon copolymer resin of 5 ~ 30 mass parts, the reactive polysiloxane of 2 ~ 10 mass parts, 0.1 ~ 0.5 mass parts aluminium titanium composite coupler and 0.1 ~ 0.5 mass parts diisocyanate biuret curing agent add in reactor, between charge period, keep whipped state, rotating speed with 200 ~ 2000 revs/min after reinforced continues to be uniformly mixed 5 ~ 20 minutes, make colourless transparent liquid and be oiliness stain control agent.
2. the application of the oiliness stain control agent that prepared by method according to claim 1, is characterized in that this oiliness stain control agent is applied to the surface soiling conservation treatment of artificial stone-like material's finished product.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310568762.7A CN103589266B (en) | 2013-11-15 | 2013-11-15 | A kind of preparation method of oiliness stain control agent and application thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310568762.7A CN103589266B (en) | 2013-11-15 | 2013-11-15 | A kind of preparation method of oiliness stain control agent and application thereof |
Publications (2)
| Publication Number | Publication Date |
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| CN103589266A true CN103589266A (en) | 2014-02-19 |
| CN103589266B CN103589266B (en) | 2015-11-18 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310568762.7A Active CN103589266B (en) | 2013-11-15 | 2013-11-15 | A kind of preparation method of oiliness stain control agent and application thereof |
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Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815245A (en) * | 2017-11-02 | 2018-03-20 | 深圳市华宇节耗电子有限公司 | A kind of application of dodecyl triethoxysilane and the tin face protective agent for PCB manufactures and the guard method of tin face |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1376755A (en) * | 2001-03-27 | 2002-10-30 | 中国科学院化学研究所 | Surface protecting agent for stone of building and its preparing process |
| CN101020750A (en) * | 2007-03-16 | 2007-08-22 | 西北工业大学 | Silicone antifoulant and its prepn |
| CN101875801A (en) * | 2009-04-30 | 2010-11-03 | 北京创意创新经济技术中心 | Product serving as coating or paint |
| CN102174290A (en) * | 2011-02-14 | 2011-09-07 | 成都理工大学 | Method for preparing ceramic tile antifouling agent |
-
2013
- 2013-11-15 CN CN201310568762.7A patent/CN103589266B/en active Active
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1376755A (en) * | 2001-03-27 | 2002-10-30 | 中国科学院化学研究所 | Surface protecting agent for stone of building and its preparing process |
| CN101020750A (en) * | 2007-03-16 | 2007-08-22 | 西北工业大学 | Silicone antifoulant and its prepn |
| CN101875801A (en) * | 2009-04-30 | 2010-11-03 | 北京创意创新经济技术中心 | Product serving as coating or paint |
| CN102174290A (en) * | 2011-02-14 | 2011-09-07 | 成都理工大学 | Method for preparing ceramic tile antifouling agent |
Non-Patent Citations (1)
| Title |
|---|
| 沈一丁等: "氟硅防污剂的合成、复配及其作用机理研究", 《精细化工》 * |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN107815245A (en) * | 2017-11-02 | 2018-03-20 | 深圳市华宇节耗电子有限公司 | A kind of application of dodecyl triethoxysilane and the tin face protective agent for PCB manufactures and the guard method of tin face |
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| Publication number | Publication date |
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| CN103589266B (en) | 2015-11-18 |
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| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20140219 Assignee: Guilin Juge Technology Co.,Ltd. Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2022450000141 Denomination of invention: Preparation and Application of an Oily Antifouling Agent Granted publication date: 20151118 License type: Common License Record date: 20221123 |
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| EE01 | Entry into force of recordation of patent licensing contract | ||
| EE01 | Entry into force of recordation of patent licensing contract |
Application publication date: 20140219 Assignee: Nanning Zhongli Environmental Protection Equipment Processing Factory Assignor: GUILIN University OF TECHNOLOGY Contract record no.: X2022450000530 Denomination of invention: Preparation and Application of an Oily Antifouling Agent Granted publication date: 20151118 License type: Common License Record date: 20221229 |
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| EE01 | Entry into force of recordation of patent licensing contract |