CN103566894A - Arsenic removal modified active carbon and preparation method thereof - Google Patents
Arsenic removal modified active carbon and preparation method thereof Download PDFInfo
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- CN103566894A CN103566894A CN201310442163.0A CN201310442163A CN103566894A CN 103566894 A CN103566894 A CN 103566894A CN 201310442163 A CN201310442163 A CN 201310442163A CN 103566894 A CN103566894 A CN 103566894A
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Abstract
The invention discloses arsenic removal modified active carbon, which is characterized by being prepared from the following raw materials in parts by weight: 5-8 parts of aluminum hydroxide, 120-130 parts of active carbon, 6-9 parts of polyethylene glycol, 3-4 parts of urea, 5-7 parts of calcium oxide, 7-9 parts of magnesium oxide, 10-15 parts of silicon dioxide, 8-10 parts of aluminum oxide, 10-15 parts of ferrous sulfate, 1-2 parts of ascorbic acid, 6-9 parts of sulfamic acid, 4-6 parts of sodium dodecyl benzene sulfonate, 4-5 parts of modified diatomite and a right amount of water. According to the invention, oxidized metals, such as calcium oxide, are used, and can remove sulfur efficiently; meanwhile, sulfamic acid is used for activating the active carbon, thus, more micropores are formed and the specific area is larger; by addition of ferrous sulfate, arsenic in water can be removed effectively, concentration of arsenic in water is reduced, and the arsenic concentration can meet the sanitary standard for drinking water. According to the invention, the technology is simple, the purification effect is remarkable, and the application foreground is substantial.
Description
Technical field
The present invention relates to a kind of modified function Material Field, relate in particular to a kind of arsenic removal modified activated carbon and preparation method thereof.
Background technology
Remove at present pollutant and often use adsorbent, mainly contain silica gel, activated alumina, active carbon, molecular sieve etc., also have in addition for certain compositional selecting absorption and the sorbing material of development.But the most adsorption capacity of these adsorbents is limited, need to study different adsorbents for different requirements, bring into play best effect.Meanwhile, find new raw material, to strengthen adsorption effect, cost-saving.
Summary of the invention
The object of the present invention is to provide a kind of arsenic removal modified activated carbon and preparation method thereof.
Technical scheme of the present invention is as follows:
A modified activated carbon, is characterized in that being made by the raw material of following weight portion: aluminium hydroxide 5-8, active carbon 120-130, polyethylene glycol 6-9, urea 3-4, calcium oxide 5-7, magnesia 7-9, silica 1 0-15, alundum (Al2O3) 8-10, ferrous sulfate 10-15, ascorbic acid 1-2, sulfamic acid 6-9, neopelex 4-6, modification infusorial earth 4-5, water are appropriate;
Described modification infusorial earth is made by the raw material of following weight portion: diatomite 150-160, bamboo charcoal 30-35, nano-sized carbon 1-2, coix seed oil 2-3, ascorbic acid 1-2, citric acid 2-3, nano titanium oxide 1-2, Radix Notoginseng powder 2-3; Preparation method puts into calcining furnace by diatomite to calcine 3-4 hour at 540-560 ℃, takes out, and the hydrochloric acid solution of putting into 12-15% soaks 4-5 hour, filter and take out, use clear water cyclic washing, dry, be added to the water, simultaneously, add nano-sized carbon, ascorbic acid, bamboo charcoal, grind and obtain slurry, spraying is dry, other residual components is mixed with dried powder, and grinding distribution evenly and get final product.
The preparation method of described arsenic removal modified activated carbon, it is characterized in that comprising the following steps: by active carbon, polyethylene glycol, urea silica, sulfamic acid, neopelex adds furnishing mud shape in suitable quantity of water together, be heated to 80-90 ℃, grind 2-3 hour to obtain 200-300 order slurry, it is neutral with clear water, washing to pH value, dries; Mix and be uniformly dispersed and get final product with other surplus stocks.
Beneficial effect of the present invention
The present invention uses the oxidized metal things such as calcium oxide, energy high-efficiency desulfurization; Use sulfamic acid activated carbon, the micropore of formation is more simultaneously, and specific area is larger; By adding ferrous sulfate, can effectively carry out removing arsenic from water, reduce the concentration of arsenic in water body, make it reach sanitary standard for drinking water; Technique of the present invention is simple, and clean-up effect is remarkable, and application prospect is considerable.
The specific embodiment
A modified activated carbon, by following weight portion (kilogram) raw material make: aluminium hydroxide 7, active carbon 126, polyethylene glycol 8, urea 3, calcium oxide 6, magnesia 8, silica 13, alundum (Al2O3) 9, ferrous sulfate 13, ascorbic acid 1, sulfamic acid 7, neopelex 5, modification infusorial earth 4, water are appropriate;
Described modification infusorial earth by following weight portion (kilogram) raw material make: diatomite 156, bamboo charcoal 34, nano-sized carbon 1.5, coix seed oil 2.5, ascorbic acid 1.5, citric acid 2.5, nano titanium oxide 1.5, Radix Notoginseng powder 2.5; Preparation method puts into calcining furnace by diatomite at 550 ℃, to calcine 3.5 hours, takes out, and puts into 14% hydrochloric acid solution and soaks 4.5 hours, filter and take out, use clear water cyclic washing, dry, be added to the water, simultaneously, add nano-sized carbon, ascorbic acid, bamboo charcoal, grind and obtain slurry, spraying is dry, other residual components is mixed with dried powder, and grinding distribution evenly and get final product.
The preparation method of described arsenic removal modified activated carbon, comprise the following steps: by active carbon, polyethylene glycol, urea silica, sulfamic acid, neopelex adds furnishing mud shape in suitable quantity of water together, be heated to 85 ℃, grind 2 hours to obtain 200 order slurries, it is neutral with clear water, washing to pH value, dries; Mix and be uniformly dispersed and get final product with other surplus stocks.
After measured, its iodine number 1589mg/g, methylene blue adsorption value 29.4mL/0.1g.
Claims (2)
1. an arsenic removal modified activated carbon, is characterized in that being made by the raw material of following weight portion: aluminium hydroxide 5-8, active carbon 120-130, polyethylene glycol 6-9, urea 3-4, calcium oxide 5-7, magnesia 7-9, silica 1 0-15, alundum (Al2O3) 8-10, ferrous sulfate 10-15, ascorbic acid 1-2, sulfamic acid 6-9, neopelex 4-6, modification infusorial earth 4-5, water are appropriate;
Described modification infusorial earth is made by the raw material of following weight portion: diatomite 150-160, bamboo charcoal 30-35, nano-sized carbon 1-2, coix seed oil 2-3, ascorbic acid 1-2, citric acid 2-3, nano titanium oxide 1-2, Radix Notoginseng powder 2-3; Preparation method puts into calcining furnace by diatomite to calcine 3-4 hour at 540-560 ℃, takes out, and the hydrochloric acid solution of putting into 12-15% soaks 4-5 hour, filter and take out, use clear water cyclic washing, dry, be added to the water, simultaneously, add nano-sized carbon, ascorbic acid, bamboo charcoal, grind and obtain slurry, spraying is dry, other residual components is mixed with dried powder, and grinding distribution evenly and get final product.
2. the preparation method of arsenic removal modified activated carbon according to claim 1, it is characterized in that comprising the following steps: by active carbon, polyethylene glycol, urea silica, sulfamic acid, neopelex adds furnishing mud shape in suitable quantity of water together, be heated to 80-90 ℃, grind 2-3 hour to obtain 200-300 order slurry, it is neutral with clear water, washing to pH value, dries; Mix and be uniformly dispersed and get final product with other surplus stocks.
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Cited By (10)
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CN104445468A (en) * | 2014-12-07 | 2015-03-25 | 浙江省淡水水产研究所 | Water purifier for cultivating Chinese softshell turtles |
CN105999877A (en) * | 2016-06-30 | 2016-10-12 | 安徽天顺环保设备股份有限公司 | Recycling bag for airtight calcium carbide furnace gas |
CN106186102A (en) * | 2016-08-11 | 2016-12-07 | 李宝全 | A kind of water purification agent based on mineral |
CN106745613A (en) * | 2017-01-03 | 2017-05-31 | 浙江新化化工股份有限公司 | A kind of processing method of organic phosphine precipitating reagent and the waste water of organic phosphine containing high concentration |
CN110016345A (en) * | 2019-04-24 | 2019-07-16 | 广西博世科环保科技股份有限公司 | A kind of steady arsenic soil passivator of drop cadmium and its application method |
CN111330466A (en) * | 2020-04-12 | 2020-06-26 | 廖响中 | Multifunctional mixing device for producing arsenic and antimony repairing agent in water and manufacturing method |
CN113509904A (en) * | 2021-04-15 | 2021-10-19 | 湖南省林业科学院 | Sulfamic acid modified camellia oleifera shell biochar material, and preparation method and application thereof |
CN114307945A (en) * | 2021-12-31 | 2022-04-12 | 中南民族大学 | Preparation method of modified mesoporous material and application of modified mesoporous material in removal of arsenic pollutants in underground water body |
CN116495753A (en) * | 2023-04-26 | 2023-07-28 | 中国科学院生态环境研究中心 | Method for recycling industrial waste salt through recrystallization and purification |
CN116924398A (en) * | 2023-07-31 | 2023-10-24 | 昆明理工大学 | Method for preparing activated carbon from municipal solid waste and product thereof |
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CN102910767A (en) * | 2012-10-17 | 2013-02-06 | 广东工业大学 | Method for removing arsenic by loading titanium dioxide with activated carbon fiber hydrothermal method by means of photoelectrocatalysis oxidation |
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CN101920191A (en) * | 2010-06-12 | 2010-12-22 | 华中农业大学 | Application of activated carbon modified material and application in removing arsenic from water |
CN102580675A (en) * | 2012-02-21 | 2012-07-18 | 太原理工大学 | Modified activated carbon, preparation method thereof and method for adsorbing hydrogen sulfide using modified activated carbon |
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Cited By (11)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104445468A (en) * | 2014-12-07 | 2015-03-25 | 浙江省淡水水产研究所 | Water purifier for cultivating Chinese softshell turtles |
CN105999877A (en) * | 2016-06-30 | 2016-10-12 | 安徽天顺环保设备股份有限公司 | Recycling bag for airtight calcium carbide furnace gas |
CN106186102A (en) * | 2016-08-11 | 2016-12-07 | 李宝全 | A kind of water purification agent based on mineral |
CN106745613A (en) * | 2017-01-03 | 2017-05-31 | 浙江新化化工股份有限公司 | A kind of processing method of organic phosphine precipitating reagent and the waste water of organic phosphine containing high concentration |
CN110016345A (en) * | 2019-04-24 | 2019-07-16 | 广西博世科环保科技股份有限公司 | A kind of steady arsenic soil passivator of drop cadmium and its application method |
CN110016345B (en) * | 2019-04-24 | 2020-10-27 | 广西博世科环保科技股份有限公司 | Cadmium-reducing arsenic-stabilizing soil passivator and use method thereof |
CN111330466A (en) * | 2020-04-12 | 2020-06-26 | 廖响中 | Multifunctional mixing device for producing arsenic and antimony repairing agent in water and manufacturing method |
CN113509904A (en) * | 2021-04-15 | 2021-10-19 | 湖南省林业科学院 | Sulfamic acid modified camellia oleifera shell biochar material, and preparation method and application thereof |
CN114307945A (en) * | 2021-12-31 | 2022-04-12 | 中南民族大学 | Preparation method of modified mesoporous material and application of modified mesoporous material in removal of arsenic pollutants in underground water body |
CN116495753A (en) * | 2023-04-26 | 2023-07-28 | 中国科学院生态环境研究中心 | Method for recycling industrial waste salt through recrystallization and purification |
CN116924398A (en) * | 2023-07-31 | 2023-10-24 | 昆明理工大学 | Method for preparing activated carbon from municipal solid waste and product thereof |
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Application publication date: 20140212 |