CN103566889A - Lignin modified activated carbon adsorbent, and preparation method thereof - Google Patents
Lignin modified activated carbon adsorbent, and preparation method thereof Download PDFInfo
- Publication number
- CN103566889A CN103566889A CN201310442065.7A CN201310442065A CN103566889A CN 103566889 A CN103566889 A CN 103566889A CN 201310442065 A CN201310442065 A CN 201310442065A CN 103566889 A CN103566889 A CN 103566889A
- Authority
- CN
- China
- Prior art keywords
- parts
- activated carbon
- lignin
- powder
- diatomite
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Pending
Links
Abstract
The invention discloses a lignin modified activated carbon adsorbent which is prepared from the following raw materials in parts by weight: 20-25 parts of rice husk, 20-25 parts of bamboo charcoal, 6-9 parts of potassium chloride, 2-3 parts of cerium oxide, 0.5-1 part of ammonium persulfate, 6-9 parts of powdered pumice, 8-10 parts of diatomite powder, 100-120 parts of activated carbon powder, 10-13 parts of attapulgite, 3-5 parts of magnesium nitride, 10-14 parts of lignin, 4-5 parts of modified diatomite and a suitable amount of water. By virtue of high-temperature carbonization of the rice husk, a thin pore structure can be easily formed, and activated carbon with more-developed pores and better adsorptive property can be prepared; by use of powdered pumice, the pores of the activated carbon can be increased; by use of the diatomite powder and attapulgite, antibacterial property, deodorization, moisture absorption, mould prevention as well as catalytic decomposition of organics can be realized; by use of the lignin, the cohesive force is improved, so the lignin modified activated carbon adsorbent is less in possibility of being disintegrated, and is safe and environment-friendly. The lignin modified activated carbon adsorbent disclosed by the invention is suitable for dust desorption.
Description
Technical field
The present invention relates to a kind of modified function Material Field, relate in particular to a kind of lignin modification acticarbon and preparation method thereof.
Background technology
Remove at present toxin and often use adsorbent, mainly contain silica gel, activated alumina, active carbon, molecular sieve etc., also have in addition for certain compositional selecting absorption and the sorbing material of development.But the most adsorption capacity of these adsorbents is limited, need to study different adsorbents for different requirements, bring into play best effect.Meanwhile, find new raw material, to strengthen adsorption effect, cost-saving.
Summary of the invention
The object of the present invention is to provide a kind of lignin modification acticarbon and preparation method thereof.
Technical scheme of the present invention is as follows:
An acticarbon, is characterized in that being made by the raw material of following weight portion: rice husk 20-25, bamboo charcoal 20-25, potassium chloride 6-9, cerium oxide 2-3, ammonium persulfate 0.5-1, ground pumice 6-9, diatomite in powder 8-10, activated carbon powder 100-120, attapulgite 10-13, magnesium nitride 3-5, lignin 10-14, modification infusorial earth 4-5, water are appropriate;
Described modification infusorial earth is made by the raw material of following weight portion: diatomite 150-160, bamboo charcoal 30-35, nano-sized carbon 1-2, coix seed oil 2-3, ascorbic acid 1-2, citric acid 2-3, nano titanium oxide 1-2, Radix Notoginseng powder 2-3; Preparation method puts into calcining furnace by diatomite to calcine 3-4 hour at 540-560 ℃, takes out, and the hydrochloric acid solution of putting into 12-15% soaks 4-5 hour, filter and take out, use clear water cyclic washing, dry, be added to the water, simultaneously, add nano-sized carbon, ascorbic acid, bamboo charcoal, grind and obtain slurry, spraying is dry, other residual components is mixed with dried powder, and grinding distribution evenly and get final product.
The preparation method of described lignin modification acticarbon, it is characterized in that comprising the following steps: attapulgite is pulverized, send in retort together with rice husk, ground pumice, diatomite in powder, at 600-700 ℃, 2-3 hour is processed in charing, take out, add furnishing mud shape in suitable quantity of water together with bamboo charcoal, potassium chloride, cerium oxide, ammonium persulfate, activated carbon powder, magnesium nitride, lignin, be heated to 75-85 ℃, grind 2-3 hour to obtain 200-300 order slurry, it is neutral with clear water, washing to pH value, dries; Mix and be uniformly dispersed and get final product with other surplus stocks.
Beneficial effect of the present invention
The present invention uses rice husk easily to form thin pore structure through high temperature carbonization, can produce that hole is more flourishing, the better active carbon of absorption property; By using ground pumice, more increased the hole of active carbon; By use diatomite in powder, attapulgite can antibacterial and deodouring, moisture absorption, mildew-resistant, can also catalytic decomposition organic matter; By using lignin, increased cohesive force, easy disintegrating not, safety and environmental protection; The present invention is applicable to dust and removes.
The specific embodiment
An acticarbon, by following weight portion (kilogram) raw material make: rice husk 23, bamboo charcoal 23, potassium chloride 8, cerium oxide 2, ammonium persulfate 0.8, ground pumice 8, diatomite in powder 9, activated carbon powder 110, attapulgite 12, magnesium nitride 4, lignin 13, modification infusorial earth 4, water are appropriate;
Described modification infusorial earth by following weight portion (kilogram) raw material make: diatomite 156, bamboo charcoal 34, nano-sized carbon 1.5, coix seed oil 2.5, ascorbic acid 1.5, citric acid 2.5, nano titanium oxide 1.5, Radix Notoginseng powder 2.5; Preparation method puts into calcining furnace by diatomite at 550 ℃, to calcine 3.5 hours, takes out, and puts into 14% hydrochloric acid solution and soaks 4.5 hours, filter and take out, use clear water cyclic washing, dry, be added to the water, simultaneously, add nano-sized carbon, ascorbic acid, bamboo charcoal, grind and obtain slurry, spraying is dry, other residual components is mixed with dried powder, and grinding distribution evenly and get final product.
The preparation method of described lignin modification acticarbon, comprise the following steps: attapulgite is pulverized, send in retort together with rice husk, ground pumice, diatomite in powder, at 660 ℃, charing is processed 3 hours, takes out, and adds furnishing mud shape in suitable quantity of water together with bamboo charcoal, potassium chloride, cerium oxide, ammonium persulfate, activated carbon powder, magnesium nitride, lignin, be heated to 80 ℃, grind 3 hours to obtain 300 order slurries, it is neutral with clear water, washing to pH value, dries; Mix and be uniformly dispersed and get final product with other surplus stocks.
After measured, its iodine number 1578mg/g, methylene blue adsorption value 27.5mL/0.1g.
Claims (2)
1. a lignin modification acticarbon, is characterized in that being made by the raw material of following weight portion: rice husk 20-25, bamboo charcoal 20-25, potassium chloride 6-9, cerium oxide 2-3, ammonium persulfate 0.5-1, ground pumice 6-9, diatomite in powder 8-10, activated carbon powder 100-120, attapulgite 10-13, magnesium nitride 3-5, lignin 10-14, modification infusorial earth 4-5, water are appropriate;
Described modification infusorial earth is made by the raw material of following weight portion: diatomite 150-160, bamboo charcoal 30-35, nano-sized carbon 1-2, coix seed oil 2-3, ascorbic acid 1-2, citric acid 2-3, nano titanium oxide 1-2, Radix Notoginseng powder 2-3; Preparation method puts into calcining furnace by diatomite to calcine 3-4 hour at 540-560 ℃, takes out, and the hydrochloric acid solution of putting into 12-15% soaks 4-5 hour, filter and take out, use clear water cyclic washing, dry, be added to the water, simultaneously, add nano-sized carbon, ascorbic acid, bamboo charcoal, grind and obtain slurry, spraying is dry, other residual components is mixed with dried powder, and grinding distribution evenly and get final product.
2. the preparation method of lignin modification acticarbon according to claim 1, it is characterized in that comprising the following steps: attapulgite is pulverized, send in retort together with rice husk, ground pumice, diatomite in powder, at 600-700 ℃, 2-3 hour is processed in charing, take out, add furnishing mud shape in suitable quantity of water together with bamboo charcoal, potassium chloride, cerium oxide, ammonium persulfate, activated carbon powder, magnesium nitride, lignin, be heated to 75-85 ℃, grind 2-3 hour to obtain 200-300 order slurry, it is neutral with clear water, washing to pH value, dries; Mix and be uniformly dispersed and get final product with other surplus stocks.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310442065.7A CN103566889A (en) | 2013-09-26 | 2013-09-26 | Lignin modified activated carbon adsorbent, and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310442065.7A CN103566889A (en) | 2013-09-26 | 2013-09-26 | Lignin modified activated carbon adsorbent, and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103566889A true CN103566889A (en) | 2014-02-12 |
Family
ID=50040117
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310442065.7A Pending CN103566889A (en) | 2013-09-26 | 2013-09-26 | Lignin modified activated carbon adsorbent, and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103566889A (en) |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104030612A (en) * | 2014-06-16 | 2014-09-10 | 闽江学院 | High-bonding-strength and antibacterial diatom mud building decoration material and preparation method thereof |
| CN104907040A (en) * | 2015-05-21 | 2015-09-16 | 安徽凤凰滤清器股份有限公司 | Rare-earth element added volcanic rock adsorbent |
| CN104945174A (en) * | 2015-07-27 | 2015-09-30 | 蒋文兰 | Method for producing pumice carbonized nutrient soil |
| CN107321323A (en) * | 2017-09-04 | 2017-11-07 | 四川建筑职业技术学院 | A kind of sorbing material and preparation method thereof |
| CN108993404A (en) * | 2018-09-17 | 2018-12-14 | 明光市飞洲新材料有限公司 | A kind of adsorbent for building and preparation method thereof with antibiosis and deodorization effects |
Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007237097A (en) * | 2006-03-09 | 2007-09-20 | Osaka Prefecture | Magnetic adsorbent and waste water treating technique using it |
| CN101053821A (en) * | 2007-02-02 | 2007-10-17 | 华南理工大学 | Organic component supported charcoal chelating adsorbent and its preparation method and application |
| CN102527337A (en) * | 2012-03-08 | 2012-07-04 | 天津市嘉腾环保设备有限公司 | Compound adsorbent grain and production method thereof |
| CN102872802A (en) * | 2012-10-10 | 2013-01-16 | 上海理工大学 | Modified activated carbon material and preparing method thereof |
| CN103272566A (en) * | 2013-05-06 | 2013-09-04 | 重庆三峡学院 | Method for preparing ammonia nitrogen adsorbent by using banana peel and application of ammonia nitrogen adsorbent |
-
2013
- 2013-09-26 CN CN201310442065.7A patent/CN103566889A/en active Pending
Patent Citations (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2007237097A (en) * | 2006-03-09 | 2007-09-20 | Osaka Prefecture | Magnetic adsorbent and waste water treating technique using it |
| CN101053821A (en) * | 2007-02-02 | 2007-10-17 | 华南理工大学 | Organic component supported charcoal chelating adsorbent and its preparation method and application |
| CN102527337A (en) * | 2012-03-08 | 2012-07-04 | 天津市嘉腾环保设备有限公司 | Compound adsorbent grain and production method thereof |
| CN102872802A (en) * | 2012-10-10 | 2013-01-16 | 上海理工大学 | Modified activated carbon material and preparing method thereof |
| CN103272566A (en) * | 2013-05-06 | 2013-09-04 | 重庆三峡学院 | Method for preparing ammonia nitrogen adsorbent by using banana peel and application of ammonia nitrogen adsorbent |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104030612A (en) * | 2014-06-16 | 2014-09-10 | 闽江学院 | High-bonding-strength and antibacterial diatom mud building decoration material and preparation method thereof |
| CN104030612B (en) * | 2014-06-16 | 2016-04-27 | 闽江学院 | The diatom ooze building and ornament materials of high bond strength and biocidal property |
| CN104907040A (en) * | 2015-05-21 | 2015-09-16 | 安徽凤凰滤清器股份有限公司 | Rare-earth element added volcanic rock adsorbent |
| CN104945174A (en) * | 2015-07-27 | 2015-09-30 | 蒋文兰 | Method for producing pumice carbonized nutrient soil |
| CN107321323A (en) * | 2017-09-04 | 2017-11-07 | 四川建筑职业技术学院 | A kind of sorbing material and preparation method thereof |
| CN108993404A (en) * | 2018-09-17 | 2018-12-14 | 明光市飞洲新材料有限公司 | A kind of adsorbent for building and preparation method thereof with antibiosis and deodorization effects |
Similar Documents
| Publication | Publication Date | Title |
|---|---|---|
| CN103566872A (en) | Dogwood kernel modified active carbon water purifier and preparation method thereof | |
| CN103551123A (en) | Composite spherical active carbon adsorbent and preparation method thereof | |
| CN103566874A (en) | Silkworm excrement modified porous active carbon and preparation method thereof | |
| CN103566889A (en) | Lignin modified activated carbon adsorbent, and preparation method thereof | |
| CN103566882B (en) | A kind of high adsorption modified activated carbon and preparation method thereof | |
| CN103566880B (en) | A kind of rice husk modified activated carbon adsorption desulfurizing agent and preparation method thereof | |
| Momčilović et al. | Removal of lead (II) ions from aqueous solutions by adsorption onto pine cone activated carbon | |
| CN103551108A (en) | Long-handle flat peach pit shell modified active carbon catalysis adsorbent and preparation method thereof | |
| CN103566901A (en) | Pine nut shell gas-phase adsorption active carbon and preparation method thereof | |
| CN103570015A (en) | Fingered citron slag activated carbon and preparation method thereof | |
| CN103553037A (en) | Jute stalk modified active carbon and preparation method thereof | |
| CN103566903B (en) | A kind of Concave-convex clay rod modified activated carbon and preparation method thereof | |
| CN103551111A (en) | Active carbon for absorbing vehicle exhaust | |
| CN103566898A (en) | Modified straw wood charcoal adsorbent and preparation method thereof | |
| CN103566873A (en) | Modified activated carbon with medicine aroma and preparation method thereof | |
| CN103566893A (en) | Oyster shell modified activated carbon desulfurizing agent, and preparation method thereof | |
| CN103551116A (en) | Not-easy disintegrated and modified active carbon and preparation method thereof | |
| CN102757048A (en) | Method for preparing activated carbon from peonies | |
| CN103787330A (en) | Method for preparing activated carbon from apricot shells, pinecones and rice hulls | |
| CN103566902A (en) | Modified activated carbon desulfurizing/dephosphorizing agent and preparation method thereof | |
| CN103803544B (en) | Method for preparing active carbon from walnut shells, phoenix tree leaves and wheat straw | |
| CN103551110A (en) | Active carbon for absorbing gasoline steam and preparation method thereof | |
| CN103553038A (en) | Longan pit modified active carbon and preparation method thereof | |
| CN101003370A (en) | Method for preparing active carbon in use for decoloring sugar | |
| CN103566922A (en) | Rare-earth modified active carbon catalytic material and preparation method thereof |
Legal Events
| Date | Code | Title | Description |
|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| SE01 | Entry into force of request for substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140212 |
|
| RJ01 | Rejection of invention patent application after publication |