CN103562129B - The production method of double (fluorosulfonyl) imide lis or double (fluorosulfonyl) acid imide sodium - Google Patents

The production method of double (fluorosulfonyl) imide lis or double (fluorosulfonyl) acid imide sodium Download PDF

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CN103562129B
CN103562129B CN201280025447.3A CN201280025447A CN103562129B CN 103562129 B CN103562129 B CN 103562129B CN 201280025447 A CN201280025447 A CN 201280025447A CN 103562129 B CN103562129 B CN 103562129B
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CN103562129A (en
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G.施密特
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Arkema France SA
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    • H01—ELECTRIC ELEMENTS
    • H01M—PROCESSES OR MEANS, e.g. BATTERIES, FOR THE DIRECT CONVERSION OF CHEMICAL ENERGY INTO ELECTRICAL ENERGY
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Abstract

The present invention relates to formula (III) (SO3 ‑)N‑‑(SO3 ‑),3C+Double (sulfonic acid) imide salts production method, wherein C+Univalent cation is represented, methods described includes formula (I) (OH) SO2‑NH2Amidosulphuric acid and formula (II) (OH) SO2The reaction of X halogenosulfonic acid and including the reaction with substratess, wherein X represents halogen atom, and the substratess are with the cation C+The salt of formation.The invention further relates to formula (V) F (SO2)‑NH‑(SO2) F double (fluorosulfonyl) acid imides acid production method and formula (VII) F (SO2)‑N‑‑(SO2)‑F,Li+Double (fluorosulfonyl) acid imide lithium salts production method.

Description

The production of double (fluorosulfonyl) imide lis or double (fluorosulfonyl) acid imide sodium Method
Technical field
The present invention relates to the preparation side of double (fluorosulfonyl) acid imide lithium salts or double (fluorosulfonyl) acid imide sodium salts Method, moreover, the invention further relates to for preparing double (fluorosulfonyl) imide lis or double (fluorosulfonyl) acid imide sodium The preparation method of intermediate product, and thus obtained double (fluorosulfonyl) imide lis or double (fluorosulfonyl) acid imides Purposes of the sodium in manufacture electrolyte and lithium ion or sodium-ion type battery.
Background technology
Lithium ion or sodium-ion battery comprise at least negative pole, positive pole, dividing plate and electrolyte.Electrolyte is by dissolving in a solvent Lithium or sodium salt composition, the solvent is usually the mixture of organic carbonate, with good between viscosity and dielectric constant It is good compromise.
Most widely used salt includes lithium hexafluoro phosphate (LiPF6), it has many required qualities but shown with hydrogen The shortcoming that the form of fluoric acid gas is decomposed.There is safety issue in this, will especially be used in Private Traffic instrument lithium from In the case of sub- battery.
It therefore, it has been developed to other salt, such as LiTFSI (double (trifluoromethane sulfonyl group) imide lis) and LiFSI (double (fluorosulfonyl) imide lis).These salt show the Auto-decomposition of very little or do not show Auto-decomposition, moreover, right Compare LiPF in hydrolysis6It is stable.However, LiTFSI shows have corrosive shortcoming to aluminium collector, the feelings are not present in LiFSI Condition.Therefore, LiFSI appears to be LiPF6Promising substitute.
There are some known synthetic routes for being used to manufacture double (fluorosulfonyl) imide lis.One of these routes are by complete The reaction composition of fluosulfonic acid and urea：In this respect referring to document WO2010/113483.Then, the product from the reaction is dissolved in In water, also, it is settled out in the form of the salt with tetrabutylammonium double (fluorosulfonyl) acid imides.But, due to the synthesis road The gross production rate of line is very low, and its large-scale production is infeasible.
Another route is the reaction of difluoro sulfoxide and ammonia：In this respect referring to document WO2010/113835.But, the party Method also forms many accessory substances, and it needs expensive purification phase.
In addition, document WO2009/123328 outlines the manufacture of sulfonyl imide compound.The document is particularly described Reaction between amidosulphuric acid and thionyl chloride and then the reaction with chlorination sulfonic acid, it is sub- to form double (chlorosulfonyl) acyls Amine, then, is subjected to the fluorination stage.But, double (chlorosulfonyl) acid imides are unstable compounds, and it can not bear Purifying.Due to the reason, until the fluorination stage terminates, existing impurity is still retained, and so that separation is increasingly difficult.
Allow to simpler mode accordingly, there exist exploitation and/or obtain LiFSI's or NaFSI with more preferable yield Method actual demand.
The content of the invention
Present invention firstly relates to formula (III) (SO3 -)-N--(SO3 -)3C+Double (sulfonic acid (sulphonato)) imide salts Preparation method, wherein C+Univalent cation is represented, methods described includes formula (I) (OH)-SO2-NH2Amidosulphuric acid and formula (II)(OH)-SO2The reaction of-X halogenosulfonic acid and including the reaction with substratess (basic species, base), it is former that wherein X represents halogen Son, the substratess are with the cation C+The salt of formation.C wherein+For proton H+In the case of, the substratess are water.
According to an embodiment, X represents chlorine atom.
According to an embodiment, C+Represent proton H+, potassium ion K+, sodium ion Na+, lithium ion Li+Or cesium ion Cs+, It is preferred that proton H+、Na+Ion and potassium ion K+。
According to an embodiment, methods described include the amidosulphuric acid of formula (I) and the halogenosulfonic acid of formula (II) comprising Cation C+Non-nucleophilic substratess in the presence of reaction, the non-nucleophilic substratess are preferably potassium carbonate K2CO3Or sodium carbonate Na2CO3。
According to alternate embodiments, methods described includes the amidosulphuric acid of formula (I) and the halogenosulfonic acid of formula (II) first Reaction in the presence of substratess, to provide formula (IV) (OH)-SO2-NH-SO2- (OH) double (sulfonyl) acid imides, then, formula (IV) double (sulfonyl) acid imides and the second substratess react to obtain double (sulfonic acid) imide salts of formula (III), described second Substratess are with the cation C+The salt of formation.
According to an embodiment, first substratess are triethylamine and second substratess are selected from potassium hydroxide, hydrogen-oxygen Change sodium and potassium carbonate.
According to another alternate embodiments, methods described includes the amidosulphuric acid of formula (I) and existed with the halogenosulfonic acid of formula (II) Reaction in the presence of chlorinating agent such as thionyl chloride, to provide double (sulfonyl) acid imides of formula (IV) after hydrolyzing.
According to an embodiment, methods described includes the purification phase of double (sulfonic acid) imide salts of formula (III), preferably By from water or from the recrystallization in polar solvent such as alcohol.
Another theme of the present invention is formula (V) F- (SO2)-NH-(SO2)-F double (fluorosulfonyl) acid imides acid system Preparation Method, including double (sulfonic acid) imide salts of formula (III) are prepared as previously described, then carry out described double (sulfonic acid) imide salts Fluorination.
According to an embodiment, the fluorination of described double (sulfonic acid) imide salts include double (sulfonic acid) imide salts with It is preferably selected from the reaction of the fluorization agent of hydrogen fluoride, diethylin sulfur trifluoride and sulfur tetrafluoride.
According to alternate embodiments, the fluorination of described double (sulfonic acid) imide salts includes：(a) by means of being preferably selected from sulfurous Acyl dichloro, phosphorus pentachloride, the chlorinating agent of phosphoryl chloride phosphorus oxychloride and oxalyl chloride make described double (sulfonic acid) imide salts occur chlorination, to obtain formula (VI)Cl-(SO2)-N-(SO2)-Cl C+Double (chlorosulfonyl) imide salts, then, (b) makes formula by means of fluorization agent (VI) double (chlorosulfonyl) imide salts are fluorinated, described to obtain double (fluorosulfonyl) acid imide acid of formula (V) Fluorization agent is preferably selected from hydrogen fluoride, diethylin sulfur trifluoride, sulfur tetrafluoride and fluoride salt especially zinc fluoride.
Another theme of the present invention is formula (VII) F- (SO2)-N--(SO2)-F M+Double (fluorosulfonyl) imide lis The preparation method of salt or double (fluorosulfonyl) acid imide sodium salts, wherein M represents Li or Na, and methods described includes making as previously described Double (fluorosulfonyl) acid imide acid of standby formula (V), then, make this pair (fluorosulfonyl) acid imide acid and lithium-base material or sodium base Thing reacts.
The very special theme of the present invention is the preparation method of double (fluorosulfonyl) acid imide lithium salts of formula (VII).
According to an embodiment, lithium-base material or the sodium substratess are selected from lithium hydroxide, sodium hydroxide, lithium carbonate or carbonic acid Sodium.
Another theme of the present invention is the manufacture method of electrolyte, including prepares double (fluoro sulphurs of formula (VII) as previously described Acyl group) imide salts and described double (fluorosulfonyl) imide salts is dissolved in solvent.
Another theme of the present invention is the manufacture method of battery or battery unit (battery cell), including as previously described The electrolyte is simultaneously inserted between negative pole and positive pole by manufacture electrolyte.
Another theme of the present invention is formula (III) (SO3 -)-N--(SO3 -)3C+Double (sulfonic acid) imide salts, wherein C+Generation Table univalent cation.
According to an embodiment, C+Represent H+Ion or Na+Ion or Li+Ion or Cs+Ion or K+Ion, and preferably H+Ion or Na+Ion or K+Ion.
The other theme of the present invention is double (chlorosulfonyl) imide compounds (salt or acid) of formula (VI).The chemical combination Thing can be separated before fluorination stage (b).
The present invention can overcome the shortcoming of prior art.More particularly, the invention provides allow to simpler side The method that formula and/or more preferable yield obtain LiFSI or NaFSI.
This is completed by the preparation method of double (sulfonic acid) acid imides of exploitation and three salt of cation, and methods described is included in The reaction of amidosulphuric acid and halogenosulfonic acid under conditions of at least one substratess for the salt comprising aforesaid cations of addition.
The salt of this pair (sulfonic acid) acid imide three can be used subsequently to prepare double (fluorosulfonyl) acid imides, and this and then obtain LiFSI or NaFSI, it than the more preferable yield of synthetic route provided in prior art to realize.
Compared to document WO2009/123328, the inventive method includes point of double (chlorosulfonyl) imide salts (VI) From so that the chlorosulfonic acid derivative of the impurity such as residual formed during can removing in the first stage.
Another theme of the present invention is double (fluorosulfonyl) imide lis of high-purity or double (fluoro sulphonyl of high-purity Base) acid imide sodium.
Embodiment
Now, in the following description in more detail and without the tacit declaration limitation ground description present invention：
The present invention is provided according to following overall plan with double (fluorosulfonyl) the acid imide lithium salts of three parts preparation：
1)(OH)-SO2-NH2+(OH)-SO2-X→(SO3 -)-N-(SO3 -)3C+
2)(SO3 -)-N--(SO3 -)3C+→F-(SO2)-NH-(SO2)-F
3)F-(SO2)-NH-(SO2)-F→F-(SO2)-N--(SO2)-F M+
The preparation of the salt of Part I-bis- (sulfonic acid) acid imide three
For the Part I, it is contemplated that two kinds of alternants.First alternant corresponds to following reaction scheme：
(OH)-SO2-NH2+(OH)-SO2-X+zCxBy→(SO3 -)-N--(SO3 -)3C++z’By’Hx’+CX
In aforementioned schemes, (OH)-SO2-NH2For amidosulphuric acid, its formula is labeled as (I)；(OH)-SO2- X is halogenosulfonic acid (X represents halogen atom), its formula is labeled as (II)；And CxByFor non-nucleophilic substratess (i.e., it is impossible to by permanent addition (add) extremely (OH)-SO2- X and disturbing reaction organic substratess), C+The univalent cation derived from the substratess is represented, moreover, x, y, z, x ', y ' And z ' is integer or fraction so that product zx and product z ' x ' is equal to 4.
Formula (the SO of three salt3 -)-N--(SO3 -)3C+Labeled as (III).
Preferably, X represents chlorine.
C+Represent such as potassium ion K+。CxByRepresent such as potassium carbonate K2CO3.In this case, C represents potassium K, B representative CO3, x is with value 2, and y has value 1, and z has value 1 with value 2, y ' with value 2, x ' and z ' is with value 2.
Or, C+Such as sodium ion Na can be represented+, cesium ion Cs+, lithium ion Li+Or H+Ion.
More than reaction can be for example at 0-150 DEG C (preferably 0-50 DEG C, particularly preferred 10-40 DEG C and especially 15-30 DEG C) Temperature and air be depressed under the up to pressure of 15 bars implement.Sulfamic acid is preferably limitation reactant and halogenosulfonic acid (OH)-SO2- X can be excessively used (1-3 equivalents).
Second alternant corresponds to following reaction scheme：
(OH)-SO2-NH2+(OH)-SO2-X+B’→(OH)-SO2-NH-SO2-(OH)+B’H+X-
(OH)-SO2-NH-SO2-(OH)+zCxBy→(SO3 -)-N--(SO3 -)3C++z’By’Hx’
In this scenario, (OH)-SO2-NH-SO2- (OH) is double (sulfonyl) acid imides, and its formula is labeled as (IV)；X still generations Table halogen atom；B ' is nucleophilic or non-nucleophilic substratess；CxByFor nucleophilic or non-nucleophilic substratess, C+Represent the unit price derived from the substratess Cation, moreover, x, y, z, x ', y ' and z ' are integer or fraction so that product zx and product z ' x ' is equal to 3.Reacted more than In scheme, the two stages are double (sulfonyl) acid imides of successive stage and non-separate type (IV).
C wherein+For proton H+In the case of, the second alternant only includes the first stage.
Preferably, X represents chlorine.
C+Represent such as potassium ion K+。
CxByRepresent such as potassium hydroxide (KOH), sodium hydroxide (NaOH) or potassium carbonate (K2CO3)。
B ' represents such as triethylamine (NEt3)。
Above reaction scheme can be for example in 0-150 DEG C of (preferably 0-50 DEG C, particularly preferred 10-40 DEG C and especially 15- 30 DEG C) temperature and air be depressed under the up to pressure of 15 bars implement.Sulfamic acid is preferably limitation reactant and halo sulphur Acid (OH)-SO2- X can be excessively used (1-3 equivalents).Substratess B ' also serves as reaction dissolvent and substratess CxByIt is excessively added until obtaining 8-14 alkaline pH.
Should be at the end of Part I, the compound (three salt or acid) of preferred pair formula (III) is purified.Because institute State three salt (III) or acid is relatively insoluble in water, however, the impurity formed during reaction is very easy to dissolving in the basic conditions Yu Shuizhong.Also the purifying can be carried out by other polar solvents such as alcohol.
The preparation of Part II-bis- (fluorosulfonyl) acid imide acid
For the Part II, it is contemplated that two kinds of alternants.Fluorination of first alternant including chlorination and then, and Second alternant includes directly being fluorinated.
First alternant corresponds to following reaction scheme：
(SO3 -)-N--(SO3 -)3C++xA1→Cl-(SO2)-N--(SO2)-Cl C++A2
Cl-(SO2)-N--(SO2)-Cl C++3HF→F-(SO2)-NH-(SO2)-F+2HCl+CF
In this scenario, F- (SO2)-NH-(SO2)-F is double (fluorosulfonyl) acid imides acid, its formula is labeled as (V)；A1 Represent chlorinating agent；A2Typically represent one or more products from chlorination reaction；C+Still represent aforementioned monovalent cation；X is whole Number or fraction；And Cl- (SO2)-N--(SO2)-Cl C+For double (chlorosulfonyl) imide salts, its formula is labeled as (VI).
A1May be, for example, thionyl chloride SOCl2(x=1), in this case, if C+For potassium ion, then A2Represent 2KCl+ 2SO2。
A1Can also be phosphorus pentachloride (PCl5), phosphoryl chloride phosphorus oxychloride (POCl3) or oxalyl chloride.
Chlorination reaction can be implemented for example in the case where 0-150 DEG C of temperature and air are depressed into the up to pressure of 15 bars.Chlorinating agent It is preferred that being excessively used and usually as solvent.Reaction temperature is advantageously near solvent boiling point.For example, in the feelings of thionyl chloride Under condition, boiling point is near 76 DEG C and therefore reaction temperature is such as 60-90 DEG C or 70-80 DEG C.
As for fluorination reaction in itself, the latter can for example 0-350 DEG C (preferably 0-50 DEG C, particularly preferred 10-40 DEG C and Especially 15-30 DEG C) temperature and air be depressed under the pressure of 15 bars implement.
It is also possible to use other fluorization agents and replace HF, other fluorization agents be, for example, diethylin sulfur trifluoride (DAST) or Sulfur tetrafluoride (SF4) or formula CxFyFluoride salt, wherein x and y is positive integer and C is cation.For example, CxFyIt can be fluorine Change zinc ZnF2, as described in document WO2009/123328.
Second alternant corresponds to for example following reaction scheme：
(SO3 -)-N--(SO3 -)3C++5HF→F-(SO2)-NH-(SO2)-F+2H2O+3CF
In this scenario, C+Still represent aforementioned monovalent cation, such as K+。
The reaction can be for example at 0-350 DEG C (preferably 0-50 DEG C, particularly preferred 10-40 DEG C and especially 15-30 DEG C) Temperature and air be depressed under the up to pressure of 15 bars implement.Hydrogen fluoride is generally excessively used.The reaction is solvent-free In the case of implement.
Other fluorization agents can be used to replace hydrogen fluoride, other fluorization agents are, for example, diethylin sulfur trifluoride (DAST) Or sulfur tetrafluoride (SF4)。
Because such fluorization agent is higher than hydrogen fluoride reaction property, therefore, in the range of identical pressure and temperature, they It can be used with the excess smaller than hydrogen fluoride.
Double (fluorosulfonyl) acid imide acid are then subjected to purifying；Because impurity is insoluble or is only very slightly soluble in organic solvent In, therefore, in the last of the reaction, the acid is extracted from residual solids using organic solvent.The organic solvent is preferably carbon Dimethyl phthalate.
Part III-MFSI preparation
The Part III corresponds to following reaction scheme：
F-(SO2)-NH-(SO2)-F+MB→F-(SO2)-N--(SO2)-F M++BH
F-(SO2)-N--(SO2)-F M+For LiFSI or NaFSI, its formula is labeled as (VII).MB is lithium-base material or sodium base Thing, i.e. by lithium cation Li+Or sodium cation Na+And anion B-The substratess of the salt form of formation.The substratess may be, for example, Lithium hydroxide, sodium hydroxide, lithium carbonate or sodium carbonate.
The reaction for example can be implemented at a temperature of 25 DEG C -80 DEG C.Lithium-base material or the sodium substratess are with the ratio of 1-1.5 equivalents Example is used, preferably in water or in polar solvent such as alcohol.
According to the present invention, the purity of double (fluorosulfonyl) imide lis or double (fluorosulfonyl) acid imide sodium (MFSI) Preferably at least equal to 99.5 weight %, advantageously at least equal to 99.9 weight %.
Impurity (such as LiCl, LiF and FSO in the presence of double (sulfonic acid) imide salts3Li or NaCl, NaF and FSO3Na at most 1000ppm and preferably up to 500ppm preferably each) are accounted for.
No matter which kind of preparation method, FSO3Li preferably accounts at most 5ppm.
According to any embodiment of the present invention, double (fluorosulfonyl) imide lis or double (fluorosulfonyl) acid imides Sodium (MFSI) preferably both moisture-free and also without by from periodic table of elements 11-15 races and the cation in 4-6 cycles (for example Zn, Cu, Sn, Pb, Bi) salt composition impurity.Due to the electro-chemical activity of these impurity, they are to Li or Na ion batteries Capacity has adverse effect.
The preparation of electrolyte
The MFSI prepared as previously described can be used for preparing electrolyte by being dissolved in appropriate solvent.
For example, such as document J.Electrochemical Society, described in 2011,158, A74-82, LiFSI can Volume ratio 5 is dissolved in 1mol/l concentration:2:3 ethylene carbonate (EC), dimethyl carbonate (DMC) and methyl ethyl carbonate (EMC) in mixture；Such electrolyte meter reveals very good electric conductivity, good cyclical stability and higher than 4.2V Aluminium corrosion.
The electrolyte then can be used to manufacture electricity by being placed between positive pole and negative pole in a way known Pond or battery unit.
Embodiment
Following examples explanation is of the invention but is not limited.
The synthesis of the salt of embodiment 1-bis- (sulfonic acid) acid imide potassium three
Reacted in the absence of solvent in dry glass round bottom flask.Under agitation, to 1.61g amino sulphurs 1.1ml chlorination sulfonic acid is added in acid.Then, 2ml triethylamines are added.The reactant mixture is set to stir 1 day.By adding 20ml water To stop the reaction.Then, 2.79g potassium hydroxide is added.Final product is precipitated and collected by filtering, moreover, with 2 × 30ml CH2Cl2Washed.
The synthesis of embodiment 2-bis- (chlorosulfonyl) acid imide potassium
Three salt described in 15.3g are added into 250ml round-bottomed flasks.Then, 60ml oxalyl chlorides are added dropwise, add thereafter 1ml dimethylformamides.The reaction medium 3 hours and the solution yellowing are stirred under reflux.In the last of the reaction, mistake Filter the solution and obtain the white solid (weight=19.0g) comprising chlorinated compound and potassium chloride.
Embodiment 3-bis- (fluorosulfonyl) imido synthesis
The 19.0g mixtures of double (chlorosulfonyl) acid imide potassium and potassium chloride are added into 800ml autoclaves.Then, 20g hydrogen fluoride is added at ambient temperature.Stir the reaction medium 3 hours.Then, excessive hydrogen fluoride is removed by air stream And the hydrogen chloride of release.Then, obtain with golden yellow solid.

Claims (19)

  1. Formula 1. (III) (SO3 -)-N--(SO3 -)3C+Double (sulfonic acid) imide salts preparation method, wherein C+Represent monovalent sun from Son, methods described includes formula (I) (OH)-SO2-NH2Amidosulphuric acid and formula (II) (OH)-SO2The reaction of-X halogenosulfonic acid is simultaneously Including the reaction with substratess, wherein X represents halogen atom, and the substratess are with the cation C+The salt of formation.
  2. 2. the method for claim 1 wherein X represents chlorine atom.
  3. 3. the method for claim 1 or 2, wherein C+Represent H+Ion, potassium ion K+, sodium ion Na+, lithium ion Li+Or cesium ion Cs+。
  4. 4. the method for claim 1 or 2, methods described includes the amidosulphuric acid of formula (I) and is including C with the halogenosulfonic acid of formula (II)+ Reaction in the presence of the non-nucleophilic substratess of cation.
  5. 5. the method for claim 1 or 2, methods described includes the amidosulphuric acid of formula (I) and the halogenosulfonic acid of formula (II) first Reaction in the presence of substratess, to provide formula (IV) (OH)-SO2-NH-SO2- (OH) double (sulfonyl) acid imides, then, formula (IV) double (sulfonyl) acid imides and the second substratess react, to obtain double (sulfonic acid) imide salts of formula (III), described second Substratess are with the cation C+The salt of formation.
  6. 6. the method for claim 5, wherein first substratess are triethylamine and second substratess are selected from potassium hydroxide, hydrogen-oxygen Change sodium and potassium carbonate.
  7. 7. the method for claim 1 or 2, includes the purification phase of double (sulfonic acid) imide salts of formula (III).
  8. 8. the method for claim 3, wherein C+Represent potassium ion K+。
  9. 9. the method for claim 4, wherein the non-nucleophilic substratess are potassium carbonate K2CO3。
  10. 10. the method for claim 7, wherein purification phase are by from the recrystallization in water.
  11. 11. the method for claim 7, wherein purification phase are by from the recrystallization in polar solvent.
  12. 12. the method for claim 11, wherein purification phase are by from the recrystallization in alcohol.
  13. 13. formula (V) F- (SO2)-NH-(SO2)-F double (fluorosulfonyl) acid imides acid preparation method, including according to right It is required that one of 1-12 prepares double (sulfonic acid) imide salts of formula (III), the fluorination of described double (sulfonic acid) imide salts is then carried out.
  14. 14. the method for claim 13, wherein the fluorination of described double (sulfonic acid) imide salts includes described double (sulfonic acid) acid imides The reaction of fluorization agent of the salt with being preferably selected from hydrogen fluoride, diethylin sulfur trifluoride and sulfur tetrafluoride.
  15. 15. the method for claim 13, wherein the fluorination of described double (sulfonic acid) imide salts includes：
    (a) it is sub- by means of described double (sulfonic acid) acyls of the chlorinating agent selected from thionyl chloride, phosphorus pentachloride, phosphoryl chloride phosphorus oxychloride and oxalyl chloride The chlorination of amine salt, to obtain formula (VI) Cl- (SO2)-N-(SO2)-Cl C+Double (chlorosulfonyl) imide salts, then
    (b) by means of fluorization agent formula (VI) double (chlorosulfonyl) imide salts fluorination, to obtain double (fluorine of formula (V) For sulfonyl) acid imide acid, the fluorization agent is selected from hydrogen fluoride, diethylin sulfur trifluoride, sulfur tetrafluoride and fluoride salt.
  16. 16. formula (VII) F- (SO2)-N--(SO2)-F M+Double (fluorosulfonyl) imide salts preparation method, including basis One of claim 13-15 prepares double (fluorosulfonyl) acid imide acid of formula (V), then, makes this pair (fluorosulfonyl) acyl Imidic acid reacts with lithium-base material or sodium substratess, and wherein M can be Li or Na.
  17. 17. the method for claim 16, wherein the lithium-base material or sodium substratess are selected from lithium hydroxide, lithium carbonate or sodium carbonate.
  18. 18. the manufacture method of electrolyte, including double (fluorosulfonyl) acyls for preparing formula (VII) according to claim 16 or 17 are sub- Amine lithium salts or double (fluorosulfonyl) acid imide sodium salts and make double (fluorosulfonyl) acid imide lithium salts or double (fluoro sulphurs Acyl group) acid imide sodium salt is dissolved in solvent.
  19. 19. the manufacture method of battery or battery unit, including electrolyte is manufactured according to claim 18 and the electrolyte is inserted Enter between negative pole and positive pole.
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