CN103555165A - Alkyd resin fireproof coating as well as preparation method thereof - Google Patents
Alkyd resin fireproof coating as well as preparation method thereof Download PDFInfo
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- CN103555165A CN103555165A CN201310546305.8A CN201310546305A CN103555165A CN 103555165 A CN103555165 A CN 103555165A CN 201310546305 A CN201310546305 A CN 201310546305A CN 103555165 A CN103555165 A CN 103555165A
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Abstract
The invention discloses an alkyd resin fireproof coating as well as a preparation method thereof. The coating is prepared from the following components in parts by weight: 100-130 parts of halogenated alkyd resin, 8-14 parts of lithium silicate, 10-15 parts of antimonous oxide, 10-15 parts of decabromodiphenyl ether, 5-8 parts of a dehydrating agent, 4-9 parts of a carbon forming agent, 3-7 parts of a foaming agent, 15-20 parts of write-color powdery antimony, 10-15 parts of asbestos fiber, 8-12 parts of tricresyl phosphate, 15-25 parts of epoxy resin and 50-70 parts of water. The coating has the beneficial effects that the flame retardant decabromodiphenyl ether is added, so that the fireproof coating disclosed by the invention is efficient; the filler write-color powdery antimony is used, not only has the effect of a paint, but also improves the synergic effect of flame retardance; the asbestos fiber is used, so that the fireproof coating is high in adhesive force and great in strength; the tricresyl phosphate is used, so that the fireproof coating is strong in flexibility; the epoxy resin is used, so that the fireproof coating is stable.
Description
Technical field
The present invention relates to frie retardant coating field, relate in particular to a kind of alkyd resin fire-retardant paint and preparation method thereof.
Background technology
Current, frie retardant coating is widely used, and frie retardant coating is applied to flammable substrates surface, in order to change material surface combustioncharacteristics, and retardance fire rapid spread; Or be applied on building slab, in order to improve the fire endurance of member.The usage of frie retardant coating is to brush on the surface of inflammable material, improves the refractory ability of material, slows down propagation of flame velocity of propagation, or can stop burning within a certain period of time.But general frie retardant coating efficiency is lower, snappiness, sticking power are also undesirable, therefore, need a kind of new technical scheme to address the above problem.
Summary of the invention
The invention provides alkyd resin fire-retardant paint of a kind of efficient, high-flexibility and preparation method thereof.
The technical solution used in the present invention: a kind of alkyd resin fire-retardant paint is formulated according to weight proportion by following composition: the Synolac of 100-130 part halogenation, 8-14 part lithium silicate, 10-15 part antimonous oxide, 10-15 part decabromodiphenyl oxide, 5-8 part dewatering agent, 4-9 part carbon forming agent, 3-7 part whipping agent, 15-20 part stibium trioxide powder, 10-15 part fibrous magnesium silicate, 8-12 part tritolyl phosphate, 15-25 part epoxy resin, 50-70 part water.
Dewatering agent is one or both of three (2 one chloropropyl) phosphoric acid ester and ammonium polyphosphate.
Carbon forming agent is a kind of or mixture of tetramethylolmethane, Dipentaerythritol or tripentaerythritol.
Whipping agent is one or both of trimeric cyanamide or Dyhard RU 100.
A preparation method for alkyd resin fire-retardant paint, is characterized in that preparation process is:
A, dewatering agent, char-forming agent and whipping agent are placed in mortar and are ground in described ratio, be transferred in beaker after powdered, and add antimonous oxide, decabromodiphenyl oxide and stibium trioxide powder, be uniformly mixed;
B, in beaker, add Synolac, lithium silicate, fibrous magnesium silicate, tritolyl phosphate and the epoxy resin of the halogenation of described ratio, and be placed in magnetic stirrer and stir;
C, the material in beaker is poured in dispersion mill, and the water of pouring described ratio into carries out high speed dispersion 1-3h, obtain Synolac fire-retardant material.
Beneficial effect of the present invention: add Decabromodiphenyl Ether, make frie retardant coating of the present invention efficient; Use filler stibium trioxide powder, both played the effect of pigment, be improved fire-retardant synergy; Fibrous magnesium silicate makes frie retardant coating sticking power of the present invention high, and intensity is large; Tritolyl phosphate makes frie retardant coating snappiness of the present invention strong; Epoxy resin provides frie retardant coating stability of the present invention.
Specific embodiments
Embodiment 1
5 parts of ammonium polyphosphates, 4 parts of tetramethylolmethanes and 3 parts of trimeric cyanamides are placed in mortar and are ground, be transferred in beaker after powdered, and add 10 parts of antimonous oxides, 10 parts of decabromodiphenyl oxides and 15 parts of stibium trioxide powder, be uniformly mixed; In beaker, add the Synolac of 100 parts of halogenations, 8 parts of lithium silicates, 10 parts of fibrous magnesium silicates, 8 parts of tritolyl phosphates and 15 parts of epoxy resin, and be placed in magnetic stirrer and stir; Material in beaker is poured in dispersion mill, and poured into 50 parts of water and carry out high speed dispersion 1h, obtain Synolac fire-retardant material.
Add Decabromodiphenyl Ether, make frie retardant coating of the present invention efficient; Use filler stibium trioxide powder, both played the effect of pigment, be improved fire-retardant synergy; Fibrous magnesium silicate makes frie retardant coating sticking power of the present invention high, and intensity is large; Tritolyl phosphate makes frie retardant coating snappiness of the present invention strong; Epoxy resin provides frie retardant coating stability of the present invention.
Embodiment 2
6 part of three (2 one chloropropyl) phosphoric acid ester, 7 parts of Dipentaerythritols and 5 parts of Dyhard RU 100s are placed in mortar and are ground, after powdered, be transferred in beaker, and add 13 parts of antimonous oxides, 13 parts of decabromodiphenyl oxides and 17 parts of stibium trioxide powder, be uniformly mixed; In beaker, add the Synolac of 120 parts of halogenations, 11 parts of lithium silicates, 13 parts of fibrous magnesium silicates, 10 parts of tritolyl phosphates and 20 parts of epoxy resin, and be placed in magnetic stirrer and stir; Material in beaker is poured in dispersion mill, and poured into 60 parts of water and carry out high speed dispersion 2h, obtain Synolac fire-retardant material.
Add Decabromodiphenyl Ether, make frie retardant coating of the present invention efficient; Use filler stibium trioxide powder, both played the effect of pigment, be improved fire-retardant synergy; Fibrous magnesium silicate makes frie retardant coating sticking power of the present invention high, and intensity is large; Tritolyl phosphate makes frie retardant coating snappiness of the present invention strong; Epoxy resin provides frie retardant coating stability of the present invention.
Embodiment 3
By 8 part of three (2 one chloropropyl) phosphoric acid ester and the mixture of ammonium polyphosphate, the mixture of the mixture of 9 parts of tetramethylolmethanes, Dipentaerythritol and tripentaerythritols, 7 parts of Dyhard RU 100s and trimeric cyanamide and being placed in mortar grind, after powdered, be transferred in beaker, and add 15 parts of antimonous oxides, 15 parts of decabromodiphenyl oxides and 20 parts of stibium trioxide powder, be uniformly mixed; In beaker, add the Synolac of 130 parts of halogenations, 14 parts of lithium silicates, 15 parts of fibrous magnesium silicates, 12 parts of tritolyl phosphates and 25 parts of epoxy resin, and be placed in magnetic stirrer and stir; Material in beaker is poured in dispersion mill, and poured into 70 parts of water and carry out high speed dispersion 3h, obtain Synolac fire-retardant material.
Add Decabromodiphenyl Ether, make frie retardant coating of the present invention efficient; Use filler stibium trioxide powder, both played the effect of pigment, be improved fire-retardant synergy; Fibrous magnesium silicate makes frie retardant coating sticking power of the present invention high, and intensity is large; Tritolyl phosphate makes frie retardant coating snappiness of the present invention strong; Epoxy resin provides frie retardant coating stability of the present invention.
Claims (5)
1. an alkyd resin fire-retardant paint, is characterized in that this frie retardant coating is formulated according to weight proportion by following composition: the Synolac of 100-130 part halogenation, 8-14 part lithium silicate, 10-15 part antimonous oxide, 10-15 part decabromodiphenyl oxide, 5-8 part dewatering agent, 4-9 part carbon forming agent, 3-7 part whipping agent, 15-20 part stibium trioxide powder, 10-15 part fibrous magnesium silicate, 8-12 part tritolyl phosphate, 15-25 part epoxy resin, 50-70 part water.
2. a kind of alkyd resin fire-retardant paint according to claim 1, is characterized in that: described dewatering agent is one or both of three (2 one chloropropyl) phosphoric acid ester and ammonium polyphosphate.
3. a kind of alkyd resin fire-retardant paint according to claim 1, is characterized in that; Described carbon forming agent is a kind of or mixture of tetramethylolmethane, Dipentaerythritol or tripentaerythritol.
4. a kind of alkyd resin fire-retardant paint according to claim 1, is characterized in that: described whipping agent is one or both of trimeric cyanamide or Dyhard RU 100.
5. the preparation method of a kind of alkyd resin fire-retardant paint according to claim 1, is characterized in that preparation process is:
A, dewatering agent, char-forming agent and whipping agent are placed in mortar and are ground in described ratio, be transferred in beaker after powdered, and add antimonous oxide, decabromodiphenyl oxide and stibium trioxide powder, be uniformly mixed;
B, in beaker, add Synolac, lithium silicate, fibrous magnesium silicate, tritolyl phosphate and the epoxy resin of the halogenation of described ratio, and be placed in magnetic stirrer and stir;
C, the material in beaker is poured in dispersion mill, and the water of pouring described ratio into carries out high speed dispersion 1-3h, obtain Synolac fire-retardant material.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
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| CN201310546305.8A CN103555165A (en) | 2013-11-07 | 2013-11-07 | Alkyd resin fireproof coating as well as preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310546305.8A CN103555165A (en) | 2013-11-07 | 2013-11-07 | Alkyd resin fireproof coating as well as preparation method thereof |
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| CN103555165A true CN103555165A (en) | 2014-02-05 |
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Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327695A (en) * | 2014-11-26 | 2015-02-04 | 江苏博腾新材料股份有限公司 | High-performance flame-retardant and fireproof coating |
| CN104559379A (en) * | 2014-12-23 | 2015-04-29 | 姜云华 | Conductive heating coating |
| CN106883655A (en) * | 2017-03-31 | 2017-06-23 | 安徽中煦环保新材料科技有限公司 | A kind of environmental protection flame retardant coating material and preparation method thereof |
| CN110484044A (en) * | 2018-05-14 | 2019-11-22 | 广东天丛新材料有限公司 | A kind of ultra-thin fire-resistant coating and spraying process applied on steel |
| CN112194879A (en) * | 2020-08-31 | 2021-01-08 | 南方电网科学研究院有限责任公司 | Flame-retardant alicyclic epoxy resin castable for outdoor insulators |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN102382559A (en) * | 2011-10-14 | 2012-03-21 | 吴江市天源塑胶有限公司 | Fire retardant coating for bamboo floor |
| CN102746775A (en) * | 2012-06-28 | 2012-10-24 | 兰州理工大学 | Bromine carbon alkyd resin cable fireproof paint and its preparation method |
| CN103305107A (en) * | 2013-06-25 | 2013-09-18 | 关锦池 | Fireproof coating and preparation method thereof |
-
2013
- 2013-11-07 CN CN201310546305.8A patent/CN103555165A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN102382559A (en) * | 2011-10-14 | 2012-03-21 | 吴江市天源塑胶有限公司 | Fire retardant coating for bamboo floor |
| CN102746775A (en) * | 2012-06-28 | 2012-10-24 | 兰州理工大学 | Bromine carbon alkyd resin cable fireproof paint and its preparation method |
| CN103305107A (en) * | 2013-06-25 | 2013-09-18 | 关锦池 | Fireproof coating and preparation method thereof |
Non-Patent Citations (1)
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| 徐晓楠等: "《防火涂料》", 31 October 2003, article "《防火涂料》", pages: 97-99 * |
Cited By (5)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104327695A (en) * | 2014-11-26 | 2015-02-04 | 江苏博腾新材料股份有限公司 | High-performance flame-retardant and fireproof coating |
| CN104559379A (en) * | 2014-12-23 | 2015-04-29 | 姜云华 | Conductive heating coating |
| CN106883655A (en) * | 2017-03-31 | 2017-06-23 | 安徽中煦环保新材料科技有限公司 | A kind of environmental protection flame retardant coating material and preparation method thereof |
| CN110484044A (en) * | 2018-05-14 | 2019-11-22 | 广东天丛新材料有限公司 | A kind of ultra-thin fire-resistant coating and spraying process applied on steel |
| CN112194879A (en) * | 2020-08-31 | 2021-01-08 | 南方电网科学研究院有限责任公司 | Flame-retardant alicyclic epoxy resin castable for outdoor insulators |
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Application publication date: 20140205 |