CN103552257A - 一种高强度高阻燃玻璃钢复合材料frp板制造方法 - Google Patents
一种高强度高阻燃玻璃钢复合材料frp板制造方法 Download PDFInfo
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- CN103552257A CN103552257A CN201310507654.9A CN201310507654A CN103552257A CN 103552257 A CN103552257 A CN 103552257A CN 201310507654 A CN201310507654 A CN 201310507654A CN 103552257 A CN103552257 A CN 103552257A
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- composite material
- strength
- reinforced plastics
- fiber reinforced
- glass fiber
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- 238000000034 method Methods 0.000 title claims abstract description 44
- 239000002131 composite material Substances 0.000 title claims abstract description 34
- 239000011152 fibreglass Substances 0.000 title claims abstract description 29
- 238000004519 manufacturing process Methods 0.000 title claims abstract description 20
- 239000000835 fiber Substances 0.000 title abstract description 21
- 229920003023 plastic Polymers 0.000 title abstract description 14
- 239000004033 plastic Substances 0.000 title abstract description 14
- 239000003677 Sheet moulding compound Substances 0.000 claims abstract description 28
- 239000011521 glass Substances 0.000 claims abstract description 15
- 238000003825 pressing Methods 0.000 claims abstract description 13
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 7
- 239000011256 inorganic filler Substances 0.000 claims abstract description 7
- 229910003475 inorganic filler Inorganic materials 0.000 claims abstract description 7
- 229920006337 unsaturated polyester resin Polymers 0.000 claims abstract description 7
- 229920000728 polyester Polymers 0.000 claims abstract description 6
- PNEYBMLMFCGWSK-UHFFFAOYSA-N Alumina Chemical compound [O-2].[O-2].[O-2].[Al+3].[Al+3] PNEYBMLMFCGWSK-UHFFFAOYSA-N 0.000 claims description 12
- RNFJDJUURJAICM-UHFFFAOYSA-N 2,2,4,4,6,6-hexaphenoxy-1,3,5-triaza-2$l^{5},4$l^{5},6$l^{5}-triphosphacyclohexa-1,3,5-triene Chemical compound N=1P(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP(OC=2C=CC=CC=2)(OC=2C=CC=CC=2)=NP=1(OC=1C=CC=CC=1)OC1=CC=CC=C1 RNFJDJUURJAICM-UHFFFAOYSA-N 0.000 claims description 10
- 239000003063 flame retardant Substances 0.000 claims description 10
- 238000000465 moulding Methods 0.000 claims description 10
- 229920006387 Vinylite Polymers 0.000 claims description 6
- UFHFLCQGNIYNRP-UHFFFAOYSA-N Hydrogen Chemical compound [H][H] UFHFLCQGNIYNRP-UHFFFAOYSA-N 0.000 claims description 4
- 229910052739 hydrogen Inorganic materials 0.000 claims description 4
- 239000001257 hydrogen Substances 0.000 claims description 4
- 238000009747 press moulding Methods 0.000 claims description 3
- 150000002978 peroxides Chemical group 0.000 claims description 2
- CWPKTBMRVATCBL-UHFFFAOYSA-N 3-[1-[1-[(2-methylphenyl)methyl]piperidin-4-yl]piperidin-4-yl]-1h-benzimidazol-2-one Chemical compound CC1=CC=CC=C1CN1CCC(N2CCC(CC2)N2C(NC3=CC=CC=C32)=O)CC1 CWPKTBMRVATCBL-UHFFFAOYSA-N 0.000 claims 1
- 239000000463 material Substances 0.000 abstract description 24
- 238000010276 construction Methods 0.000 abstract description 5
- 229920005989 resin Polymers 0.000 abstract description 5
- 239000011347 resin Substances 0.000 abstract description 5
- 239000004744 fabric Substances 0.000 abstract description 2
- UHOVQNZJYSORNB-UHFFFAOYSA-N benzene Substances C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 abstract 1
- 239000003638 chemical reducing agent Substances 0.000 abstract 1
- 230000005611 electricity Effects 0.000 abstract 1
- 238000003754 machining Methods 0.000 abstract 1
- 125000000391 vinyl group Chemical group [H]C([*])=C([H])[H] 0.000 abstract 1
- 229920002554 vinyl polymer Polymers 0.000 abstract 1
- 238000009740 moulding (composite fabrication) Methods 0.000 description 12
- 238000002485 combustion reaction Methods 0.000 description 7
- 239000003365 glass fiber Substances 0.000 description 6
- 230000018109 developmental process Effects 0.000 description 5
- 230000000694 effects Effects 0.000 description 4
- 238000005516 engineering process Methods 0.000 description 4
- GJBRNHKUVLOCEB-UHFFFAOYSA-N tert-butyl benzenecarboperoxoate Chemical compound CC(C)(C)OOC(=O)C1=CC=CC=C1 GJBRNHKUVLOCEB-UHFFFAOYSA-N 0.000 description 4
- 229910000975 Carbon steel Inorganic materials 0.000 description 3
- 238000005452 bending Methods 0.000 description 3
- 239000010962 carbon steel Substances 0.000 description 3
- 150000001875 compounds Chemical class 0.000 description 3
- 230000007797 corrosion Effects 0.000 description 3
- 238000005260 corrosion Methods 0.000 description 3
- 239000011159 matrix material Substances 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000012779 reinforcing material Substances 0.000 description 3
- 229920003002 synthetic resin Polymers 0.000 description 3
- 239000000057 synthetic resin Substances 0.000 description 3
- 229920001187 thermosetting polymer Polymers 0.000 description 3
- ZOXJGFHDIHLPTG-UHFFFAOYSA-N Boron Chemical compound [B] ZOXJGFHDIHLPTG-UHFFFAOYSA-N 0.000 description 2
- 229920000049 Carbon (fiber) Polymers 0.000 description 2
- 239000004593 Epoxy Substances 0.000 description 2
- 229920002430 Fibre-reinforced plastic Polymers 0.000 description 2
- 229910000831 Steel Inorganic materials 0.000 description 2
- 230000032683 aging Effects 0.000 description 2
- 239000002585 base Substances 0.000 description 2
- 229910052796 boron Inorganic materials 0.000 description 2
- 239000004566 building material Substances 0.000 description 2
- 239000004917 carbon fiber Substances 0.000 description 2
- 238000007906 compression Methods 0.000 description 2
- 230000006835 compression Effects 0.000 description 2
- 230000007423 decrease Effects 0.000 description 2
- 230000007547 defect Effects 0.000 description 2
- 238000007723 die pressing method Methods 0.000 description 2
- 239000011151 fibre-reinforced plastic Substances 0.000 description 2
- 239000011810 insulating material Substances 0.000 description 2
- 238000009413 insulation Methods 0.000 description 2
- 239000012212 insulator Substances 0.000 description 2
- 230000007774 longterm Effects 0.000 description 2
- 229910052751 metal Inorganic materials 0.000 description 2
- 239000002184 metal Substances 0.000 description 2
- VNWKTOKETHGBQD-UHFFFAOYSA-N methane Chemical compound C VNWKTOKETHGBQD-UHFFFAOYSA-N 0.000 description 2
- 230000002265 prevention Effects 0.000 description 2
- 239000002990 reinforced plastic Substances 0.000 description 2
- 239000011378 shotcrete Substances 0.000 description 2
- 239000000779 smoke Substances 0.000 description 2
- 239000010959 steel Substances 0.000 description 2
- 230000035882 stress Effects 0.000 description 2
- 239000000126 substance Substances 0.000 description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 2
- 238000004804 winding Methods 0.000 description 2
- 229910000851 Alloy steel Inorganic materials 0.000 description 1
- CWYNVVGOOAEACU-UHFFFAOYSA-N Fe2+ Chemical compound [Fe+2] CWYNVVGOOAEACU-UHFFFAOYSA-N 0.000 description 1
- 229920000433 Lyocell Polymers 0.000 description 1
- 238000002679 ablation Methods 0.000 description 1
- 239000002253 acid Substances 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 description 1
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 description 1
- 229910021502 aluminium hydroxide Inorganic materials 0.000 description 1
- 229920006231 aramid fiber Polymers 0.000 description 1
- 239000011230 binding agent Substances 0.000 description 1
- 238000000748 compression moulding Methods 0.000 description 1
- 239000007822 coupling agent Substances 0.000 description 1
- 239000000428 dust Substances 0.000 description 1
- 238000001125 extrusion Methods 0.000 description 1
- 239000000945 filler Substances 0.000 description 1
- 230000009970 fire resistant effect Effects 0.000 description 1
- 239000004615 ingredient Substances 0.000 description 1
- 239000011229 interlayer Substances 0.000 description 1
- 238000010409 ironing Methods 0.000 description 1
- 238000010030 laminating Methods 0.000 description 1
- 238000011031 large-scale manufacturing process Methods 0.000 description 1
- 239000002932 luster Substances 0.000 description 1
- 238000003913 materials processing Methods 0.000 description 1
- 239000003921 oil Substances 0.000 description 1
- 230000035699 permeability Effects 0.000 description 1
- 230000002787 reinforcement Effects 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 238000010008 shearing Methods 0.000 description 1
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 1
- 229910010271 silicon carbide Inorganic materials 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000010935 stainless steel Substances 0.000 description 1
- 229910001220 stainless steel Inorganic materials 0.000 description 1
- 230000001052 transient effect Effects 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
Classifications
-
- B—PERFORMING OPERATIONS; TRANSPORTING
- B29—WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
- B29C—SHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
- B29C70/00—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts
- B29C70/04—Shaping composites, i.e. plastics material comprising reinforcements, fillers or preformed parts, e.g. inserts comprising reinforcements only, e.g. self-reinforcing plastics
- B29C70/28—Shaping operations therefor
- B29C70/40—Shaping or impregnating by compression not applied
- B29C70/50—Shaping or impregnating by compression not applied for producing articles of indefinite length, e.g. prepregs, sheet moulding compounds [SMC] or cross moulding compounds [XMC]
Landscapes
- Chemical & Material Sciences (AREA)
- Engineering & Computer Science (AREA)
- Composite Materials (AREA)
- Mechanical Engineering (AREA)
- Reinforced Plastic Materials (AREA)
Abstract
Description
CLASS A | CLASS B | CLASS C | |
火焰传播指数,FSI | 0-25 | 26-75 | 76-200 |
烟气发展指数,SDI | 0-450 | 0-450 | 0-450 |
序号 | 项次执行标准单位指标要求数值 |
1 | 火焰传播指数ASTM E84≤255 |
2 | 烟气发展指数ASTM E84≤45045 |
3 | 热传导系数ASTM C177w/(mk)≤0.3在24℃下0.25 |
4 | 最高使用温度ASTM C447℃96200 |
5 | 受压强度ASTM C165N/mm2≥350365 |
Claims (8)
Priority Applications (1)
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CN201310507654.9A CN103552257B (zh) | 2013-10-24 | 2013-10-24 | 一种高强度高阻燃玻璃钢复合材料frp板制造方法 |
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CN201310507654.9A CN103552257B (zh) | 2013-10-24 | 2013-10-24 | 一种高强度高阻燃玻璃钢复合材料frp板制造方法 |
Publications (2)
Publication Number | Publication Date |
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CN103552257A true CN103552257A (zh) | 2014-02-05 |
CN103552257B CN103552257B (zh) | 2016-09-21 |
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CN201310507654.9A Active CN103552257B (zh) | 2013-10-24 | 2013-10-24 | 一种高强度高阻燃玻璃钢复合材料frp板制造方法 |
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CN (1) | CN103552257B (zh) |
Cited By (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108237749A (zh) * | 2016-12-23 | 2018-07-03 | 比亚迪股份有限公司 | 一种复合材料及其制备方法 |
CN111469446A (zh) * | 2020-04-17 | 2020-07-31 | 杭州卡涞复合材料科技有限公司 | 一种汽车复合材料防火电池箱的快速成型方法 |
CN111675889A (zh) * | 2020-06-20 | 2020-09-18 | 郑振勇 | 一种高阻燃防火玻璃钢材料及其制备方法 |
CN115710364A (zh) * | 2022-12-13 | 2023-02-24 | 南通汇泽新材料有限公司 | 阻燃玻璃钢的生产工艺 |
Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5497650A (en) * | 1978-01-19 | 1979-08-01 | Teijin Ltd | Flame retardant resin composition |
CN101935441A (zh) * | 2010-09-16 | 2011-01-05 | 浦海 | 玻璃钢材料固化剂组合物、由其制成的玻璃钢材料及变压器台 |
CN102408692A (zh) * | 2011-09-13 | 2012-04-11 | 青岛润兴高分子材料有限公司 | 高性能双抗片状模塑料及制造方法 |
CN102529123A (zh) * | 2011-11-25 | 2012-07-04 | 南昌大学 | 电磁波吸波复合材料的smc工艺制备方法 |
-
2013
- 2013-10-24 CN CN201310507654.9A patent/CN103552257B/zh active Active
Patent Citations (4)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
JPS5497650A (en) * | 1978-01-19 | 1979-08-01 | Teijin Ltd | Flame retardant resin composition |
CN101935441A (zh) * | 2010-09-16 | 2011-01-05 | 浦海 | 玻璃钢材料固化剂组合物、由其制成的玻璃钢材料及变压器台 |
CN102408692A (zh) * | 2011-09-13 | 2012-04-11 | 青岛润兴高分子材料有限公司 | 高性能双抗片状模塑料及制造方法 |
CN102529123A (zh) * | 2011-11-25 | 2012-07-04 | 南昌大学 | 电磁波吸波复合材料的smc工艺制备方法 |
Cited By (5)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN108237749A (zh) * | 2016-12-23 | 2018-07-03 | 比亚迪股份有限公司 | 一种复合材料及其制备方法 |
CN111469446A (zh) * | 2020-04-17 | 2020-07-31 | 杭州卡涞复合材料科技有限公司 | 一种汽车复合材料防火电池箱的快速成型方法 |
CN111469446B (zh) * | 2020-04-17 | 2021-04-27 | 杭州卡涞复合材料科技有限公司 | 一种汽车复合材料防火电池箱的快速成型方法 |
CN111675889A (zh) * | 2020-06-20 | 2020-09-18 | 郑振勇 | 一种高阻燃防火玻璃钢材料及其制备方法 |
CN115710364A (zh) * | 2022-12-13 | 2023-02-24 | 南通汇泽新材料有限公司 | 阻燃玻璃钢的生产工艺 |
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Publication number | Publication date |
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CN103552257B (zh) | 2016-09-21 |
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C14 | Grant of patent or utility model | ||
GR01 | Patent grant | ||
C56 | Change in the name or address of the patentee | ||
CP01 | Change in the name or title of a patent holder |
Address after: 313000, Changxing County Town, Zhejiang, Huzhou province Huashan Industrial Zone, south of the town Patentee after: Zhejiang four new materials Limited by Share Ltd Address before: 313000, Changxing County Town, Zhejiang, Huzhou province Huashan Industrial Zone, south of the town Patentee before: At Meishan, changxing, zhejiang Province Si Da matrix material company limited |
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TR01 | Transfer of patent right |
Effective date of registration: 20180720 Address after: 313000 South Huashan Industrial Zone, Si an town, Changxing County, Huzhou, Zhejiang Co-patentee after: Suzhou Jufeng Electrical Insulation System Co., Ltd. Patentee after: Zhejiang four new materials Limited by Share Ltd Address before: 313000 South Huashan Industrial Zone, Si an town, Changxing County, Huzhou, Zhejiang Patentee before: Zhejiang four new materials Limited by Share Ltd |
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Effective date of registration: 20200108 Address after: 313100, Changxing County Town, Zhejiang, Huzhou province Huashan Industrial Zone, south of the town Patentee after: Zhejiang four new materials Limited by Share Ltd Address before: 313000, Changxing County Town, Zhejiang, Huzhou province Huashan Industrial Zone, south of the town Co-patentee before: Suzhou Jufeng Electrical Insulation System Co., Ltd. Patentee before: Zhejiang four new materials Limited by Share Ltd |
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PE01 | Entry into force of the registration of the contract for pledge of patent right |
Denomination of invention: A manufacturing method of FRP plate with high strength and high flame retardant Effective date of registration: 20210617 Granted publication date: 20160921 Pledgee: Huzhou branch of Industrial Bank Co., Ltd Pledgor: ZHEJIANG SIDA COMPOSITE MATERIAL Co.,Ltd. Registration number: Y2021330000592 |
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