CN103549687A - Rubber gloves with corrosion resisting function and preparation method thereof - Google Patents
Rubber gloves with corrosion resisting function and preparation method thereof Download PDFInfo
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- CN103549687A CN103549687A CN201310557646.5A CN201310557646A CN103549687A CN 103549687 A CN103549687 A CN 103549687A CN 201310557646 A CN201310557646 A CN 201310557646A CN 103549687 A CN103549687 A CN 103549687A
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Abstract
The invention relates to a pair of rubber gloves with a corrosion resisting function and a preparation method thereof. By adopting an improved formula and process, the rubber gloves produced by adopting the method has the function that the harm to hands caused by the fact that the hands work in a highly-corrosive environment, in particular for a highly-corrosive place, can be effectively prevented. The preparation method for the rubber gloves with the corrosion resisting function, which is disclosed by the invention, is complete in operation and is rigorous in process; the production quality of enterprises is greatly improved.
Description
Technical field
The present invention relates to a kind of rubber gloves, particularly a kind of rubber gloves with anti-corrosion function, belongs to rubber technology field.
Background technology
Gloves, owing to having barrier protection effect, can be good at protecting user's safety, have been widely used in people's productive life.According to the difference of its purposes, can be divided into medical gloves, industrial gloves and domestic purpose gloves, rubber gloves only plays simple isolating and protecting effect to people's hand at present, and do not there is corrosion-resistant function, make user in use, especially the place severe at environment, corrosivity intensity is high, can produce harm to skin.
Summary of the invention
Technical problem to be solved by this invention is to provide a kind of rubber gloves with anti-corrosion function for above drawback, and the preparation method of this rubber gloves is provided, and this preparation method is easy to operate.Gloves of the present invention, have adopted improved composition and engineering, make the rubber gloves with the method production, and especially severe at environment, the place that corrosivity intensity is high, can effectively protect hand.
For solving the problems of the technologies described above, technical scheme of the present invention is:
A rubber gloves with anti-corrosion function, its preparation method is as follows:
A. heating adds a certain amount of impregnating fluid in rubber-based adhesive, and heating-up temperature scope is 70 ℃-90 ℃, and the heat time is 5-10min;
B. stir, be clockwise stirring, stir speed (S.S.) is 100-130r/min, and adjusting solid content is 25%-33%;
C. heating, will regulate the epoxy glue of solid content to heat, and heating-up temperature scope is 60 ℃-85 ℃, and the heat time is 5-10min;
D. moulding, after mould is dried, then mould floods the above-mentioned epoxy glue preparing; Pass through again the high temperature drying of 130-150 ℃, 30-40 minute; Naturally cool to normal temperature, handle sleeve is taken off from mould;
E. dipping is dried, and the gloves of forming are impregnated in impregnating fluid, carries out hyperthermia drying after making its surfaces externally and internally evenly speckle with one deck impregnating fluid, and bake out temperature is that 95-110 ℃, drying time are 15-25 minute, naturally cools to normal temperature, again dipping after oven dry
Enter impregnating fluid, repeat, after 2-3 dipping baking operations, to obtain finished product.
Above-mentioned a kind of rubber gloves with anti-corrosion function, wherein, described rubber-based adhesive is one or more in acrylonitrile-butadiene rubber, natural rubber, fluorubber, silicon rubber, polyurethane rubber.
Above-mentioned a kind of rubber gloves with anti-corrosion function, wherein, preferably, described rubber-based adhesive is the mixture of acrylonitrile-butadiene rubber and natural rubber, acrylonitrile-butadiene rubber: natural rubber is 68:35, by weight meter.
Above-mentioned a kind of rubber gloves with anti-corrosion function, wherein, the ratio of described rubber-based adhesive and impregnating fluid is 95:15, by weight meter.
Above-mentioned a kind of rubber gloves with anti-corrosion function, wherein, described impregnating fluid, meter is as follows by weight:
Phenmethylol 75-78 part
Acrylic acid 30-33 part
Ethylenediamine tetra-acetic acid 17-20 part
Vulcanizing agent 12-15 part
Above-mentioned a kind of rubber gloves with anti-corrosion function, wherein, described impregnating fluid, preferably, meter is as follows by weight:
77 parts of phenmethylols
32 parts, acrylic acid
18 parts of ethylenediamine tetra-acetic acids
13 parts of vulcanizing agents
Beneficial effect of the present invention is: adopted improved composition and engineering, made the rubber gloves with the method production, severe at environment, the place that corrosivity intensity is high, can effectively protect hand.A kind of rubber gloves preparation method with anti-corrosion function of the present invention operates perfect, and process is rigorous, greatly improves enterprise's quality of production.
The specific embodiment
By specific embodiment, the specific embodiment of the present invention is described in further detail below.
Phenmethylol of the present invention, molecular formula is: C
7h
8o; Described acrylic acid, molecular formula is: C
3h
4o
2, described ethylenediamine tetra-acetic acid molecular formula is: C
10h
16n
2o
8, molecular weight is: 292.25.Described vulcanizing agent is sulphur, and molecular formula is S.
Example one:
A rubber gloves with anti-corrosion function, first take acrylonitrile-butadiene rubber: the ratio preparation rubber-based adhesive that natural rubber is 68:35, by weight; Then with 77 parts of phenmethylols, 32 parts of acrylic acid, 18 parts of ethylenediamine tetra-acetic acid preparation impregnating fluids, by weight meters; Then the impregnating fluid adding in rubber-based adhesive, the ratio of rubber-based adhesive and impregnating fluid liquid is 95:15, and meter, first heats by weight, adds a certain amount of impregnating fluid in rubber-based adhesive, and heating-up temperature scope is 70 ℃-90 ℃, and the heat time is 5-10min; Stir, be clockwise stirring, stir speed (S.S.) is 110r/min, and regulating solid content is 30%; To regulate the epoxy glue of solid content to heat afterwards, heating-up temperature be 75 ℃, and the heat time is 8min; After mould is dried, then mould floods the above-mentioned epoxy glue preparing; Again through the high temperature drying of 140 ℃, 35 minutes; Naturally cool to normal temperature, handle sleeve is taken off from mould; The gloves of forming are impregnated in impregnating fluid, after making its surfaces externally and internally evenly speckle with one deck impregnating fluid, carry out hyperthermia drying, bake out temperature is that 105 ℃, drying time are 20 minutes, after oven dry, naturally cool to normal temperature, again be impregnated into impregnating fluid, finally repeat, after 3 dipping baking operations, to obtain finished product.
The rubber gloves obtaining by above-described embodiment is carried out to wearing test, and its process and result are as follows:
Experimenter is 8 of female employees that select unlike material gloves, in corrosivity, just dress significantly continuous 35 days 5 weeks of emgloves, require test woman worker not to be coated with any cosmetics every day, 8 hours every days of work hours, left hand was dressed the rubber gloves of the method production of embodiment, the right hand is dressed General Purpose Rubber gloves, 35 days wearing tests finish rear to right-hand man's contrast of taking pictures, and comparing result is in Table one
Table one
Because upper table experimental data shows, the prepared gloves of the present invention, in the larger place of corrosivity, can effectively be protected hand.A kind of rubber gloves with anti-corrosion function of the present invention, adopted improved composition and engineering, make the rubber gloves of producing by the method, especially in the larger place of corrosivity, can effectively prevent that hand from producing harm because of the opponent that works under compared with large environment in corrosivity.A kind of rubber gloves preparation method with anti-corrosion function of the present invention operates perfect, and process is rigorous, greatly improves enterprise's quality of production.
Here description of the invention and application is illustrative, not wants that therefore, the present invention is not subject to the restriction of the present embodiment by scope restriction of the present invention in the above-described embodiments, and the technical scheme that any employing equivalence replacement obtains is all in the scope of protection of the invention.
Claims (6)
1. a rubber gloves with anti-corrosion function, is characterized in that, its preparation method is as follows:
Heating adds a certain amount of impregnating fluid in rubber-based adhesive, and heating-up temperature scope is 70 ℃-90 ℃, and the heat time is 5-10min;
Stir, be clockwise stirring, stir speed (S.S.) is 100-130r/min, and adjusting solid content is 25%-33%;
Heating, will regulate the epoxy glue of solid content to heat, and heating-up temperature scope is 60 ℃-85 ℃, and the heat time is 5-10min;
Moulding, after mould is dried, then mould floods the above-mentioned epoxy glue preparing; Pass through again the high temperature drying of 130-150 ℃, 30-40 minute; Naturally cool to normal temperature, handle sleeve is taken off from mould;
Dipping is dried, the gloves of forming are impregnated in impregnating fluid, after making its surfaces externally and internally evenly speckle with one deck impregnating fluid, carry out hyperthermia drying, bake out temperature is that 95-110 ℃, drying time are 15-25 minute, after oven dry, naturally cool to normal temperature, again be impregnated into impregnating fluid, repeat, after 2-3 dipping baking operations, to obtain finished product.
2. a kind of rubber gloves with anti-corrosion function as claimed in claim 1, is characterized in that, described impregnating fluid, and meter is as follows by weight:
Phenmethylol 75-78 part
Acrylic acid 30-33 part
Ethylenediamine tetra-acetic acid 17-20 part
Vulcanizing agent 12-15 part.
3. a kind of rubber gloves with anti-corrosion function as claimed in claim 1, is characterized in that, described impregnating fluid, and preferably, meter is as follows by weight:
77 parts of phenmethylols
32 parts, acrylic acid
18 parts of ethylenediamine tetra-acetic acids
13 parts of vulcanizing agents.
4. a rubber gloves with anti-corrosion function, is characterized in that described rubber-based adhesive is one or more in acrylonitrile-butadiene rubber, natural rubber, fluorubber, silicon rubber, polyurethane rubber.
5. a kind of rubber gloves with anti-corrosion function as claimed in claim 1, is characterized in that, preferably, described rubber-based adhesive is the mixture of acrylonitrile-butadiene rubber and natural rubber, acrylonitrile-butadiene rubber: natural rubber is 68:35, by weight meter.
6. a kind of rubber gloves with anti-corrosion function as claimed in claim 1, is characterized in that, the ratio of described rubber-based adhesive and impregnating fluid is 95:15, by weight meter.
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CN201310557646.5A CN103549687A (en) | 2013-11-11 | 2013-11-11 | Rubber gloves with corrosion resisting function and preparation method thereof |
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Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104530505A (en) * | 2014-10-30 | 2015-04-22 | 镇江苏惠乳胶制品有限公司 | Rubber gloves capable of preventing ultraviolet and preparation method thereof |
CN107522989A (en) * | 2017-09-29 | 2017-12-29 | 王迅 | A kind of industrial antisepsis rubber gloves |
CN108250471A (en) * | 2017-12-31 | 2018-07-06 | 镇江华扬乳胶制品有限公司 | A kind of degradation environment protection rubber gloves and preparation method thereof |
Citations (8)
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FR92518E (en) * | 1967-04-26 | 1968-11-22 | Manuf Nationale Du Caoutchouc | Protective glove |
CN1352593A (en) * | 1997-10-20 | 2002-06-05 | 生物屏障公司 | Method for forming latex or polymer membrane, including multiple discrete layers |
CN1698485A (en) * | 2005-06-09 | 2005-11-23 | 徐国清 | Two-color emulsion glove and making method thereof |
WO2009156811A1 (en) * | 2008-06-25 | 2009-12-30 | Lesavoy Malcolm A | Sterile surgical glove engaged with abrasive cleaning pad for use in surgery |
CN102113718A (en) * | 2010-12-29 | 2011-07-06 | 俞清秀 | Fluorine/butadiene rubber composite glove and manufacturing method thereof |
CN102414021A (en) * | 2009-04-23 | 2012-04-11 | 纳幕尔杜邦公司 | Selectively permeable protective structure and articles therefrom |
CN102488340A (en) * | 2011-11-29 | 2012-06-13 | 镇江苏惠乳胶制品有限公司 | Antiskid rubber gloves and processing method thereof |
CN103384707A (en) * | 2010-11-19 | 2013-11-06 | Isp投资公司 | A stable and aqueous concentrated preservative composition of dehydroacetic acid (DHA) and methylisothiazolinone (MIT) |
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2013
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Patent Citations (8)
Publication number | Priority date | Publication date | Assignee | Title |
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FR92518E (en) * | 1967-04-26 | 1968-11-22 | Manuf Nationale Du Caoutchouc | Protective glove |
CN1352593A (en) * | 1997-10-20 | 2002-06-05 | 生物屏障公司 | Method for forming latex or polymer membrane, including multiple discrete layers |
CN1698485A (en) * | 2005-06-09 | 2005-11-23 | 徐国清 | Two-color emulsion glove and making method thereof |
WO2009156811A1 (en) * | 2008-06-25 | 2009-12-30 | Lesavoy Malcolm A | Sterile surgical glove engaged with abrasive cleaning pad for use in surgery |
CN102414021A (en) * | 2009-04-23 | 2012-04-11 | 纳幕尔杜邦公司 | Selectively permeable protective structure and articles therefrom |
CN103384707A (en) * | 2010-11-19 | 2013-11-06 | Isp投资公司 | A stable and aqueous concentrated preservative composition of dehydroacetic acid (DHA) and methylisothiazolinone (MIT) |
CN102113718A (en) * | 2010-12-29 | 2011-07-06 | 俞清秀 | Fluorine/butadiene rubber composite glove and manufacturing method thereof |
CN102488340A (en) * | 2011-11-29 | 2012-06-13 | 镇江苏惠乳胶制品有限公司 | Antiskid rubber gloves and processing method thereof |
Non-Patent Citations (1)
Title |
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聂恒凯主编: "《橡胶材料与配方》", 30 June 2009, pages: 255 * |
Cited By (3)
Publication number | Priority date | Publication date | Assignee | Title |
---|---|---|---|---|
CN104530505A (en) * | 2014-10-30 | 2015-04-22 | 镇江苏惠乳胶制品有限公司 | Rubber gloves capable of preventing ultraviolet and preparation method thereof |
CN107522989A (en) * | 2017-09-29 | 2017-12-29 | 王迅 | A kind of industrial antisepsis rubber gloves |
CN108250471A (en) * | 2017-12-31 | 2018-07-06 | 镇江华扬乳胶制品有限公司 | A kind of degradation environment protection rubber gloves and preparation method thereof |
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Application publication date: 20140205 |