CN103548865A - Bird repellent composition, liquid preparations and preparation method thereof - Google Patents
Bird repellent composition, liquid preparations and preparation method thereof Download PDFInfo
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- CN103548865A CN103548865A CN201210307327.4A CN201210307327A CN103548865A CN 103548865 A CN103548865 A CN 103548865A CN 201210307327 A CN201210307327 A CN 201210307327A CN 103548865 A CN103548865 A CN 103548865A
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Abstract
The present invention relates to a bird repellent, specifically to a bird repellent composition, a microemulsion, a microcapsule suspending emulsion, and a preparation method thereof. The biological factor-rich perfume comprises three or four materials selected from 10-60% by weight of methyl anthranilate, 5-6% by weight of nerol, 0.5-1.5% by weight of ethyl cinnamate, 0.1-0.2% by weight of cinnamic aldehyde, and 22-28% by weight of cinnamamide. According to the present invention, water is adopted as a dispersing phase and gelatin and arabic gum are adopted as slow-release carrier capsule wall materials under effects of a plurality of auxiliary agents to prepare the bird repellent microemulsion and the bird repellent microcapsule suspending agent. According to the prepared liquid preparation product, birds can be effectively expelled under the premise of no harm on birds, the environmental protection characteristic is provided during use and a production process, and the product belongs to the real biological preparation harmless bird repellent product.
Description
Technical field
The present invention relates to a kind of birds repellant, relate in particular to a kind of bird driving composition, its microemulsion and microcapsules suspension emulsion and preparation method thereof.
Background technology
In recent years, due to the enforcement of country's conceding the land to forestry policy, the improvement of natural environment and the people enhancing to bird preservation consciousness, increases birds, and orchard and field crop bird pest are serious, and the facilities such as airport, electric power are also deeply hurt.At present domesticly claim that the producer that produces nontoxic biologic product type birds repellant also emerges in an endless stream, production scale is all less, probably has family more than 30.Make a general survey of the bird driving composition of these producers, formulation and preparation method, substantially be to copy < < bird driving composition and the colloid mixture thereof that the inventor writes for 2008, the preparation of colloidal suspending agent and preparation method thereof > > patent specification, in view of inventing at that time the experiment condition restriction of this birds repellant, study not enough with the spices that is rich in biotic factor to driving bird active ingredient composition, the effect on driving birds of product is unsatisfactory, and preparation technology's employing is chemical method, can not be at last environment protection biological formulation products truly.
Summary of the invention
The object of the invention is to the deficiency existing in existing birds repellant product and preparation method, new a kind of bird driving composition and liquid preparation thereof and preparation method thereof are provided.
The technical solution adopted in the present invention is:
A kind of bird driving composition, contain the spices that is rich in biotic factor, in total weight percent, comprise following component: in methyl anthranilate 10%～60%, nerol 5%～6%, ethyl cinnamate 0.5%～1.5%, cinnamic acid 0.1%～0.2%, cinnamamide 22%～28% three kinds or four kinds; All the other are water, capsule material and auxiliary agent.
Drive bird microemulsion, in total weight percent, methyl anthranilate 50%～60%, nerol 5%～10%, ethyl cinnamate 0.5%～1.0%.Water 5%～10%(does not adopt chemical solvent preparation method), auxiliary agent is sorbitan fatty acid ester APEO 10%～24.5%, neopelex 15%～20%.
Drive bird microemulsion, active constituent content is high, packing not, adopts the preparation that is mixed of water-based physical method, be beneficial to hang active ingredient in bottle use procedure for a long time, high concentration volatilizees fast.
Drive bird microemulsion preparation method, comprise the following steps:
(1), by component ratio, will drive bird spices mix and blend, be heated to 65 ± 3 ℃ of dissolvings;
(2), press component ratio by water, auxiliary agent mixing and stirring;
(3), the spice mixt that in the mixture of step (2), step (1) made adds wherein, is uniformly mixed stablely, sampling, check, obtain finished product.
Drive bird microcapsules suspension emulsion, in total weight percent, methyl anthranilate 10%～15%, ethyl cinnamate 1.1%～1.5%, cinnamic acid 0.1%～0.2%, cinnamamide 20%～30%.Slow-released carrier capsule material is gelatin 0.5%～1% and arabia gum glue 0.5%～1%; Emulsifier is sorbitan fatty acid ester APEO 2%～3%, neopelex 2%～3%; Stabilizing agent is sodium carboxymethylcellulose 0.1%～0.2%; Anti-settling agent is lithium magnesium silicate 0.7%～1.0% and aluminium-magnesium silicate 0.7%～1.0%; Preservative is Sodium Benzoate 0.2%～0.5%; Acidity-basicity regulator is appropriate citric acid; Dispersant is sodium phosphate trimer 0.5%～1%; Micro capsule curing agent is aminotransferase 0.2%～0.3%; Antifreeze is glycerine 2%～3%; Disperse phase is that water 40%～50%(does not adopt chemical solvent preparation method).
In addition, drive and in bird microcapsules suspension emulsion, be also added with the flavor enhancement capsaicine 0.5%～2.5% that is rich in biotic factor in total weight percent.
Drive bird microcapsules suspension emulsion, be liquid to be driven to bird spices be prepared into part microcapsules, drive bird solid spice and be prepared into suspending agent, the high concentration that is beneficial to spraying use procedure is slowly volatilized, and permanently effective release, be on market, to generally acknowledge the best birds repellant product of effect on driving birds now.
The preparation method who drives bird microcapsules suspension emulsion, comprises the following steps:
(1), by component ratio by driving bird spices, flavor enhancement mix and blend, be heated to 65 ± 3 ℃ of dissolvings except cinnamamide;
(2), by component ratio, slow-released carrier capsule material and acidity-basicity regulator are added to the water to high speed shear stirring and dissolving, mixed stability, and mix by high-shear emulsifying pump reflux;
(3) spice mixt, step (1) being made adds in the capsule material solution that step (2) makes, high speed shear stirs, and disperse pump reflux to make micro-capsule by high shear, Water-cooling circulating is down to feed liquid room temperature, add again preservative and dispersant and micro capsule curing agent, low speed is opened shear agitation, makes microcapsules be unlikely to sedimentation;
(4), by component ratio, water and anti-settling agent are uniformly mixed and make colloidal solution, then open high speed shear and stir and add spices cinnamamide to mix, by component ratio, add emulsifier, stabilizing agent and antifreeze, stir;
(5), microcapsules mixture that step (3) is made adds in the suspension that step (4) makes under high-speed stirred, opens macerator pump, grinds, homogeneous, check, obtains finished product.
Product prepared by the present invention, effective repellent birds under the prerequisite that does not injure birds, environmental protection while not only using, and production process environmental protection, belong to the harmless bird product that drives of biologic product truly.
Below with reference to embodiment, the present invention is described in detail.
Embodiment
embodiment 1
Drive bird microemulsion, preparation method's step is as follows:
(1), get methyl anthranilate 500g, nerol 60g, ethyl cinnamate 15g, in reactor, heating (65 ℃ of left and right of temperature control) is uniformly mixed, evenly, standby.
(2), get sorbitan fatty acid ester APEO 200g, neopelex 155g, water 70g, mixing and stirring in emulsifying kettle; Then the flavor compositions (1) being made adds wherein, opens high-speed stirred, and by high-shear emulsifying pump homogeneous (forming w/o type ME), sampling, check, obtain finished product.
embodiment 2
Drive bird microemulsion, preparation method's step is as follows:
(1), get methyl anthranilate 550g, nerol 55g, ethyl cinnamate 10g, in reactor, heating (65 ℃ of left and right of temperature control) is uniformly mixed, evenly, standby.
(2), get sorbitan fatty acid ester APEO 165g, neopelex 160g, water 60g, mixing and stirring in emulsifying kettle; Then the flavor compositions (1) being made adds wherein, opens high-speed stirred, and by high-shear emulsifying pump homogeneous (forming w/o type ME), sampling, check, obtain finished product.
embodiment 3
Drive bird microemulsion, preparation method's step is as follows:
(1), get methyl anthranilate 600g, nerol 50g, ethyl cinnamate 5g, in reactor, heating (65 ℃ of left and right of temperature control) is uniformly mixed, evenly, standby.
(2), get sorbitan fatty acid ester APEO 130g, neopelex 165g, water 50g, mixing and stirring in emulsifying kettle; Then the flavor compositions (1) being made adds wherein, opens high-speed stirred, and by high-shear emulsifying pump homogeneous (forming w/o type ME), sampling, check, obtain finished product.
embodiment 4
Drive bird microcapsules suspension emulsion, preparation method's step is as follows:
(1), get methyl anthranilate 110g, ethyl cinnamate 11g, cinnamic acid 1g, capsaicine 10g, in reactor heating (65 ℃ of left and right of temperature control) be uniformly mixed, standby.
(2), water intaking 200g, open after high shear stirs, add successively gelatin 5g, arabia gum glue 5g to dissolve, then add citric acid appropriate, by high-shear emulsifying pump pump reflux, mix.
(3) spice mixt, step (1) being made adds in gelatin-arabia gum sol solution that step (2) makes, high speed shear stirs, and disperse pump reflux to make micro-capsule by high shear, Water-cooling circulating is down to feed liquid to room temperature, add again Sodium Benzoate 2g, sodium phosphate trimer 5g, aminotransferase 2g, low speed is opened shear agitation, makes generation curing microcapsules be unlikely to sedimentation.
(4), water intaking 288g, open after stirring at low speed, add lithium magnesium silicate 10g, aluminium-magnesium silicate 10g to make colloidal solution, opening high speed shear stirring adds cinnamamide 280g to mix again, add successively sorbitan fatty acid ester APEO 20g, neopelex 20g, glycerine 20g and sodium carboxymethylcellulose 1g, stir.
(5), microcapsules mixture that step (3) is made adds in the suspension that step (4) makes under high-speed stirred, open macerator pump reflux grind, homogeneous, check, obtains finished product.
embodiment 5
Drive bird microcapsules suspension emulsion, preparation method's step is as follows:
(1), get methyl anthranilate 125g, ethyl cinnamate 12.5g, cinnamic acid 1.5g, capsaicine 13g, in reactor heating (65 ℃ of left and right of temperature control) be uniformly mixed, standby.
(2), water intaking 200g, open after high shear stirs, add successively gelatin 7.5g, arabia gum glue 7.5g to dissolve, then add citric acid appropriate, by high-shear emulsifying pump pump reflux, mix.
(3) spice mixt, step (1) being made adds in gelatin-arabia gum sol solution that step (2) makes, high speed shear stirs, and disperse pump reflux to make micro-capsule by high shear, Water-cooling circulating is down to feed liquid to room temperature, add again Sodium Benzoate 3g, sodium phosphate trimer 6g, aminotransferase 2.5g, low speed is opened shear agitation, makes generation curing microcapsules be unlikely to sedimentation.
(4), water intaking 273g, open after stirring at low speed, add lithium magnesium silicate 9g, aluminium-magnesium silicate 9g to make colloidal solution, opening high speed shear stirring adds cinnamamide 250g to mix again, add successively sorbitan fatty acid ester APEO 25g, neopelex 25g, glycerine 25g and sodium carboxymethylcellulose 1.5g, stir.
(5), microcapsules mixture that step (3) is made adds in the suspension that step (4) makes under high-speed stirred, open macerator pump reflux grind, homogeneous, check, obtains finished product.
embodiment 6
Drive bird microcapsules suspension emulsion, preparation method's step is as follows:
(1), get methyl anthranilate 150g, ethyl cinnamate 15g, cinnamic acid 2g, capsaicine 15g, in reactor heating (65 ℃ of left and right of temperature control) be uniformly mixed, standby.
(2), water intaking 200g, open after high shear stirs, add successively gelatin 10g, arabia gum glue 10g to dissolve, then add citric acid appropriate, by high-shear emulsifying pump pump reflux, mix.
(3) spice mixt, step (1) being made adds in gelatin-arabia gum sol solution that step (2) makes, high speed shear stirs, and disperse pump reflux to make micro-capsule by high shear, Water-cooling circulating is down to feed liquid to room temperature, add again Sodium Benzoate 4g, sodium phosphate trimer 7g, aminotransferase 3g, low speed is opened shear agitation, makes generation curing microcapsules be unlikely to sedimentation.
(4), water intaking 258g, open after stirring at low speed, add lithium magnesium silicate 7g, aluminium-magnesium silicate 7g to make colloidal solution, opening high speed shear stirring adds cinnamamide 220g to mix again, add successively sorbitan fatty acid ester APEO 30g, neopelex 30g, glycerine 30g and sodium carboxymethylcellulose 2g, stir.
(5), microcapsules mixture that step (3) is made adds in the suspension that step (4) makes under high-speed stirred, open macerator pump reflux grind, homogeneous, check, obtains finished product.
Above content is only made for the present invention giving an example and explanation; affiliated those skilled in the art make various modifications to described specific embodiment or supplement or adopt similar mode to substitute; only otherwise depart from the design of invention or surmount this scope as defined in the claims, all should belong to protection scope of the present invention.
Claims (6)
1. a bird driving composition, contain the spices that is rich in biotic factor, in total weight percent, comprise following component: in methyl anthranilate 10%～60%, nerol 5%～6%, ethyl cinnamate 0.5%～1.5%, cinnamic acid 0.1%～0.2%, cinnamamide 22%～28% three kinds or four kinds; All the other are water, capsule material and auxiliary agent.
2. the microemulsion that adopts claim 1 bird driving composition to make, is characterized in that, in total weight percent, and described methyl anthranilate 50%～60%, described nerol 5%～10%, described ethyl cinnamate 0.5%～1.0%;
Described water 5%～10%, described auxiliary agent is sorbitan fatty acid ester APEO 10%～24.5%, neopelex 15%～20%.
3. the microcapsules suspension emulsion that adopts claim 1 bird driving composition to make, it is characterized in that, in total weight percent, described methyl anthranilate is 10%～15%, described ethyl cinnamate 1.1%～1.5%, described cinnamic acid 0.1%～0.2%, described cinnamamide 20%～30%;
Described slow-released carrier capsule material is gelatin 0.5%～1% and arabia gum glue 0.5%～1%; Described emulsifier is sorbitan fatty acid ester APEO 2%～3%, neopelex 2%～3%; Described stabilizing agent is sodium carboxymethylcellulose 0.1%～0.2%; Described anti-settling agent is lithium magnesium silicate 0.7%～1.0% and aluminium-magnesium silicate 0.7%～1.0%; Described preservative is Sodium Benzoate 0.2%～0.5%; Described acidity-basicity regulator is appropriate citric acid; Described dispersant is sodium phosphate trimer 0.5%～1%; Described micro capsule curing agent is aminotransferase 0.2%～0.3%; Described antifreeze is glycerine 2%～3%; Described disperse phase is water 40%～50%.
4. microcapsules suspension emulsion as claimed in claim 3, is characterized in that, is also added with the flavor enhancement capsaicine 0.5%～2.5% that is rich in biotic factor in total weight percent.
5. a method of preparing microemulsion described in claim 2, is characterized in that, comprises the following steps:
(1), by component ratio, will drive bird spices mix and blend, be heated to 65 ± 3 ℃ of dissolvings;
(2), press component ratio by water, auxiliary agent mixing and stirring;
(3), the spice mixt that in the mixture of step (2), step (1) made adds wherein, is uniformly mixed stablely, sampling, check, obtain finished product.
6. a method of preparing microcapsules suspension emulsion described in claim 4, is characterized in that, comprises the following steps:
(1), by component ratio by driving bird spices, flavor enhancement mix and blend, be heated to 65 ± 3 ℃ of dissolvings except cinnamamide;
(2), by component ratio, slow-released carrier capsule material and acidity-basicity regulator are added to the water to high speed shear stirring and dissolving, mixed stability, and mix by high-shear emulsifying pump reflux;
(3) spice mixt, step (1) being made adds in the capsule material solution that step (2) makes, high speed shear stirs, and disperse pump reflux to make micro-capsule by high shear, Water-cooling circulating is down to feed liquid room temperature, add again preservative and dispersant and micro capsule curing agent, low speed is opened shear agitation, makes microcapsules be unlikely to sedimentation;
(4), by component ratio, water and anti-settling agent are uniformly mixed and make colloidal solution, then open high speed shear and stir and add spices cinnamamide to mix, by component ratio, add emulsifier, stabilizing agent and antifreeze, stir;
(5), microcapsules mixture that step (3) is made adds in the suspension that step (4) makes under high-speed stirred, opens macerator pump, grinds, homogeneous, check, obtains finished product.
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| CN201210307327.4A CN103548865A (en) | 2012-08-27 | 2012-08-27 | Bird repellent composition, liquid preparations and preparation method thereof |
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| CN201210307327.4A CN103548865A (en) | 2012-08-27 | 2012-08-27 | Bird repellent composition, liquid preparations and preparation method thereof |
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Cited By (10)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104824031A (en) * | 2014-02-11 | 2015-08-12 | 吕夫成 | Pollution-free bird-dispelling seed-dressing agent and preparation method thereof |
| CN106047482A (en) * | 2016-06-06 | 2016-10-26 | 南通伟德动力电池研究所（普通合伙） | Preparation method of fragrance microcapsules for dispelling birds |
| CN107114364A (en) * | 2017-06-19 | 2017-09-01 | 邾溪生 | A kind of birds repellent special aerosol and preparation method thereof |
| CN108124912A (en) * | 2018-02-10 | 2018-06-08 | 王鹏飞 | A kind of bird driving composition and preparation method thereof |
| CN109169658A (en) * | 2018-08-29 | 2019-01-11 | 西安高科理化技术有限责任公司 | A kind of gel-type sustained release bird repellent and preparation method thereof |
| CN110495453A (en) * | 2018-05-19 | 2019-11-26 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of rat destruction drives rabbit agent and its application method |
| CN112056314A (en) * | 2020-09-25 | 2020-12-11 | 纽想科技(上海)有限公司 | Bird-repelling preparation and production equipment thereof |
| CN112167247A (en) * | 2020-11-13 | 2021-01-05 | 博德锐普(南京)科技有限公司 | Microcapsule bird-repelling insect-repellent agent, slow-release liquid bird-repelling insect-repellent agent and preparation method thereof |
| CN114467941A (en) * | 2020-11-13 | 2022-05-13 | 博德锐普(南京)科技有限公司 | Slow-release solid bird-repelling insect-repellent and preparation method thereof |
| CN115200420A (en) * | 2022-07-22 | 2022-10-18 | 萍乡市金坪烟花制造有限公司 | Environment-friendly airport high-altitude bird-repelling bomb and preparation method thereof |
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Cited By (11)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104824031A (en) * | 2014-02-11 | 2015-08-12 | 吕夫成 | Pollution-free bird-dispelling seed-dressing agent and preparation method thereof |
| CN106047482A (en) * | 2016-06-06 | 2016-10-26 | 南通伟德动力电池研究所（普通合伙） | Preparation method of fragrance microcapsules for dispelling birds |
| CN107114364A (en) * | 2017-06-19 | 2017-09-01 | 邾溪生 | A kind of birds repellent special aerosol and preparation method thereof |
| CN108124912A (en) * | 2018-02-10 | 2018-06-08 | 王鹏飞 | A kind of bird driving composition and preparation method thereof |
| CN110495453A (en) * | 2018-05-19 | 2019-11-26 | 安徽省农业科学院植物保护与农产品质量安全研究所 | A kind of rat destruction drives rabbit agent and its application method |
| CN109169658A (en) * | 2018-08-29 | 2019-01-11 | 西安高科理化技术有限责任公司 | A kind of gel-type sustained release bird repellent and preparation method thereof |
| CN112056314A (en) * | 2020-09-25 | 2020-12-11 | 纽想科技(上海)有限公司 | Bird-repelling preparation and production equipment thereof |
| CN112167247A (en) * | 2020-11-13 | 2021-01-05 | 博德锐普(南京)科技有限公司 | Microcapsule bird-repelling insect-repellent agent, slow-release liquid bird-repelling insect-repellent agent and preparation method thereof |
| CN114467941A (en) * | 2020-11-13 | 2022-05-13 | 博德锐普(南京)科技有限公司 | Slow-release solid bird-repelling insect-repellent and preparation method thereof |
| CN115200420A (en) * | 2022-07-22 | 2022-10-18 | 萍乡市金坪烟花制造有限公司 | Environment-friendly airport high-altitude bird-repelling bomb and preparation method thereof |
| CN115200420B (en) * | 2022-07-22 | 2023-09-01 | 萍乡市金坪烟花制造有限公司 | Environment-friendly airport high-altitude bird-expelling bomb and preparation method thereof |
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