CN103538408B - A kind of frosting corrosion typography of glass - Google Patents
A kind of frosting corrosion typography of glass Download PDFInfo
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- CN103538408B CN103538408B CN201310489980.1A CN201310489980A CN103538408B CN 103538408 B CN103538408 B CN 103538408B CN 201310489980 A CN201310489980 A CN 201310489980A CN 103538408 B CN103538408 B CN 103538408B
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- 239000011521 glass Substances 0.000 title claims abstract description 95
- 230000007797 corrosion Effects 0.000 title claims abstract description 19
- 238000005260 corrosion Methods 0.000 title claims abstract description 19
- 238000007639 printing Methods 0.000 claims abstract description 94
- 238000004140 cleaning Methods 0.000 claims abstract description 37
- 238000000034 method Methods 0.000 claims abstract description 23
- 239000002761 deinking Substances 0.000 claims abstract 3
- 229920002120 photoresistant polymer Polymers 0.000 claims description 30
- 230000002000 scavenging effect Effects 0.000 claims description 26
- 238000005498 polishing Methods 0.000 claims description 20
- 239000012530 fluid Substances 0.000 claims description 19
- 239000007788 liquid Substances 0.000 claims description 18
- 239000003795 chemical substances by application Substances 0.000 claims description 14
- 239000002994 raw material Substances 0.000 claims description 14
- WCUXLLCKKVVCTQ-UHFFFAOYSA-M Potassium chloride Chemical compound [Cl-].[K+] WCUXLLCKKVVCTQ-UHFFFAOYSA-M 0.000 claims description 12
- 159000000013 aluminium salts Chemical class 0.000 claims description 12
- 229910000329 aluminium sulfate Inorganic materials 0.000 claims description 12
- 239000001103 potassium chloride Substances 0.000 claims description 12
- 235000011164 potassium chloride Nutrition 0.000 claims description 12
- 238000005530 etching Methods 0.000 claims description 8
- 238000007650 screen-printing Methods 0.000 claims description 8
- 239000002253 acid Substances 0.000 claims description 7
- NLXLAEXVIDQMFP-UHFFFAOYSA-N Ammonia chloride Chemical compound [NH4+].[Cl-] NLXLAEXVIDQMFP-UHFFFAOYSA-N 0.000 claims description 6
- OYPRJOBELJOOCE-UHFFFAOYSA-N Calcium Chemical compound [Ca] OYPRJOBELJOOCE-UHFFFAOYSA-N 0.000 claims description 6
- QAOWNCQODCNURD-UHFFFAOYSA-L Sulfate Chemical compound [O-]S([O-])(=O)=O QAOWNCQODCNURD-UHFFFAOYSA-L 0.000 claims description 6
- 229940095054 ammoniac Drugs 0.000 claims description 6
- 239000011575 calcium Substances 0.000 claims description 6
- 229910052791 calcium Inorganic materials 0.000 claims description 6
- 238000007654 immersion Methods 0.000 claims description 6
- 239000000463 material Substances 0.000 claims description 4
- BQCADISMDOOEFD-UHFFFAOYSA-N Silver Chemical compound [Ag] BQCADISMDOOEFD-UHFFFAOYSA-N 0.000 claims description 3
- 239000004332 silver Substances 0.000 claims description 3
- 229910052709 silver Inorganic materials 0.000 claims description 3
- 239000003963 antioxidant agent Substances 0.000 claims description 2
- 230000003078 antioxidant effect Effects 0.000 claims description 2
- 235000006708 antioxidants Nutrition 0.000 claims description 2
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 claims description 2
- 238000007747 plating Methods 0.000 claims 3
- 239000003513 alkali Substances 0.000 claims 1
- 238000000576 coating method Methods 0.000 claims 1
- 238000011010 flushing procedure Methods 0.000 claims 1
- 230000035807 sensation Effects 0.000 abstract description 6
- 238000003754 machining Methods 0.000 abstract description 5
- 235000011266 Passiflora quadrangularis Nutrition 0.000 description 21
- 244000179684 Passiflora quadrangularis Species 0.000 description 21
- 230000000694 effects Effects 0.000 description 4
- 238000004519 manufacturing process Methods 0.000 description 4
- HEMHJVSKTPXQMS-UHFFFAOYSA-M Sodium hydroxide Chemical compound [OH-].[Na+] HEMHJVSKTPXQMS-UHFFFAOYSA-M 0.000 description 3
- 229910000831 Steel Inorganic materials 0.000 description 3
- 238000009472 formulation Methods 0.000 description 3
- 239000000203 mixture Substances 0.000 description 3
- 239000010959 steel Substances 0.000 description 3
- KRHYYFGTRYWZRS-UHFFFAOYSA-N Fluorane Chemical compound F KRHYYFGTRYWZRS-UHFFFAOYSA-N 0.000 description 2
- VEXZGXHMUGYJMC-UHFFFAOYSA-N Hydrochloric acid Chemical compound Cl VEXZGXHMUGYJMC-UHFFFAOYSA-N 0.000 description 2
- 239000004576 sand Substances 0.000 description 2
- HBMJWWWQQXIZIP-UHFFFAOYSA-N silicon carbide Chemical compound [Si+]#[C-] HBMJWWWQQXIZIP-UHFFFAOYSA-N 0.000 description 2
- 229910010271 silicon carbide Inorganic materials 0.000 description 2
- 241000237502 Ostreidae Species 0.000 description 1
- 230000009286 beneficial effect Effects 0.000 description 1
- 230000007812 deficiency Effects 0.000 description 1
- 230000001804 emulsifying effect Effects 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 230000001788 irregular Effects 0.000 description 1
- 235000020636 oyster Nutrition 0.000 description 1
- 239000002245 particle Substances 0.000 description 1
- 239000004033 plastic Substances 0.000 description 1
- 229920003023 plastic Polymers 0.000 description 1
- 239000013049 sediment Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 239000000725 suspension Substances 0.000 description 1
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- Surface Treatment Of Glass (AREA)
- Inks, Pencil-Leads, Or Crayons (AREA)
Abstract
The present invention relates to glass working arts field, particularly relate to a kind of frosting corrosion typography of glass, comprise following procedure of processing: steps A, one-step print; Step B, once to clean; Step C, frosting corrode; Step D, plain edge; Step e, deinking; Step F, secondary cleaning; Step G, secondary printing; Step H, three printings.It is high that the present invention has working (machining) efficiency, and pattern can be made to present protruding stereoscopic sensation and gradation sense, and without the advantage that finger mark remains.
Description
Technical field
The present invention relates to glass working arts field, particularly relate to a kind of frosting corrosion typography of glass.
Background technology
The glass with craft pattern of deep processing in the market mainly contains two large classes: one is be ejected on glass with air compressor machine spray gun by silicon carbide, pattern plastics posting in time on glass is cut out and is formed, the part that silicon carbide is cut out without posting in time, just define the pattern be sunken, its pattern is coarse, and edge is irregular, yields poorly, time-consuming, effect is bad.Another kind of figured plate glass-the emulsifying glass being chemical acid etching method and producing, although it defines pattern on glass, pattern is without the stereoscopic sensation of projection and gradation sense, of low grade, weak effect.
Chinese Patent Application No. is the patent of invention of 200710035643.X, discloses a kind of production method of non-print glass, but this production method exists following shortcoming: one is, this production method is only cut glass for sand or beautiful sand glass, and the scope of application is little.Two are, etching process is for up to 20-30 minute, and etching time is long, and working (machining) efficiency is low.Three are, sodium hydroxide solution soak time reaches 17-23 minute, and soak time is long, and working (machining) efficiency reduces further.Four are, the pattern on the glass that this production method obtains cannot demonstrate protruding stereoscopic sensation and gradation sense, and obtained glass surface is without frosting effect, and decorative effect is undesirable.
Therefore, need badly in the market and provide a kind of working (machining) efficiency high, pattern can be made to present protruding stereoscopic sensation and gradation sense, and remain without finger mark, the glass corrosion typography that result of use is good.
Summary of the invention
The object of the invention is to for the deficiencies in the prior art, a kind of frosting corrosion typography of glass is provided, there is working (machining) efficiency high, pattern can be made to present protruding stereoscopic sensation and gradation sense, and without the advantage that finger mark remains.
The present invention is achieved through the following technical solutions.
A frosting corrosion typography for glass, comprises following procedure of processing:
Steps A, one-step print: first as requested flat glass sawing sheet is processed into required specification, and make glass shape molding by punching, rounding process, then the planar transparent glass put in order is carried out corrosion-resistanting ink printing.
Step B, once cleaning: carry out surface cleaning to the glass after one-step print by ultrasonic wave with scavenging solution, remove glass surface finger mark, spot; By ultrasonic cleaning, scavenging period is short, and flush time is 1 ~ 5 minute, and cleaning performance is good, shortens process period.Described scavenging solution is glass cleaning solution, and the raw material of this glass cleaning solution and the weight percent of each raw material are: hydrofluoric acid 10-20%, hydrochloric acid 5-10%, and surplus is water.
Step C, frosting corrode: corrode corrosion-resistanting ink unwanted on glass with frosting corrosive fluid, remove excess ink, and form patterned layer, process period is 3 ~ 10 minutes; Make the surface of glass form frosting effect, promote the feel of glass.
Step D, plain edge: carry out plain edge processing to glass circumferential side frame with the machine of clearing off, make glass circumferential side frame smooth surface; After plain edge process, the circumferential side frame surface smoothness of glass is high, and has certain surface gloss concurrently, and inside glass then has frosting effect, is conducive to the added value of improving product.
Step e, deinking: remove corrosion-resistanting ink residual on glass with strong alkali solution, process period is 1 ~ 5 minute; Described strong alkali solution is the sodium hydroxide solution that the concentration of Dongguan Dongjiang chemical reagent company limited production is not less than 99.5%.
Step F, secondary cleaning: carry out surface cleaning flushing to the glass after deinking with clear water, flush time is 1 ~ 5 minute, and the corrosion-resistanting ink making glass surface residual rinses to be removed, and guarantees that glass surface cleans.
Step G, secondary printing: carry out silk-screen ink printing with the silk screen of pre-designed pattern, form pattern ink layer; The printing of ink makes pattern displaying on glass out, and make pattern present protruding stereoscopic sensation and gradation sense, processing effect is good.
Step H, three printings: carry out protection ink printing with the silk screen of pre-designed pattern, make pattern ink layer outside surface cover a protection ink layer, prevent pattern ink layer oxidized, improve printing quality.
Wherein, between described step G and step H, also vacuum plating is included; Carry out vacuum plating with vacuum plating unit, make the glass surface after secondary printing form coatings.This coatings can be chromium coating, aluminium coated, plating AF layer or plating Ar layer.
Wherein, step I, three cleanings is also included after described step H: carry out surface cleaning to the glass after three printings by ultrasonic wave with scavenging solution, scavenging period is 1 ~ 3 minute.Ultrasonic cleaning is short for process period, effectively can remove the ink that glass surface is residual, guarantees that glass surface cleans.Described scavenging solution is glass cleaning solution, and the raw material of this glass cleaning solution and the weight percent of each raw material are: hydrofluoric acid 5-10%, hydrochloric acid 5-15%, and surplus is water.
Wherein, described steps A, one-step print, be specially: first carry out the first corrosion-resistanting ink printing and the second corrosion-resistanting ink printing respectively to the front of glass with silk screen; Then, with silk screen, the 3rd corrosion-resistanting ink printing and the 4th corrosion-resistanting ink printing are carried out respectively to the back side of glass.
Wherein, the storing temperature of described first corrosion-resistanting ink printing is 100 ± 10 DEG C, and baking time is 10 ± 2min, and obtained ink thickness is 6-10nm; The storing temperature of the second corrosion-resistanting ink printing is 100 ± 10 DEG C, and baking time is 30 ± 5min, and obtained ink thickness is 10-15 μm; The storing temperature of the 3rd corrosion-resistanting ink printing is 100 ± 10 DEG C, and baking time is 10 ± 2min, obtained ink thickness is 6-10 μm; The storing temperature of the 4th corrosion-resistanting ink printing is 100 ± 10 DEG C, and baking time is 30 ± 5min, and obtained ink thickness is < 15 μm.The grenadine order number of described first corrosion-resistanting ink printing is 450 ~ 500 orders, first corrosion-resistanting ink printing adopts the silk screen printing of woven wire roller, the grenadine order number of the second corrosion-resistanting ink printing is 300 ~ 350 orders, and the grenadine order number of the 3rd corrosion-resistanting ink printing, the 4th corrosion-resistanting ink printing is 250 ~ 300 orders.
Particularly, the ink formulations adopted in above-mentioned four corrosion-resistanting ink printings is: the ink that the model of six rich peaceful products is the black ink of JX-2005, the model of six rich peaceful products is 1900 solidifying agent, the ratio of the model of six rich peaceful products to be 1800 thinners with weight part ratio be 100:1:3 is mixed, wherein, the concentration of solidifying agent is 1%, and the concentration of thinner is 3%.
Wherein, the storing temperature of the first corrosion-resistanting ink is 100 ± 10 DEG C, and baking time is 10 ± 2min, and photoresists thickness, frictioning hardness are respectively 7 ± 1 μm, 85A, and obtained ink thickness is 6-10nm.The storing temperature of the second corrosion-resistanting ink is 100 ± 10 DEG C, and baking time is 30 ± 5min, and photoresists thickness, frictioning hardness are respectively 12 ± 1 μm, 85A, and obtained ink thickness is 10-15 μm.The storing temperature of the 3rd corrosion-resistanting ink is 100 ± 10 DEG C, and baking time is 10 ± 2min, and photoresists thickness, frictioning hardness are respectively 12 ± 1 μm, 85A, and obtained ink thickness is 6-10 μm.The storing temperature of the 4th corrosion-resistanting ink is 100 ± 10 DEG C, and baking time is 30 ± 5min, and photoresists thickness, frictioning hardness are respectively 12 ± 1 μm, 85A, and obtained ink thickness is < 15 μm.
Wherein, described step C, frosting corrode, and be specially: C1, precleaning, carry out surface cleaning with scavenging solution to glass, cleaning time is 1 ~ 3 minute; C2, frosting, put into frosted liquid immersion 1 ~ 5 minute by the glass after clean; C3, polishing, put into polishing fluid and soak 30 ~ 120 seconds by the glass after frosting process.Described scavenging solution is glass cleaning solution, and the raw material of this glass cleaning solution and the weight percent of each raw material are: hydrofluoric acid 5-15%, hydrochloric acid 5-15%, and surplus is water.
Wherein, described frosted liquid is made up of the raw material of following mass percent: fluorochemical 30-40%, calcium cpd 10-15%, sulfate of ammoniac 5-12%, ammonia chloride 3-10%, sylvite 2-5%, aluminium salt 3-10%, vitriol 2-8%, hydrochlorate 10-15%.
The frosting etching solution of frosted liquid of the present invention to be model that essence Er Mei glass material company limited of Foshan City produces be GDXX-KN2320.This frosted liquid is in a liquid state, microstimulation smell, and the subsidiary particle suspensions of oyster white, pH value is 2-3.
Wherein, described polishing fluid is made up of the raw material of following mass percent: vitriol 15-20%, fluorochemical 10-15%, sylvite 5-10%, aluminium salt 5-10%, acid solution 20-30%, water-soluble agents 30-35%.
The liquid of polishing fluid of the present invention to be model that essence Er Mei glass material company limited of Foshan City produces be GDXX-YPI throws etching solution, and the clear look of its color, irritating smell, the obvious particulate state sediment of shape band, pH value is 1-2.
Wherein, described step G, secondary printing, be specially and adopt ink to carry out five silk screen printings successively, the first impression adopts mirror-like silver ink, storing temperature is 150 ± 10 DEG C, and baking time is 10 ± 1min, and photoresists thickness, frictioning hardness are respectively 7 ± 1 μm, 85A; The second impression adopts white ink, and storing temperature is 150 ± 10 DEG C, and baking time is 10 ± 1min, and photoresists thickness, frictioning hardness are respectively 15 ± 1 μm, 85A, and ink thickness is 7-10 μm; The third printing adopts white ink, and storing temperature is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 18 ± 1 μm, 75A, and ink thickness is 16-20 μm; 4th printing adopts white ink, and storing temperature is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 18 ± 1 μm, 75A, and ink thickness is 23-26 μm; 5th printing adopts ash end ink, and storing temperature is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 5 ± 1 μm, 75A, and ink thickness is 26-32 μm.
The grenadine order number of the first impression is 400 ~ 500 orders, the grenadine order number of the second impression is 300 ~ 350 orders, the grenadine order number of the third printing is 250 ~ 300 orders, and the grenadine order number of the 4th printing is 250 ~ 300 orders, and the grenadine order number of the 5th printing is 300 ~ 350 orders.
Particularly, the ink that model that Yin great waves are produced that what the described first impression adopted is is the mirror-like silver ink of MK-6000A, the ratio of model to be MK-120 and PEF-103/H with weight percent be 100:6:3 is mixed.Its storing temperature of ink that the first impression is formed is 150 ± 10 DEG C, and baking time is 10 ± 1min, and photoresists thickness, frictioning hardness are respectively 7 ± 1 μm, 85A.
The ink that what the described second impression adopted is grants that color model of producing is EM-0208 white ink, model is AF-01A, the ratio of model to be AF-01B, EM-219 and EM-219/H with weight percent be 100:7:3:5:3-4 is mixed.Its storing temperature of ink that the second impression is formed is 150 ± 10 DEG C, and baking time is 10 ± 1min, and photoresists thickness, frictioning hardness are respectively 15 ± 1 μm, 85A, and ink thickness is 7-10 μm.
The ink that what the described third printing adopted is grants that color model of producing is EM-0208 white ink, model is AF-01A, the ratio of model to be AF-01B, EM-219 and EM-219/H with weight percent be 100:7:3:5:3-5 is mixed.Its storing temperature of ink that the third printing is formed is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 18 ± 1 μm, 75A, and ink thickness is 16-20 μm.
The ink that what described 4th printing adopted is grants that color model of producing is EM-0208 white ink, model is AF-01A, the ratio of model to be AF-01B, EM-219 and EM-219/H with weight percent be 100:7:3:5:3-5 is mixed.Its storing temperature of ink that 4th printing is formed is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 18 ± 1 μm, 75A, and ink thickness is 23-26 μm.
The ink that what described 5th printing adopted is grants that color model of producing is CX03-EM-0208 ash end ink, model is CX03-EM0041, EM-AF-01A, the ratio of model to be EM-AF-01B and EM-219 with weight percent be 45:0.3:7:3:5 is mixed.Its storing temperature of ink that 5th printing is formed is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 5 ± 1 μm, 75A, and ink thickness is 26-32 μm.
Wherein, described step H, three times printing, be specially employing once, twice or or five ink carry out silk screen printing, described protection ink is anti-oxidant ink.
Particularly; when adopting an ink to print in three typographies; described protection ink is the ink that the model that Yin great waves are produced is GSF-911 (H) black ink, TPE-105 solidifying agent and RJ-204 (B) thinner take weight percent as 100:1:5 ratio is mixed; wherein the concentration of solidifying agent is 10%, and the concentration of thinner is 5%.This ink adopts grenadine order number to be the silk screen printing of 400-450 object, and the storing temperature of ink layer is 150 ± 10 DEG C, and baking time is 30 ± 5min, and photoresists thickness, frictioning hardness are respectively 12 ± 1 μm, 85A, and ink thickness is 6-13 μm.
Particularly, when adopting secondary ink to print in three typographies, the ink that described ink is that the model of six rich peaceful products is the black ink of JX-2005, the model of six rich peaceful products is 1900 solidifying agent, the ratio of the model of six rich peaceful products to be 1800 thinners with weight part ratio be 100:1:3 is mixed, wherein, the concentration of solidifying agent is 1%, and the concentration of thinner is 3%.
First adopt order number to be that 450-500 object steel wire half tone prints in above-mentioned ink, storing temperature is 100 ± 5 DEG C, and baking time is 10 ± 1min, and photoresists thickness, frictioning hardness are respectively 7 ± 1 μm, 85A, and ink thickness is 6-10nm.Be that 300-350 object half tone prints with order number again, storing temperature is 100 ± 10 DEG C, and baking time is 10 ± 2min, and photoresists thickness, frictioning hardness are respectively 12 ± 1 μm, 85A, and ink thickness is 10-15nm.
Particularly, adopt or five ink when carrying out silk screen printing in three typographies, its ink formulations adopted and corresponding typography and parameter and the ink formulations that the secondary printing technique of step G adopts, typography parameter are identical.In three typographies, described solidifying agent, thinner are ink class solidifying agent, the ink class thinner that this area is commonly used.
Beneficial effect of the present invention is: glass frosting corrosion typography of the present invention, adopt and print for three times and the combination of frosting etching process, obtained glass surface glossiness is high, and the pattern on glass surface can present protruding stereoscopic sensation and gradation sense, and remains without finger mark.
Embodiment
Below in conjunction with embodiment, the present invention is further illustrated.
Embodiment 1.
A frosting corrosion typography for glass, comprises following procedure of processing:
Steps A, one-step print: first the first corrosion-resistanting ink printing and the second corrosion-resistanting ink printing are carried out respectively to the front of planar transparent glass; Then, the 3rd corrosion-resistanting ink printing and the 4th corrosion-resistanting ink printing are carried out respectively to the back side of planar transparent glass; The grenadine order number of described first corrosion-resistanting ink printing is 450 orders, first corrosion-resistanting ink printing adopts the silk screen printing of woven wire roller, the grenadine order number of the second corrosion-resistanting ink printing is 300 orders, and the grenadine order number of the 3rd corrosion-resistanting ink printing, the 4th corrosion-resistanting ink printing is 250 orders.
Step B, once cleaning: carry out surface cleaning to the glass after one-step print by ultrasonic wave with scavenging solution, remove glass surface finger mark, spot, scavenging period is 1 minute.
Step C, frosting corrode: corrode corrosion-resistanting ink unwanted on glass with frosting corrosive fluid, and form patterned layer, process period is 3 minutes; Frosting corrodes, and be specially: C1, precleaning, carry out surface cleaning with scavenging solution to glass, cleaning time is 1 minute; C2, frosting, put into frosted liquid immersion 5 minutes by the glass after clean; C3, polishing, put into polishing fluid and soak 30 seconds by the glass after frosting process.
Described frosted liquid is made up of the raw material of following mass percent: fluorochemical 30%, calcium cpd 15%, sulfate of ammoniac 12%, ammonia chloride 10%, sylvite 5%, aluminium salt 10%, vitriol 8%, hydrochlorate 10%.
Described polishing fluid is made up of the raw material of following mass percent: vitriol 15%, fluorochemical 10%, sylvite 5%, aluminium salt 10%, acid solution 30%, water-soluble agents 30%.
Step D, plain edge: carry out plain edge processing to glass circumferential side frame with the machine of clearing off, make glass circumferential side frame smooth surface.
Step e, deinking: remove corrosion-resistanting ink residual on glass with strong alkali solution, process period is 1 minute.
Step F, secondary cleaning: carry out surface cleaning flushing to the glass after deinking with clear water, flush time is 1 minute.
Step G, secondary printing: carry out silk-screen ink printing with the silk screen of pre-designed pattern, form pattern ink layer.
Secondary printing, be specially and adopt ink to carry out five silk screen printings successively, the first impression adopts 420 order nylon printings, the grenadine order number of the second impression is 300 orders, the grenadine order number of the third printing is 250 orders, the grenadine order number of the 4th printing is 250 orders, and the grenadine order number of the 5th printing is 300 orders.
Vacuum plating; Carry out vacuum plating with vacuum plating unit, make the glass surface after secondary printing form coatings.
Step H, three printings: carry out protection ink printing with the silk screen of pre-designed pattern, make pattern ink layer outside surface cover a protection ink layer.
Three printings, be specially employing ink and print, described protection ink is anti-oxidant ink.
Described protection ink is the ink that the model that Yin great waves are produced is GSF-911 (H) black ink, TPE-105 solidifying agent and RJ-204 (B) thinner take weight percent as 100:1:5 ratio is mixed; wherein the concentration of solidifying agent is 10%, and the concentration of thinner is 5%.This ink adopts grenadine order number to be the silk screen printing of 400-450 object, and the storing temperature of ink layer is 150 ± 10 DEG C, and baking time is 30 ± 5min, and photoresists thickness, frictioning hardness are respectively 12 ± 1 μm, 85A, and ink thickness is 6-13 μm.
Step I, three cleanings: carry out surface cleaning to the glass after three printings by ultrasonic wave with scavenging solution, scavenging period is 1 minute.
Embodiment 2.
A frosting corrosion typography for glass, comprises following procedure of processing:
Steps A, one-step print: first the first corrosion-resistanting ink printing and the second corrosion-resistanting ink printing are carried out respectively to the front of planar transparent glass; Then, the 3rd corrosion-resistanting ink printing and the 4th corrosion-resistanting ink printing are carried out respectively to the back side of planar transparent glass; The grenadine order number of described first corrosion-resistanting ink printing is 500 orders, and the grenadine order number of the second corrosion-resistanting ink printing is 320 orders, and the grenadine order number of the 3rd corrosion-resistanting ink printing, the 4th corrosion-resistanting ink printing is 300 orders.
Step B, once cleaning: carry out surface cleaning to the glass after one-step print by ultrasonic wave with scavenging solution, remove glass surface finger mark, spot, scavenging period is 2 minutes.
Step C, frosting corrode: corrode corrosion-resistanting ink unwanted on glass with frosting corrosive fluid, and form patterned layer, process period is 5 minutes; Frosting corrodes, and be specially: C1, precleaning, carry out surface cleaning with scavenging solution to glass, cleaning time is 2 minutes; C2, frosting, put into frosted liquid immersion 3 minutes by the glass after clean; C3, polishing, put into polishing fluid and soak 60 seconds by the glass after frosting process.
Described frosted liquid is made up of the raw material of following mass percent: fluorochemical 35%, calcium cpd 13%, sulfate of ammoniac 11%, ammonia chloride 7%, sylvite 4%, aluminium salt 8%, vitriol 7%, hydrochlorate 15%.
Described polishing fluid is made up of the raw material of following mass percent: vitriol 16%, fluorochemical 11%, sylvite 6%, aluminium salt 7%, acid solution 28%, water-soluble agents 32%.
Step D, plain edge: carry out plain edge processing to glass circumferential side frame with the machine of clearing off, make glass circumferential side frame smooth surface.
Step e, deinking: remove corrosion-resistanting ink residual on glass with strong alkali solution, process period is 2 minutes.
Step F, secondary cleaning: carry out surface cleaning flushing to the glass after deinking with clear water, flush time is 2 minutes.
Step G, secondary printing: carry out silk-screen ink printing with the silk screen of pre-designed pattern, form pattern ink layer.
Secondary printing, be specially and adopt ink to carry out five silk screen printings successively, the first impression adopts 450 nylon printings, the grenadine order number of the second impression is 350 orders, the grenadine order number of the third printing is 300 orders, the grenadine order number of the 4th printing is 260 orders, and the grenadine order number of the 5th printing is 320 orders.
Vacuum plating; Carry out vacuum plating with vacuum plating unit, make the glass surface after secondary printing form coatings.
Step H, three printings: carry out protection ink printing with the silk screen of pre-designed pattern, make pattern ink layer outside surface cover a protection ink layer.
Three printings, be specially employing twice ink and print, described protection ink is anti-oxidant ink.
When adopting secondary ink to print, the ink that described ink is that the model of six rich peaceful products is the black ink of JX-2005, the model of six rich peaceful products is 1900 solidifying agent, the ratio of the model of six rich peaceful products to be 1800 thinners with weight part ratio be 100:1:3 is mixed, wherein, the concentration of solidifying agent is 1%, and the concentration of thinner is 3%.
First adopt order number to be that 450 object steel wire half tones print in above-mentioned ink, storing temperature is 95 DEG C, and baking time is 11min, and photoresists thickness, frictioning hardness are respectively 7 ± 1 μm, 85A, and ink thickness is 10nm.Be that 350 object half tones print with order number again, storing temperature is 105 DEG C, and baking time is 8min, and photoresists thickness, frictioning hardness are respectively 12 ± 1 μm, 85A, and ink thickness is 15nm.
Step I, three cleanings: carry out surface cleaning to the glass after three printings by ultrasonic wave with scavenging solution, scavenging period is 2 minutes.
Embodiment 3.
A frosting corrosion typography for glass, comprises following procedure of processing:
Steps A, one-step print: first the first corrosion-resistanting ink printing and the second corrosion-resistanting ink printing are carried out respectively to the front of planar transparent glass; Then, the 3rd corrosion-resistanting ink printing and the 4th corrosion-resistanting ink printing are carried out respectively to the back side of planar transparent glass; The grenadine order number of described first corrosion-resistanting ink printing is 480 orders, and the grenadine order number of the second corrosion-resistanting ink printing is 330 orders, and the grenadine order number of the 3rd corrosion-resistanting ink printing, the 4th corrosion-resistanting ink printing is 250 orders.
Step B, once cleaning: carry out surface cleaning to the glass after one-step print by ultrasonic wave with scavenging solution, remove glass surface finger mark, spot, scavenging period is 2 minutes.
Step C, frosting corrode: corrode corrosion-resistanting ink unwanted on glass with frosting corrosive fluid, and form patterned layer, process period is 8 minutes; Frosting corrodes, and be specially: C1, precleaning, carry out surface cleaning with scavenging solution to glass, cleaning time is 2 minutes; C2, frosting, put into frosted liquid immersion 3 minutes by the glass after clean; C3, polishing, put into polishing fluid and soak 90 seconds by the glass after frosting process.
Described frosted liquid is made up of the raw material of following mass percent: fluorochemical 38%, calcium cpd 145%, sulfate of ammoniac 10%, ammonia chloride 9%, sylvite 3%, aluminium salt 7%, vitriol 6%, hydrochlorate 13%.
Described polishing fluid is made up of the raw material of following mass percent: vitriol 17%, fluorochemical 12%, sylvite 7%, aluminium salt 6%, acid solution 25%, water-soluble agents 33%.
Step D, plain edge: carry out plain edge processing to glass circumferential side frame with the machine of clearing off, make glass circumferential side frame smooth surface.
Step e, deinking: remove corrosion-resistanting ink residual on glass with strong alkali solution, process period is 3 minutes.
Step F, secondary cleaning: carry out surface cleaning flushing to the glass after deinking with clear water, flush time is 2 minutes.
Step G, secondary printing: carry out silk-screen ink printing with the silk screen of pre-designed pattern, form pattern ink layer.
Secondary printing, be specially and adopt ink to carry out five silk screen printings successively, the first impression adopts 420 nylon printings, the grenadine order number of the second impression is 350 orders, the grenadine order number of the third printing is 300 orders, the grenadine order number of the 4th printing is 280 orders, and the grenadine order number of the 5th printing is 350 orders.
Vacuum plating; Carry out vacuum plating with vacuum plating unit, make the glass surface after secondary printing form coatings.
Step H, three printings: carry out protection ink printing with the silk screen of pre-designed pattern, make pattern ink layer outside surface cover a protection ink layer.
Three printings, be specially employing twice ink and print, described protection ink is anti-oxidant ink.
When adopting secondary ink to print, the ink that described ink is that the model of six rich peaceful products is the black ink of JX-2005, the model of six rich peaceful products is 1900 solidifying agent, the ratio of the model of six rich peaceful products to be 1800 thinners with weight part ratio be 100:1:3 is mixed, wherein, the concentration of solidifying agent is 1%, and the concentration of thinner is 3%.
First adopt order number to be that 500 object steel wire half tones print in above-mentioned ink, storing temperature is 100 DEG C, and baking time is 10min, and photoresists thickness, frictioning hardness are respectively 7 ± 1 μm, 85A, and ink thickness is 6nm.Be that 300 object half tones print with order number again, storing temperature is 100 DEG C, and baking time is 10min, and photoresists thickness, frictioning hardness are respectively 12 ± 1 μm, 85A, and ink thickness is 10nm.
Step I, three cleanings: carry out surface cleaning to the glass after three printings by ultrasonic wave with scavenging solution, scavenging period is 2 minutes.
Embodiment 4.
A frosting corrosion typography for glass, comprises following procedure of processing:
Steps A, one-step print: first the first corrosion-resistanting ink printing and the second corrosion-resistanting ink printing are carried out respectively to the front of planar transparent glass; Then, the 3rd corrosion-resistanting ink printing and the 4th corrosion-resistanting ink printing are carried out respectively to the back side of planar transparent glass; The grenadine order number of described first corrosion-resistanting ink printing is 500 orders, and the grenadine order number of the second corrosion-resistanting ink printing is 350 orders, and the grenadine order number of the 3rd corrosion-resistanting ink printing, the 4th corrosion-resistanting ink printing is 300 orders.
Step B, once cleaning: carry out surface cleaning to the glass after one-step print by ultrasonic wave with scavenging solution, remove glass surface finger mark, spot, scavenging period is 3 minutes.
Step C, frosting corrode: corrode corrosion-resistanting ink unwanted on glass with frosting corrosive fluid, and form patterned layer, process period is 10 minutes; Frosting corrodes, and be specially: C1, precleaning, carry out surface cleaning with scavenging solution to glass, cleaning time is 3 minutes; C2, frosting, put into frosted liquid immersion 1 minute by the glass after clean; C3, polishing, put into polishing fluid and soak 120 seconds by the glass after frosting process.
Described frosted liquid is made up of the raw material of following mass percent: fluorochemical 40%, calcium cpd 12%, sulfate of ammoniac 9%, ammonia chloride 8%, sylvite 5%, aluminium salt 6%, vitriol 5%, hydrochlorate 15%.
Described polishing fluid is made up of the raw material of following mass percent: vitriol 19%, fluorochemical 13%, sylvite 8%, aluminium salt 5%, acid solution 20%, water-soluble agents 35%.
Step D, plain edge: carry out plain edge processing to glass circumferential side frame with the machine of clearing off, make glass circumferential side frame smooth surface.
Step e, deinking: remove corrosion-resistanting ink residual on glass with strong alkali solution, process period is 3 minutes.
Step F, secondary cleaning: carry out surface cleaning flushing to the glass after deinking with clear water, flush time is 2 minutes.
Step G, secondary printing: carry out silk-screen ink printing with the silk screen of pre-designed pattern, form pattern ink layer.
Secondary printing, be specially and adopt ink to carry out five silk screen printings successively, the first impression adopts 500 nylon printings, the grenadine order number of the second impression is 320 orders, the grenadine order number of the third printing is 250 orders, the grenadine order number of the 4th printing is 300 orders, and the grenadine order number of the 5th printing is 300 orders.
Vacuum plating; Carry out vacuum plating with vacuum plating unit, make the glass surface after secondary printing form coatings.
Step H, three printings: carry out protection ink printing with the silk screen of pre-designed pattern, make pattern ink layer outside surface cover a protection ink layer.
Three printings, are specially employing or five ink carry out silk screen printing, and described protection ink is anti-oxidant ink.
Adopt or five ink when carrying out silk screen printing, model that Yin great waves are produced that what the described first impression adopted is be the mirror-like silver ink of MK-6000A, ink that the ratio of model to be MK-120 and PEF-103/H with weight percent be 100:6:3 is mixed.Its storing temperature of ink that the first impression is formed is 150 ± 10 DEG C, and baking time is 10 ± 1min, and photoresists thickness, frictioning hardness are respectively 7 ± 1 μm, 85A.
The ink that what the described second impression adopted is grants that color model of producing is EM-0208 white ink, model is AF-01A, the ratio of model to be AF-01B, EM-219 and EM-219/H with weight percent be 100:7:3:5:3-4 is mixed.Its storing temperature of ink that the second impression is formed is 150 ± 10 DEG C, and baking time is 10 ± 1min, and photoresists thickness, frictioning hardness are respectively 15 ± 1 μm, 85A, and ink thickness is 7-10 μm.
The ink that what the described third printing adopted is grants that color model of producing is EM-0208 white ink, model is AF-01A, the ratio of model to be AF-01B, EM-219 and EM-219/H with weight percent be 100:7:3:5:3-5 is mixed.Its storing temperature of ink that the third printing is formed is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 18 ± 1 μm, 75A, and ink thickness is 16-20 μm.
The ink that what described 4th printing adopted is grants that color model of producing is EM-0208 white ink, model is AF-01A, the ratio of model to be AF-01B, EM-219 and EM-219/H with weight percent be 100:7:3:5:3-5 is mixed.Its storing temperature of ink that 4th printing is formed is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 18 ± 1 μm, 75A, and ink thickness is 23-26 μm.
The ink that what described 5th printing adopted is grants that color model of producing is CX03-EM-0208 ash end ink, model is CX03-EM0041, EM-AF-01A, the ratio of model to be EM-AF-01B and EM-219 with weight percent be 45:0.3:7:3:5 is mixed.Its storing temperature of ink that 5th printing is formed is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 5 ± 1 μm, 75A, and ink thickness is 26-32 μm.
Step I, three cleanings: carry out surface cleaning to the glass after three printings by ultrasonic wave with scavenging solution, scavenging period is 3 minutes.
The above embodiment, just better embodiment of the present invention, be not limit the scope of the present invention, therefore all equivalences done according to structure, feature and the principle described in the present patent application the scope of the claims change or modify, and all should comprise in patent claim of the present invention.
Claims (7)
1. a frosting corrosion typography for glass, is characterized in that: comprise following procedure of processing:
Steps A, one-step print: planar transparent glass is carried out corrosion-resistanting ink printing;
Step B, once cleaning: carry out surface cleaning to the glass after one-step print by ultrasonic wave with scavenging solution, remove glass surface finger mark, spot;
Step C, frosting corrode: corrode corrosion-resistanting ink unwanted on glass with frosting corrosive fluid, and form patterned layer, process period is 3 ~ 10 minutes;
Step D, plain edge: carry out plain edge processing to glass circumferential side frame with the machine of clearing off, make glass circumferential side frame smooth surface;
Step e, deinking: remove corrosion-resistanting ink residual on glass with strong alkali solution, process period is 1 ~ 5 minute;
Step F, secondary cleaning: surface cleaning flushing is carried out to the glass after deinking with clear water;
Step G, secondary printing: carry out silk-screen ink printing with the silk screen of pre-designed pattern, form pattern ink layer;
Step H, three printings: carry out protection ink printing with the silk screen of pre-designed pattern, make pattern ink layer outside surface cover a protection ink layer;
Described step C, frosting corrode, and are specially:
C1, precleaning, carry out surface cleaning with scavenging solution to glass, and cleaning time is 1 ~ 3 minute;
C2, frosting, glass after clean is put into frosted liquid immersion 1 ~ 5 minute, described frosted liquid is made up of the raw material of following mass percent: fluorochemical 30-40%, calcium cpd 10-15%, sulfate of ammoniac 5-12%, ammonia chloride 3-10%, sylvite 2-5%, aluminium salt 3-10%, vitriol 2-8%, hydrochlorate 10-15%, or the frosting etching solution of frosted liquid to be model that essence Er Mei glass material company limited of Foshan City produces be GDXX-KN2320;
C3, polishing, glass after frosting process is put into polishing fluid to soak 30 ~ 120 seconds, described polishing fluid is made up of the raw material of following mass percent: vitriol 15-20%, fluorochemical 10-15%, sylvite 5-10%, aluminium salt 5-10%, acid solution 20-30%, water-soluble agents 30-35%, or the liquid of polishing fluid to be model that essence Er Mei glass material company limited of Foshan City produces be GDXX-YPI throws etching solution.
2. the frosting corrosion typography of a kind of glass according to claim 1, is characterized in that: between described step G and step H, also include vacuum plating; Carry out vacuum plating with vacuum plating unit, make the glass surface after secondary printing form coatings.
3. the frosting corrosion typography of a kind of glass according to claim 1, it is characterized in that: also include step I, three cleanings after described step H: carry out surface cleaning to the glass after three printings by ultrasonic wave with scavenging solution, scavenging period is 1 ~ 3 minute.
4. the frosting corrosion typography of a kind of glass according to claim 1, is characterized in that: described steps A, one-step print, be specially: first carry out the first corrosion-resistanting ink printing and the second corrosion-resistanting ink printing respectively to the front of glass with silk screen; Then, with silk screen, the 3rd corrosion-resistanting ink printing and the 4th corrosion-resistanting ink printing are carried out respectively to the back side of glass.
5. the frosting corrosion typography of a kind of glass according to claim 4, is characterized in that: the storing temperature of described first corrosion-resistanting ink printing is 100 ± 10 DEG C, and baking time is 10 ± 2min, and obtained ink thickness is 6-10nm; The storing temperature of the second corrosion-resistanting ink printing is 100 ± 10 DEG C, and baking time is 30 ± 5min, and obtained ink thickness is 10-15 μm; The storing temperature of the 3rd corrosion-resistanting ink printing is 100 ± 10 DEG C, and baking time is 10 ± 2min, and obtained ink thickness is 6-10 μm; The storing temperature of the 4th corrosion-resistanting ink printing is 100 ± 10 DEG C, and baking time is 30 ± 5min, and obtained ink thickness is < 15 μm.
6. the frosting corrosion typography of a kind of glass according to claim 1, it is characterized in that: described step G, secondary printing, be specially and adopt ink to carry out five silk screen printings successively, the first impression adopts mirror-like silver ink, storing temperature is 150 ± 10 DEG C, baking time is 10 ± 1min, and photoresists thickness, frictioning hardness are respectively 7 ± 1 μm, 85A; The second impression adopts white ink, and storing temperature is 150 ± 10 DEG C, and baking time is 10 ± 1min, and photoresists thickness, frictioning hardness are respectively 15 ± 1 μm, 85A, and ink thickness is 7-10 μm; The third printing adopts white ink, and storing temperature is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 18 ± 1 μm, 75A, and ink thickness is 16-20 μm; 4th printing adopts white ink, and storing temperature is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 18 ± 1 μm, 75A, and ink thickness is 23-26 μm; 5th printing adopts ash end ink, and storing temperature is 150 ± 10 DEG C, and baking speed is 2 meters/min, and photoresists thickness, frictioning hardness are respectively 5 ± 1 μm, 75A, and ink thickness is 26-32 μm.
7. the frosting corrosion typography of a kind of glass according to claim 1, is characterized in that: described step H, three printings, be specially employing once, twice or five ink and carry out silk screen printing, described protection ink is anti-oxidant ink.
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