CN1035376C - Finishing iron aventurine glaze brick - Google Patents
Finishing iron aventurine glaze brick Download PDFInfo
- Publication number
- CN1035376C CN1035376C CN93106290A CN93106290A CN1035376C CN 1035376 C CN1035376 C CN 1035376C CN 93106290 A CN93106290 A CN 93106290A CN 93106290 A CN93106290 A CN 93106290A CN 1035376 C CN1035376 C CN 1035376C
- Authority
- CN
- China
- Prior art keywords
- iron
- glaze
- aventurine
- crystal
- brick
- Prior art date
- Legal status (The legal status is an assumption and is not a legal conclusion. Google has not performed a legal analysis and makes no representation as to the accuracy of the status listed.)
- Expired - Fee Related
Links
Classifications
-
- C—CHEMISTRY; METALLURGY
- C03—GLASS; MINERAL OR SLAG WOOL
- C03C—CHEMICAL COMPOSITION OF GLASSES, GLAZES OR VITREOUS ENAMELS; SURFACE TREATMENT OF GLASS; SURFACE TREATMENT OF FIBRES OR FILAMENTS MADE FROM GLASS, MINERALS OR SLAGS; JOINING GLASS TO GLASS OR OTHER MATERIALS
- C03C8/00—Enamels; Glazes; Fusion seal compositions being frit compositions having non-frit additions
- C03C8/02—Frit compositions, i.e. in a powdered or comminuted form
Landscapes
- Chemical & Material Sciences (AREA)
- Life Sciences & Earth Sciences (AREA)
- Engineering & Computer Science (AREA)
- Chemical Kinetics & Catalysis (AREA)
- General Chemical & Material Sciences (AREA)
- Geochemistry & Mineralogy (AREA)
- Materials Engineering (AREA)
- Organic Chemistry (AREA)
- Glass Compositions (AREA)
- Compositions Of Oxide Ceramics (AREA)
Abstract
The present invention belongs to an architectural decoration material, which relates to an iron aventurine glaze decoration brick which solves the problems that the dimension of a glaze iron aventurine crystal is small, the sintering temperature of the glaze iron aventurine crystal is low, the glaze iron aventurine crystal is not suitable for serving as a decoration face brick of an outer wall, etc. An iron aventurine glaze is applied to the surface of a ceramic biscuit, and contains SiO2, B2O3, Al2O3, Fe2O3, CaO, MgO, Na2O and K2O, and 4 to 8% of an additional nucleating agent. The firing temperature of the iron aventurine glaze is from 1050 DEG C to 1150 DEG C, and the dimension of an iron aventurine crystal of the face brick can reach 0.3 to 0.8mm. The present invention has a low water absorption ratio, and is suitable for serving as a decoration material of the outer wall of a building.
Description
The invention belongs to a kind of building and ornament materials, relate in particular to a kind of finishing iron aventurine glaze brick that in the pottery adobe, imposes the iron aventurine glaze.
The consisting of of Russian Patent SU945111 glaze in the prior art: SiO
229.11～33.59 Al
2O
30.85～0.91Fe
2O
320.80～22.95 B
2O
329.38～30.93CaO 1.06～1.16 MgO 0.03～0.04Na
2O 13.29～13.79 SO
31.00～1.11, its firing temperature is 930～945 ℃, maximum iron Venus crystalline size is 10～100 μ.Because the firing temperature of glaze is lower, higher and can not be used for decoration of exterior wall with the water-intake rate of its preparation ceramic veneer, the iron Venus crystal of Xing Chenging is less in addition, has limited its application on decoration of exterior wall so decorative effect is undesirable.
It is little that purpose of the present invention solves glaze iron Venus crystalline size, and firing temperature is on the low side to be unsuitable for doing problem such as decoration of exterior wall face brick, improves the Venus decorative effect of glaze layer, and a kind of face brick that can be used for decoration of exterior wall is provided.
The present invention applies iron Venus glaze on the biscuit of ceramics surface, contain SiO in the iron goldstone glaze
2, B
2O
3, AlO
3, Fe
2O
3, Cao, MgO, Na
2O, K
2O, its firing temperature are 1050 ℃～1150 ℃, and the component of iron goldstone glaze is as follows: (weight %) SiO
256.83 B
2O
317.27Al
2O
32.88 Fe
2O
313.08CaO 0.24 MgO 0.65Na
2O 8.22 K
2O 0.83 adds Nucleating Agent 4～8%, and the chemical formula of Nucleating Agent is: ZrO
21.9Al
2O
35SiO
2Change SiO in the glaze component
2With B
2O
3Ratio, and trace adjusts alkali content and iron content, makes it to adapt to and burn till various base substrates in 1050 ℃～1150 ℃ temperature.
Technical process of the present invention is: above-mentioned glaze is formed make frit, add suspending agent and Nucleating Agent, mix in ball mill and wet-milling becomes glaze slip, the method that adopts glaze spraying, waters glaze or be coated with glaze imposes on the ceramic veneer biscuit.Pottery glaze firing can be adopted roller kilns, polychannel tunnel kiln or electric furnace, burns till under oxidizing atmosphere, then with the stove cool to room temperature, can obtain finishing iron aventurine glaze brick.
Positively effect of the present invention is to adopt out-phase crystallization technology, has increased the crystalline size of glaze layer, has improved the decorative effect of iron aventurine glaze face brick.Crystalline size can reach 0.3～0.8mm.And improved temperature of glaze firing, the water absorption rate of ceramic veneer can reach below 3%, satisfies the requirement as building outer wall decorative material.
Most preferred embodiment of the present invention: adopt following component: (weight %) SiO
256.83, B
2O
317.27, Al
2O
32.88, Fe
2O
313.08, Cao 0.24, MgO 0.65, Na
2O 8.22, K
2O 0.83, make batch with quartz sand, float stone, iron oxide red, industrial borax and soda ash, under 1280 ℃, be melting into glassy state, and shrend becomes frit, in 100 parts of frits, add 5 parts of bentonites, 0.2 part methylcellulose and 5 parts of Nucleating Agents add water and ground 24 hours in ball mill, make proportion and be 1.52 glaze slip.Nucleating Agent consist of 1 ZrO
21.9 Al
2O
35SiO
2Glaze slip is imposed on the ceramic veneer biscuit, and glazing thickness is about 0.8mm, through seasoning, burns till after 30 minutes furnace cooling to room temperature, iron Venus crystal 0.3～0.6mm in the glaze layer in 1100 ℃ electric furnace.
Claims (1)
1, a kind of finishing iron aventurine glaze brick is to apply iron Venus glaze on the biscuit of ceramics surface, contains SiO in the iron goldstone glaze
2, B
2O
3, Al
2O
3, Fe
2O
3, Cao, MgO, Na
2O, K
2O, its firing temperature are 1050 ℃～1150 ℃, and the component of iron goldstone glaze is as follows: (weight %) SiO
256.83 B
2O
317.27Al
2O
32.88 Fe
2O
313.08CaO 0.24 MgO 0.65Na
2O 8.22 K
2O 0.83 adds Nucleating Agent 4～8%, and the chemical formula of Nucleating Agent is: ZrO
21.9Al
2O
35SiO
2
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93106290A CN1035376C (en) | 1993-05-29 | 1993-05-29 | Finishing iron aventurine glaze brick |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN93106290A CN1035376C (en) | 1993-05-29 | 1993-05-29 | Finishing iron aventurine glaze brick |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN1096018A CN1096018A (en) | 1994-12-07 |
| CN1035376C true CN1035376C (en) | 1997-07-09 |
Family
ID=4986159
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN93106290A Expired - Fee Related CN1035376C (en) | 1993-05-29 | 1993-05-29 | Finishing iron aventurine glaze brick |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN1035376C (en) |
Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106567078B (en) * | 2016-10-21 | 2018-07-20 | 陕西科技大学 | A kind of preparation method of Venus enamel |
| CN108129027B (en) * | 2018-01-30 | 2020-09-01 | 广东宏海陶瓷实业发展有限公司 | Devitrified glazed tile with surface having golden star stone effect, base glaze and preparation method thereof |
| CN109264997A (en) * | 2018-10-26 | 2019-01-25 | 张丹丹 | A kind of pottery iron aventurine glaze and preparation method thereof |
| CN112897881A (en) * | 2021-01-15 | 2021-06-04 | 景德镇陶瓷大学 | High-temperature iron sand gold glaze and preparation method and application thereof |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU787585A1 (en) * | 1979-12-19 | 1980-12-15 | Казахское Отделение Ордена Трудового Красного Знамени Центрального Научно- Исследовательского И Проектного Института Строительных Металлоконструкций | Suspended multistorey building |
| SU945111A1 (en) * | 1980-11-20 | 1982-07-23 | Специализированная Проектно-Конструкторская Организация По Наладке Технологических Процессов Производства И Оказанию Помощи Предприятиям "Оргтехстром" Министерства Промышленности Строительных Материалов Латвсср | Crystalline glazing composition |
-
1993
- 1993-05-29 CN CN93106290A patent/CN1035376C/en not_active Expired - Fee Related
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| SU787585A1 (en) * | 1979-12-19 | 1980-12-15 | Казахское Отделение Ордена Трудового Красного Знамени Центрального Научно- Исследовательского И Проектного Института Строительных Металлоконструкций | Suspended multistorey building |
| SU945111A1 (en) * | 1980-11-20 | 1982-07-23 | Специализированная Проектно-Конструкторская Организация По Наладке Технологических Процессов Производства И Оказанию Помощи Предприятиям "Оргтехстром" Министерства Промышленности Строительных Материалов Латвсср | Crystalline glazing composition |
Also Published As
| Publication number | Publication date |
|---|---|
| CN1096018A (en) | 1994-12-07 |
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|---|---|---|---|
| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| C14 | Grant of patent or utility model | ||
| GR01 | Patent grant | ||
| C19 | Lapse of patent right due to non-payment of the annual fee | ||
| CF01 | Termination of patent right due to non-payment of annual fee |