CN103529097A - Blue oxygen water condensation test part, cold sterilizer comprising same and sterilization method - Google Patents
Blue oxygen water condensation test part, cold sterilizer comprising same and sterilization method Download PDFInfo
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- CN103529097A CN103529097A CN201310451627.4A CN201310451627A CN103529097A CN 103529097 A CN103529097 A CN 103529097A CN 201310451627 A CN201310451627 A CN 201310451627A CN 103529097 A CN103529097 A CN 103529097A
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Abstract
The invention discloses a blue oxygen water condensation test part which comprises a stainless steel or graphite measurement electrode, a silver or silver chloride reference electrode as well as a data processing display piece connected with the measurement electrode and the reference electrode and used for calculating and displaying blue oxygen water condensation according to an oxidation reduction potential. The invention further discloses a cold sterilizer comprises the blue oxygen water condensation test part. According to the cold sterilizer, the low-cost blue oxygen water condensation test part is mounted, so that the safety potential hazard that water with no dissolved blue oxygen washes a skin mucosa wound can be avoided; a washing accessory (particularly a washing brush) can be attached, so that blue oxygen water can be prevented from entering an object surface; a water heating unit can further be mounted, so that blue oxygen can be guaranteed to be infused into water efficiently, and a human body washing requirement is met; and a blue oxygen exhaust gas monitoring device can be further assembled, and an alarm can be given when gas blue oxygen leaks. The invention further discloses a sterilization method. The blue oxygen water condensation test part is used for testing the blue oxygen water condensation, and when the condensation meets a requirement, the blue oxygen water is used for washing and sterilization.
Description
Technical field
The present invention relates to sterilization and medical instruments field, particularly, relate to a kind of blue oxygen water concentration test component, the cold sterilizer that contains it and cold sterilization method.
Background technology
China is the fastest and the highest country of the density of population of the rate of economic development in the world, and oral hygiene (bacterial plaque, dental caries disease, gingivitis, periodontosis, sensitivity of tooth, halitosis), nasopharynx health (pharyngitis, rhinitis, nasosinusitis), vagina health (chronic colpomycosis), skin health (beriberi, face acnes, pudendal infection itch), fruits and vegetables are sterilized and brought the new challenge of many basic medical health to basic medical health.
If can solve above many new challenges by producing, manufacture by a kind of new technology and popularizing safe, effective, low-cost healthy equipment comprehensively, not only can prophylacticly occur, also can promote the people's holistic health comprehensively.Blue oxygen (ozone, active oxygen) is one of the most effective cold sterilization material of generally acknowledging, blue oxygen water may be eliminated the inflammation of mucocutaneous wound, and the universal blue oxygen wetting system of new type of safe manufacture stabilizing dissolved that uses can solve above many new challenges completely.
For example, helicobacter pylori has been generally acknowledged stomach trouble (as chronic gastritis, peptic ulcer, cancer of the stomach etc.) Etiological, and the helicobacter pylori of eradicating in human body is very difficult, even after helicobacter pylori radical cure, stomach trouble recurrence rate is also very high.This is because the helicobacter pylori in oral cavity is playing the part of a considerable role in the air, and " ”Ji oral cavity, critical point could be eliminated helicobacter pylori in crable only to hold first.Oral cavity, as helicobacter pylori another important " storage vault ", is followed food to send into intestines and stomach helicobacter pylori continuously by swallowing act, and in the situation that condition is suitable, is caused stomach palindromia.Helicobacter pylori does not have any impact to oral health, can not cause mouth disease yet, belongs to conventional flora, and this is just easy to be ignored by doctor and patient, and causes oral helicobacter pylori to grow wild.Carefully brush teeth and also can not remove the helicobacter pylori in oral cavity completely.Clinical practice is thought, the method of eliminating helicobacter pylori in oral cavity has two steps: the first step is regular toothwash, remove tartar and calculus dentalis, by periodontal treatment, remove the bacterial plaque in gingival sulcus, effectively destroy biofilm structure under gum, eliminate the environment that grows of helicobacter pylori, thereby effectively remove intraoral helicobacter pylori, reduce the infection chance again of helicobacter pylori.Second step is to gargle every day with special mouthwash, kills the helicobacter pylori in saliva.The universal new type of safe that uses is manufactured the blue oxygen water of stabilizing dissolved serial equipment, can solve oral cavity as the challenge of helicobacter pylori " storage vault ".
Again for example, the suction of pars oralis pharyngis pathogenic microorganism is to cause the elderly that remarkable hazards of pneumonia occur.The old man that scientific research personnel arranges to lose in home for destitute self-care ability carries out the clean and/or sanitizer of the stomatological medical of 5 months by a definite date containing gargling.They monitor the whole bacteriums of pars oralis pharyngis, streptococcus, staphylococcus, candida albicans, pseudomonad and bacteroides melanogenicus.Result demonstration, after the professional oral health care through weekly (by dentist's cleaning teeth, artificial tooth, tongue and mucous membrane of mouth), the level of these pars oralis pharyngis bacteriums all declines, and even disappears.In dining, use afterwards the effect that PVP-I is gargled to be not so good as professional oral health.The universal new type of safe that uses is manufactured the blue oxygen wetting system of stabilizing dissolved, can solve the challenge of pars oralis pharyngis bacterium.
In human body, have many beneficial bacterias (normal flora) and harmful bacteria, harmful bacteria just may cause a disease in the situation that body immunity is low.Normal flora has known function at enteron aisle and vagina, can not destroyed and thoroughly kill, to safeguard the ecologic equilibrium in body.Oral cavity and nature are linkers, after bacterium in oral cavity is killed, in two hours, just can return to normal, that is to say that two hours ecologic equilibriums just can be restored, also not evidence show that in the world oral bacteria excessively killed the serious consequence that there will be the ecologic equilibrium destroyed.Only there is the problem of killing in intraoral bacterium, can not have " can cause so-called flora imbalance in oral cavity after killing " problem.The blue oxygen water of safe handling dissolving is gargled or toothwash, and the growth and breeding of long-term control (not being thoroughly to kill for a long time) oral cavity harmful bacteria, may control mouth disease, naso-pharynageal disease, breathing problem and gastric ulcer.
Again for example, skin, due to hidrosis, humidity, has caused a more damp and hotter environment, for many microbial growths and breeding provide good condition, so the incidence of disease of skin infection is higher.
Again for example, acne is the chronic inflammation pathology of a kind of hair follicle relevant with sebum metabolism, sebaceous glands unit, 3male hormone secretion increase with follicular orifice in the effects of the microorganisms such as bacillus acnes be two principal elements of pathogenesis of acne.
Again for example, bedsore is due to the long-term pressurized of local organization, continuous ischemia, anoxic occurs, malnutritive Er Zhi tissue fester is downright bad.Skin bedsore is the problem of a universality in rehabilitation, nursing.
Again for example, burn is more with hydrothermal solution burn at ordinary times, take flame burn wartime as main.Adolescents in male is common, and men and women's ratio is about 3:1.Summer is multiple, and take the exposure portion such as head, neck, hand, four limbs as multiple.
Again for example, the bacterium of fruits and vegetables and pollution by pesticides are invisible killers, and the fruits and vegetables of edible bacterium and pollution by pesticides can cause one of main Health challenges that fitness declines and the multiple ，Shi of various diseases China faced in the high-speed developing period for a long time.
Because gas indigo plant oxygen has strong impulse effect to people's respiratory mucosa, there is Environmental Safety standard in country, is difficult for universal use, and safe manufacturing and the blue oxygen water of use stabilizing dissolved are only the universal approach that uses blue oxygen.
Because blue oxygen cold sterilizer is wound, skin, mucous membrane sterilization use, during use, must know in blue oxygen water and have or not and dissolve blue oxygen, to avoid using this hidden danger of water contaminated wound of not dissolving blue oxygen.Therefore, blue oxygen cold sterilizer need to be furnished with and in reliable, durable water, dissolves blue oxygen (blue oxygen water concentration) test component.The blue oxygen water concentration test component using on market now, generally adopts electrochemical membrane electrode to dissolve blue oxygen assay method or adopts expensive ultraviolet light to detect and dissolve blue oxygen assay method or adopt expensive platinum to measure the method for total ion concentration in electrode and oxidizing potential mensuration water.Therefore, need a kind of cheap, reliable, durable blue oxygen water concentration test component of exploitation.
Although the blue oxygen water of stabilizing dissolved is external efficient germicide, but disturbed by the material that consumes blue oxygen in water, when soaking disinfection is used, be difficult for reaching effective concentration, and the blue oxygen water of stabilizing dissolved is because permeance property is poor, how realizing effective sterilization, is urgent problem.
Above-described problem is the problem that existing domestic and international product does not also solve completely, address these problems, need to solve stable manufacture and the low detection part of cost that is difficult for discharging blue oxygen water, also needing to do the inside and outside research work of a large amount of careful human bodies, is that the development institute of domestic and international blue oxygen sterile products is necessary.For example, oral cavity is the organ communicating with the external world, has abundance of food residual, and for the amount reproductions of various bacteriums provides necessary condition, the bacterium between oral cavity and tooth is difficult to be killed completely.Brushing teeth in conjunction with Li Shidelin mouthwash is widespread use in the world and best oral disinfecting and the oral disease prevention and control method of generally acknowledging, its weak point is a, kill mouth; After gargling, b, child can not swallow; C, there are chemical residual and potential spinoff; D, expensive, is not suitable in China universal; E, not obvious to the inhibiting effect of oral cavity gingivitis; A little less than f, the effect of eliminating the unusual smell relatively; G, Li Shidelin mouthwash have color, are unfavorable for tooth whitening; H, oral cleaning sense are poor.Searching and Li Shidelin mouthwash have the oral cavity flushing washing lotion of same sterilization effects, again without the weak point of Li Shidelin mouthwash, have powerful inhibition of inflammation, do not kill mouthful, can swallow, without chemical residual, cheap, eliminate the unusual smell and can bleach, have obvious oral cleaning sense, can thoroughly solve the problem of preventing and treating of mouth disease, be the dream of oral cavity educational circles always.Blue oxygen (active oxygen, the ozone) water of stabilizing dissolved has powerful bactericidal effect and inhibition of inflammation (having the effect of inflammation-inhibiting pain concurrently), do not kill mouthful, can swallow, without chemical residual, cheap, eliminate the unusual smell and can bleach, have obvious oral cleaning effect, what without the blue oxygen of gas, leak safely can detect the blue oxygen water manufacture of the stabilizing dissolved device that dissolves blue oxygen in water automatically, and the washer that is included in the blue oxygen water of the high, normal, basic variable concentrations stabilizing dissolved of manufacture within the scope of 18-28 degree may be the approach that realizes this dream.
In a word, following developing direction of dissolving blue oxygen aquatic products depends mainly on research and the checking ability of the inside and outside effect of the blue oxygen water of stabilizing dissolved human body and security both at home and abroad, need to solve stable manufacture and the low detection part of cost that is difficult for discharging blue oxygen water, need manufacturing industry and life science unit jointly to determine.
Summary of the invention
Object of the present invention provides a kind of cost low, can half-quantitative detection blue oxygen water concentration, guarantees that blue oxygen water is used the blue oxygen water concentration test component of safety.
Another object of the present invention is to provide a kind of cold sterilizer of using safely and cold sterilization method.
For achieving the above object, the present invention adopts following technical scheme:
Blue oxygen water concentration test component, comprises stainless steel or graphite mensuration electrode, silver or silver chloride reference electrode, also comprises the data processing display part being connected with mensuration electrode and reference electrode, for converting according to oxidation-reduction potential and demonstrating blue oxygen water concentration.
Further, also comprise housing, be provided with water inlet and water delivering orifice on described housing, described mensuration electrode is arranged on enclosure interior and all by signal amplification board, is connected with data processing display part with reference electrode, and described data processing display part is arranged on housing.
Cold sterilizer, comprises and can produce the cold sterilizer main body of dissolving blue oxygen in water, also comprises above-mentioned blue oxygen water concentration test component, and the mensuration electrode of described blue oxygen water concentration test component and reference electrode contact with blue oxygen water.
Further, also include the special-purpose annex that rinses of resistance to blue oxygen that blue oxygen water passes through, described flushing annex includes the resistance to blue oxygen Special punching that blue oxygen water passes through and scrubs and/or syringe pipe; Described washout comprises the washout main body with bristle, also comprises blue oxygen waterpipe, and the water delivering orifice of described blue oxygen waterpipe is positioned at bristle place, and the water inlet of described blue oxygen waterpipe is connected with cold sterilizer main body by pump; Described syringe pipe is built-in with blue oxygen waterpipe, and the water inlet of described blue oxygen waterpipe is connected with cold sterilizer main body by pump.
Further, described washout comprises electronic Rinsing toothbrush, manual flushing toothbrush, facial washout, body pin washout and/or the general washout of fruits and vegetables tableware; Described syringe pipe comprises flushing of nasopharynx head, vaginal irrigation tip, wound irrigation head and/or periodontal syringe pipe; Between described flushing annex and cold sterilizer main body for removably connecting.
Further, described cold sterilizer main body preparation has water heating unit.
Further, described water heating unit is circulating water heating unit, comprises well heater, water pump, connecting tube, and described well heater is connected with described cold sterilizer main body circulation by water pump and connecting tube, also comprises the temperature probe of control heater and water pump.
Further, described cold sterilizer main body is furnished with blue oxygen tail gas monitoring device, and described blue oxygen tail gas monitoring device is the blue oxygen sensing device of semiconductor that uses tin ash.
Further, the gas-liquid transfer device of described cold sterilizer main body adopts the gas-liquid transfer device of non-high-pressure spray towing type, and the gas-liquid transfer device of described non-high-pressure spray towing type comprises that rotatable Multilayer Network covers inversed umbrella type or the positive umbellate form gas-liquid transfer device on umbrella top.
Further, the described cold sterilizer main body of dissolving blue oxygen in water that produces, its gas source is oxygenerator.
The cold sterilization method of above-mentioned cold sterilizer is: first adopt blue oxygen water concentration detection part to detect blue oxygen water concentration, when concentration meets the requirements, utilize blue oxygen water to carry out cold sterilization.
Further, described blue oxygen water is by there being the mode that resistance to blue oxygen Special punching that blue oxygen water passes through is scrubbed to carry out cold sterilization.
Owing to adopting technique scheme, the present invention has following beneficial effect:
(1) blue oxygen water concentration test component of the present invention, with low cost, simple and practical, and easily whether maintenance, can be dissolved in water to blue oxygen, and the size of amount that is dissolved in the blue oxygen of water does a basic judgement, guarantees the safe handling of blue oxygen water.It coordinates blue oxygen cold sterilizer to apply human body, thereby the blue oxygen of the dissolving that medical personnel or user of service can be judged whether contain in blue oxygen water effective concentration, avoid using or wound this potential safety hazard mucocutaneous without the water treatment without disinfective action of dissolving blue oxygen, reached the object that can use and declare by Safe of Medical Device.
(2) blue oxygen cold sterilizer of the present invention is used and dissolves blue oxygen water in conjunction with electronic or manual flushing toothbrush, facial washout, body pin washout, the general washout of fruits and vegetables tableware, can brush simultaneously and rinse the surfaces such as mucocutaneous, fruits and vegetables, by brush, the bacterial plaque biological membrane mill of mucocutaneous, fruit and vegetable surfaces etc. can be opened, promote the blue oxygen water of dissolving of efficient degerming, sterilization, anti-inflammatory to infiltrate through the sticky and fruit and vegetable surfaces of skin, greatly improved blue oxygen water sterilization ability.Be that blue oxygen cold sterilizer of the present invention inside and outside Disinfection Effect is good, washout assist to dissolve blue oxygen infiltration, and the non-steeped purging method of employing is subject in water and the blue oxygen species of the consumption of body surface disturbs few.
(3) the flushing annex in the present invention is mainly used in washing away and washes oral cavity, tooth, nasopharynx, vagina, wound disinfection, face, body pin, fruits and vegetables, tableware, can sterilization, inflammation-inhibiting, have the effect of inflammation-inhibiting pain concurrently, be used for the treatment of and caries prevention, periodontosis, gingivitis, rhinitis, pharyngitis, beriberi, vaginitis, skin disease, burn, bedsore and wound infection, also can be used for sterilize fruits and vegetables and tableware.
(4) blue oxygen cold sterilizer of the present invention is furnished with circulating water heating unit, can regulate water temperature, to guarantee that blue oxygen incorporates efficiently in water and is applicable to Human body washing needs.
(5) blue oxygen cold sterilizer of the present invention has blue oxygen tail gas monitoring device, at the blue oxygen of gas, leaks alarm.
(6) blue oxygen cold sterilizer of the present invention is used rotatable Multilayer Network to cover umbrella top inversed umbrella type or positive umbellate form gas-liquid transfer device belong to non-high-pressure spray towing type gas-liquid exchange principle, can manufacture and be difficult for forming in use gas, the difficult stable blue oxygen water discharging.In non-high-pressure spray towing type gas-liquid exchanged water, there is no air pocket, do not affect blue oxygen water concentration and measure, flushing annex is gone out the blue oxygen evolution amount of rear gas and is less than harmful level.The water outlet of high pressure high flow capacity easily makes to dissolve blue oxygen in water and becomes air release, so high-pressure spray and the high pressure aeration gas-liquid mass transfer method that has not been, and non-high-pressure spray towing type gas-liquid exchange is normal pressure jet, effective.
(7) blue oxygen cold sterilizer of the present invention leaks outside without gas, and the blue carrier of oxygen of water outlet discharges and detects the safe concentration that reaches international requirement, reaches the safe concentration of international requirement without bromate and nitrite.
Below by drawings and Examples, technical scheme of the present invention is described in further detail.
Accompanying drawing explanation
Fig. 1 is blue oxygen water concentration test component structural representation;
Fig. 2 is cold sterilizer complete machine structure schematic diagram;
Fig. 3 is electronic Rinsing toothbrush structural representation;
Fig. 4 is facial washout structural representation;
Fig. 5 is the general washout structural representation of body pin fruits and vegetables tableware;
Fig. 6 is non-high-pressure spray towing type gas liquid exchanger cellular construction schematic diagram;
Fig. 7 is that A-A in Fig. 6 is to sectional structure schematic diagram;
Fig. 8 is that the blue oxygen of cold sterilizer enters gas circuit line chart;
Fig. 9 is the blue oxygen exhaust gas path of cold sterilizer line chart;
Figure 10 is cold sterilizer Inlet and outlet water route map;
Figure 11 is cold sterilizer circulating water heating route map;
Figure 12 is being used oxygenerator (1 liter/min) to dissolve blue oxygen concentration and oxidizing potential measurement result schematic diagram (longitudinal axis is oxidizing potential measured value-mV, and transverse axis is m-second in time after starting shooting) with the on time;
Figure 13 dissolves blue oxygen concentration figure (21-23 degree) in cold sterilizer water outlet;
Figure 14 dissolves blue oxygen concentration figure (24-26 degree) in cold sterilizer water outlet.
Embodiment
Below in conjunction with accompanying drawing, the preferred embodiments of the present invention are described, be to be understood that preferred embodiment described herein, only for description and interpretation the present invention, is not intended to limit the present invention.
The invention discloses a kind of blue oxygen water concentration test component, as shown in Figure 1, comprise stainless steel or graphite mensuration electrode 34, silver or silver chloride reference electrode 35, also comprise the data processing display part being connected with mensuration electrode 34 and reference electrode 35, it is for converting according to oxidation-reduction potential and demonstrating blue oxygen water concentration.Also comprise housing, be provided with water inlet 31 and water delivering orifice 33 on housing, measure electrode 34 and be arranged on enclosure interior and all by signal amplification board, be connected with data processing display part with reference electrode 35, data processing display part is arranged on housing.Above-mentioned blue oxygen water concentration test component can also comprise the fixture that contains fixed orifice 32.
The present invention goes back emphasis and discloses a kind of blue oxygen cold sterilizer, and blue oxygen water concentration test component is cheaply housed, and can avoid rinsing mucocutaneous or this potential safety hazard of wound without the water that dissolves blue oxygen; Also can, with rinsing annex (especially washout), can effectively promote blue oxygen water to enter body surface; Also water heating unit can be housed, to guarantee that blue oxygen incorporates efficiently in water and is applicable to Human body washing needs; Also can be furnished with blue oxygen tail gas monitoring device, at the blue oxygen of gas, leak alarm.Be described in detail below.
As shown in Figure 2, for cold sterilizer, comprise and can produce the cold sterilizer main body 1 of dissolving blue oxygen in water, also comprise blue oxygen water concentration test component 3, the mensuration electrode of blue oxygen water concentration test component 3 and reference electrode contact (as blue oxygen water concentration test component 3 is communicated with the water outlet of cold sterilizer main body 1) with blue oxygen water.
As shown in Figure 2, cold sterilizer also comprises flushing annex 2, rinses annex 2 and comprises washout (electronic Rinsing toothbrush 21, manual flushing toothbrush 24, facial washout 22, the general washout 23 of body pin fruits and vegetables tableware) and syringe pipe (flushing of nasopharynx head 25, vaginal irrigation tip 26, wound irrigation head 27, periodontal syringe pipe 28).Rinse between annex 2 and cold sterilizer main body 1 as removably connecting.
Coordinate shown in Fig. 3, electronic Rinsing toothbrush 21 comprises that conventional electric toothbrush part 212(is with the washout main body of bristle) and blue oxygen waterpipe part 211, blue oxygen waterpipe water inlet 213 is connected with cold sterilizer main body 1 by pump, and blue oxygen waterpipe water delivering orifice 214 is positioned at hairbrush and partly hits exactly.
Coordinate shown in Fig. 4, facial washout 22 comprises face brush 222 and blue oxygen waterpipe 221, and blue oxygen waterpipe water inlet 223 is connected with cold sterilizer main body 1 by pump, and blue oxygen waterpipe water delivering orifice 224 is positioned at face brush center.
Coordinate shown in Fig. 5, the general washout 23 of body pin fruits and vegetables tableware comprises that, with the washout main body 232 of bristle and blue oxygen waterpipe 231, blue oxygen waterpipe water inlet 233 is connected with cold sterilizer main body 1 by pump, and blue oxygen waterpipe water delivering orifice 234 is positioned at the center of brush.
Similar with washout, syringe pipe is also built-in with blue oxygen waterpipe, and the water inlet of blue oxygen waterpipe is connected with cold sterilizer main body 1 by pump.
Shown in Fig. 2, specifically introduce the structure of cold sterilizer main body 1.Cold sterilizer main body 1 comprises back shroud 11 and is fixed on the dry post 13 of air, blue Oxygen Generator unit 12, the blue oxygen tail gas elimination unit 18 on back shroud 11, be positioned at the oxygenerator unit 15 of back shroud 11 lower positions, be arranged on position placed in the middle, top non-high-pressure spray towing type gas liquid exchanger unit 19, enter water water outlet tongue tube magnetic force water level control module 110, host computer control and display unit 111, front shroud 17, castor 16, gas meter 14.
Blue Oxygen Generator unit 12 comprises retaining valve 121, refrigerating fan 122, blue oxygengenerating plant 123, air intake opening 124, gas outlet 125.Wherein refrigerating fan 122 holding temperatures are less than 40 unit of blue Oxygen Generator while spending 12 stable blue oxygen and produce, and retaining valve 121 prevents liquid backflow and enters blue Oxygen Generator unit 12.
Coordinate shown in Fig. 6,7, non-high-pressure spray towing type gas liquid exchanger unit 19, comprise motor 191, reaction warehouse upper cover 192, reaction warehouse lower cover 193, gas liquid exchanger sump 194, Multilayer Network cover the inversed umbrella type on umbrella top or positive umbellate form gas-liquid transfer device 195, lifting column 196(only with fall umbrella and be used in conjunction with), recirculated water water delivering orifice 197, water inlet 1921, water delivering orifice 198, recirculated water water return outlet 1923, blue oxygen tail gas gas outlet 1924, blue oxygen air intake 1922.Wherein, the umbrella mouth opposite direction of positive umbellate form and positive umbellate form.
As shown in Fig. 2,7; enter water water outlet tongue tube magnetic force water level control module 110; comprise that from the bottom to top lack of water shuts down water-level probe 1104, inversed umbrella type or positive umbellate form gas-liquid transfer device and starting to rotate operating water level probe 1103, continuing that operation adds water water-level probe 1102, water-level probe 1101 is shut down in tail gas outlet, when also including water solenoid valve 1105(and using tap water) or enter water pump (while using physiological saline or other disinfectants), go out water pump 1106.
As shown in Figure 2, blue oxygen tail gas elimination unit 18 comprises well heater tail gas air intake 185, well heater 182, well heater tail gas gas outlet 184, the blue VPO catalysts post 181 of manganese dioxide activated charcoal, catalyst column air intake 183, tail gas gas outlet 186.
As shown in Figure 2,1 preparation of cold sterilizer main body has the water heating unit (circulating water heating unit 4) of interior circulation, comprise well heater 41, water pump 43, connecting tube, well heater 41 is connected with described cold sterilizer main body 1 circulation by water pump 43 and connecting tube, also comprises the temperature probe of control heater and water pump.
As shown in Figure 2, cold sterilizer main body 1 is furnished with blue oxygen tail gas monitoring device 5, and blue oxygen tail gas monitoring device 5 is the blue oxygen sensing devices of semiconductor that use tin ash.
The blue oxygen of above-mentioned cold sterilizer enters gas circuit line, blue oxygen tail gas route, Inlet and outlet water route, circulating water heating route specifically as shown in Fig. 8-11.
Adopt the cold sterilization method of above-mentioned cold sterilizer to be: first adopt blue oxygen water concentration detection part to detect blue oxygen water concentration, when concentration meets the requirements, utilize blue oxygen water to carry out cold sterilization, wherein blue oxygen water carries out cold sterilization by the mode of washout.
Manufacture and experimental example by cold sterilizer further illustrates beneficial effect of the present invention below:
Experimental example 1
Object: be a kind of blue oxygen water concentration test component of blue oxygen cold sterilizer Development and Production
Method: this experimental study is mainly for a kind of blue oxygen water concentration test component of Development and Production, coordinate the application of blue oxygen cold sterilizer (the blue oxygen water medical apparatus irrigation and disinfection device that has oxygenerator) human body, thereby the blue oxygen of the dissolving that medical personnel or user of service can be judged whether contain in wash-down water effective concentration, avoid using the water without disinfective action without dissolving blue oxygen to rinse mucocutaneous or this potential safety hazard of wound, reached the object that can use and declare by Safe of Medical Device.In addition, whether a kind of blue oxygen water concentration test component of Development and Production, can be dissolved in water to blue oxygen, and the size of amount that is dissolved in the blue oxygen of water is done a basic judgement.A kind of blue oxygen water concentration test component of this experimental study Development and Production, cheap, to dissolve blue oxygen assay method method completely different from the electrochemical membrane electrode using on present market, do not adopt expensive ultraviolet light to detect and dissolve blue oxygen assay method, be also obviously different from the method for using expensive platinum mensuration electrode to measure total ion concentration in water with oxidizing potential in present market different yet.We adopt cheap stainless steel or graphite to do mensuration electrode, adopt cheap silver or silver chloride to make reference electrode, a kind of blue oxygen water concentration test module of Development and Production or parts, comprise water inlet, stainless steel or graphite mensuration electrode, silver or silver chloride reference electrode, water delivering orifice, fixed orifice, signal amplification board, dissolve blue oxygen concentration display screen, as shown in Figure 1.
Result: this blue oxygen cold sterilizer is used parts shown in Fig. 1 to measure the oxidizing potential of blue oxygen water generates, has also measured and has closed the oxidizing potential that oxygenerator uses the blue oxygen water generates of air, experimental result in Table 1, Figure 12 and table 2.
Table 1, dissolve blue oxygen concentration and oxidizing potential measurement result using in the different oxygen flow situations of oxygenerator.
| Oxidizing potential (mV) | 7±8 | 162±8 | 172±8 | 182±8 |
| Dissolve blue oxygen concentration (mg/L) | Be less than 0.1 | 2.0 | 2.8 | 3.0 |
| Oxygenerator flow (liter/min) | 0.0 | 2.5 | 1.0 | 0.5 |
Table 2, dissolve blue oxygen concentration and oxidizing potential measurement result not using in oxygenerator (use air) situation.
| Oxidizing potential (mV) | 7±8 | 62±8 | 72±8 | 82±8 |
| Dissolve blue oxygen concentration (mg/L) | 0.0 | 0.3 | 0.5 | 0.8 |
Conclusion: 1, blue oxygen water concentration test component cost is low, can measure blue oxygen concentration in water by rapid semi-quantitative; 2, in oxygenerator oxygen flow 0.5-1 liter/min water, dissolve blue oxygen concentration high.
Experimental example 2
Object: using on market and stablize and sell stable for many years heater block, is a kind of cool water heating loop module of blue oxygen cold sterilizer Development and Production or parts.
Method: use the blue oxygen water flushing of dissolving human body skin, mucous membrane, wound need to control water temperature in comfortable scope, when being greater than 28 abilities that blue oxygen is dissolved into water while spending, water temperature obviously declines, blue oxygen degradation speed increases, and from water, discharges also and increases, and this is the bottleneck that uses blue oxygen.We press the circulating water heating route shown in Figure 10, production cycle water heating unit, the temperature probe of pipeline, water pump, control heater and the water pump that comprise well heater, heat water storehouse, is connected with gas-liquid exchange storehouse, be arranged in blue oxygen cold sterilizer, measure the relation of dissolving between blue oxygen concentration and water temperature, upper temperature limit is 28 degree.
Result: test result shows, blue oxygen cold sterilizer output water temperature on request security control between 24-28 degree, to entering water requirement between 5-24 degree.Result also shows that in water, dissolve blue oxygen concentration degrades and be less than 15% under uniform temp contrast condition, completely can be by the velocity compensation that in gas liquid exchanger, blue oxygen transmits.When water temperature is greater than 29 while spending, in water, blue oxygen concentration starts obvious decline.
Conclusion: the circulating water heating unit of this blue oxygen cold sterilizer requires between 5-24 degree entering water, security control is between 24-28 degree, through on probation stable and without potential safety hazard completely on request.
Experimental example 3
Object: manufacture and try out the electronic Rinsing toothbrush of blue oxygen, blue oxygen face washout, the general washout of body pin fruits and vegetables tableware.
Method: cooperate with production electric toothbrush, face brush, body pin fruits and vegetables Tableware brush producer, transform their original mould, integrate and add blue oxygen waterpipe part, blue oxygen waterpipe intake section, blue oxygen waterpipe outlet is positioned at hairbrush center part.Use brush and the cold sterilizer of transformation to do respectively the electronic Rinsing toothbrush of blue oxygen (Fig. 3), blue oxygen face washout (Fig. 4), the general washout of body pin fruits and vegetables tableware (Fig. 5) checking.
Result: the electronic Rinsing toothbrush of blue oxygen, blue oxygen face washout, the general washout of body pin fruits and vegetables tableware are shown in respectively structure shown in Fig. 3, Fig. 4, Fig. 5, and experimental result table 3, table 4, table 5, table 6 show that blue oxygen washout is better than independent blue oxygen water syringe pipe bactericidal effect.
Table 3, the electronic Rinsing toothbrush of blue oxygen and blue oxygen water syringe pipe tooth surface Comparison of effect on sterilization.
| ? | The electronic Rinsing toothbrush of blue oxygen | Blue oxygen water syringe pipe |
| Tooth surface sample sterilization percent | 87.9±10.9% | 43.5±17.2% |
Table 4, blue oxygen face washout and blue oxygen water syringe pipe skin of face Comparison of effect on sterilization.
| ? | Blue oxygen face washout | Blue oxygen water syringe pipe |
| Skin of face surface sample sterilization percent | 97.4±20.9% | 63.5±10.2% |
Table 5, the general washout of blue oxysome pin fruits and vegetables tableware and blue oxygen water syringe pipe Comparison of effect on sterilization.
| ? | The general washout of blue oxysome pin fruits and vegetables tableware | Blue oxygen water syringe pipe |
| Foot's skin surface sample sterilization percent | 95.4±20.9% | 33.5±10.2% |
Table 6, the general brush syringe pipe of blue oxysome pin fruits and vegetables tableware and blue oxygen water syringe pipe Comparison of effect on sterilization.
| ? | The general washout of blue oxysome pin fruits and vegetables tableware | Blue oxygen water syringe pipe |
| Cucumber surface sample sterilization percent | 98.4±23.9% | 70.5±12.2% |
Conclusion: blue oxygen is efficient surface germifuge, but permeance property is relatively bad.Adopt hairbrush syringe pipe with physics mode, to open the bacterial membrane of body surface, increase the Surface Permeability of blue oxygen.Experimental result shows that the electronic Rinsing toothbrush of blue oxygen, blue oxygen face washout, the general washout of body pin fruits and vegetables tableware have solved the Surface Permeability problem of blue oxygen, obviously superior more than blue oxygen syringe pipe bactericidal effect.
Experimental example 4
Object: blue oxygen cold sterilizer model machine is manufactured and parameter is determined.
Method: manufacture blue oxygen cold sterilizer (Fig. 2), collect various parameters, determine following form (table 7).
Table 7, blue oxygen cold sterilizer parameter.
Experimental example 5
Object: blue oxygen concentration determination is dissolved in the water outlet of blue oxygen cold sterilizer.
Method: in the scope of synthermal output water temperature, measure the water outlet of blue oxygen cold sterilizer and dissolve blue oxygen concentration, blue oxygen concentration determination is used GB iodimetric titration.
Blue oxygen concentration (21-23 degree) is dissolved in result: Figure 13, the water outlet of blue oxygen cold sterilizer.Note: it is 4 that each time period sample number of blue oxygen concentration determination is dissolved in the water outlet of blue oxygen cold sterilizer.Blue oxygen concentration (24-26 degree) is dissolved in Figure 14, the water outlet of blue oxygen cold sterilizer.Note: it is 3 that each time period sample number of blue oxygen concentration determination is dissolved in the water outlet of blue oxygen cold sterilizer.
Conclusion: above result shows that it is 1.8-3.2mg/L that blue oxygen concentration is dissolved in the water outlet of blue oxygen cold sterilizer between 21-26 degree, within effective and safe scope.
Experimental example 6
Object: the water outlet of blue oxygen cold sterilizer is dissolved blue oxygen water body and killed different pathogenic bacteria effects outward.
Method: use 25 milliliters of blue oxygen water of dissolving of blue oxygen cold sterilizer manufacture to do the external different pathogenic bacteria experiments of killing, add the various pathogenic bacteria of concentration known, then detect the bacterial population of existence.
The blue oxygen water of stabilizing dissolved that the concentration of table 8, the manufacture of blue oxygen cold sterilizer is 2.0-3.5mg/L is killed the different pathogenic bacteria time (18 degree).
Conclusion: 25 milliliters of the manufacture of blue oxygen cold sterilizer dissolve blue oxygen water body and kill different pathogenic bacteria successfuls, also effective degrading pesticide outward.
Experimental example 7
Object: the aseptic checking of the blue oxygen water of dissolving that blue oxygen cold sterilizer is manufactured.
Method: the bacterial population of measuring the blue oxygen water of dissolving of blue oxygen cold sterilizer manufacture.
Result: table 9, blue oxygen cold sterilizer water outlet Bacteria Detection
| Sample one | Sample two | Sample three | Sample four |
| 0 | 0 | 0 | 0 |
Conclusion: the blue oxygen water of dissolving that blue oxygen cold sterilizer is manufactured is aseptic.
Experimental example 8
Object: the safety problem that the blue carrier of oxygen of blue oxygen cold sterilizer leaks.
Method: study blue oxygen cold sterilizer and produce the blue oxygen leakage situation of gas while dissolving blue oxygen water.
Table 10, the research of the blue oxygen leakage situation of blue oxygen cold sterilizer gas.Note: the blue oxygen water concentration of stabilizing dissolved is 2.0-3.5mg/L.
| ? | Tail gas outlet | Upper and lower 10cm | Front and back 10cm | Left and right 10cm |
| Blue oxygen concentration | <0.05PPM | <0.05PPM | <0.05PPM | <0.05PPM |
Conclusion: blue oxygen cold sterilizer is produced while dissolving blue oxygen water and leaked without the blue oxygen of gas.
Experimental example 9
Object: dissolve the safety problem that blue carrier of oxygen leaks during flushing in water.
Method: the blue oxygen leakage situation of gas while studying blue oxygen cold sterilizer flushing skin and vegetables.
Result: the blue oxygen concentration research of environmental gas when table 11, blue oxygen cold sterilizer rinse skin and vegetables.Note: the blue oxygen water concentration of stabilizing dissolved is 2.0-3.5mg/L.
| ? | Be rinsed 20cm place on skin | Be rinsed 20cm place on vegetables |
| The blue oxygen concentration of environmental gas | <0.05PPM | <0.05PPM |
Conclusion: leak without the blue oxygen of gas when blue oxygen cold sterilizer rinses skin and vegetables.
Experimental example 10
Object: the disposable external Escherichia coli effect of killing of the blue oxygen water (2.0-3.5mg/L) of stabilizing dissolved that blue oxygen cold sterilizer is manufactured.
Method: the disposable external Escherichia coli that kill of the blue oxygen water (2.0-3.5mg/L) of stabilizing dissolved of using blue oxygen cold sterilizer to manufacture, then measure Escherichia coli quantity.
Result: the disposable external Escherichia coli effect of killing of the blue oxygen water of stabilizing dissolved of table 12, the manufacture of the blue oxygen cold sterilizer of 25ml.
| ? | The thin 5X10-7 of inoculation high concentration | The thin 5x10-6 of inoculation low concentration |
| |
100% | 100% |
Conclusion: it is effective that the blue oxygen water of stabilizing dissolved of blue oxygen cold sterilizer manufacture kills Escherichia coli.
Experimental example 11
Object: the disposable bactericidal effect research of gargling of the blue oxygen water of stabilizing dissolved.
Method: the blue oxygen water of stabilizing dissolved that uses the blue oxygen cold sterilizer of 300ml to manufacture
(2.0-3.5mg/L) gargle, the mouthwash sample, tooth surface sample, the teeth space sample that before and after gargling, gather, measure bacterium amount, and control group is that the toothbrushes Jia Lishidelin mouthwash 25ml that brushes teeth gargles.
Result: the blue oxygen water of stabilizing dissolved that table 13, the blue oxygen cold sterilizer of 300ml are manufactured
(2.0-3.5mg/L) bactericidal effect of gargling (n=6).
Table 14, the toothbrushes disposable extracorporeal disinfecting effect of Jia Lishidelin mouthwash 25m of brushing teeth.
Conclusion: use separately bactericidal effect that the blue oxygen water of stabilizing dissolved (2.0-3.5mg/L) gargles than Li Shidelin mouthwash weak effect, the blue oxygen water of stabilizing dissolved (2.0-3.5mg/L) is gargled and is not the efficient germicide of good penetrability, need be in conjunction with the toothbrush increase perviousness of brushing teeth.
Experimental example 12
Object: disposable brushing teeth in conjunction with rinsing bactericidal effect research in the blue oxygen water body of stabilizing dissolved
Method: the blue oxygen cold sterilizer of the blue oxygen water (2.0-3.5mg/L) of the stabilizing dissolved toothbrush that blue oxygen washer is manufactured is brushed teeth to rinse and increased perviousness sterilization.
Result: the blue oxygen water of stabilizing dissolved (2.0-3.5mg/L) that table 15, blue oxygen cold sterilizer are manufactured by toothbrush brush teeth rinse kill Escherichia coli effect (n=6).
Conclusion: the blue oxygen water of stabilizing dissolved (2.0-3.5mg/L) that blue oxygen cold sterilizer is manufactured is brushed teeth by toothbrush, and be combined Li Shidelin mouthwash effect with toothbrush suitable for the bactericidal effect that rinses.
Experimental example 13
Object: dissolve blue oxygen water degradation experiment research
The blue oxygen water of stabilizing dissolved (2.0-3.5mg/L) that the blue oxygen cold sterilizer of method: 50ml is manufactured was gargled after 3 and 6 seconds, measured and dissolved blue oxygen concentration.
Result: the blue oxygen concentration determination of dissolving that the blue oxygen water of stabilizing dissolved (2.0-3.5mg/L) that table 16, the blue oxygen cold sterilizer of 50ml are manufactured was gargled after 3 and 6 seconds.
| Before gargling, dissolve blue oxygen concentration | After gargling 6 seconds, dissolve blue oxygen concentration | After gargling 9 seconds, dissolve blue oxygen concentration |
| 3.5mg/L | 0.3mg/L | <0.05mg/L |
Conclusion: the blue oxygen water degraded of dissolving that blue oxygen cold sterilizer is manufactured is rapid, safety.
Experimental example 14
Object: bromate and content of nitrite research in the blue oxygen water of dissolving that blue oxygen cold sterilizer is manufactured.
Method: study bromate and content of nitrite in the blue oxygen water of dissolving that blue oxygen cold sterilizer manufactures.
Result: bromate and content of nitrite in blue oxygen water (2.0-3.5mg/L) water of stabilizing dissolved that table 17, blue oxygen washer are manufactured.
| ? | Sample one | Sample two | Sample three |
| Bromate | <0.005 | <0.005 | <0.005 |
| Nitrite | <0.0033 | <0.0033 | <0.0033 |
Conclusion: in blue oxygen water (2.0-3.5mg/L) water of stabilizing dissolved that blue oxygen washer is manufactured, bromate and content of nitrite meet national standard.
Experimental example 15
Object: safety and stability is dissolved the effect research of blue oxygen water removing abnormal flavor in oral cavity, dental bleaching, oral cleaning.
Method: use six adult experimenters, the effect of the blue oxygen water of research safety stabilizing dissolved removing abnormal flavor in oral cavity, dental bleaching, oral cleaning.
Result: table 18, high-concentration stable dissolve the effect assessment (n=6) that blue oxygen water 2.0-3.5mg/L rinses removing abnormal flavor in oral cavity, dental bleaching, oral cleaning.
| ? | Oral peculiar smell | Dental bleaching | Oral cleaning sense |
| Effect after rinsing | Nothing | Not yellow | Clearly |
Conclusion: safety and stability is dissolved the successful of blue oxygen water removing abnormal flavor in oral cavity, dental bleaching, oral cleaning.
Experimental example 16
Object: research cold sterilizer dissolves gentle relation of dissolving between blue oxygen concentration of adding of blue oxygen water.
Method: when day cold, cold sterilizer dissolves blue oxygen water and rinses human body and cause and feel uncomfortable, we have manufactured and designed the water heating unit of interior circulation, comprise well heater, water pump, connecting tube, described well heater is connected with described cold sterilizer main body circulation by water pump and connecting tube, also comprises the temperature probe of control heater and water pump.
Result: start after blue oxygen cold sterilizer and wash-down water cock of water drain, restart heater switch, water temperature is increased to 28 degree by entering water water temperature 17 degree in 2 minutes, be stabilized between 24 degree-28 degree, in the water of water temperature 17 degree, 24 degree, 28 degree, dissolve blue oxygen concentration, be respectively 3.5mg/L, 2.5mg/L, 2.0mg/L, the blue oxygen concentration of the outer gas of bath place 20cm is less than 0.05ppm.
Conclusion: the water heating unit of interior circulation is effectively controlled at wash-down water water temperature between the suitable 24-28 degree of human body, in 28 wash-down waters while spending, dissolve blue oxygen concentration and still can reach effective cold sterilization standard, in wash-down water, dissolve the 0.05ppm that the blue oxygen evolution of blue carrier of oxygen is less than national regulation.
Finally it should be noted that: the foregoing is only the preferred embodiments of the present invention, be not limited to the present invention, although the present invention is had been described in detail with reference to previous embodiment, for a person skilled in the art, its technical scheme that still can record previous embodiment is modified, or part technical characterictic is wherein equal to replacement.Within the spirit and principles in the present invention all, any modification of doing, be equal to replacement, improvement etc., within all should being included in protection scope of the present invention.
Claims (12)
1. blue oxygen water concentration test component, it is characterized in that, comprise stainless steel or graphite mensuration electrode, silver or silver chloride reference electrode, also comprise the data processing display part being connected with mensuration electrode and reference electrode, for converting according to oxidation-reduction potential and demonstrating blue oxygen water concentration.
2. blue oxygen water concentration test component according to claim 1, it is characterized in that, also comprise housing, on described housing, be provided with water inlet and water delivering orifice, described mensuration electrode is arranged on enclosure interior and all by signal amplification board, is connected with data processing display part with reference electrode, and described data processing display part is arranged on housing.
3. cold sterilizer, comprises and can produce the cold sterilizer main body of dissolving blue oxygen in water, it is characterized in that, also comprises the blue oxygen water concentration test component described in claim 1 or 2, and the mensuration electrode of described blue oxygen water concentration test component and reference electrode contact with blue oxygen water.
4. cold sterilizer according to claim 3, is characterized in that, also includes the special-purpose annex that rinses of resistance to blue oxygen that blue oxygen water passes through, and described flushing annex includes the resistance to blue oxygen Special punching that blue oxygen water passes through and scrubs and/or syringe pipe;
Described washout comprises the washout main body with bristle, also comprises blue oxygen waterpipe, and the water delivering orifice of described blue oxygen waterpipe is positioned at bristle place, and the water inlet of described blue oxygen waterpipe is connected with cold sterilizer main body by pump;
Described syringe pipe is built-in with blue oxygen waterpipe, and the water inlet of described blue oxygen waterpipe is connected with cold sterilizer main body by pump.
5. cold sterilizer according to claim 4, is characterized in that, described washout comprises electronic Rinsing toothbrush, manual flushing toothbrush, facial washout, body pin washout and/or the general washout of fruits and vegetables tableware;
Described syringe pipe comprises flushing of nasopharynx head, vaginal irrigation tip, wound irrigation head and/or periodontal syringe pipe;
Between described flushing annex and cold sterilizer main body for removably connecting.
6. according to the cold sterilizer described in claim 3-5 any one, it is characterized in that, described cold sterilizer main body preparation has water heating unit.
7. cold sterilizer according to claim 6, it is characterized in that, described water heating unit is circulating water heating unit, comprise well heater, water pump, connecting tube, described well heater is connected with described cold sterilizer main body circulation by water pump and connecting tube, also comprises the temperature probe of control heater and water pump.
8. according to the cold sterilizer described in claim 3-5 any one, it is characterized in that, described cold sterilizer main body is furnished with blue oxygen tail gas monitoring device, and described blue oxygen tail gas monitoring device is the blue oxygen sensing device of semiconductor that uses tin ash.
9. according to the cold sterilizer described in claim 3-5 any one, it is characterized in that, the gas-liquid transfer device of described cold sterilizer main body adopts the gas-liquid transfer device of non-high-pressure spray towing type, and the gas-liquid transfer device of described non-high-pressure spray towing type comprises that rotatable Multilayer Network covers inversed umbrella type or the positive umbellate form gas-liquid transfer device on umbrella top.
10. according to the cold sterilizer described in claim 3-5 any one, it is characterized in that, the described cold sterilizer main body of dissolving blue oxygen in water that produces, its gas source is oxygenerator.
11. according to the cold sterilization method of the cold sterilizer described in claim 3-10 any one, it is characterized in that, first adopts blue oxygen water concentration detection part to detect blue oxygen water concentration, when concentration meets the requirements, utilizes blue oxygen water to carry out cold sterilization.
12. cold sterilization methods according to claim 11, is characterized in that, described blue oxygen water carries out cold sterilization by the mode of brushing and rinsing simultaneously.
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