CN103525240A - Metal powder anti-rust paint and preparation method thereof - Google Patents
Metal powder anti-rust paint and preparation method thereof Download PDFInfo
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- CN103525240A CN103525240A CN201310448987.9A CN201310448987A CN103525240A CN 103525240 A CN103525240 A CN 103525240A CN 201310448987 A CN201310448987 A CN 201310448987A CN 103525240 A CN103525240 A CN 103525240A
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- metal powder
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- rust paint
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- 239000003973 paint Substances 0.000 title claims abstract description 24
- 239000000843 powder Substances 0.000 title claims abstract description 20
- 229910052751 metal Inorganic materials 0.000 title claims abstract description 17
- 239000002184 metal Substances 0.000 title claims abstract description 17
- 238000002360 preparation method Methods 0.000 title claims description 15
- JEIPFZHSYJVQDO-UHFFFAOYSA-N iron(III) oxide Inorganic materials O=[Fe]O[Fe]=O JEIPFZHSYJVQDO-UHFFFAOYSA-N 0.000 title abstract description 13
- CTQNGGLPUBDAKN-UHFFFAOYSA-N O-Xylene Chemical compound CC1=CC=CC=C1C CTQNGGLPUBDAKN-UHFFFAOYSA-N 0.000 claims abstract description 13
- 229920005989 resin Polymers 0.000 claims abstract description 13
- 239000011347 resin Substances 0.000 claims abstract description 13
- -1 alkenyl succinic acid, Chemical compound 0.000 claims abstract description 11
- KDYFGRWQOYBRFD-UHFFFAOYSA-N Succinic acid Natural products OC(=O)CCC(O)=O KDYFGRWQOYBRFD-UHFFFAOYSA-N 0.000 claims abstract description 7
- DOOTYTYQINUNNV-UHFFFAOYSA-N Triethyl citrate Chemical compound CCOC(=O)CC(O)(C(=O)OCC)CC(=O)OCC DOOTYTYQINUNNV-UHFFFAOYSA-N 0.000 claims abstract description 7
- XAGFODPZIPBFFR-UHFFFAOYSA-N aluminium Chemical compound [Al] XAGFODPZIPBFFR-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920003180 amino resin Polymers 0.000 claims abstract description 7
- 239000003822 epoxy resin Substances 0.000 claims abstract description 7
- SZVJSHCCFOBDDC-UHFFFAOYSA-N ferrosoferric oxide Chemical compound O=[Fe]O[Fe]O[Fe]=O SZVJSHCCFOBDDC-UHFFFAOYSA-N 0.000 claims abstract description 7
- 229920000647 polyepoxide Polymers 0.000 claims abstract description 7
- 239000001069 triethyl citrate Substances 0.000 claims abstract description 7
- VMYFZRTXGLUXMZ-UHFFFAOYSA-N triethyl citrate Natural products CCOC(=O)C(O)(C(=O)OCC)C(=O)OCC VMYFZRTXGLUXMZ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 235000013769 triethyl citrate Nutrition 0.000 claims abstract description 7
- XEKOWRVHYACXOJ-UHFFFAOYSA-N Ethyl acetate Chemical compound CCOC(C)=O XEKOWRVHYACXOJ-UHFFFAOYSA-N 0.000 claims description 18
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims description 12
- 238000003756 stirring Methods 0.000 claims description 12
- HCHKCACWOHOZIP-UHFFFAOYSA-N Zinc Chemical compound [Zn] HCHKCACWOHOZIP-UHFFFAOYSA-N 0.000 claims description 6
- 239000004411 aluminium Substances 0.000 claims description 6
- 229910052782 aluminium Inorganic materials 0.000 claims description 6
- WNROFYMDJYEPJX-UHFFFAOYSA-K aluminium hydroxide Chemical compound [OH-].[OH-].[OH-].[Al+3] WNROFYMDJYEPJX-UHFFFAOYSA-K 0.000 claims description 6
- 229910021502 aluminium hydroxide Inorganic materials 0.000 claims description 6
- 238000006243 chemical reaction Methods 0.000 claims description 6
- MTHSVFCYNBDYFN-UHFFFAOYSA-N diethylene glycol Chemical compound OCCOCCO MTHSVFCYNBDYFN-UHFFFAOYSA-N 0.000 claims description 6
- FPAFDBFIGPHWGO-UHFFFAOYSA-N dioxosilane;oxomagnesium;hydrate Chemical compound O.[Mg]=O.[Mg]=O.[Mg]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O.O=[Si]=O FPAFDBFIGPHWGO-UHFFFAOYSA-N 0.000 claims description 6
- MTZQAGJQAFMTAQ-UHFFFAOYSA-N ethyl benzoate Chemical compound CCOC(=O)C1=CC=CC=C1 MTZQAGJQAFMTAQ-UHFFFAOYSA-N 0.000 claims description 6
- 235000013312 flour Nutrition 0.000 claims description 6
- 239000000377 silicon dioxide Substances 0.000 claims description 6
- BFKJFAAPBSQJPD-UHFFFAOYSA-N tetrafluoroethene Chemical group FC(F)=C(F)F BFKJFAAPBSQJPD-UHFFFAOYSA-N 0.000 claims description 6
- JCVQKRGIASEUKR-UHFFFAOYSA-N triethoxy(phenyl)silane Chemical compound CCO[Si](OCC)(OCC)C1=CC=CC=C1 JCVQKRGIASEUKR-UHFFFAOYSA-N 0.000 claims description 6
- 239000011701 zinc Substances 0.000 claims description 6
- 229910052725 zinc Inorganic materials 0.000 claims description 6
- 239000002994 raw material Substances 0.000 claims description 5
- OKTJSMMVPCPJKN-UHFFFAOYSA-N Carbon Chemical compound [C] OKTJSMMVPCPJKN-UHFFFAOYSA-N 0.000 claims description 3
- BGYHLZZASRKEJE-UHFFFAOYSA-N [3-[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxy]-2,2-bis[3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoyloxymethyl]propyl] 3-(3,5-ditert-butyl-4-hydroxyphenyl)propanoate Chemical compound CC(C)(C)C1=C(O)C(C(C)(C)C)=CC(CCC(=O)OCC(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)(COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)COC(=O)CCC=2C=C(C(O)=C(C=2)C(C)(C)C)C(C)(C)C)=C1 BGYHLZZASRKEJE-UHFFFAOYSA-N 0.000 claims description 3
- 125000003342 alkenyl group Chemical group 0.000 claims description 3
- KDYFGRWQOYBRFD-NUQCWPJISA-N butanedioic acid Chemical compound O[14C](=O)CC[14C](O)=O KDYFGRWQOYBRFD-NUQCWPJISA-N 0.000 claims description 3
- 229910052799 carbon Inorganic materials 0.000 claims description 3
- 238000000227 grinding Methods 0.000 claims description 3
- 239000003112 inhibitor Substances 0.000 claims description 3
- 239000000463 material Substances 0.000 claims description 3
- 239000001683 mentha spicata herb oil Substances 0.000 claims description 3
- KOVKEDGZABFDPF-UHFFFAOYSA-N n-(triethoxysilylmethyl)aniline Chemical compound CCO[Si](OCC)(OCC)CNC1=CC=CC=C1 KOVKEDGZABFDPF-UHFFFAOYSA-N 0.000 claims description 3
- 239000002105 nanoparticle Substances 0.000 claims description 3
- 230000003647 oxidation Effects 0.000 claims description 3
- 238000007254 oxidation reaction Methods 0.000 claims description 3
- 239000002245 particle Substances 0.000 claims description 3
- 235000019721 spearmint oil Nutrition 0.000 claims description 3
- 239000001384 succinic acid Substances 0.000 claims description 3
- 238000010792 warming Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 abstract description 5
- 230000007613 environmental effect Effects 0.000 abstract description 3
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Substances O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 abstract description 3
- 238000005260 corrosion Methods 0.000 abstract description 2
- 230000007797 corrosion Effects 0.000 abstract description 2
- NXQMCAOPTPLPRL-UHFFFAOYSA-N 2-(2-benzoyloxyethoxy)ethyl benzoate Chemical compound C=1C=CC=CC=1C(=O)OCCOCCOC(=O)C1=CC=CC=C1 NXQMCAOPTPLPRL-UHFFFAOYSA-N 0.000 abstract 2
- 230000035943 smell Effects 0.000 abstract 2
- 238000005299 abrasion Methods 0.000 abstract 1
- 230000007547 defect Effects 0.000 abstract 1
- NAGJZTKCGNOGPW-UHFFFAOYSA-N dithiophosphoric acid Chemical compound OP(O)(S)=S NAGJZTKCGNOGPW-UHFFFAOYSA-N 0.000 abstract 1
- RTZKZFJDLAIYFH-UHFFFAOYSA-N ether Substances CCOCC RTZKZFJDLAIYFH-UHFFFAOYSA-N 0.000 abstract 1
- 239000008096 xylene Substances 0.000 abstract 1
- 238000001035 drying Methods 0.000 description 2
- 238000005187 foaming Methods 0.000 description 2
- 230000002401 inhibitory effect Effects 0.000 description 2
- 239000000203 mixture Substances 0.000 description 2
- 239000003921 oil Substances 0.000 description 2
- 235000019198 oils Nutrition 0.000 description 2
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 238000004140 cleaning Methods 0.000 description 1
- 239000011248 coating agent Substances 0.000 description 1
- 238000000576 coating method Methods 0.000 description 1
- 230000003628 erosive effect Effects 0.000 description 1
- 238000001914 filtration Methods 0.000 description 1
- 238000010422 painting Methods 0.000 description 1
- 150000003839 salts Chemical class 0.000 description 1
- 239000007787 solid Substances 0.000 description 1
- 239000007921 spray Substances 0.000 description 1
- 238000004381 surface treatment Methods 0.000 description 1
Landscapes
- Paints Or Removers (AREA)
Abstract
The invention discloses metal powder anti-rust paint. The metal powder anti-rust paint comprises the components in parts by weight as follows: 16-19 parts of xylene, 68-72 parts of E-51 epoxy resin, 3-4 parts of iron oxide black, 3-4 parts of aluminum powder, 4-6 parts of diethylene glycol dibenzoate, 8-12 parts of triethyl citrate, 2-3 parts of alkenyl succinic acid, 1-2 parts of phosphorodithioic acid, 9-12 parts of amino resin, 3-4 parts of tributyl methyl ether and 3-4 parts of film-forming resin. The metal powder anti-rust paint is simple in process and low in product cost. The film-forming resin is added to a formula of the anti-rust paint, the adhesion is high, the flexibility of a paint film is good, and meanwhile, the anti-rust paint is good in corrosion resistance, water resistance, abrasion resistance and environmental protection, smells fragrant and overcomes the defect of unpleasant smell of conventional anti-rust paint.
Description
Technical field
The present invention relates to a kind of metallic anti-rust paint, specifically a kind of metal powder anti-corrosive paint and preparation method thereof.
Background technology
According to statistics, the direct economic loss that China causes due to metallic corrosion every year accounts for 4% of gross national product.Therefore the Anticorrosion Problems of metal more and more causes people's concern.In anticorrosive metal application techniques before, before japanning, pretreatment of metal surface accounts for 45% left and right of whole coating project total price.If can reduce or save rust cleaning, oil removing, the surface treatment procedure such as dewater, can significantly lower painting cost, also can greatly simplify enamelling process simultaneously, thereby reduce labor intensity and reduce the harm of rust dirt to human body.Develop not only environmental protection but also convenient use, the paint of superior performance becomes exigence.
Summary of the invention
The invention provides a kind of metal powder anti-corrosive paint and preparation method thereof, there is good mechanical stability, snappiness and surface hardness, good weatherability.
Technical scheme of the present invention is:
A kind of metal powder anti-corrosive paint, it is characterized in that, by the raw material preparation of following weight part, obtained: dimethylbenzene 16-19, E-51 epoxy resin 68-72, iron oxide black 3-4, aluminium powder 3-4, glycol ether benzoic ether 4-6, triethyl citrate 8-12, alkenyl succinic acid 2-3, zinc dialkyl dithiophosphate 1-2, aminoresin 9-12, three fourth MEE 3-4, film-forming resin 3-4.
The preparation method of described metal powder anti-corrosive paint, is characterized in that, comprises the following steps:
Dimethylbenzene is dropped in reactor, then add successively E-51 epoxy resin, glycol ether benzoic ether, triethyl citrate, alkenyl succinic acid, zinc dialkyl dithiophosphate, aminoresin, fully after stirring reaction, add again the clouts such as iron oxide black, aluminium powder, three fourth MEEs, film-forming resin under the rotating speed of 800-1000r/min, stir 20-35min, the material of reactor is emitted, adopt shredder to be ground to particle diameter and be less than 60 μ m, filter.
Described metal powder anti-corrosive paint, is characterized in that: described film-forming resin is by the raw material preparation of following weight part and obtain:
Alcohol ester 12 15-18, nanometer boronation silica flour 1-2, tetrafluoroethylene 2-3, talcum powder 1-2, aluminium hydroxide 1-2, ethyl acetate 13-16, spearmint oil 1-2, nano-sized carbon 0.1-0.2, irgasfos 168 1-2, oxidation inhibitor 1035 1-2, phenyl triethoxysilane 2-3, anilinomethyl triethoxysilane 1-2.
Preparation method mixes nanometer boronation silica flour, tetrafluoroethylene, talcum powder, aluminium hydroxide, ethyl acetate, grinding distribution, add again alcohol ester 12, antioxidant 1010, phenyl triethoxysilane, be warming up to 80-85 ℃, stirring reaction 60-90 minute, add again other remaining component, continue to stir 30-45 minute, obtain.
Technique of the present invention is simple, low cost product.Rust-inhibiting paint of the present invention, adds film-forming resin in formula, strong adhesion, and paint film flexibility is good, has good erosion resistance, water tolerance, wear resistance simultaneously, and the good feature of environmental protection, has overcome the bad smell of conventional rust-inhibiting paint at fragrant odour.
Embodiment
, by following composition weight (kilogram) feed composition make:
Dimethylbenzene 18, E-51 epoxy resin 70, iron oxide black 3, aluminium powder 4, glycol ether benzoic ether 4, triethyl citrate 9, alkenyl succinic acid 2, zinc dialkyl dithiophosphate 2, aminoresin 10, three fourth MEEs 3, film-forming resin 4.
Preparation method comprises the following steps:
(1) be first prepared into film resin
Film-forming resin is obtained by the raw material preparation of following weight (kg):
Alcohol ester 12, nanometer boronation silica flour 2, tetrafluoroethylene 2, talcum powder 2, aluminium hydroxide 1, ethyl acetate 15, spearmint oil 2, nano-sized carbon 0.2, irgasfos 168 1, oxidation inhibitor 1,035 2, phenyl triethoxysilane 2, anilinomethyl triethoxysilane 2.
Preparation method mixes nanometer boronation silica flour, tetrafluoroethylene, talcum powder, aluminium hydroxide, ethyl acetate, grinding distribution, add again alcohol ester 12, antioxidant 1010, phenyl triethoxysilane, be warming up to 80-85 ℃, stirring reaction 60-90 minute, add again other remaining component, continue to stir 30-45 minute, obtain;
(2) prepare metal powder anti-corrosive paint, comprise the following steps:
Dimethylbenzene is dropped in reactor, then add successively E-51 epoxy resin, glycol ether benzoic ether, triethyl citrate, alkenyl succinic acid, zinc dialkyl dithiophosphate, aminoresin, fully after stirring reaction, add again the clouts such as iron oxide black, aluminium powder, three fourth MEEs, film-forming resin under the rotating speed of 800-1000r/min, stir 20-35min, the material of reactor is emitted, adopt shredder to be ground to particle diameter and be less than 60 μ m, filter, then the product after filtering is packed to warehouse-in.
Metallic anti-rust paint performance index of the present invention:
1, time of drying (25 ℃): surface drying 25-35min, does solid work 40h
2, snappiness mm≤1
3, hardness >=2H
4, high temperature resistant (130 ℃) >=490h
5, shock-resistance 51
6, salt spray resistance (120h level) >=3
7, water tolerance (29 ± 1 ℃ of 240h): non-foaming, do not come off
8, oil resistant (90# gasoline, 56h): non-foaming, do not come off
9, alkali resistance (GB/T9755-2001): by 48 hours
10, artificial weathering ageing resistance (GB/T9755-2001): by 1200 hours.
Claims (3)
1. a metal powder anti-corrosive paint, it is characterized in that, by the raw material preparation of following weight part, obtained: dimethylbenzene 16-19, E-51 epoxy resin 68-72, iron oxide black 3-4, aluminium powder 3-4, glycol ether benzoic ether 4-6, triethyl citrate 8-12, alkenyl succinic acid 2-3, zinc dialkyl dithiophosphate 1-2, aminoresin 9-12, three fourth MEE 3-4, film-forming resin 3-4.
2. the preparation method of metal powder anti-corrosive paint according to claim 1, is characterized in that, comprises the following steps:
Dimethylbenzene is dropped in reactor, then add successively E-51 epoxy resin, glycol ether benzoic ether, triethyl citrate, alkenyl succinic acid, zinc dialkyl dithiophosphate, aminoresin, fully after stirring reaction, add again the clouts such as iron oxide black, aluminium powder, three fourth MEEs, film-forming resin under the rotating speed of 800-1000r/min, stir 20-35min, the material of reactor is emitted, adopt shredder to be ground to particle diameter and be less than 60 μ m, filter.
3. metal powder anti-corrosive paint according to claim 1, is characterized in that: described film-forming resin is by the raw material preparation of following weight part and obtain:
Alcohol ester 12 15-18, nanometer boronation silica flour 1-2, tetrafluoroethylene 2-3, talcum powder 1-2, aluminium hydroxide 1-2, ethyl acetate 13-16, spearmint oil 1-2, nano-sized carbon 0.1-0.2, irgasfos 168 1-2, oxidation inhibitor 1035 1-2, phenyl triethoxysilane 2-3, anilinomethyl triethoxysilane 1-2;
Preparation method mixes nanometer boronation silica flour, tetrafluoroethylene, talcum powder, aluminium hydroxide, ethyl acetate, grinding distribution, add again alcohol ester 12, antioxidant 1010, phenyl triethoxysilane, be warming up to 80-85 ℃, stirring reaction 60-90 minute, add again other remaining component, continue to stir 30-45 minute, obtain.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310448987.9A CN103525240A (en) | 2013-09-28 | 2013-09-28 | Metal powder anti-rust paint and preparation method thereof |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310448987.9A CN103525240A (en) | 2013-09-28 | 2013-09-28 | Metal powder anti-rust paint and preparation method thereof |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103525240A true CN103525240A (en) | 2014-01-22 |
Family
ID=49927605
Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310448987.9A Pending CN103525240A (en) | 2013-09-28 | 2013-09-28 | Metal powder anti-rust paint and preparation method thereof |
Country Status (1)
| Country | Link |
|---|---|
| CN (1) | CN103525240A (en) |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312381A (en) * | 2014-11-11 | 2015-01-28 | 合肥皖为电气设备工程有限责任公司 | Noise-reduction anti-rusting paint for power distribution cabinet and preparation method for noise-reduction anti-rusting paint |
Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1223283A (en) * | 1998-01-14 | 1999-07-21 | 田乃信 | Metal powder anti-corrosive paint |
| CN101070447A (en) * | 2006-05-08 | 2007-11-14 | 上海开林造漆厂 | Epoxy anti-rust paint capable of thick-film coating and saitable for construction in winter and preparing method |
| CN101880505A (en) * | 2010-07-06 | 2010-11-10 | 庞贝捷(涂料)昆山有限公司 | Thick film type antirust coating and preparation method thereof |
| CN103073969A (en) * | 2012-10-15 | 2013-05-01 | 怀远县巨龙机械制造有限公司 | Epoxy resin antirust paint and preparation method thereof |
-
2013
- 2013-09-28 CN CN201310448987.9A patent/CN103525240A/en active Pending
Patent Citations (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN1223283A (en) * | 1998-01-14 | 1999-07-21 | 田乃信 | Metal powder anti-corrosive paint |
| CN101070447A (en) * | 2006-05-08 | 2007-11-14 | 上海开林造漆厂 | Epoxy anti-rust paint capable of thick-film coating and saitable for construction in winter and preparing method |
| CN101880505A (en) * | 2010-07-06 | 2010-11-10 | 庞贝捷(涂料)昆山有限公司 | Thick film type antirust coating and preparation method thereof |
| CN103073969A (en) * | 2012-10-15 | 2013-05-01 | 怀远县巨龙机械制造有限公司 | Epoxy resin antirust paint and preparation method thereof |
Cited By (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104312381A (en) * | 2014-11-11 | 2015-01-28 | 合肥皖为电气设备工程有限责任公司 | Noise-reduction anti-rusting paint for power distribution cabinet and preparation method for noise-reduction anti-rusting paint |
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| C06 | Publication | ||
| PB01 | Publication | ||
| C10 | Entry into substantive examination | ||
| SE01 | Entry into force of request for substantive examination | ||
| RJ01 | Rejection of invention patent application after publication | ||
| RJ01 | Rejection of invention patent application after publication |
Application publication date: 20140122 |