CN103602208B - A kind of high-temperature-resistant flame-retardant anti-rust paint and preparation method thereof - Google Patents
A kind of high-temperature-resistant flame-retardant anti-rust paint and preparation method thereof Download PDFInfo
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- CN103602208B CN103602208B CN201310468759.8A CN201310468759A CN103602208B CN 103602208 B CN103602208 B CN 103602208B CN 201310468759 A CN201310468759 A CN 201310468759A CN 103602208 B CN103602208 B CN 103602208B
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Abstract
The invention discloses high-temperature-resistant flame-retardant anti-rust paint, be made up of the feed composition of following component weight part: resol 28-32, E-12 epoxy resin 36-40, Sodium hexametaphosphate 99 8-10, alcohol ester 12 5-8, trolamine 8-10, aluminium triphosphate 9-12, titanium dioxide 13-16, Tetra hydro Phthalic anhydride 3-4, boric acid 1-2, dimethylbenzene 20-23, cobalt naphthenate 4-5, cis-butenedioic anhydride 12-14, ethylene glycol 4-5, film-forming resin 4-5 etc.Flame-retardant anti-rust paint of the present invention, has feature that is high temperature resistant, resistance combustion, simultaneously capable of coating with rust, can remove rust cleaning or phosphatization operation from, easy to use.
Description
Technical field
The present invention relates to a kind of metallic anti-rust paint, specifically a kind of high-temperature-resistant flame-retardant anti-rust paint and preparation method thereof.
Background technology
According to statistics, the direct economic loss that China causes due to metallic corrosion every year accounts for 4% of gross national product.Therefore the Anticorrosion Problems of metal more and more causes the concern of people.In anticorrosive metal application techniques before, before japanning, pretreatment of metal surface accounts for about 45% of whole coating project total price.If the surface treatment procedure such as can reduce or save rust cleaning, oil removing, dewater, significantly can lower painting cost, also greatly can simplify enamelling process simultaneously, thus reduce labor intensity and reduce rust dirt to the harm of human body.Develop not only environmental protection but also easy to use, the paint of superior performance becomes exigence.
Summary of the invention
The invention provides a kind of high-temperature-resistant flame-retardant anti-rust paint and preparation method thereof, there is good mechanical stability, snappiness and surface hardness, high temperature resistant.
Technical scheme of the present invention is:
A kind of high-temperature-resistant flame-retardant anti-rust paint, is characterized in that being made up of the feed composition of following component weight part:
Resol 28-32, E-12 epoxy resin 36-40, Sodium hexametaphosphate 99 8-10, alcohol ester 12 5-8, trolamine 8-10, aluminium triphosphate 9-12, titanium dioxide 13-16, Tetra hydro Phthalic anhydride 3-4, boric acid 1-2, dimethylbenzene 20-23, cobalt naphthenate 4-5, cis-butenedioic anhydride 12-14, ethylene glycol 4-5, film-forming resin 4-5.
The preparation method of described high-temperature-resistant flame-retardant anti-rust paint, is characterized in that, comprises the following steps:
(1) first dimethylbenzene, ethylene glycol are added after reactor mixes, add resol, cobalt naphthenate, E-12 epoxy resin, cis-butenedioic anhydride, abundant stirring 15-20 minute, add Tetra hydro Phthalic anhydride, stir after 5-10 minute, add Sodium hexametaphosphate 99, aluminium triphosphate, titanium dioxide, boric acid, film-forming resin and leftover materials successively again, high-speed stirring 10-15 minute;
(2) material be stirred joined in sand mill grind, then filter with 500 order filter cloths.
Described high-temperature-resistant flame-retardant anti-rust paint, is characterized in that: described film-forming resin is prepared by the raw material of following weight part and obtains:
Alcohol ester 12 14-17, vinyl cyanide 2-3, methylolurea 1-2, Zirconium tetrafluoride 1-2, dimethyl tin oxide 1-2, ethyl acetate 12-14, Iron-ore Slag powder 1-2, sepiolite powder 3-4, wintergreen oil 1-2, nano-sized carbon 0.1-0.2, Vulcanization accelerator TMTD 1-2, linking agent TAC1-2; Zirconium tetrafluoride, Iron-ore Slag powder, sepiolite powder, wintergreen oil mix with ethyl acetate by preparation method, grinding distribution, then vinyl cyanide, methylolurea, Vulcanization accelerator TMTD, linking agent TAC is added, stir, be warming up to 45-50 DEG C, stirring reaction 30-45 minute, add other remaining component again, be warming up to 75-85 DEG C, stirring reaction 45-60 minute, to obtain final product.
The beneficial effect of the invention is: flame-retardant anti-rust paint of the present invention, has feature that is high temperature resistant, resistance combustion, simultaneously capable of coating with rust, can remove rust cleaning or phosphatization operation from, easy to use.
Embodiment
A kind of high-temperature-resistant flame-retardant anti-rust paint, be made up of the feed composition of following component weight (kilogram):
Resol 30, E-12 epoxy resin 38, Sodium hexametaphosphate 99 9, alcohol ester 12, trolamine 9, aluminium triphosphate 11, titanium dioxide 15, Tetra hydro Phthalic anhydride 3, boric acid 1, dimethylbenzene 22, cobalt naphthenate 5, cis-butenedioic anhydride 13, ethylene glycol 5, film-forming resin 4.
Preparation method comprises the following steps:
(1), the preparation of film-forming resin, film-forming resin is prepared by the raw material of following weight (kg) and obtains:
Alcohol ester 12, vinyl cyanide 3, methylolurea 1, Zirconium tetrafluoride 1, dimethyl tin oxide 2, ethyl acetate 14, Iron-ore Slag powder 2, sepiolite powder 3, wintergreen oil 1, nano-sized carbon 0.1, Vulcanization accelerator TMTD 1, linking agent TAC1,
Zirconium tetrafluoride, Iron-ore Slag powder, sepiolite powder, wintergreen oil mix with ethyl acetate by preparation method, grinding distribution, then vinyl cyanide, methylolurea, Vulcanization accelerator TMTD, linking agent TAC is added, stir, be warming up to 45-50 DEG C, stirring reaction 30-45 minute, then add other remaining component, be warming up to 75-85 DEG C, stirring reaction 45-60 minute and get final product;
(2), the preparation of high-temperature-resistant flame-retardant anti-rust paint, comprise the following steps:
A, first dimethylbenzene, ethylene glycol are added after reactor mixes, add resol, cobalt naphthenate, E-12 epoxy resin, cis-butenedioic anhydride, abundant stirring 15-20 minute, add Tetra hydro Phthalic anhydride, stir after 5-10 minute, add Sodium hexametaphosphate 99, aluminium triphosphate, titanium dioxide, boric acid, film-forming resin and leftover materials successively again, high-speed stirring 10-15 minute;
B, the material be stirred joined in sand mill and grinds, then filter with 500 order filter cloths, then the product after filtering is packed, warehouse-in.
Metallic anti-rust paint performance index of the present invention:
1, time of drying (25 DEG C): surface drying 15-25min, 32h is done solid work
2, snappiness mm≤2
3, hardness >=3H
4, high temperature resistant (130 DEG C) >=6000h
5, shock-resistance 56
6, salt spray resistance (120h level) >=2
7, water tolerance (29 ± 1 DEG C of 240h): non-foaming, does not come off
8, oil resistant (90# gasoline, 56h): non-foaming, does not come off
9, alkali resistance (GB/T9755-2001): by 48 hours
10, artificial weathering ageing resistance (GB/T9755-2001): by 1200 hours.
Claims (2)
1. a high-temperature-resistant flame-retardant anti-rust paint, is characterized in that being made up of the feed composition of following component weight part:
Resol 28-32, E-12 epoxy resin 36-40, Sodium hexametaphosphate 99 8-10, alcohol ester 12 5-8, trolamine 8-10, aluminium triphosphate 9-12, titanium dioxide 13-16, Tetra hydro Phthalic anhydride 3-4, boric acid 1-2, dimethylbenzene 20-23, cobalt naphthenate 4-5, cis-butenedioic anhydride 12-14, ethylene glycol 4-5, film-forming resin 4-5;
Described film-forming resin is prepared by the raw material of following weight part and obtains:
Alcohol ester 12 14-17, vinyl cyanide 2-3, methylolurea 1-2, Zirconium tetrafluoride 1-2, dimethyl tin oxide 1-2, ethyl acetate 12-14, Iron-ore Slag powder 1-2, sepiolite powder 3-4, wintergreen oil 1-2, nano-sized carbon 0.1-0.2, Vulcanization accelerator TMTD 1-2, linking agent TAC1-2; Zirconium tetrafluoride, Iron-ore Slag powder, sepiolite powder, wintergreen oil mix with ethyl acetate by preparation method, grinding distribution, then vinyl cyanide, methylolurea, Vulcanization accelerator TMTD, linking agent TAC is added, stir, be warming up to 45-50 DEG C, stirring reaction 30-45 minute, then add other remaining component, be warming up to 75-85 DEG C, stirring reaction 45-60 minute and get final product.
2. the preparation method of high-temperature-resistant flame-retardant anti-rust paint according to claim 1, is characterized in that, comprises the following steps:
(1) first dimethylbenzene, ethylene glycol are added after reactor mixes, add resol, cobalt naphthenate, E-12 epoxy resin, cis-butenedioic anhydride, abundant stirring 15-20 minute, add Tetra hydro Phthalic anhydride, stir after 5-10 minute, add Sodium hexametaphosphate 99, aluminium triphosphate, titanium dioxide, boric acid, film-forming resin and leftover materials successively again, high-speed stirring 10-15 minute;
(2) material be stirred joined in sand mill grind, then filter with 500 order filter cloths.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310468759.8A CN103602208B (en) | 2013-10-10 | 2013-10-10 | A kind of high-temperature-resistant flame-retardant anti-rust paint and preparation method thereof |
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| CN201310468759.8A CN103602208B (en) | 2013-10-10 | 2013-10-10 | A kind of high-temperature-resistant flame-retardant anti-rust paint and preparation method thereof |
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| CN103602208A CN103602208A (en) | 2014-02-26 |
| CN103602208B true CN103602208B (en) | 2016-01-20 |
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Families Citing this family (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104194572B (en) * | 2014-09-25 | 2016-07-13 | 芜湖县双宝建材有限公司 | A kind of corrosion-resistant anti-flaming dope |
| CN104194574B (en) * | 2014-09-28 | 2016-08-24 | 芜湖县双宝建材有限公司 | A kind of high fire-retardance high adhesion paint |
| CN104497780A (en) * | 2014-11-21 | 2015-04-08 | 芜湖市鸿坤汽车零部件有限公司 | Heat resistant anticorrosive paint and preparation method thereof |
| CN107841233A (en) * | 2017-11-29 | 2018-03-27 | 镇江兴润土石方工程有限公司 | A kind of green new excavator antirusting paint |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1442799A1 (en) * | 2001-10-17 | 2004-08-04 | Kansai Paint Co., Ltd. | Process for coating metallic bodies and primer compositions to be used in the process |
| CN101139497A (en) * | 2007-09-24 | 2008-03-12 | 广州擎天实业有限公司 | Anticorrosive paint capable of welding with paint film |
| CN101935498A (en) * | 2010-09-25 | 2011-01-05 | 江门市制漆厂有限公司 | Heat-resisting organic silicon antiseptic inner tank coating |
Family Cites Families (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| US7745010B2 (en) * | 2005-08-26 | 2010-06-29 | Prc Desoto International, Inc. | Coating compositions exhibiting corrosion resistance properties, related coated substrates, and methods |
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Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| EP1442799A1 (en) * | 2001-10-17 | 2004-08-04 | Kansai Paint Co., Ltd. | Process for coating metallic bodies and primer compositions to be used in the process |
| CN101139497A (en) * | 2007-09-24 | 2008-03-12 | 广州擎天实业有限公司 | Anticorrosive paint capable of welding with paint film |
| CN101935498A (en) * | 2010-09-25 | 2011-01-05 | 江门市制漆厂有限公司 | Heat-resisting organic silicon antiseptic inner tank coating |
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Denomination of invention: A kind of high temperature resistant flame retardant antirust paint and preparation method thereof Effective date of registration: 20220801 Granted publication date: 20160120 Pledgee: Xinhe Sub-branch of Anhui Qingyang Rural Commercial Bank Co., Ltd. Pledgor: ANHUI ZHENXIN PAINT Co.,Ltd. Registration number: Y2022980011723 |