CN103524907B - 一种矿用电缆橡胶护套料及其制备方法 - Google Patents

一种矿用电缆橡胶护套料及其制备方法 Download PDF

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CN103524907B
CN103524907B CN201310461657.3A CN201310461657A CN103524907B CN 103524907 B CN103524907 B CN 103524907B CN 201310461657 A CN201310461657 A CN 201310461657A CN 103524907 B CN103524907 B CN 103524907B
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何成龙
何源
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Chongqing Ke Fei wire cable Co., Ltd.
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Abstract

本发明公开了一种矿用电缆橡胶护套料及其制备方法，其由以下重量份的原料制成：氯磺化聚乙烯橡胶60-80、氯丁橡胶20-30、SG-2型聚氯乙烯树脂10-15、气相白碳黑15-20、轻质氧化镁2-3、氢氧化铝10-15、氯化石蜡4-8、锡酸锌3-6、三氧化二锑5-10、癸二酸二正己酯10-15、高耐磨炭黑N550？20-30、三烯丙基异三聚氰酸酯2-3、过氧化二异丙苯0.4-0.6、γ-缩水甘油醚丙基三甲氧基硅烷1-2、富马酸二辛脂8-12、防老剂OD？1-2、促进剂CZ？2-3、复合填料4-6。本发明制得的护套料具有优异的耐高温性、耐酸碱性和耐油性，且阻燃效果好，具有不延燃性和自熄灭性，燃烧时发烟量少，完全可靠，经久耐用，完全能够满足矿用电缆护套的需要。

Description

一种矿用电缆橡胶护套料及其制备方法
技术领域
本发明涉及一种电缆护套料及其制备方法，具体涉及一种矿用电缆橡胶护套料及其制备方法。
背景技术
电缆护套是电缆不可缺少的中间结构部分，起着保护电缆的作用，保证电缆的通电安全，让铜丝和水、空气等介质隔绝，避免出现漏电现象。其中矿用电缆大多是在井下高温、易燃和腐蚀性介质等恶劣工作环境中使用，因此要求矿用电缆的护套不仅具有优异的耐高温性、阻燃性，而且还要具有优异的耐酸碱、耐油等耐介质腐蚀性。
发明内容
本发明的目的在于提供一种矿用电缆橡胶护套料及其制备方法，该护套料具有优异的耐高温性、阻燃性、耐酸碱性和耐油性。
本发明采用的技术方案如下：
一种矿用电缆橡胶护套料，由以下重量份的原料制成：氯磺化聚乙烯橡胶60-80、氯丁橡胶20-30、SG-2型聚氯乙烯树脂10-15、气相白碳黑15-20、轻质氧化镁2-3、氢氧化铝10-15、氯化石蜡4-8、锡酸锌3-6、三氧化二锑5-10、癸二酸二正己酯10-15、高耐磨炭黑N55020-30、三烯丙基异三聚氰酸酯2-3、过氧化二异丙苯0.4-0.6、γ-缩水甘油醚丙基三甲氧基硅烷1-2、富马酸二辛脂8-12、防老剂OD1-2、促进剂CZ2-3、复合填料4-6；
所述复合填料的制备方法如下：a、按重量比4-8:3-6:2-4称取高岭土、硅藻土、白云石粉碎、混合均匀后湿法球磨18-24h，再在110-120℃下烘干，然后在550-580℃下煅烧1-2h，冷却至室温后加入适量的水打浆制成浓度为40-50%的浆液，然后加浓度为10-15%的盐酸溶液调节浆液PH至4.0-5.0，70-80℃水浴加热2-3h，再用浓度为15-20%的氢氧化钠溶液调节浆液PH至中性，然后加入浆液重量1-2%的十二烷基苯磺酸钠、2-3%的六偏磷酸钠、3-5%的聚丙烯酸、2-3%的水溶性硅溶胶、1-2%的羟乙基纤维素和0.5-1%的乙二醇丁醚醋酸酯，高速研磨20-30min，烘干，过300-400目筛；b、上述过筛后的粉末中加入1-2%的纳米氮化铝、2-3%的乙烯基硅油、3-4%的季戊四醇硬脂酸酯、1-2%的玉石粉，高速剪切分散10-15min即可。
一种矿用电缆橡胶护套料的制备方法，包括以下步骤：
（1）将氯磺化聚乙烯橡胶、氯丁橡胶、SG-2型聚氯乙烯树脂加入密炼机中，加热至55-65℃，混炼3-6min；然后升温至90-100℃，再加入轻质氧化镁、氢氧化铝、氯化石蜡、锡酸锌、三氧化二锑、高耐磨炭黑N550，混炼4-8min，再加入气相白碳黑、复合填料、γ-缩水甘油醚丙基三甲氧基硅烷、癸二酸二正己酯、富马酸二辛脂，继续混炼3-5min；然后降温至40-50℃，加入其余原料混炼2-3min，得到混炼胶；
（2）将上述混炼胶置于平板硫化机上，在155-175℃温度下硫化15-20min，即得所需的护套料。
本发明的有益效果：
本发明制得的护套料具有优异的耐高温性、耐酸碱性和耐油性，且阻燃效果好，具有不延燃性和自熄灭性，燃烧时发烟量少，完全可靠，经久耐用，完全能够满足矿用电缆护套的需要。
具体实施方式
一种矿用电缆橡胶护套料，由以下重量（kg）的原料制成：氯磺化聚乙烯橡胶70、氯丁橡胶20、SG-2型聚氯乙烯树脂10、气相白碳黑18、轻质氧化镁2、氢氧化铝12、氯化石蜡6、锡酸锌4、三氧化二锑8、癸二酸二正己酯15、高耐磨炭黑N55025、三烯丙基异三聚氰酸酯2、过氧化二异丙苯0.5、γ-缩水甘油醚丙基三甲氧基硅烷1、富马酸二辛脂10、防老剂OD1.5、促进剂CZ2、复合填料5；
所述复合填料的制备方法如下：a、按重量比6:5:3称取高岭土、硅藻土、白云石粉碎、混合均匀后湿法球磨22h，再在115℃下烘干，然后在580℃下煅烧1h，冷却至室温后加入适量的水打浆制成浓度为40%的浆液，然后加浓度为15%的盐酸溶液调节浆液PH至4.0，70℃水浴加热3h，再用浓度为20%的氢氧化钠溶液调节浆液PH至中性，然后加入浆液重量2%的十二烷基苯磺酸钠、%的六偏磷酸钠、4%的聚丙烯酸、3%的水溶性硅溶胶、1.5%的羟乙基纤维素和0.8%的乙二醇丁醚醋酸酯，高速研磨25min，烘干，过400目筛；b、上述过筛后的粉末中加入2%的纳米氮化铝、3%的乙烯基硅油、3%的季戊四醇硬脂酸酯、1.5%的玉石粉，高速剪切分散15min即可。
一种矿用电缆橡胶护套料的制备方法，包括以下步骤：
（1）将氯磺化聚乙烯橡胶、氯丁橡胶、SG-2型聚氯乙烯树脂加入密炼机中，加热至60℃，混炼4min；然后升温至95℃，再加入轻质氧化镁、氢氧化铝、氯化石蜡、锡酸锌、三氧化二锑、高耐磨炭黑N550，混炼6min，再加入气相白碳黑、复合填料、γ-缩水甘油醚丙基三甲氧基硅烷、癸二酸二正己酯、富马酸二辛脂，继续混炼3min；然后降温至45℃，加入其余原料混炼2min，得到混炼胶；
（2）将上述混炼胶置于平板硫化机上，在165℃温度下硫化18min，即得所需的护套料。
制得的护套料的性能测试结果如下：

Claims (2)

1.一种矿用电缆橡胶护套料，其特征在于，由以下重量份的原料制成：氯磺化聚乙烯橡胶60-80、氯丁橡胶20-30、SG-2型聚氯乙烯树脂10-15、气相白碳黑15-20、轻质氧化镁2-3、氢氧化铝10-15、氯化石蜡4-8、锡酸锌3-6、三氧化二锑5-10、癸二酸二正己酯10-15、高耐磨炭黑N55020-30、三烯丙基异三聚氰酸酯2-3、过氧化二异丙苯0.4-0.6、γ-缩水甘油醚丙基三甲氧基硅烷1-2、富马酸二辛酯8-12、防老剂OD1-2、促进剂CZ2-3、复合填料4-6；所述复合填料的制备方法如下：a、按重量比4-8:3-6:2-4称取高岭土、硅藻土、白云石粉碎、混合均匀后湿法球磨18-24h，再在110-120℃下烘干，然后在550-580℃下煅烧1-2h，冷却至室温后加入适量的水打浆制成浓度为40-50%的浆液，然后加浓度为10-15%的盐酸溶液调节浆液pH至4.0-5.0，70-80℃水浴加热2-3h，再用浓度为15-20%的氢氧化钠溶液调节浆液pH至中性，然后加入浆液重量1-2%的十二烷基苯磺酸钠、2-3%的六偏磷酸钠、3-5%的聚丙烯酸、2-3%的水溶性硅溶胶、1-2%的羟乙基纤维素和0.5-1%的乙二醇丁醚醋酸酯，高速研磨20-30min，烘干，过300-400目筛；b、上述过筛后的粉末中加入1-2%的纳米氮化铝、2-3%的乙烯基硅油、3-4%的季戊四醇硬脂酸酯、1-2%的玉石粉，高速剪切分散10-15min即可。
2.如权利要求1所述的矿用电缆橡胶护套料的制备方法，其特征在于包括以下步骤：将氯磺化聚乙烯橡胶、氯丁橡胶、SG-2型聚氯乙烯树脂加入密炼机中，加热至55-65℃，混炼3-6min；然后升温至90-100℃，再加入轻质氧化镁、氢氧化铝、氯化石蜡、锡酸锌、三氧化二锑、高耐磨炭黑N550，混炼4-8min，再加入气相白碳黑、复合填料、γ-缩水甘油醚丙基三甲氧基硅烷、癸二酸二正己酯、富马酸二辛酯，继续混炼3-5min；然后降温至40-50℃，加入其余原料混炼2-3min，得到混炼胶；将上述混炼胶置于平板硫化机上，在155-175℃温度下硫化15-20min，即得所需的护套料。
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CN104277347A (zh) * 2014-10-27 2015-01-14 安徽锐视光电技术有限公司 一种色选机用环保合成橡胶及其制备方法
CN104327400A (zh) * 2014-10-30 2015-02-04 安徽电信器材贸易工业有限责任公司 一种环保抗静电电缆料及其制备方法
CN107342130B (zh) * 2017-05-16 2019-07-02 安徽瑞鑫自动化仪表有限公司 一种仪表用电缆
CN111499981A (zh) * 2020-04-10 2020-08-07 安徽龙庵电缆集团有限公司 一种风力发电用氯磺化聚乙烯橡胶护套料及其制备方法
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Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102977434A (zh) * 2012-11-02 2013-03-20 铜陵市明诚铸造有限责任公司 一种纳米钾长石粉改性的氯丁橡胶密封垫及其制备方法
CN102993585A (zh) * 2012-10-31 2013-03-27 蚌埠凯盛工程技术有限公司 一种氯磺化聚乙烯橡胶/氯丁橡胶密封垫及其制备方法

Patent Citations (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN102993585A (zh) * 2012-10-31 2013-03-27 蚌埠凯盛工程技术有限公司 一种氯磺化聚乙烯橡胶/氯丁橡胶密封垫及其制备方法
CN102977434A (zh) * 2012-11-02 2013-03-20 铜陵市明诚铸造有限责任公司 一种纳米钾长石粉改性的氯丁橡胶密封垫及其制备方法

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