CN103517955B - 水性丙烯酸涂料体系和改善纹理化的木材表面外观的方法 - Google Patents
水性丙烯酸涂料体系和改善纹理化的木材表面外观的方法 Download PDFInfo
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- CN103517955B CN103517955B CN201280009424.3A CN201280009424A CN103517955B CN 103517955 B CN103517955 B CN 103517955B CN 201280009424 A CN201280009424 A CN 201280009424A CN 103517955 B CN103517955 B CN 103517955B
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Abstract
本发明涉及单组分(1K)涂料体系,其包含水性聚丙烯酸酯聚合物分散体和元素周期表第5和/或6副族元素的一种或多种化合物,其中所述具体元素具有至少+4的氧化态。
Description
本发明涉及包含聚丙烯酸酯聚合物的基础丙烯酸涂料体系,其用于增强纹理化木材表面(grained wood surface)的外观。本发明还涉及改善纹理化木材表面外观的方法,本发明的涂料体系用于涂布纹理化的木材表面的用途,以及包含通过涂布本发明的涂料体系和随后干燥该涂料体系而获得的涂层的纹理化木材表面。
水性涂料组合物正不断代替包含溶剂的体系来使用,目标是减少有机溶剂的排放。聚丙烯酸酯分散体包含一个重要类的水性漆基料(binders),其以相对持久公知,并通过丙烯酸或乙烯基单体在乳液聚合条件下的自由基聚合来制备。
聚丙烯酸酯分散体结合了耐水、耐化学品和耐久性的重要性质。因此,对于室内和室外应用,特别是对于涂布同时暴露于机械应力和湿气的表面,采用聚丙烯酸酯分散体是有利的。
木材纹理的外观在透明木材清漆中是重要点。木材内的高对比度对于木材表面比如镶花地板(parquet flooring)和家具是所希望的。
因此本发明的目的是提供涂料体系和方法,其用于以简单方式增强木材的纹理化外观,而没有牺牲涂料体系的其它积极特征比如耐化学品性和耐水性。
根据本发明,此目的是通过单组分涂料体系实现的,所述单组分涂料体系包含
水性聚丙烯酸酯聚合物分散体,和
元素周期表第5和/或6副族元素的一种或多种化合物,其中所述具体元素具有至少+4的氧化态,
其中所述聚丙烯酸酯聚合物不包含任何氨基甲酸酯(urethane)结构部分(urethane moieties)并且涂料体系不包含任何选自由酮亚胺基固化剂,脂族胺固化剂,芳族胺固化剂,聚酰胺固化剂,硫醇-基固化剂,异氰酸酯,,封端形式的异氰酸酯,多异氰酸酯加成物,封端形式的多异氰酸酯加成物,和异氰酸酯官能单体的(共)聚合物的固化剂。
氨基甲酸酯结构部分表示结构式-NH-C(=O)-O-的二价基团。
惊奇地发现上述元素周期表第5和/或6副族元素的化合物加入到包含聚丙烯酸酯聚合物的水性分散体中,当与缺乏这些化合物的那些水性分散体相比时,导致所希望的木材中纹理的对比度方面的改进。因此,现有的聚合物基料可以被使用,使得额外的配方研发需求减少。
胺固化剂是脂族胺和它们的加成物(如2021),烷基酚醛胺(phenalkamines),脂环族胺(如2196),酰氨-胺(如2426),聚酰胺和它们的加成物,以及其混合物。
异氰酸酯固化剂是脂族的、脂环族的、和芳族的多异氰酸酯,比如三亚甲基二异氰酸酯,1,2-亚丙基二异氰酸酯,四亚甲基二异氰酸酯,2,3-亚丁基二异氰酸酯,六亚甲基二异氰酸酯,八亚甲基二异氰酸酯,2,4-三甲基六亚甲基二异氰酸酯,2,4,4-三甲基六亚甲基二异氰酸酯,十二亚甲基二异氰酸酯,α,α’-二丙基醚二异氰酸酯,1,3-亚环戊基二异氰酸酯,1,2-亚环己基二异氰酸酯,1,4-亚环己基二异氰酸酯,4-甲基-1,3-亚环己基二异氰酸酯,4,4’-二亚环己基二异氰酸酯甲烷,3,3’-二甲基-4,4’-二亚环己基二异氰酸酯甲烷,间-和对-亚苯基二异氰酸酯,1,3-和1,4-双(异氰酸酯甲基)苯,1,5-二甲基-2,4-双(异氰酸酯甲基)苯,1,3,5-三异氰酸酯苯(1,3,5-thisocyanate benzene),2,4-甲苯二异氰酸酯,2,6-甲苯二异氰酸酯,2,4,6-甲苯三异氰酸酯,α,α,α’,α’-四甲基邻-、间、和对亚二甲苯基二异氰酸酯(α,α,α',α'-tetramethyl o-,m-,and p-xylylene diisocyanate),4,4’-二亚苯基二异氰酸酯甲烷,4,4’-二亚苯基二异氰酸酯,3,3’-二氯-4,4’-二亚苯基二异氰酸酯,萘-1,5-二异氰酸酯,异佛尔酮二异氰酸酯,反式亚乙烯基二异氰酸酯(transvinylidene diisocyanate),以及前述多异氰酸酯的混合物。多异氰酸酯的加成物是,例如缩二脲,异氰脲酸酯,脲基甲酸酯(allophonates),脲二酮(uretdiones),和它们的混合物。这些加成物的实例是,两分子六亚甲基二异氰酸酯或异佛尔酮二异氰酸酯对二醇比如乙二醇的加成物,3分子的六亚甲基二异氰酸酯和1分子水的反应产物,1分子三羟甲基丙烷对3分子的异佛尔酮二异氰酸酯的加成物,1分子的季戊四醇对4分子的甲苯二异氰酸酯的加成物,六亚甲基二异氰酸酯的异氰脲酸酯(N3390),六亚甲基二异氰酸酯的脲二酮(N3400),六亚甲基二异氰酸酯的脲基甲酸酯(LS2101),和异佛尔酮二异氰酸酯的异氰脲酸酯(T1890)。此外,异氰酸酯官能单体的(共)聚合物包括α,α’-二甲基-间-异丙烯基苄基异氰酸酯。
本发明中采用的水性聚合物分散体的溶剂是水和,任选地,在配制过程中加入的有机溶剂或有机溶剂混合物,以在室温下更好成膜。
作为有机溶剂有可能采用所有的已知溶剂。在漆工业当中使用的优选的溶剂比如,脂族烃(如矿油精(mineral spirit),煤油,高闪点VM&P石脑油,和类似物);芳香烃(如苯,甲苯,二甲苯,溶剂石脑油100,150,200和类似物);醇类(如乙醇,正丙醇,异丙醇,正丁醇,异丁醇和类似物),酮类(如丙酮,2-丁酮,环己酮,甲基芳基酮类,乙基芳基酮类,甲基异戊基酮类,和类似物);酯类(如乙酸乙酯,乙酸丁酯,和类似物);二醇类(如丁二醇);二醇醚(如甲氧基丙醇);二醇醚类(如乙二醇单甲醚,乙二醇单乙醚,乙二醇单丁醚,丙二醇单甲醚,和类似物);二醇酯类(如丁基二醇乙酸酯,甲氧基丙基乙酸酯和类似物);以及它们的混合物。
任选地,有机溶剂的用量优选基于涂料体系的总体重量在0.1-10%的重量范围内,更优选0.1-8%的重量范围内,最优选0.1-5%的重量范围内。
通过传统方法由本发明的单组分涂料体系制备漆、油墨和其它制剂。
本发明的水性涂料体系适合用于使用对于膜的耐受性有着严格要求的水性涂漆和涂料体系的所有应用领域。特别地,这是指木材和木材基材料的涂布和密封(sealing),并且在这里作为透明底漆,和/或面漆材料,清漆材料和高光泽及亚光涂层材料,潜在地可用于完整涂布装置的所有涂层的构建。
优选地,木材和木材基材料涂布在通常的处理温度下比如5℃-100℃下。
关于优选的实施方案,本发明会进一步进行说明,除非明确的另外指出,所述实施方案可以自由组合。
根据本发明的方法的另一实施方案,聚丙烯酸酯聚合物可以通过下述材料的反应获得:
(a)0-60重量%的选自苯乙烯和/或其它乙烯基芳族化合物的至少一种化合物,和
(b)0-99.5重量%的至少一种丙烯酸酯,和
(c)0.5-5重量%的至少一种酸官能的、烯属不饱和单体,和
(d)0-99.5重量%至少一种甲基丙烯酸酯,
其中组分(a)-(d)总重量比例为100重量%。
合适的乙烯基芳族化合物(a)是,例如,乙烯基甲苯,邻-和对-甲基苯乙烯,丁基苯乙烯,4-正丁基苯乙烯,4-正癸基苯乙烯,卤代苯乙烯如单氯苯乙烯,二氯苯乙烯,三溴苯乙烯或四溴苯乙烯。苯乙烯是优选的。
合适的丙烯酸酯(b)特别地包含,丙烯酸甲酯,丙烯酸乙酯,丙烯酸丙酯,丙烯酸异丙酯,丙烯酸正丁酯,丙烯酸仲丁酯,丙烯酸叔丁酯,丙烯酸戊酯,丙烯酸己酯,丙烯酸庚酯,丙烯酸辛酯,丙烯酸2-辛酯,丙烯酸乙基己酯,丙烯酸壬基酯,丙烯酸2-甲基-辛酯,丙烯酸2-叔丁基庚酯,丙烯酸3-异-丙基庚酯,丙烯酸癸酯,丙烯酸十一烷基酯,丙烯酸5-甲基十一烷基酯,丙烯酸十二烷基酯,丙烯酸2-甲基十二烷基酯,丙烯酸十三烷基酯,丙烯酸5-甲基十三烷基酯,丙烯酸十四烷基酯,丙烯酸十五烷基酯,丙烯酸十六烷基酯,丙烯酸2-甲基十六烷基酯,丙烯酸十七烷基酯,丙烯酸5-异丙基十七烷基酯,丙烯酸5-乙基十八烷基酯,丙烯酸十八烷基酯,丙烯酸十九烷基酯,丙烯酸二十烷基酯,丙烯酸环烷基酯例如,丙烯酸环戊酯,丙烯酸环己酯,丙烯酸3-乙烯基-2-丁基环己酯,丙烯酸环庚酯,丙烯酸环辛酯,丙烯酸冰片酯,丙烯酸四氢糠基酯和丙烯酸异冰片酯。优选的是,丙烯酸乙酯,丙烯酸正丁酯,丙烯酸乙基己酯,丙烯酸环己酯;特别优选的是,丙烯酸乙酯,丙烯酸正丁酯,或丙烯酸乙基己酯。
合适的烯属不饱和的、酸官能的单体是,砜、磷酸酯或羧酸官能的单体,不饱和羧酸官能的单体例如,丙烯酸,甲基丙烯酸,丙烯酸β-羧基乙基酯(β-carboxyethylacrlate),巴豆酸,富马酸,马来酸酐,衣康酸或二元酸或酸酐的单烷基酯比如马来酸单烷基酯是优选的。此外,具有磷酸酯或膦酸酯基团或磺酸或磺酸酯基团的不饱和的、可自由基聚合的化合物,比如WO-A00/39181(p.8,1.13-p.9,1.19)中描述的,也适合作为组分(d)的化合物。丙烯酸和甲基丙烯酸是特别优选的;丙烯酸最优选。
合适的甲基丙烯酸酯(d)具体地包括,甲基丙烯酸甲酯,甲基丙烯酸乙酯,甲基丙烯酸丙酯,甲基丙烯酸异丙酯,甲基丙烯酸正丁酯,甲基丙烯酸仲丁酯,甲基丙烯酸叔丁酯,甲基丙烯酸戊酯,甲基丙烯酸己酯,甲基丙烯酸庚酯,甲基丙烯酸辛酯,甲基丙烯酸2-辛酯,甲基丙烯酸乙基己酯,甲基丙烯酸壬基酯,甲基丙烯酸2-甲基-辛酯,甲基丙烯酸2-叔丁基庚酯,甲基丙烯酸3-异-丙基庚酯,甲基丙烯酸癸酯,甲基丙烯酸十一烷基酯,甲基丙烯酸5-甲基十一烷基酯,甲基丙烯酸十二烷基酯,甲基丙烯酸2-甲基十二烷基酯,甲基丙烯酸十三烷基酯,甲基丙烯酸5-甲基十三烷基酯,甲基丙烯酸十四烷基酯,甲基丙烯酸十五烷基酯,甲基丙烯酸十六烷基酯,甲基丙烯酸2-甲基十六烷基酯,甲基丙烯酸十七烷基酯,甲基丙烯酸5-异丙基十七烷基酯,甲基丙烯酸5-乙基十八烷基酯,甲基丙烯酸十八烷基酯,甲基丙烯酸十九烷基酯,甲基丙烯酸二十烷基酯,甲基丙烯酸环烷基酯例如,甲基丙烯酸环戊酯,甲基丙烯酸环己酯,甲基丙烯酸3-乙烯基-2-丁基环己酯,甲基丙烯酸环庚酯,甲基丙烯酸环辛酯,甲基丙烯酸冰片酯,甲基丙烯酸四氢糠基酯和甲基丙烯酸异冰片酯。此外,也可使用相应腈或酰胺的形式的甲基丙烯酸衍生物,例如甲基丙烯腈或甲基丙烯酰胺。并且根据所需的应用可以使用其它官能的单体,例如双丙酮甲基丙烯酰胺或甲基丙烯酸乙酰乙酸基乙酯(acetoacetoxyethyl methacrylate)。优选的是,甲基丙烯酸甲酯,甲基丙烯酸乙酯,甲基丙烯酸丁酯,甲基丙烯酸叔丁酯;特别优选的是甲基丙烯酸甲酯,甲基丙烯酸叔丁酯或甲基丙烯酸丁酯。
根据本发明的另一实施方案,组分a)、b)、c)和d)以下述量存在,基于a)、b)、c)和d)的重量,a)、b)、c)和d)的百分比加起来为100重量%:
a)≥10重量%到≤70重量%,优选的是≥20重量%到≤60重量%;
b)≥10重量%到≤80重量%,优选的是≥20重量%到≤70重量%;
c)≥0.5重量%到≤4重量%,优选的是≥0.5重量%到≤2重量%;
d)≥10重量%到≤80重量%,优选的是≥20重量%到≤702重量%;
聚丙烯酸酯分散体的制备以本身已知的方式进行,比如利用乳液聚合。便利地,通过流入法(inflow method)进行,其中,合适地,水、乳化剂和少量引发剂首先加入。在进行其时,合适地,所加入的材料优选含有基于水的总量40到80重量份的水,基于固体物质0.1到1.5重量份的乳化剂,和基于固体物质0.01到0.3%重量的引发剂,其中,给定的重量份数加起来达100.00重量份。随后,加入少量的单体,优选5-15%的重量,以及同时任选加入引发剂,优选0.01-0.3%的重量,以形成在其上发生进一步的聚合步骤的内部种子(internalseed)。
然后将前述比例的单体连续地添加至该内部种子,并且聚合直至转化率基于它们分别的总重量至少为95.0%的重量,优选至少98.0%的重量,更优选至少99.0%的重量,最优选至少99.5%的重量。
通常,乳液在30-100℃,优选50-90℃的温度下聚合。
包含聚丙烯酸酯聚合物的分散体尤其通过离子型和/或非离子型乳化剂和/或保护性胶体稳定的。作为离子生成型(ionogenic)乳化剂,主要地阴离子型乳化剂是可以想到。这些可以是烷基、芳基或烷芳基磺酸酯、磷酸酯、膦酸酯或具有其它阴离子端基的化合物的碱金属或铵盐,其中低聚-或聚环氧烷单元还可以位于烃基和阴离子基团之间。典型的例子包括,十二烷基硫酸钠,十二烷基二乙二醇硫酸钠(sodiumlauryldiglykolsulphate),癸基乙二醇醚硫酸钠(sodium decylglykoethersulphate),辛基苯酚乙二醇醚硫酸钠(sodium octylphenolglykolethersulphate),或十二烷基benol硫酸钠(sodium dodecylbenolsulphate)。
作为非离子型乳化剂,通常使用烷基聚乙二醇醚类(alkylpolyglycol ethers),如月桂醇、油醇或十八烷醇或混合物如椰子油醇的乙氧基化产物。烷基酚聚乙二醇醚类,如辛基苯酚或壬基苯酚、二异丙基苯酚、三异丙基苯酚、二或三叔丁基苯酚的乙氧基化产物,也是适合的。除提及的化合物种类之外,还可以使用环氧丙烷的乙氧基化产物。
作为合适的保护胶体,使用天然物质,如阿拉伯胶、淀粉、藻酸盐,或改性天然物质,如甲基纤维素、乙基纤维素、羟烷基纤维素或羧甲基纤维素,或合成物质,如聚乙烯醇或改性聚乙烯醇或聚乙烯吡咯烷酮。
还可以通过相应的官能化来改性乳化剂以使它们与所述单体(表面活性单体(surfmer))自由基共聚合。
此外,也可以使用上述乳化剂的混合物。
优选使用磷酸烷基酯,如非离子型聚氧乙烯加合物(adducts)的磷酸酯(以Dextrol名称可从美国Hercules firm获得),作为乳化剂。基于固体物质,乳化剂的总量为0.3-1.5重量%,优选0.3-1.0重量%。
乳液通常在30-100℃,优选50-90℃下聚合。聚合介质可以由水单独组成或由水和可与其溶混的液体(如甲醇)的混合物组成。优选仅使用水。乳液聚合可以作为间歇法和以包括阶段或梯度(gradient)操作的流入法的形式这二者来进行;优选流入法。对于流入法,聚合以相对小的单体垫(monomer pad)实施,其中以经多个空间分隔地流入的阶段或梯度形式,连续地添加纯的或乳化形式的一种或多种单体和大部分水溶性助剂。通过内部种子的原位形成来设定粒度,所述种子的粒度由乳化剂对单体的比率来确定。也可以通过首先加入具有规定粒度的外部种子来控制粒度。在自由基水性乳液聚合过程中,引发剂添加到聚合容器中的方式对本领域技术人员来说是已知的。可以首先完全地加入它或按照它在自由基水性乳液聚合中的消耗量连续地或分阶段地使用它。特别地,这取决于引发剂体系的化学性质以及聚合温度。优选地首先加入一部份以及其余的按照消耗量提供给聚合区域。
聚丙烯酸酯聚合物具有根据DIN55672/1测定的优选103到106g/mol范围,更优选104到5×105g/mol范围,最优选2×104到2×105g/mol范围的重均分子质量Mw。
优选地,涂料体系的聚丙烯酸酯聚合物具有40到200nm范围内,更优选80到160nm范围内的平均粒径。粒径通过激光相关光谱学(仪器:Malvern Zetasizer 1000,MalvernInstruments LTD)确定,以及给出了Z-均至(Z-averages)。
本发明要求保护的涂料体系优选具有10-70重量%,更优选25-60重量%和最优选35-55重量%的固体质量含量,根据DIN-EN ISO 3251测定。
聚丙烯酸酯聚合物分散体组组合物的粘度可以是介于5和300mPa·s,优选介于10和150mPa·s,最优选介于15和100mPa·s。粘度的测定是根据DIN53019采用Fa.Haake的VT-500旋转粘度计(rotation viscosimeter)来进行。
本发明涂料体系的另一实施方案当中,元素周期表中第5和/或6副族元素的化合物是选自钒,钽,钼,和钨的元素的化合物。
依照本发明采用的钼和/或钨的化合物的实例可以选自钼酸铵,钼酸锂,钼酸钠,钼酸钾,钼酸铷,钼酸铯,仲钼酸铵(NH4)6Mo7O24.4H2O,二乙酰丙酮氧钼MoO2(C5H7O5)2,四甲基庚二酮二氧化钼(molybdenum dioxide tetramethylheptadionate)MoO2(TMHD)2,由1,2、1,3、和/或1,4二醇例如乙二醇,丙二醇,或1,4-丁二醇形成的烷醇钼,钼酸,钼氧化物,钼酸四乙基铵,钨酸钠,钼酸镁,钼酸钙,钨酸,钨酸锂和磷钨酸。
优选地,元素周期表中第5和/或6副族元素的化合物选自钼酸铵,钼酸锂,钼酸钠,钼酸钾,钼酸铷,钼酸铯,仲钼酸铵,二乙酰丙酮氧钼,(四甲基庚二酮)二氧化钼,1,2、1,3、和/或1,4二醇的钼醇化物,氧化钼,钼酸四乙基铵,钼酸镁和钼酸钙。钼酸锂是特别优选的。
根据本发明涂料体系的另一实施方案当中,元素周期表中第5和/或6副族元素的化合物在水性分散体中的存在量是≥0.0001重量%到≤0.1重量%。优选的范围是≥0.001重量%到≤0.05重量%。这些化合物的效力与其加入方式无关。它们可以直接加入分散体中或也可以在之前的步骤过程中在分散体制备中加入。
本发明还涉及改善纹理化的木材表面外观的方法,其包括以下步骤:
-提供纹理化的木材表面,和
-将包含水性聚丙烯酸酯聚合物分散体和元素周期表第5和/或6副族元素的一种或多种化合物的涂料体系施加到所述纹理化的木材表面,其中所述元素具有至少+4的氧化态,其中所述聚丙烯酸酯聚合物不包含任何氨基甲酸酯结构部分。
关于木材,术语“纹理”指的是由于在不同季节出现的不同生长参数导致的相对较深和较浅木材的交替区域。纹理化的木材表面因而是表现出不同于纤维板的这种交替区域的表面。优选地,木材表面换句话说在涂布分散体之前未经处理。
根据本发明的方法,将涂料体系施加到所述纹理化的木材表面。所述施加通常可以通过例如喷涂,利用光面辊,凹印辊(gravure roller),丝网辊(screen roller),以绢印(serigraphy),也可以旋转绢印,和利用刮刀涂布器,带腔的刮刀(chambered doctorblade)或旋转刮刀来实现。
优选地,木材表面选自由橡木,枫木,桦木,柚木,孪叶苏木(Jatoba wood),萨佩莱木(sapele wood),美洲胡桃木,山毛榉木,樱桃木,中国枫木,香脂木豆木(santosmohagony wood)和甘巴豆(kempas)木。
本发明再又一个方面是根据本发明的涂料体系用于涂布纹理化的木材表面的用途。
本发明也指向包含涂层的纹理化的木材表面,所述涂层通过施加本发明的涂料体系并随后干燥所述涂料体系而得到。优选地,所述木材表面选自橡木,枫木,桦木,柚木,孪叶苏木,萨佩莱木,美洲胡桃木,山毛榉木,樱桃木,中国枫木,香脂木豆木和甘巴豆木。涂料体系的干燥可以在用于处理1K基料体系的通常温度下,优选在20-100℃的温度下,更优选在20℃和50℃的温度下进行,优。
本发明就下述实施例的方式进行进一步说明,但并不想要受它们限制。
实施例
1.方法
1.1粒径的测定
平均粒径(APS)通过激光相关光谱学(仪器:Malvern Zetasizer 1000,MalvernInstruments LTD)测定,以及给出了Z-均值。
1.2固体物质含量测定(SMC)
固体物质含量依照DIN-EN ISO 3251来测定。
1.3粘度的测定
粘度的测定可以根据DIN 53019采用Fa.Haake的VT-500旋转粘度计来进行。
术语表:
Sty 苯乙烯,Aldrich,德国
MMA 甲基丙烯酸甲酯,Aldrich,德国
n-BA 丙烯酸正丁酯,Aldrich,德国
AA 丙烯酸,Aldrich,德国
APS 过硫酸铵,Aldrich,德国
Dextrol40(PHT)离子型表面活性剂,CAS 009046-01-9(>25%),CAS024938-91-8(<10%),CAS 007664-38-2(<10%)的混合物,Hercules,美国
分散体1:水性单组分(1K)聚丙烯酸酯分散体
在一个3L的具备可控制的加热和冷却和搅拌器马达的玻璃反应器中,在氮气气氛下,首先加入水和4.5g的Dextrol40。随后,将溶液加热到给定温度。在达到聚合温度后,通过计量泵在30分钟内加入包含14.1gMMA、2.5gBA和14g Sty的单体混合物以及0.5gAPS在22g水中的引发剂混合物,以制备内部种子。然后,在相应温度下,在120分钟内加入包含123g MMA、14g BA、130g Sty和9.4g AA的单体混合物,以及2.2g APS和2.5g Dextrol在300g水中的水溶液,以制备核。在核聚合后,通过加入包含200.6g MMA、230g BA、183g Sty和9.4g AA的单体混合物以及同时2.2g APS和2.5g Dextrol在300g水中的水溶液立即开始壳的添加。
在单体混合物和水性溶液的加入完成后,0.5g APS在50g水中的水溶液在60分钟内加入,用于未反应单体的后活化(post-activation)。分散体继续搅拌60分钟的时间并接下来冷却。为了设定pH为7,缓慢滴加相应量的氨溶液,并将完成的分散体通过125mm过滤器排出。形成具备下述性质的材料:
固体含量:39.9%(稀释的)
平均粒度:101nm
pH:7.4
粘度:25mPa·S
实施例1(比较例)
制备以下配制剂(给出的数字是重量百分数):
实施例2
制备与实施例1相同的配制剂。另外地,在制备后加入35ppm的Li2MoO4。
如在实施例1和2描述的配制剂在增稠剂溶液的协助下设定为25-30秒的流杯粘度(flow cup viscosity),并用刷子施加至橡木表面(大约120g/m2)。在室温下干燥6小时后,轻微砂磨第一层,然后施加第二涂层(120g/m2)。在第二层干燥后,木材的着色(coloring)强度按照1-5的等级进行视觉评价。1的值为没有表现出木材纹理的不希望的情况,和5为(希望的)纹理的强烈表现。
结果总结在下面(PAC:聚丙烯酸酯)
Claims (12)
1.单组分涂料体系,其包含:
水性聚丙烯酸酯聚合物分散体,和
元素周期表第5和/或6副族元素的一种或多种化合物,其中所述具体元素具有至少+4的氧化态,
其中所述聚丙烯酸酯聚合物不包含任何氨基甲酸酯结构部分并且所述涂料体系不包含任何选自酮亚胺基固化剂,脂族胺固化剂,芳族胺固化剂,聚酰胺固化剂,硫基固化剂,异氰酸酯,异氰脲酸酯,异氰酸酯官能单体的(共)聚合物和封端的异氰酸酯的固化剂,
并且元素周期表中第5和/或6副族元素的化合物在水性分散体中的存在量是≥0.0001重量%到≤0.1重量%。
2.根据权利要求1的涂料体系,其中所述聚丙烯酸酯聚合物通过以下材料的反应获得:
(a) 0-60重量%的选自苯乙烯和/或其它乙烯基芳族化合物的至少一种化合物,和
(b) 0-99.5重量%的至少一种丙烯酸酯,和
(c) 0.5-5重量%的至少一种酸官能的烯属不饱和单体,和
(d) 0-99.5重量%至少一种甲基丙烯酸酯,
其中所述组分(a)至(d)的总重量比例为100重量%。
3.根据权利要求1的涂料体系,其中所述元素周期表中第5和/或6副族元素的化合物为选自钒,钽,钼,和钨的元素的化合物。
4.根据权利要求1或3的涂料体系,其中所述元素周期表中第5和/或6副族元素的化合物选自钼酸铵,钼酸锂,钼酸钠,钼酸钾,钼酸铷,钼酸铯,仲钼酸铵,二乙酰丙酮氧钼,四甲基庚二酮二氧化钼,1,2、1,3、和/或1,4二醇的钼醇化物,氧化钼,钼酸四乙基铵,钼酸镁和钼酸钙。
5.根据权利要求1,3或4的涂料体系,其中所述元素周期表第5和/或6副族元素的化合物在所述水性分散体中的存在量为≥0.0001重量%到≤0.1重量%。
6.改善纹理化的木材表面外观的方法,该方法包括以下步骤:
-提供纹理化的木材表面,和
-将包含水性聚丙烯酸酯聚合物分散体和元素周期表中第5和/或6副族元素的一种或多种化合物的涂料体系施加至所述纹理化的木材表面,其中所述具体元素具有至少+4的氧化态,其中所述聚丙烯酸酯聚合物不包含任何氨基甲酸酯结构部分,并且元素周期表中第5和/或6副族元素的化合物在水性分散体中的存在量是≥0.0001重量%到≤0.1重量%。
7.根据权利要求6的方法,其中所述聚丙烯酸酯聚合物通过以下材料的反应获得:
(a) 0-60重量%的选自苯乙烯和/或其它乙烯基芳族化合物的至少一种化合物,和
(b) 0-99.5重量%的至少一种丙烯酸酯,和
(c) 0.5-5重量%的至少一种酸官能的烯属不饱和单体,和
(d) 0-99.5重量%至少一种甲基丙烯酸酯,
其中组分(a)至(d)的总重量比例为100重量%。
8.根据权利要求6的方法,其中所述元素周期表中第5和/或6副族元素的化合物为选自钒,钽,钼,和钨的元素的化合物。
9.根据权利要求6或8的方法,其中所述元素周期表第5和/或6副族元素的化合物选自钼酸铵,钼酸锂,钼酸钠,钼酸钾,钼酸铷,钼酸铯,仲钼酸铵,二乙酰丙酮氧钼,四甲基庚二酮二氧化钼,1,2、1,3、和/或1,4二醇的钼醇化物,氧化钼,钼酸四乙基铵,钼酸镁和钼酸钙。
10.根据权利要求7、8或9的涂料体系,其中所述元素周期表中第5和/或6副族元素的化合物在所述水性分散体中的存在量为≥0.0001重量%到≤0.1重量%。
11.包含水性聚丙烯酸酯聚合物分散体和元素周期表第5和/或6副族元素的一种或多种化合物的涂料体系用于涂布纹理化木材表面的用途,其中所述具体元素具有至少+4的氧化态,其中所述聚丙烯酸酯聚合物不包含任何氨基甲酸酯结构部分,并且元素周期表中第5和/或6副族元素的化合物在水性分散体中的存在量是≥0.0001重量%到≤0.1重量%。
12.纹理化的木材表面,所述表面包含涂层,该涂层通过将包含水性聚丙烯酸酯聚合物分散体和元素周期表第5和/或6副族元素的一种或多种化合物的涂料体系施加到所述纹理化木材表面以及随后干燥所述涂料体系来获得,其中所述具体元素具有至少+4的氧化态,其中所述聚丙烯酸酯聚合物不包含任何氨基甲酸酯结构部分,并且元素周期表中第5和/或6副族元素的化合物在水性分散体中的存在量是≥0.0001重量%到≤0.1重量%。
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US9624387B2 (en) | 2017-04-18 |
EP2675855A1 (en) | 2013-12-25 |
WO2012110515A1 (en) | 2012-08-23 |
EP2675855B1 (en) | 2016-06-08 |
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