CN103509655A - Liquid detergent contained in non-gaseous foaming container - Google Patents
Liquid detergent contained in non-gaseous foaming container Download PDFInfo
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- CN103509655A CN103509655A CN201310250292.XA CN201310250292A CN103509655A CN 103509655 A CN103509655 A CN 103509655A CN 201310250292 A CN201310250292 A CN 201310250292A CN 103509655 A CN103509655 A CN 103509655A
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Abstract
The present invention provides a liquid detergent contained in a non-gaseous foaming container, which provides smooth and creamy foam which is good for skin smoothness and tack-free after being washed, brings soft and excellent using feelings for washed skin, and has excellent spitting performance. The viscosity of the liquid detergent under 25 DEG C is 1-20 mPa.s, and the liquid detergent includes the following ingredients (A), (B), (C) and (D), wherein (A) is N-acylamino acid or salt thereof, which s higher than 2 mass% and lower than 10 mass% by acid; (B) is an ampholytic surfactant, which is higher than 0.2 mass% and lower than 3 mass%; (C) is glycerol, which is higher than 5 mass% and lower than 28 mass%; and (D) is polyethylene glycol whose number-average molecular weight is 1500-20000, which is higher than 2 mass% and lower than 8 mass%; the mass ratio ((B) / (A) ) between ingredients (A) and (B) is higher than 0.05 and lower than 1.5; and the total of the contents of the ingredients (C) and (D) is higher than 10 mass% and lower than 30 mass%.
Description
Technical field
The present invention relates to non-pneumatic bubbling container dress liquid washing agent.
Background technology
The washing composition using in the washing of the skin of health washing composition etc. requires in recent years low to skin irritation and has good alveolar substance, a use sense etc.N-acyl acidic amino acid salt is the anion surfactant that skin irritation is low; compare with other the anion surfactant such as soap, alkyl sulfuric ester salt or laureth sulfate; the leeway that alveolar substance or use sense are improved, has also developed the washing composition of the N-acyl acidic amino acid salt described in various uses so far.
For example, in patent documentation 1, disclosing is also the washing composition of the water such as tensio-active agent and glycerine and exothermicity material with the acyl glutamic acid of 2～30 quality %, by add water when being coated with, seeks skin to give warmth sensation and improve whipability.In addition, in patent documentation 2, by alkanolamine salt 3～30 quality % at acylamino acid and with specific polyvalent alcohol 3～20 quality % and tackifier, obtain bringing the washing composition of excellent alveolar substance and good use sense.
On the other hand; in patent documentation 3; the washing composition of the N-acylamino acid series anion promoting agent, the amphoterics of 1～5 quality % and the polyvalent alcohol of 30～50 quality % that contain 1～5 quality % is disclosed; in addition; in patent documentation 4; disclose N-acyl amino acid type anion surfactant and amphoterics are set as specifically measuring ratio, and used the washing composition of the polyoxyethylene glycol of specific molecular-weight average, all attempted improving alveolar substance and improving low-temperature stability etc.
Prior art document
Patent documentation
Patent documentation 1: Japanese Patent Laid-Open 2004-292584 communique
Patent documentation 2: Japanese Patent Laid-Open 2004-137247 communique
Patent documentation 3: Japanese Patent Laid-Open 2010-59247 communique
Patent documentation 4: Japanese Patent Laid-Open 2009-120546 communique
Summary of the invention
The invention provides a kind of non-pneumatic bubbling container dress liquid washing agent, wherein, the viscosity of described non-pneumatic bubbling container dress liquid washing agent at 25 ℃ is 1～20mPas, and contains following composition (A), (B), (C) and (D):
(A) N-acylamino acid or its salt, count 2～10 quality % with acid;
(B) amphoterics, 0.2～3 quality %;
(C) glycerine, 5～28 quality %; With
(D) polyoxyethylene glycol that number-average molecular weight is 1500～20000,2～8 quality %,
The mass ratio ((B)/(A)) of the content of acid and the content of composition (B) of take of composition (A) is 0.05～1.5, the content of composition (C) and composition (D) add up to 10～30 quality %.
Embodiment
Yet, the washing composition of recording in patent documentation 1 contains a large amount of glycerine, heat release produces warmth sensation owing to using, and therefore also likely becomes hotness and produces skin irritation, and also have the distinctive technical problem of aerosol being restricted at operation or the aspect such as discarded.In addition, the quality exquisiteness of the foam of the washing composition of recording in patent documentation 2 or elasticity improve, but the easy ductility of foam or wash after the soft sense of touch of skin on there is technical problem.Further, if as the washing composition of recording in patent documentation 3, although can obtain creamy alveolar substance and give skin refreshing moist feeling, but because the kind of the polyvalent alcohol using or its combination, content cause the leeway being still improved aspect the creaminess of foam, slipperiness or the ductility of foam on skin is not enough, in addition, may have foam spuing property from container and reduce, the reduction of the alveolar substance of the quality exquisiteness reduction of foam etc.And then, even in the situation of the washing composition as described in patent documentation 4, also due to the amount ratio of N-acyl amino acid type anion surfactant and amphoterics, cause increasing the glutinous soapy feeling while rinsing and be difficult to improve use sense.
Like this; although also can bring the washing composition of various performances at application N-acyl acidic amino acid; but; the washing composition using as spuing from non-pneumatic bubbling container; still not yet realize the creamy foam of quality exquisiteness; and foam well, easily extends and has excellent spuing property in skin glazing slip, and glutinous soapy feeling during flushing is few, make the soft and washing composition that use sense is good of skin after washing.
Therefore, the invention provides the creamy foam as quality exquisiteness, and the slipperiness of foam on skin is good, not glutinous soapy feeling during flushing, and bring soft good use sense to the skin after washing, and there is the non-pneumatic bubbling container dress liquid washing agent of good spuing property.
At this, the present inventors are from reducing the irritating viewpoint to skin, in order to develop, to contain N-acylamino acid and have both excellent alveolar substance and the non-pneumatic bubbling container of use sense and good spuing property dress liquid washing agent and carried out various research, found that, by using N-acylamino acid with specific content and total amount and specific ratio, amphoterics, the polyoxyethylene glycol of glycerine and specific number-average molecular weight, and in the extremely specific scope of viscosity adjustment, can accomplished high performance foam, to the skin after washing, bring the liquid washing agent of good use sense and spuing property excellence.
According to the present invention, not only the pungency of skin is reduced, and also good as creamy alveolar substance and the ductility of foam on skin of quality exquisiteness, not glutinous soapy feeling during flushing, bring soft good use sense to the skin after washing, and spuing property is also excellent, can easily from non-bubbling container, extrude.
Below, the present invention is described in detail.
Non-pneumatic bubbling container dress liquid washing agent of the present invention contains (A) N-acylamino acid or its salt is counted 2～10 quality % with acid.By contain described composition (A) with specified quantitative, can realize good whipability and washability.(A) acyl group of N-acylamino acid or its salt is from the viewpoint of whipability etc.; the acyl group of the lipid acid with saturated or undersaturated straight or branched that to be preferably from carbonatoms be 8～18; the acyl group of the lipid acid with saturated or undersaturated straight or branched that is more preferably 8～16 from carbonatoms, the acyl group of the lipid acid with saturated or undersaturated straight or branched that to be more preferably from carbonatoms be 8～14.As such lipid acid, can enumerate sad, capric acid, lauric acid, tetradecanoic acid, palmitinic acid, stearic acid, oleic acid etc.In these lipid acid, from the viewpoint of alveolar substance or storage stability, preferably lauric acid, tetradecanoic acid, palmitinic acid, oleic acid, be more preferably lauric acid.In addition, the acyl group of N-acylamino acid can be also the acyl group of the mixing acid from above-mentioned lipid acid, for example, take the acyl group that Oleum Cocois, palm-kernel wet goods obtain as raw material.Wherein, preferably using the acyl group that coco-nut oil fatty acid or palm kernel fatty acid obtain as raw material, be more preferably and using the acyl group that coco-nut oil fatty acid obtains as raw material.
(A) amino acid moiety of N-acylamino acid or its salt, skin from foam to the good high-quality alveolar substance of the slipperiness of skin and washing is soft and have the viewpoint of salubrious moistening good use sense, is preferably the neutral amino acids that is selected from glycine, L-Ala; And the acidic amino acid that is selected from L-glutamic acid, aspartic acid, more preferably acidic amino acid, is more preferably L-glutamic acid.In addition, what these amino acid moieties can be in the mixture of D body, L body or D body and L body is any number of, is preferably L body.
Above-mentioned (A) N-acylamino acid or its salt can be used separately a kind also can combine two or more use.Wherein, good to the slipperiness of skin from obtaining foam, skin after holding ductile good alveolar substance and washing is soft, and the viewpoint of salubrious moistening good use sense is set out, be preferably N-lauroyl glutamate, N-myristoyl L-glutamic acid, N-cocoyl L-glutamic acid, N-PALM FATTY ACID L-glutamic acid, N-lauroyl aspartic acid, N-cocoyl glycine, N-cocoyl L-Ala or their salt, N-lauroyl glutamate more preferably, N-myristoyl L-glutamic acid, N-cocoyl L-glutamic acid, N-PALM FATTY ACID L-glutamic acid, N-lauroyl aspartic acid, N-cocoyl glycine or their salt, be more preferably N-lauroyl glutamate, N-myristoyl L-glutamic acid, N-cocoyl L-glutamic acid, N-lauroyl aspartic acid or their salt, further be preferably N-cocoyl L-glutamic acid, N-lauroyl aspartic acid or their salt, further be more preferably N-cocoyl L-glutamic acid or its salt.
As the salt of above-mentioned (A) N-acylamino acid or its salt, from guaranteeing the viewpoint of whipability or alveolar substance, can be enumerated as an alkali metal salt of sodium, potassium etc.; The alkali earth metal salt of calcium, magnesium etc.; The inorganic salt of other of aluminium, zinc etc.; Ammonium salt; Monoethanolamine, diethanolamine, trolamine, AMP(2-amino-2-methyl-1-propyl alcohol), other organic amine salt of TRIS etc.; Other organic salt of the alkaline amino acid salt of arginine, Methionin, Histidine, ornithine etc. etc.Salt as (A) N-acylamino acid or its salt; from the viewpoint to the pungency of skin or acquisition easiness; preferred as alkali salt, triethanolamine salt, arginic acid salt; more preferably sodium salt, sylvite, triethanolamine salt, arginic acid salt; be more preferably sodium salt, sylvite, be further preferably sodium salt.
In addition, in the situation that coordinating N-acylamino acid, can by with in alkali with use.Alkali as neutralization, can enumerate sodium hydroxide, potassium hydroxide, monoethanolamine, trolamine, diethanolamine, ammonia, AMP(2-amino-2-methyl-1-propyl alcohol), 2-amino-2-methylol-1, ammediol, Methionin, arginine, Histidine, sodium-acetate, Potassium ethanoate etc., from whipability or alveolar substance, the viewpoint of skin irritation or acquisition easiness is set out, be preferably and be selected from sodium hydroxide, potassium hydroxide, arginine, the alkali of trolamine is to form sodium salt, sylvite, arginic acid salt, triethanolamine salt, more preferably be selected from sodium hydroxide, 1 kind or the alkali of 2 kinds in potassium hydroxide.In addition, for making the pH of liquid washing agent reach final desirable value, can append as required the common various alkali that uses sodium hydroxide, potassium hydroxide, trolamine, ammonia, Methionin, arginine, Histidine etc.In addition, in situation arbitrarily, can also further append in order to regulate the pH of liquid washing agent the common various acid of using hydrochloric acid, sulfuric acid, phosphoric acid, acetic acid, citric acid, oxysuccinic acid, lactic acid, fumaric acid, succsinic acid etc.
(A) content in acid of N-acylamino acid or its salt; the viewpoint of the good use sense from obtaining excellent whipability and high alveolar substance and washing; in the liquid washing agent of non-pneumatic bubbling container of the present invention dress, be more than 2 quality % below 10 quality %; more preferably more than 3 quality %; be preferably in addition below 8 quality %, more preferably below 6 quality %.(A) content of acid of take of N-acylamino acid or its salt is 2～10 quality %, and more preferably 2～8 quality %, are more preferably 3～6 quality %.
Non-pneumatic bubbling container dress liquid washing agent of the present invention contains below the above 3 quality % of (B) amphoterics 0.2 quality %.By containing described composition (B) specifically to measure, and merging (C) glycerine that contains aftermentioned specified quantitative and (D) polyoxyethylene glycol with specific number-average molecular weight, can obtain as the foam of creaminess quality exquisiteness and the foam of the high-quality that the slipperiness of foam on skin is good, ductility is good, glutinous soapy feeling in the time of can suppressing to rinse, and the soft sense of touch of the skin after being washed.As described (B) amphoterics, be preferably a kind of being selected from alkyl sulfo betaines, alkyl hydroxy sultaine, alkyl-carbonyl trimethyl-glycine, alkylamide hydroxyl sulfo betaine, alkylamide amine type trimethyl-glycine, alkyl imidazoline type trimethyl-glycine or two or more.Wherein, from realize the high-quality that the ductility of foam is good foam viewpoint and washed the viewpoint of good use sense of skin softness, be more preferably and be selected from a kind of having in alkylamide propyl-betaine that carbonatoms is 8～14 alkyl and alkyl hydroxy sultaine or two or more, be more preferably alkyl hydroxy sultaine, more further preferred lauryl hydroxyl sulfo betaine.
From the foam as creamy quality exquisiteness, can access the good quality froth that the slipperiness of foam on skin is good and ductility is good, and the viewpoint that realizes the foam of the glutinous soapy feeling while having suppressed to rinse is set out, (B) content of amphoterics is in non-pneumatic bubbling container dress liquid washing agent of the present invention, be below the above 3 quality % of 0.2 quality %, more than being preferably 0.4 quality %, more than being more preferably 1 quality %, from making the viewpoint of the glutinous soapy feeling the good and further inhibition of alveolar substance washes, be preferably below 2.5 quality %, more preferably below 2.4 quality %, be more preferably below 2 quality %.(B) viewpoint of the glutinous soapy feeling of the content of amphoterics from taking into account sense of touch alveolar substance and good washing, while suppressing to rinse, in non-pneumatic bubbling container dress liquid washing agent of the present invention, be preferably 0.4～2.5 quality %, more preferably 1～2.4 quality %, is more preferably 1～2 quality %.
In non-pneumatic bubbling container dress liquid washing agent of the present invention, from having both the alveolar substance of excellent whipability and creaminess exquisiteness, and the high alveolar substance that the slipperiness of foam is good and ductility is good, and the glutinous soapy feeling while effectively suppressing to rinse, and the viewpoint of the soft good use sense of the skin after being washed is set out, mentioned component (A) take the mass ratio ((B)/(A)) of the content of acid and the content of composition (B) as more than 0.05 below 1.5, be preferably more than 0.08, more preferably more than 0.15, be more preferably more than 0.2, from making the viewpoint of the glutinous soapy feeling the good and further inhibition of alveolar substance washes, be preferably below 1.1, more preferably below 0.5, be more preferably below 0.4, more preferably below 0.35.In addition, the mass ratio ((B)/(A)) of the content of acid and the content of composition (B) of take of composition (A) is 0.05～1.5, is preferably 0.08～1.1, is more preferably 0.15～0.5, further be preferably 0.2～0.4, more more preferably 0.2～0.35.
Non-pneumatic bubbling container dress liquid washing agent of the present invention contains below the above 28 quality % of (C) glycerine 5 quality %.By the described composition (C) that contains specified quantitative together with the composition with specified quantitative (A), composition (B), composition (D), can realize and give good viscosity, improve foam retentivity and be creaminess, foam slipperiness is good, ductility is good foam, can bring while having rinsed the soft and salubrious moistening good use sense of skin.In addition, can make the spuing property from non-pneumatic bubbling container good.
From improve foam retentivity and give the viewpoint of excellent alveolar substance and guarantee to wash the soft and good salubrious moist feeling of skin, the viewpoint of good spuing property, (C) content of glycerine is in the liquid washing agent of non-pneumatic bubbling container dress of the present invention, be below the above 28 quality % of 5 quality %, more than being preferably 10 quality %, more preferably more than 12 quality %, be preferably below 25 quality %, more preferably below 23.5 quality %.In addition, (C) content of glycerine is 5～28 quality % in non-pneumatic bubbling container dress liquid washing agent of the present invention, is preferably 10～25 quality %, is more preferably 12～23.5 quality %.
Non-pneumatic bubbling container of the present invention dress liquid washing agent contains (D) polyoxyethylene glycol that number-average molecular weight that polystyrene measures as the GPC method of standard is 1500～20000 of take below the above 8 quality % of 2 quality %.By the amount with above-mentioned, contain (D) polyoxyethylene glycol with described specific number-average molecular weight, can realize the foam spuing from non-pneumatic bubbling container is that creaminess and quality exquisiteness have conformality, and the foam that foam slipperiness is good and ductility is excellent.In addition, can maintain well the spuing property from non-pneumatic bubbling container.The number-average molecular weight of composition (D) is from having both so good alveolar substance and the viewpoint of spuing property, be preferably more than 2000, more preferably more than 2500, be more preferably more than 3000, be preferably below 12000, more preferably, below 10000, be more preferably below 9500, be further preferably below 9000.In addition, the number-average molecular weight of composition (D) is preferably 2000～12000, and more preferably 2500～10000, be more preferably 2500～9500, more more preferably 3000～9000.
The content of above-mentioned (D) polyoxyethylene glycol, from the foam spuing in non-pneumatic bubbling container, it is the good quality froth that creaminess and quality exquisiteness have conformality, and the alveolar substance that foam slipperiness excellence and ductility are good, and the viewpoint of the good use sense after keeping washing and guarantee that the viewpoint of good spuing property sets out, in non-pneumatic bubbling container of the present invention dress liquid washing agent, be more than 2 quality % below 8 quality %, more than being preferably 2.5 quality %, be preferably below 5 quality %, more preferably below 4.5 quality %.In addition, (D) content of polyoxyethylene glycol is 2～8 quality % in non-pneumatic bubbling container dress liquid washing agent of the present invention, is preferably 2～5 quality %, is more preferably 2.5～4.5 quality %.
In non-pneumatic bubbling container dress liquid washing agent of the present invention, from the foam spuing in non-pneumatic bubbling container, it is the good quality froth that creaminess and quality exquisiteness have conformality, prevent foam hardening, give the viewpoint of the good excellent alveolar substance of the ductility of foam; The viewpoint of the soft skin feel after being washed; And prevent the hypertonia of pump and guarantee that the viewpoint of good spuing property sets out, being aggregated in non-pneumatic bubbling container dress liquid washing agent of the present invention of the content of mentioned component (C) and composition (D) is below the above 30 quality % of 10 quality %, more than being preferably 12 quality %, more preferably more than 15 quality %, be preferably below 27 quality %, more preferably below 26 quality %.In addition, the content of composition (C) and composition (D) is aggregated in non-pneumatic bubbling container of the present invention dress liquid washing agent to be 10～30 quality %, to be preferably 12～27 quality %, be more preferably 15～26 quality %.
Non-pneumatic bubbling container of the present invention dress liquid washing agent preferably further contains (E) and has the glyceryl ether that carbonatoms is the alkyl of 8～12 straight or branched.By containing described (E) specific glyceryl ether, can improve whipability and foam retentivity.Described composition (E) is from improve the viewpoint of whipability and foam retentivity simultaneously, preferably there is carbonatoms and is the glyceryl ether of the alkyl of 8～10 straight chain or side chain, more preferably there is carbonatoms and be the glyceryl ether of the alkyl of 8 straight chain or side chain, be more preferably the glyceryl ether of the alkyl with side chain.
The content of above-mentioned (E) glyceryl ether, from further effectively improving the viewpoint of whipability and foam retentivity, be preferably below the above 1.5 quality % of 0.1 quality %, more preferably more than 0.2 quality %, more than being more preferably 0.3 quality %, further be preferably below 1 quality %, more more preferably below 0.7 quality %.
Non-pneumatic bubbling container of the present invention dress liquid washing agent is preferably usings water dissolves or disperse the liquid that mentioned component forms form as medium.As water, the viewpoint never storage stability being exerted an influence is set out, and can use distilled water or ion exchanged water.The content of described water is except the Purified Water of the ion exchanged water that coordinates etc., the content that also comprises water contained in the composition of cooperation, from the spuing property in container or whipability, keep good alveolar substance, and the viewpoint of storage stability is set out, be preferably 40 quality % in liquid washing agent of the present invention more than, more preferably more than 45 quality %, more than being more preferably 55 quality %, be preferably below 85 quality %, more preferably below 80 quality %, be more preferably below 75 quality %, and be outside mentioned component (A)～(D), the surplus of other composition containing as required.
The pH of liquid washing agent of the present invention is from good whipability and the irritating viewpoint of reduction to skin of composition (A); be preferably in the scope of pH4.5～9.5; be more preferably pH4.5～8.5; in the situation that composition (A) is N-acyl acidic amino acid or its salt; be preferably the scope of pH4.5～8.0; more preferably pH5.0～7.5, are more preferably pH5.5～6.5.Described pH can be adjusted to after 25 ℃ by 100ml liquid washing agent is filled in beaker in the thermostatic bath of 25 ℃, and pH is measured with electrode dipping and measured for 3 minutes.
The composition (A) that liquid washing agent of the present invention can contain alkyl ether sulphate or its salt, Voranol EP 2001 sulfuric ester or its salt, soap etc. in the scope of not damaging effect of the present invention other anion surfactant in addition.The content of soap in liquid washing agent of the present invention, from good spuing property, suppress the stimulation of skin, the viewpoint of the soft skin feel washing, be preferably below 0.5 quality %, more preferably below 0.1 quality %, be more preferably below 0.01 quality %, be preferably the situation except unavoidably sneaking into and do not contain.The content of the composition in liquid washing agent of the present invention (A) anion surfactant that is selected from alkyl sulfuric ester or its salt and Voranol EP 2001 sulfuric ester or its salt is in addition from suppressing the viewpoint to the viewpoint of the stimulation of skin, alveolar substance, preferably few than the content of the total of composition of the present invention (A), be preferably below 7 quality %, more preferably below 4 quality %, be more preferably below 1 quality %, be more preferably the situation except unavoidably sneaking into and do not contain.In addition, in liquid washing agent of the present invention, the content that is selected from the aniorfic surfactant of alkyl sulfuric ester or its salt and Voranol EP 2001 sulfuric ester or its salt is that 0.3 quality % is below, further that 0.1 quality % also can obtain good whipability and alveolar substance below.
Further, liquid washing agent of the present invention is except mentioned component, can also contain the composition using in common liquid washing agent in the scope of not damaging effect of the present invention, mentioned component (C) and composition (D) alcohols or polyalcohols in addition such as 1,3 butylene glycol, propylene glycol etc.Further, can contain in the scope of not damaging effect of the present invention the nonionogenic tensides such as alkyl poly glucoside, Voranol EP 2001, polyoxyethylene sorbitan fatty acid ester; The tinting material of dyestuff etc.; Plant milk extract class; Sanitas; Sequestrant; Vitamin preparation; The anti-inflammatory agent of glycyrrhetinic acid, Potenlini and their derivative, wallantoin etc.; Spices; UV light absorber; Antioxidant etc.
Liquid washing agent of the present invention can contain in the scope of not damaging effect of the present invention the macromolecule tackifer of anionic property, nonionic or cationic.The content of macromolecule tackifer is from making the good viewpoint of alveolar substance, preferably in liquid washing agent of the present invention, be less than 0.2 quality %, more preferably be less than 0.1 quality %, be more preferably below 0.01 quality %, be more preferably and in fact do not contain macromolecule tackifer.As these macromolecule tackifer, can enumerate be selected from carrageenin, xanthan gum, gelatin, guar gum, cellulose gum, wilkinite, JR-125, Poise C-80M more than a kind.
The viscosity of non-pneumatic bubbling container dress liquid washing agent of the present invention at 25 ℃, from the exquisiteness of good quality of foam and the viewpoint of the conformality of foam of guaranteeing to spue and the viewpoint of also guaranteeing good spuing property, be preferably 1～20mPas, 2～15mPas more preferably, be more preferably 3～13mPas, be further preferably 5～11mPas.In addition, (eastern machine industry, TVB-10), rotor No.1, is to rotate under 60r/min at rotating speed to the Brookfield type viscometer that described viscosity can be by 25 ℃, measures the viscosity after rotation beginning 60 seconds and obtains.
Non-pneumatic bubbling container dress liquid washing agent of the present invention can be used above-mentioned each composition, according to common method manufacture.In addition, described liquid washing agent, preferably as skin use for washing, is more preferably as hand soaps, clean agent, bath soap and uses.Liquid detergent composition of the present invention can be for coming washed skin to use by common skin washing methods.As washing methods, the method of have the method washed by hand, use the sponge of being made by the man-made fiber of cotton or nylon etc., towel, pot-scouring brush etc. being washed, from reducing the viewpoint of the stimulation of skin and effectively bringing into play the foaming properties of product of the present invention and the viewpoint of use sense, preferably for the method being directly placed on hand and wash by hand, using.In addition, non-pneumatic bubbling container of the present invention dress liquid washing agent is because low irritant and alveolar substance, whipability are good, can access the soft sense of touch of the skin after washing, thereby be suitable for being selected from the washing of the skin in infant's skin that sensitive skin, dry skin, mixing skin and stratum corneum are thin, be more preferably the washing that is suitable for being selected from the skin in sensitive skin, dry skin and infant's skin.At this, the sensitive skin in the present invention refers to that nerve fiber extends in epidermis and under stratum corneum, easily recognizes the skin of the oxypathy state of sensory stimuli.Particularly, refer to because sensory nerve is irritated and also easily influenced for a little outside stimulus (temperature, humidity, dust, allergen etc.), by use or the outside stimulus of makeup, produce burning, the skin of sensory stimuli pinprick, that itch sense continuously.In addition, infant refers to baby and child, and baby refers to that latter 0 day of birth is to discontented one-year-old child, child refer to 1 years old above to the child before going to school, be more preferably in the present invention the child below 5 years old.
Non-pneumatic bubbling container of the present invention dress liquid washing agent is to form by aforesaid liquid washing composition being filled in the non-pneumatic bubbling container of the type spuing with spumescence.N-acylamino acid or its salt of composition (A) are compared with fatty acid soaps; although there is the character of shortcoming a little at the aspects such as creaminess of foam; but in the situation that the aforesaid liquid washing composition forming in being filled in non-pneumatic bubbling container is spued from container; spuing property excellence not only; and can bring quality fine and smooth and be creaminess; the alveolar substance that foam slipperiness is good and ductility is good to skin; and do not have fatty acid soaps such wash after sense of discomfort, can make the skin after washing there is soft use sense.As the foam of the non-pneumatic type container that spues, so long as can and the container that spues as foam of air mixed, just can use any number ofly, for example, can enumerate the pump bubbling container spuing by pressing pump head; Or the extruding bubbling container spuing by extruding body portion, particularly, can enumerate the bubbling container of Yoshino Kogyosho Co., Ltd's manufacture, tank manufacture large and processed etc.In addition, for example, also can use the bubbling container of recording in Japanese kokai publication hei 7-315463, Japanese kokai publication hei 8-230961 and TOHKEMY 2005-193972 communique etc.Wherein, the viewpoint of the convenience from the environment using liquid washing agent, the pump bubbling container preferably spuing by pressing pump head from further making the measured viewpoint of alveolar substance, preferably possesses membrane filtering device on the stream that spues.Such porous film strainer is from further obtaining the viewpoint of the fine and smooth good alveolar substance of quality, be preferably 100～400 object strainers, 200～400 object strainers more preferably, be more preferably 200～305 object strainers, preferably on the stream that spues, configure 1～3 piece of such membrane filtering device, more preferably configure 2 pieces.In addition, in the ratio of mixture that pumps up bubble liquid in containers washing composition and air, from obtaining the viewpoint of the alveolar substance of good bubble amount and easy washed skin, the density of the foam preferably spuing (volume of the quality/air of liquid washing agent) is 0.03～0.14g/cm
3, 0.05～0.11g/cm more preferably
3.
About the embodiment of the invention described above, following non-pneumatic bubbling container dress liquid washing agent is further disclosed.
[1] a bubbling container dress liquid washing agent, wherein, the viscosity of described non-pneumatic bubbling container dress liquid washing agent at 25 ℃ is 1～20mPas, and contains following composition (A), (B), (C) and (D):
(A) N-acylamino acid or its salt, count below the above 10 quality % of 2 quality % with acid;
(B) amphoterics, below the above 3 quality % of 0.2 quality %;
(C) glycerine, below the above 28 quality % of 5 quality %; With
(D) polyoxyethylene glycol that number-average molecular weight is 1500～20000, below the above 8 quality % of 2 quality %,
The mass ratio of the content of composition (A) and composition (B) ((B)/(A)) is more than 0.05 below 1.5, the adding up to below the above 30 quality % of 10 quality % of the content of composition (C) and composition (D).
[2] dress of the non-pneumatic bubbling container as described in above-mentioned [1] liquid washing agent, wherein, the content of composition (A) is below the above 10 quality % of 2 quality %, more than being preferably 3 quality %, is preferably below 8 quality %, is more preferably below 6 quality %.
[3] dress of the non-pneumatic bubbling container as described in above-mentioned [1] or [2] liquid washing agent; wherein; the acyl group of the lipid acid with saturated or undersaturated straight or branched that it is 8～18 that composition (A) preferably has from carbonatoms; the acyl group of the lipid acid with saturated or undersaturated straight or branched that further preferably to have from carbonatoms be 8～16, is more preferably the acyl group of the lipid acid with saturated or undersaturated straight or branched that to have from carbonatoms be 8～12.
[4] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[3]; wherein; composition (A) is for being selected from N-lauroyl glutamate, N-myristoyl L-glutamic acid, N-cocoyl L-glutamic acid, N-PALM FATTY ACID L-glutamic acid, N-lauroyl aspartic acid, N-cocoyl glycine, N-cocoyl L-Ala or their salt a kind or two or more, being preferably a kind of being selected from N-cocoyl L-glutamic acid, N-lauroyl aspartic acid or their salt or two or more.
[5] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[4], wherein, composition (A) is N-acyl acidic amino acid or its salt.
[6] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[5], wherein, the content of composition (B) is below the above 3 quality % of 0.2 quality %, more than being preferably 0.4 quality %, more than being more preferably 1 quality %, be preferably below 2.5 quality %, more preferably, below 2.4 quality %, be more preferably below 2 quality %.
[7] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[6], wherein, composition (B) is preferably and is selected from alkyl sulfo betaines, alkyl hydroxy sultaine, alkyl-carbonyl trimethyl-glycine, alkylamide hydroxyl sulfo betaine, alkylamide amine type trimethyl-glycine, and in alkyl imidazoline type trimethyl-glycine a kind or two or more, be more preferably to be selected from and there is the alkyl sulfo betaines that carbonatoms is 8～14 alkyl, or in alkyl hydroxy sultaine a kind or two or more, be more preferably lauryl hydroxyl sulfo betaine.
[8] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[7], wherein, the mass ratio of the content of composition (A) and composition (B) ((B)/(A)) is more than 0.05 below 1.5, be preferably more than 0.08, more preferably more than 0.15, be more preferably more than 0.2, be preferably below 1.1, more preferably, below 0.5, be more preferably below 0.4, more preferably below 0.35.
[9] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[8], wherein, the content of composition (C) is below the above 28 quality % of 5 quality %, more than being preferably 10 quality %, more preferably more than 12 quality %, be preferably below 25 quality %, more preferably below 23.5 quality %.
[10] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[9], wherein, the content of composition (D) is below the above 8 quality % of 2 quality %, more than being preferably 2.5 quality %, be preferably below 5 quality %, more preferably below 4.5 quality %.
[11] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[10], wherein, the number-average molecular weight of composition (D) is 1500～20000, be preferably 2000～12000, more preferably 2500～10000, be more preferably 2500～9500, more more preferably 3000～9000.
[12] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[11], wherein, adding up to below the above 30 quality % of 10 quality % of the content of composition (C) and composition (D), more than being preferably 12 quality %, more preferably more than 15 quality %, be preferably below 27 quality %, more preferably below 26 quality %.
[13] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[12], wherein, further contains (E) and has below the above 1.5 quality % of glyceryl ether 0.1 quality % of alkyl that carbonatoms is 8～12 straight or branched.
[14] dress of the non-pneumatic bubbling container as described in above-mentioned [13] liquid washing agent, wherein, the content of composition (E) is below the above 1.5 quality % of 0.1 quality %, more than being preferably 0.2 quality %, more preferably more than 0.3 quality %, be preferably below 1 quality %, more preferably below 0.7 quality %.
[15] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[14], wherein, the content of water is below the above 85 quality % of 40 quality %, more than being preferably 45 quality %, more than being more preferably 55 quality %, be preferably below 80 quality %, be more preferably below 75 quality %.
[16] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[14], wherein, the viscosity of described non-pneumatic bubbling container dress liquid washing agent at 25 ℃ is 1～20mPas, be preferably 2～15mPas, more preferably 3～13mPas, is more preferably 5～11mPas.
[17] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[16], wherein, pH is 4.5～9.5, is preferably pH4.5～8.5.
[18] the non-pneumatic bubbling container dress liquid washing agent as described in any one in above-mentioned [1]～[16], wherein, composition (A) is N-acyl acidic amino acid or its salt, pH is 4.5～8.0, more preferably 5.0～7.5, be more preferably 5.5～6.5.
[19] in a kind of above-mentioned [1]～[18], the non-pneumatic bubbling container described in any one fills liquid washing agent in the purposes of the washing for skin.
[20] in a kind of above-mentioned [1]～[18], the non-pneumatic bubbling container described in any one fills liquid washing agent in the purposes for the manufacture of in skin detergent.
[21] in a kind of above-mentioned [1]～[18] dress of the non-pneumatic bubbling container described in any one liquid washing agent for being selected from the purposes of washing of the skin of sensitive skin, dry skin, mixed skin and infant's skin.
[22] in a kind of above-mentioned [1]～[18] dress of the non-pneumatic bubbling container described in any one liquid washing agent for being directly placed on hand and washing by hand the purposes of washing skin.
[embodiment]
Below, based on embodiment, for the present invention, be specifically described.In addition, in table, unless stated otherwise, the content of each composition represents quality %.
[embodiment 1～21, comparative example 1～10]
According to the composition shown in table 1～3, according to common method, manufacture each liquid washing agent, according to following method, measure viscosity and pH and carry out various evaluations.The results are shown in table 1～table 3.In addition, the raw material of each liquid washing agent is used following raw material.
Cocoyl Sodium Glutamate: trade(brand)name " Amisoft CS-11(F), molecular weight 359”， Ajincomoto Co., Inc
Lauryl hydroxyl sulfo betaine liquid (30%): trade(brand)name " AMPHITOL20HD ”， Kao Corp
Lauric amide CAB liquid (30%): trade(brand)name " AMPHITOL20AB ”， Kao Corp
Glycerine (100%): trade(brand)name " concentrated glycerin ”， Kao Corp
PEG20000: trade(brand)name " PEG-10000 ", number-average molecular weight=10000, Sanyo Chemical Industries, Ltd.
Polyethylene glycol 6000: trade(brand)name " PEG#600 ", number-average molecular weight=8600, Japan Oil Co
Macrogol 4000: trade(brand)name " PEG-4000S ", number-average molecular weight=3400, Sanyo Chemical Industries, Ltd.
Macrogol 4000: trade(brand)name " PEG-600(-G) ", number-average molecular weight=600， Sanyo Chemical Industries, Ltd.
2-Sensiva SC50 ether: Kao Corp
Propylene glycol: Asahi Glass Co., Ltd
" mensuration of viscosity "
At 25 ℃, with Brookfield type viscometer, (eastern machine industry, TVB-10) measures.Rotor is used the rotor of No.1, at rotating speed, is to rotate under 60r/min, tries to achieve rotation and starts the viscosity after latter 60 seconds, as the viscosity of liquid washing agent.
" mensuration of pH "
The liquid washing agent 100mL obtaining is filled in beaker, in the thermostatic bath of 25 ℃, is adjusted to 25 ℃.PH is measured with electrode and impregnated in the sample that is adjusted to constant temperature 3 minutes, measure pH.
" spuing property "
The liquid washing agent obtaining is filled in the pump bubbling container (mesh size that is arranged on the membrane filtering device spuing on stream is 1 piece of 200 order and 1 piece of 305 order) of company of the wild industrial institute of the Ji manufacture by spuing by pumping head, at 25 ℃ of room temperatures, spue and press the foam of 2 times (discharge-amount of pressing 1 time is about 1g, and air capacity is about 13cm
3), according to the benchmark evaluation of following 5 grades, press the state of the foam spuing for the 2nd time.
A: do not have air pocket to sneak into, evenly, foam has conformality and quality is fine and smooth for foam size.
B: slightly air pocket is sneaked into, foam size is roughly even, and foam has conformality and quality is fine and smooth.
C: have air pocket to sneak into, the size of part foam is inhomogeneous, and foam has conformality.
D: have a large amount of air pockets to sneak into, the size of foam is inhomogeneous, and the conformality of foam is low, and the quality of foam is coarse.
As shown in Table 1 to Table 3, the content of composition (D) is the adding up in comparative examples 4 and 5 more than 30 quality % of content of more than 8 quality % comparative example 3, composition (C) and composition (D), in the foam spuing, there is air pocket to sneak into, foam is inhomogeneous, the quality of foam is very coarse, do not have frothy conformality, therefore, the glutinous greasy property when sense of touch of the skin about the creaminess of foam, the ductility of foam recorded below, after washing and washing is that the liquid washing agent that spuing property is evaluated as to A～C is evaluated.
" creaminess of foam, the ductility of foam good "
The liquid washing agent that is A～C to spuing property, was well evaluated with 1～5 minute respectively according to following using method the ductility of the creaminess of foam, foam by 5 special evaluation group members.In table 1～table 3, represent the average score of evaluating.
Using method is in 25 ℃ of room temperatures, relative humidity Wei40% room, the liquid washing agent of embodiment and comparative example is filled in the pump bubbling container (mesh size that is arranged on the membrane filtering device spuing on stream is 1 piece of 200 order and 1 piece of 305 order) of company of the wild industrial institute of the Ji manufacture by spuing by pumping head, by the deal of pressing 2 times, (discharge-amount of pressing 1 time is about 1ml, about 13cm
3) spue in dry palm, use the foam spue, with rub two hands rinse approximately 7 seconds of palm of palm.Use afterwards tap water (25 ℃) fully to rinse, with dry towel wiping.
(1) the creamy judgement criteria of foam: sensation foam is creaminess
5: feel very much
4: feel
3: slightly feel
2: basic not sensation
1: do not feel
(2) the good judgement criteria of the ductility of foam: the skin smoothness of sensation foam is good, and the ductility of foam on skin is good
5: feel very much
4: feel
3: slightly feel
2: basic not sensation
1: do not feel
" during flushing without glutinous soapy feeling, the soft feel(ing) of the skin after washing "
Further, by the soft feel(ing) of 5 special group members of evaluation skin without glutinous soapy feeling, after washing when rinsing, according to following using method, with 1～5 minute, evaluate respectively.In table 1～table 3, show the average score of evaluating.
Using method is in 25 ℃ of room temperatures, relative humidity Wei40% room, the liquid washing agent of embodiment and comparative example is filled in the pump bubbling container (mesh size that is arranged on the membrane filtering device spuing on stream is 1 piece of 200 order and 1 piece of 305 order) of company of the wild industrial institute of the Ji manufacture by spuing by pumping head, by the deal of pressing 2 times, (discharge-amount of pressing 1 time is about 1ml, about 13cm
3) spue in palm, with the foam spuing, wash one's face.Use afterwards tap water (25 ℃) fully to rinse, with dry towel wiping.
(3) judgement criteria of the soft feel(ing) of the skin after washing: feel that the skin after washing is soft
5: feel very much
4: feel
3: slightly feel
2: basic not sensation
1: do not feel
(4) while rinsing without the judgement criteria of glutinous soapy feeling: during flushing, skin is glutinous not greasy
5: feel very much
4: feel
3: slightly feel
2: basic not sensation
1: do not feel
[table 1]
[table 2]
[table 3]
Known as shown in table 1～3, the liquid washing agent of embodiment is compared with the liquid washing agent of comparative example, the creamy high alveolar substance of quality exquisiteness, and the ductility of foam is good, can bring into play well the glutinous soapy feeling while suppressing to rinse and wash after the balance of good use sense.
Claims (24)
1. non-pneumatic bubbling container fills a liquid washing agent, wherein,
The viscosity of described non-pneumatic bubbling container dress liquid washing agent at 25 ℃ is 1～20mPas, and contains following composition (A), (B), (C) and (D):
(A) N-acylamino acid or its salt, count below the above 10 quality % of 2 quality % with acid;
(B) amphoterics, below the above 3 quality % of 0.2 quality %;
(C) glycerine, below the above 28 quality % of 5 quality %; With
(D) polyoxyethylene glycol that number-average molecular weight is 1500～20000, below the above 8 quality % of 2 quality %,
As the mass ratio of the content of composition (A) and composition (B), (B)/(A) be more than 0.05 below 1.5, the adding up to below the above 30 quality % of 10 quality % of the content of composition (C) and composition (D).
2. non-pneumatic bubbling container as claimed in claim 1 fills liquid washing agent, wherein,
Composition (A) is N-acyl acidic amino acid or its salt.
3. non-pneumatic bubbling container as claimed in claim 1 or 2 fills liquid washing agent, wherein,
The acyl group of composition (A) is from a kind or lipid acid of more than two kinds being selected from lauric acid, tetradecanoic acid, coco-nut oil fatty acid and palm kernel fatty acid.
4. the non-pneumatic bubbling container as described in any one in claim 1～3 fills liquid washing agent, wherein,
The amino acid moiety of composition (A) is a kind or 2 kinds that is selected from L-glutamic acid and aspartic acid.
5. the non-pneumatic bubbling container as described in any one in claim 1～4 fills liquid washing agent, wherein,
Composition (B) is for being selected from a kind of having in alkylamide propyl-betaine, alkyl sulfo betaines and the alkyl hydroxy sultaine that carbonatoms is 8～14 alkyl or two or more.
6. the non-pneumatic bubbling container as described in any one in claim 1～5 fills liquid washing agent, wherein,
Composition (B) is lauryl hydroxyl sulfo betaine.
7. the non-pneumatic bubbling container as described in any one in claim 1～6 fills liquid washing agent, wherein,
Further containing (E) has below the above 1.5 quality % of glyceryl ether 0.1 quality % of alkyl that carbonatoms is 8～12 straight or branched.
8. the non-pneumatic bubbling container as described in any one in claim 1～7 fills liquid washing agent, wherein,
Composition (A) take the content of acid more than 3 quality % below 6 quality %.
9. the non-pneumatic bubbling container as described in any one in claim 1～8 fills liquid washing agent, wherein,
The content of composition (B) is below the above 2 quality % of 1 quality %.
10. the non-pneumatic bubbling container as described in any one in claim 1～9 fills liquid washing agent, wherein,
As the mass ratio of the content in acid of composition (A) and the content of composition (B), (B)/(A) be more than 0.2 below 0.35.
11. non-pneumatic bubbling container as described in any one in claim 1～10 dress liquid washing agents, wherein,
The content of composition (C) is below the above 23.5 quality % of 12 quality %.
12. non-pneumatic bubbling container as described in any one in claim 1～11 dress liquid washing agents, wherein,
The content of composition (D) is below the above 4.5 quality % of 2.5 quality %.
13. non-pneumatic bubbling container as described in any one in claim 1～12 dress liquid washing agents, wherein,
The number-average molecular weight of composition (D) is more than 3000 below 9000.
14. non-pneumatic bubbling container as described in any one in claim 1～13 dress liquid washing agents, wherein,
Adding up to below the above 26 quality % of 15 quality % of the content of composition (C) and composition (D).
15. non-pneumatic bubbling container as described in any one in claim 7～14 dress liquid washing agents, wherein,
The content of composition (E) is below the above 0.7 quality % of 0.3 quality %.
16. non-pneumatic bubbling container as described in any one in claim 1～15 dress liquid washing agents, wherein,
The content of water is below the above 85 quality % of 40 quality %.
17. non-pneumatic bubbling container as described in any one in claim 1～16 dress liquid washing agents, wherein,
The viscosity of described non-pneumatic bubbling container dress liquid washing agent at 25 ℃ is 5～11mPas.
18. non-pneumatic bubbling container as described in any one in claim 1～17 dress liquid washing agents, wherein,
The content of soap is below 0.1 quality %, or does not contain soap.
19. non-pneumatic bubbling container as described in any one in claim 1～18 dress liquid washing agents, wherein,
The content of composition (A) anion surfactant that is selected from alkyl sulfuric ester or its salt and Voranol EP 2001 sulfuric ester or its salt is in addition below 7 quality %.
20. non-pneumatic bubbling container as described in any one in claim 1～18 dress liquid washing agents, wherein,
The content of composition (A) anion surfactant that is selected from alkyl sulfuric ester or its salt and Voranol EP 2001 sulfuric ester or its salt is in addition below 0.1 quality %, or does not contain composition (A) anion surfactant that is selected from alkyl sulfuric ester or its salt and Voranol EP 2001 sulfuric ester or its salt in addition.
21. non-pneumatic bubbling container as described in any one in claim 1～20 dress liquid washing agents, wherein,
The content of macromolecule tackifer is less than 0.2 quality %, or does not contain macromolecule tackifer.
Non-pneumatic bubbling container dress liquid washing agent in 22. 1 kinds of claims 1～21 described in any one is in the purposes of the washing for skin.
Non-pneumatic bubbling container in 23. 1 kinds of claims 1～21 described in any one dress liquid washing agent is for being directly placed on hand and washing by hand the purposes of washing skin.
Non-pneumatic bubbling container in 24. 1 kinds of claims 1～21 described in any one dress liquid washing agent is for being selected from the purposes in the washing of skin of sensitive skin, dry skin, mixed skin and infant's skin.
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| JP2012-141442 | 2012-06-22 | ||
| JP2012141442 | 2012-06-22 | ||
| JP2012-143535 | 2012-06-26 | ||
| JP2012143535A JP5947121B2 (en) | 2012-06-22 | 2012-06-26 | Liquid cleaner in non-gas former container |
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Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106473948A (en) * | 2015-09-02 | 2017-03-08 | 花王株式会社 | Cleanser compositions |
| CN110114054A (en) * | 2016-12-28 | 2019-08-09 | 花王株式会社 | Skin cleaner article |
| CN113396206A (en) * | 2019-01-31 | 2021-09-14 | 味之素株式会社 | Low viscosity liquid cleaning agent |
Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006183039A (en) * | 2004-11-30 | 2006-07-13 | Lion Corp | Detergent composition contained in foamer container |
| JP2008189869A (en) * | 2007-02-07 | 2008-08-21 | Kao Corp | Liquid detergent composition |
-
2013
- 2013-06-21 CN CN201310250292.XA patent/CN103509655B/en active Active
Patent Citations (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| JP2006183039A (en) * | 2004-11-30 | 2006-07-13 | Lion Corp | Detergent composition contained in foamer container |
| JP2008189869A (en) * | 2007-02-07 | 2008-08-21 | Kao Corp | Liquid detergent composition |
Non-Patent Citations (1)
| Title |
|---|
| 徐宝财等: "《洗涤剂配方设计6步》", 30 April 2010 * |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN106473948A (en) * | 2015-09-02 | 2017-03-08 | 花王株式会社 | Cleanser compositions |
| CN106473948B (en) * | 2015-09-02 | 2021-08-27 | 花王株式会社 | Detergent composition |
| CN110114054A (en) * | 2016-12-28 | 2019-08-09 | 花王株式会社 | Skin cleaner article |
| CN113396206A (en) * | 2019-01-31 | 2021-09-14 | 味之素株式会社 | Low viscosity liquid cleaning agent |
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