CN103503929A - Pesticide composition containing wilfordine and coumoxystrobin, and applications thereof - Google Patents

Pesticide composition containing wilfordine and coumoxystrobin, and applications thereof Download PDF

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Publication number
CN103503929A
CN103503929A CN201310275039.XA CN201310275039A CN103503929A CN 103503929 A CN103503929 A CN 103503929A CN 201310275039 A CN201310275039 A CN 201310275039A CN 103503929 A CN103503929 A CN 103503929A
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wilfordine
syp
pesticide composition
agent
grams
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张惠明
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FIVESTAR (NANTONG) CHEMICAL Co Ltd
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FIVESTAR (NANTONG) CHEMICAL Co Ltd
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Abstract

The invention discloses a pesticide composition containing wilfordine and coumoxystrobin as active ingredients, and applications thereof. The pesticide comprises common auxiliary agents, 0.1 to 80% of wilfordine and 0.1 to 85% of coumoxystrobin. The pesticide composition is capable of realizing relatively obvious synergistic interaction, is suitable for prevention of crop pests and diseases caused by various fungi, and is capable of controlling pests and diseases at the same time, reducing labor intensity to a certain degree and reducing cost. The pesticide composition can be used for prevention of following pests and diseases: crop pests such as nematode, cutworm, aphid, thrips and leafhopper; rice blast and banded sclerotial blight; powdery mildew, rust disease, septoria nodorum, rhynchosporium secalis davis, and black point of wheat; grape powdery mildew; powdery mildew, anthracnose, septoria lycopersici, cucumber downy mildew of cucurbites and solanaceae; and peanut cercospora leaf spot and rust disease. In addition, the pesticide composition is especially suitable for seed treatment, and prevention of germinated seeds against diseases.

Description

A kind of composition pesticide that contains wilfordine and SYP-3375 and application thereof
Technical field
The present invention relates to a kind of composition pesticide, relate in particular to a kind of composition pesticide that wilfordine and SYP-3375 be active ingredient of take, be applicable to crops pest, prevent and treat disease, strong sprout, promotion are adjusted growth, belong to biochemical pesticide field.
Background technology
The control of damage by disease and insect develops into present entomogenous fungi with killing from single desinsection, sterilization, on producing, has saved cost and labour, has saved equally in the use peasant's agriculture in the fields simultaneously originally and the activity duration, is a kind of progressive performance of Agrochemicals.As seed treatment, entomogenous fungi, with killing, can not only prevent and treat soil insect better if nematode, cutworm, crop pest are as aphid, thrips, leafhopper, again can be to rice blast and banded sclerotial blight; The powdery mildew of wheat, rust, glume blight, moire disease, black embryo disease; Grape powdery mildew; Melon and Solanaceae powdery mildew, anthracnose, spot blight, cucumber downy mildew and anthracnose are prevented; The disease such as leaf spot of peanut and rust, and time and labour saving, agricultural chemicals availability is high.Because biochemical pesticide is few, how to utilize better environmental protection type agricultural chemical to become current pesticide research person's important topic.
Wilfordine is one of main active in thunder godvine, there is the features such as insecticidal spectrum is wide, activity is high, toxicity is low, to lepidopterous diamond-back moth, cabbage caterpillar, suffixation of a nonsyllabic "r" snout moth's larva, the Asiatic migratory locust of orthoptera, dipterous midge, the corn weevil of coleoptera, the kind insects such as the tetranychus viennensis of Acarina all have stronger food refusal and toxic action, and there is paralysis insect, suppress it and grow, suppress the specificity insecticidal actions such as population augment, wilfordine is that a kind of natural insecticide , field has good effect.
SYP-3375 is a kind of methoxy-methyl acrylate compounds, English common name: coumoxystrobin, chemical name: (E)-2-(2-((3-butyl-4-methyl-coumarin-7-Ji-oxygen base) methyl) phenyl)-3-methoxy-methyl acrylate.There is protection and therapeutic action; a kind of disinfectant use in agriculture of high-efficiency broad spectrum, to having good preventive effect by mastigomycetes, the plant disease that causes in conjunction with bacterium, sac fungi, basidiomycetes and imperfect fungus as sclerotinia rot of colza, apple valsa canker, cucumber downy mildew, powdery mildew of cucumber, rice blast, sigatoka, alternaria leaf spot of apple etc.
Summary of the invention
The object of this invention is to provide a kind of insecticidal and bactericidal composition biochemical pesticide component, high-efficiency low-toxicity that contains, to various crop effectively pest, prevent and treat disease.
Another object of the present invention is to provide by this composition pesticide for seed pelleting, prevent and treat underground pests simultaneously, disease, improves emergence rate, to future elite seed have positive meaning.
Technical solution of the present invention: for achieving the above object, the invention provides the composition pesticide that a kind of effective ingredient is comprised of wilfordine and SYP-3375, the ratio of weight and number of wilfordine and SYP-3375 is 0.1~80:0.1~85, wilfordine and the percentage by weight of SYP-3375 weight summation in composition pesticide are 5~80%, preferred weight percent is 20~60%, and all the other are in agricultural chemicals, to allow to use and acceptable auxiliary element.
Composition pesticide of the present invention can be according to well known to a person skilled in the art method, be mixed with and dispersible oil suspending agent, suspending agent, aqueous emulsion, microemulsion, suspension seed-coating agent, microcapsule formulations, wetting powder, wet seed dressing, the formulation of the applicable agricultural uses such as water-dispersible granules, missible oil, soluble liquid, tablet.
Described composition pesticide also contains usual auxiliaries, comprises wetting agent, dispersant, solvent, emulsifier, thickener, defoamer, antifreezing agent, disintegrant, binding agent, film forming agent, stabilizing agent, filler, one or more the mixing such as deionized water.According to different situations, can change to some extent, be not particularly limited.
Product of the present invention can finished product preparation form provide, insecticide-applying way can be sprayed, pesticide-clay mixture, seed dressing is spread fertilizer over the fields etc. multiple.
The present composition, the insect and the disease that can be used for preventing and treating the crops such as paddy rice, wheat, corn, soybean, cotton, peanut, beet, rape, melon and fruit.
Compared with prior art, the invention has the advantages that: 1, select biochemical pesticide, more environmental protection, more energy-conservation; 2, composite have an obvious synergistic effect, improved control efficiency; 3, delay the pesticide resistance of damage by disease and insect; 4, two kinds of active ingredients are composite, reduced agricultural chemicals usage amount, reduced cost and the pollution to environment.
Specific embodiments
In order to make object of the present invention, technical scheme and advantage clearer, the present invention is described further technical scheme of the present invention with following specific embodiment.But the invention is not restricted to following specific embodiment.
embodiment 1: the control of combining to rape aphid and stalk break that is mixed of wilfordine and SYP-3375
Experimental technique: experimental pharmacy adopts the former medicine of 25% wilfordine and the former medicine of 96% SYP-3375, is mixed with required preparation, the matched proportion density according to setting, is mixed with desired concn liquid standby.Experiment adopts pot-culture method to survey stalk break: by large 100 the full seed seed dressings of medicament and grain, be seeded in the soil with sclerotinite, after planting move on in illumination box and cultivate, 25 ℃ of temperature, humidity 70%~80%, observes the situation of emerging every day, 20 days " Invest, Then Investigate " emergence rates and control efficiency.
Figure DEST_PATH_DEST_PATH_IMAGE001
Figure DEST_PATH_DEST_PATH_IMAGE002
Figure DEST_PATH_DEST_PATH_IMAGE003
Aphid: by medicament and seed seed dressing, after planting move on in illumination box and cultivate, 27 ℃ of temperature, humidity 80%~90%, while waiting rape to grow to 6 leaf, inoculates 100 aphids on rape leaf, 15d, 30d, 45d " Invest, Then Investigate " borer population alive.
Figure DEST_PATH_DEST_PATH_IMAGE004
Figure DEST_PATH_DEST_PATH_IMAGE005
Indoor biometrics result is as shown in the table:
The different complex preparation indoor measurement of table one result
As can be seen from the table, wilfordine and SYP-3375 single dose are used the successful when preventive effect of sclerotinia rot of colza is mixed to use than two kinds on the low side, and two kinds not only have good preventive effect to sclerotinia rot of colza after being mixed, and also better to the control of aphid.Especially emergence rate is greatly improved, and has guaranteed the normal production of agricultural, has saved labour.From test data it can also be seen that wilfordine and SYP-3375 more economic, practical to approach 1:20 medication.
embodiment 2: 21% wilfordine cloves bacterium ester suspension seed-coating agent
Take 1 gram of wilfordine, 20 grams of SYP-3375s, 2 grams of alkyl naphthalene sulfonic acid condensation polymer sodium salts, 1 gram of lauryl sodium sulfate, 1.5 grams of alkylphenol polyoxyethylene, 0.5 gram of aluminium-magnesium silicate, 0.5 gram of white carbon, 0.1 gram of xanthans, 4 grams of ethylene glycol, 3 grams of permanent bordeauxs, (851) 2 grams of seed coat agent film forming agents, 0.5 gram of defoamer, 0.1 gram of preservative (sterilizing solution), water complement to 100 grams.Above-mentioned mixing of materials is even, and porphyrize in sand mill, makes suspension seed-coating agent.
embodiment 3: the 42% wilfordine cloves bacterium ester seed dressing that wets
Take 2 grams of wilfordines, 40 grams of SYP-3375s, 3 grams of alkyl naphthalene sulfonic acid condensation polymer sodium salts, 2 grams of lauryl sodium sulfate, 1 gram of carboxymethyl cellulose, 5 grams of soluble starches, 3 grams of permanent bordeauxs, 3 grams of white carbons, kaolin complement to 100 grams.Above-mentioned mixing of materials is even, be crushed to 325 orders in airslide disintegrating mill more than, make wet seed dressing.
embodiment 4: 21% wilfordine cloves bacterium ester dispersibles oil-suspending agent
Take 1 gram of wilfordine, 20 grams of SYP-3375s, 2 grams of calcium dodecyl benzene sulfonates, 3 grams of alkyl polyoxyethylene ether amber acid ester sodium sulfonates, 3 grams of 10 grams of organobentonites of aliphatic alcohol polyethenoxy polyethenoxy ether, soya oil acid methyl esters complement to 100 grams.Above-mentioned mixing of materials is even, and porphyrize in sand mill, makes and dispersibles oil-suspending agent.
embodiment 5: 21% wilfordine cloves bacterium ester water dispersible granule
Take 1 gram of wilfordine, 20 grams of SYP-3375s, (2700) 3 grams of dispersants, 5 grams of alkyl naphthalene sulfonic acid condensation polymer sodium salts, (1004) 2 grams of wetting agents, 4 grams, ammonium sulfate, 10 grams of soluble starches, kaolin complement to 100 grams.Above-mentioned mixing of materials is even, be crushed to 325 orders in airslide disintegrating mill more than, add mix after 13 grams of water, put into Squeezinggranulator granulation, after drying, screening can make water dispersible granule.
embodiment 6: 42% wilfordine cloves bacterium ester wetting powder
Take 2 grams of wilfordines, 40 grams of SYP-3375s, 3 grams of alkyl naphthalene sulfonic acid condensation polymer sodium salts, 2 grams of lauryl sodium sulfate, 3 grams of white carbons, kaolin complement to 100 grams.Above-mentioned mixing of materials is even, be crushed to 325 orders in airslide disintegrating mill more than, make wetting powder.
embodiment 7: 21% wilfordine cloves bacterium emulsifiable concentrate
Take 1 gram of wilfordine, 20 grams of SYP-3375s, 3.5 grams of calcium dodecyl benzene sulfonates, dense newborn No. 604 6.5 grams, No. 150 solvent naphthas complement to 100 grams.Above-mentioned material stirring is even, can make missible oil.
embodiment 8: 10.5% wilfordine cloves bacterium ester aqueous emulsion
Take 0.5 gram of wilfordine, 10 grams of SYP-3375s, 2 grams of calcium dodecyl benzene sulfonates, dense newborn No. 604 4 grams join in 40 grams of No. 150 solvent naphthas and fully dissolve, above-mentioned material is joined in 43.5 grams of water, normal temperature high speed shear 30 minutes, can obtain aqueous emulsion.
application case
Xinjiang Production and Construction Army Corps' agriculture seven teachers, select 500 type machine concrete mixers, add 100kg cotton seeds, open agitator, under rotary state, add suspension seed-coating agent described in embodiment of the present invention, continue to stir 15 minutes, to the even enclosing characteristic look of the surface of the seed suspension seed-coating agent, take out and in normal temperature ventilation, dry sowing after 2 weeks.The observed result that table 2 is kept a full stand of seedings to cotton in seedling stage for this suspension seed-coating agent dressing.
Table 2 suspension seed-coating agent dressing is to the cotton in seedling stage observed result table of keeping a full stand of seedings:
Figure DEST_PATH_DEST_PATH_IMAGE007
The present invention can use without prejudice to the concrete form of spirit of the present invention or principal character and summarize; above-mentioned embodiment is only in order to technical scheme of the present invention to be described but not design of the present invention and protection domain are limited; those of ordinary skill of the present invention is modified or is equal to replacement technical scheme of the present invention; and not departing from aim and the scope of technical scheme, it all should be encompassed in claim scope of the present invention.

Claims (6)

1. containing a composite insecticidal bactericidal pesticide composition for wilfordine and SYP-3375, it is characterized in that: take wilfordine and SYP-3375 as main active ingredient, wherein, the ratio of weight and number of wilfordine and SYP-3375 is 0.1~80:0.1~85.
2. a kind of composite insecticidal bactericidal pesticide composition containing wilfordine and SYP-3375 according to claim 1, it is characterized in that: described wilfordine and the percentage by weight of SYP-3375 weight summation in composition pesticide are 5~80%, preferred percentage by weight is 20~60%.
3. a kind of composite insecticidal bactericidal pesticide composition that contains wilfordine and SYP-3375 according to claim 1, it is characterized in that: described usual auxiliaries is solvent, emulsifier, wetting agent, dispersant, thickener, defoamer, antifreezing agent, disintegrant, binding agent, stabilizing agent, filler, one or more in deionized water.
4. a kind of composite insecticidal bactericidal pesticide composition that contains wilfordine and SYP-3375 according to claim 1, it is characterized in that: the formulation of the composition pesticide that contains wilfordine and SYP-3375 is to dispersible oil-suspending agent, suspending agent, aqueous emulsion, microemulsion, suspension seed-coating agent, microcapsule formulations, wetting powder, wet seed dressing, a kind of in water-dispersible granules, missible oil, soluble liquid, Tabules.
5. a kind of composite insecticidal bactericidal pesticide composition that contains wilfordine and SYP-3375 according to claim 4, is characterized in that: its preferred dosage form is suspension seed-coating agent and wet seed dressing.
6. a kind of composite insecticidal bactericidal pesticide composition that contains wilfordine and SYP-3375 according to claim 5, it is characterized in that: described suspension seed-coating agent, wet seed dressing is mainly used in the seed dressing of the crop such as paddy rice, wheat, corn, soybean, cotton, peanut, beet, rape, melon and fruit and uses, and pest, prevents and treats disease.
CN201310275039.XA 2013-07-03 2013-07-03 Pesticide composition containing wilfordine and coumoxystrobin, and applications thereof Pending CN103503929A (en)

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Cited By (4)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104542726A (en) * 2014-12-24 2015-04-29 青岛锐志农业技术服务有限公司 Wilforine and pyraclostrobin seed-dressing suspension and preparation method thereof
CN104725137A (en) * 2015-03-20 2015-06-24 武汉理工大学 Corn seed coating agent and preparation method thereof
CN104982463A (en) * 2015-08-06 2015-10-21 杨新兰 Bactericide containing coumoxystrobin and astragalus membranaceus
CN105076243A (en) * 2015-08-10 2015-11-25 谢绪叶 Fungicide containing coumoxystrobin and scutellaria baicalensis

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Cited By (5)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104542726A (en) * 2014-12-24 2015-04-29 青岛锐志农业技术服务有限公司 Wilforine and pyraclostrobin seed-dressing suspension and preparation method thereof
CN104725137A (en) * 2015-03-20 2015-06-24 武汉理工大学 Corn seed coating agent and preparation method thereof
CN104725137B (en) * 2015-03-20 2018-01-12 武汉理工大学 A kind of corn seed coating agent and preparation method thereof
CN104982463A (en) * 2015-08-06 2015-10-21 杨新兰 Bactericide containing coumoxystrobin and astragalus membranaceus
CN105076243A (en) * 2015-08-10 2015-11-25 谢绪叶 Fungicide containing coumoxystrobin and scutellaria baicalensis

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Application publication date: 20140115