CN103497434A - Antiskid rubber sole composition - Google Patents
Antiskid rubber sole composition Download PDFInfo
- Publication number
- CN103497434A CN103497434A CN201310473723.9A CN201310473723A CN103497434A CN 103497434 A CN103497434 A CN 103497434A CN 201310473723 A CN201310473723 A CN 201310473723A CN 103497434 A CN103497434 A CN 103497434A
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- China
- Prior art keywords
- rubber combination
- weight
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- agent
- carbon black
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Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/18—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms
- C08L23/20—Homopolymers or copolymers of hydrocarbons having four or more carbon atoms having four to nine carbon atoms
- C08L23/22—Copolymers of isobutene; Butyl rubber ; Homo- or copolymers of other iso-olefins
-
- A—HUMAN NECESSITIES
- A43—FOOTWEAR
- A43B—CHARACTERISTIC FEATURES OF FOOTWEAR; PARTS OF FOOTWEAR
- A43B13/00—Soles; Sole-and-heel integral units
- A43B13/02—Soles; Sole-and-heel integral units characterised by the material
- A43B13/04—Plastics, rubber or vulcanised fibre
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08K—Use of inorganic or non-macromolecular organic substances as compounding ingredients
- C08K2201/00—Specific properties of additives
- C08K2201/002—Physical properties
- C08K2201/004—Additives being defined by their length
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/14—Polymer mixtures characterised by other features containing polymeric additives characterised by shape
- C08L2205/16—Fibres; Fibrils
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Engineering & Computer Science (AREA)
- Materials Engineering (AREA)
- Compositions Of Macromolecular Compounds (AREA)
Abstract
The invention relates to an antiskid rubber sole composition. The composition consists of the following components in parts by weight: 60-90 parts of butyl rubber, 20-45 parts of chloroprene rubber, 8-18 parts of short fiber, 1-4 parts of an activating agent, 2-5 parts of a vulcanizing agent, 8-14 parts of a reinforcing agent and 15-30 parts of a filler. Antiskid soles prepared from the rubber composition are obvious in antiskid performance at low temperature. The rubber composition, through selecting reasonable ingredients, is excellent in antiskid performance and other mechanical properties.
Description
Technical field
The present invention relates to the rubber soles technical field, relate in particular to a kind of Antiskid sole rubber combination.
Background technology
In general, rubber composition for footwear must be able to support wearer's body weight, the load that bears the motion generation and impact intensity of force, improves comfort level, security and the anti-skid of shoes.
Manufacture shoes and first will make the large end, the usually large end, consist of basic materials such as rubber.To the key property requirement at this large end, while walking exactly, be difficult for skidding, to demonstrate good grabbing property.Up to now, in order to improve the non-skid property at the large end, take a lot of methods, as selected specific rubber size to improve anti-skid etc.
The many employings of current Antiskid sole do not add the elastomeric material of any weighting agent, certain anti-skidding effect can only be played in the large end that this material is made on common road surface, for the road surface of smoother or under the environment of low temperature, will lose its non-skid property, therefore, there is the defect of non-skid property aspect.
Summary of the invention
The object of the present invention is to provide a kind of Antiskid sole rubber combination.
For reaching this purpose, the present invention by the following technical solutions:
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The present invention, by selecting the rational proportion of rational basic glue and adjustment basis glue and Synergist S-421 95, strengthens the synergy of basic glue and Synergist S-421 95, solves the problem of prior art, prepares the good rubber combination that disappears of non-skid property.
The parts by weight of isoprene-isobutylene rubber of the present invention can select 60.02～89.6,65～84.5,68.9～80,72.2～78,76 etc.
The parts by weight of chloroprene rubber of the present invention can select 20.1～44.8,24～42,28.6～40,35 etc.
The parts by weight of staple fibre of the present invention can select 8.01～17.8,10～15.6,11.2～14,13 etc.
The parts by weight of promoting agent of the present invention can select 1.02～3.89,1.3～3.67,1.52～3.47,1.8～3.2,2.3～2.8,2.6 etc.
The parts by weight of vulcanizing agent of the present invention can select 2.01～4.95,2.3～4.5,2.75～4.1,3～3.78,3.56 etc.
The parts by weight of strengthening agent of the present invention can select 8.01～13.94,8.6～12,9.3～11.4,9.8～10.2 etc.
The parts by weight of weighting agent of the present invention can select 15.01～29.8,17.6～26.7,18.9～23,21.7 etc.
As the preferred technical solution of the present invention, described composition comprises following component by weight:
Staple fibre of the present invention is selected from the mixture of a kind of in glass fibre, aramid fiber, carbon fiber bar, trevira or cotton fibre or at least two kinds, its typical but non-limiting example comprises: glass fibre, carbon fiber bar, aramid fiber, cotton fibre, the combination of glass fibre and aramid fiber, the combination of aramid fiber and trevira, the combination of glass fibre and cotton fibre, the combination of glass fibre, aramid fiber and trevira, the combination of glass fibre, carbon fiber bar, trevira and cotton fibre, all can be used for implementing the present invention.The mixture of a kind of in preferred glass fibers, aramid fiber or trevira or at least two kinds, further preferred glass fibers and/or aramid fiber.
The length of staple fibre of the present invention is less than 10mm, for example can select 9.9mm, 9mm, 7.6mm, 5.8mm, 5mm, 4.3mm, 3.5mm, 2mm, 1.4mm, 0.23mm, 0.15mm etc., preferred 0.2～5mm, further preferred 3mm.
Stearic acid selected by described promoting agent or/and Zinic stearas.
Described vulcanizing agent is that magnesium oxide is or/and zinc oxide, further preferential oxidation magnesium and zinc oxide.
Described strengthening agent is selected from the mixture of a kind of in carclazyte, carbon black N234, carbon black N220 or carbon black N330 or at least two kinds, typical but non-limiting example comprises: carclazyte, carbon black N220, carbon black N330, the combination of carclazyte and carbon black N330, the combination of carbon black 234 and carbon black N220, the combination of carclazyte, carbon black N234 and carbon black N330 etc., all can be used for implementing the present invention.Preferably carclazyte LT-102 is or/and carbon black N330.
Described weighting agent is selected from calcium carbonate and/or potter's clay.
Described composition also comprises promotor.The parts by weight of described promotor are preferably 5～8, for example can select 5.02～7.96,5.3～7.7,6～7.12,6.86 etc.
Described promotor is selected from accelerant CZ, Vulcanization accelerator TMTD, vulkacit D, altax, accelerator DZ, the mixture of a kind of in accelerant N A-22 or accelerant NOBS or at least two kinds, typical but non-limiting example comprises: accelerant CZ, vulkacit D, altax, accelerant N A-22, the combination of Vulcanization accelerator TMTD and accelerator DZ, vulkacit D, the combination of altax and accelerant NOBS, accelerant CZ, vulkacit D, the combination of accelerator DZ and accelerant N A-22 etc., all can be used for implementing the present invention, further preferred accelerators DM is or/and accelerant N A-22.
Described composition also comprises dispersion agent.The parts by weight of described dispersion agent are preferably 0.31～1.96, and 0.5～1.8,0.75～1.63,0.96～1.5,1.36 etc.Described dispersion agent is dispersion agent FL.
As the most preferred technical scheme of the present invention, described composition comprises following component by weight:
" comprising " of the present invention, mean it except described component, can also comprise other components, these other components give described rubber combination different characteristics.In addition, " comprising " of the present invention, can also replace with enclosed " being " or " by ... form ".
With the prior art scheme, compare, the present invention has following beneficial effect:
The Antiskid sole prepared by rubber combination of the present invention non-skid property at low temperatures is more outstanding.The present invention, by selecting rational Synergist S-421 95, makes the rubber combination finally made have good anti-skid and other mechanical propertys.
Below the present invention is described in more detail.But following example is only simple and easy example of the present invention, does not represent or limit the scope of the present invention, and protection scope of the present invention is as the criterion with claims.Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical but non-limiting embodiment of the present invention is as follows:
Embodiment 1
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said staple fibre is 6mm.
Embodiment 2
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said staple fibre is 9.5mm.
Embodiment 3
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said staple fibre is 5mm.
Embodiment 4
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said staple fibre is 0.2mm.
Embodiment 5
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said glass fibre is 3mm.
Applicant's statement, the person of ordinary skill in the field is on the basis of above-described embodiment, concrete content point value by above-described embodiment component, combined with the technical scheme of summary of the invention part, thereby the new numerical range produced, be also one of record scope of the present invention, the application, for making specification sheets simple and clear, is no longer enumerated these numerical ranges.
Claims (10)
1. an Antiskid sole rubber combination, is characterized in that, described composition comprises following component by weight:
2. rubber combination as claimed in claim 1, is characterized in that, described composition comprises following component by weight:
3. rubber combination as claimed in claim 1 or 2, it is characterized in that, described staple fibre is selected from the mixture of a kind of in glass fibre, aramid fiber, carbon fiber bar, trevira or cotton fibre or at least two kinds, the mixture of a kind of in preferred glass fibers, aramid fiber or trevira or at least two kinds, further preferred glass fibers and/or aramid fiber.
4. rubber combination as described as one of claim 1-3, is characterized in that, the length of described staple fibre is less than 10mm, preferred 0.2～5mm, further preferred 3mm.
5. rubber combination as described as one of claim 1-4, is characterized in that, stearic acid selected by described promoting agent or/and Zinic stearas;
Preferably, described vulcanizing agent is that magnesium oxide is or/and zinc oxide, further preferential oxidation magnesium and zinc oxide.
6. rubber combination as described as one of claim 1-5, is characterized in that, described strengthening agent is selected from the mixture of a kind of in carclazyte, carbon black N234, carbon black N220 or carbon black N330 or at least two kinds, and preferably carclazyte LT-102 is or/and carbon black N330.
7. rubber combination as described as one of claim 1-6, is characterized in that, described weighting agent is selected from calcium carbonate and/or potter's clay.
8. rubber combination as described as one of claim 1-7, is characterized in that, described composition also comprises promotor; The parts by weight of described promotor are preferably 5～8;
Preferably, described promotor is selected from the mixture of a kind of in accelerant CZ, Vulcanization accelerator TMTD, vulkacit D, altax, accelerator DZ, accelerant N A-22 or accelerant NOBS or at least two kinds, and further preferred accelerators DM is or/and accelerant N A-22.
9. rubber combination as described as one of claim 1-8, is characterized in that, described composition also comprises dispersion agent; The parts by weight of described dispersion agent are preferably 0.3～2;
Preferably, described dispersion agent is dispersion agent FL.
10. rubber combination as described as one of claim 1-9, is characterized in that, described composition comprises following component by weight:
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310473723.9A CN103497434A (en) | 2013-10-11 | 2013-10-11 | Antiskid rubber sole composition |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310473723.9A CN103497434A (en) | 2013-10-11 | 2013-10-11 | Antiskid rubber sole composition |
Publications (1)
| Publication Number | Publication Date |
|---|---|
| CN103497434A true CN103497434A (en) | 2014-01-08 |
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Family Applications (1)
| Application Number | Title | Priority Date | Filing Date |
|---|---|---|---|
| CN201310473723.9A Pending CN103497434A (en) | 2013-10-11 | 2013-10-11 | Antiskid rubber sole composition |
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| CN (1) | CN103497434A (en) |
Cited By (4)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104086906A (en) * | 2014-05-30 | 2014-10-08 | 航天材料及工艺研究所 | Butyl rubber composition, preparation method and method for preparing pressure hose |
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN107163419A (en) * | 2017-05-23 | 2017-09-15 | 林玉萍 | A kind of anti-slip rubber sole |
| CN107586451A (en) * | 2017-10-25 | 2018-01-16 | 徐冰 | A kind of cold-proof rubber soles |
Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087359A (en) * | 2012-11-15 | 2013-05-08 | 青岛融鑫源橡胶机械有限公司 | Wearable and anti-skidding rubber formula for soles of sports shoes |
-
2013
- 2013-10-11 CN CN201310473723.9A patent/CN103497434A/en active Pending
Patent Citations (1)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN103087359A (en) * | 2012-11-15 | 2013-05-08 | 青岛融鑫源橡胶机械有限公司 | Wearable and anti-skidding rubber formula for soles of sports shoes |
Non-Patent Citations (2)
| Title |
|---|
| 王忠等: "《氯丁橡胶丁基橡胶的成型工艺研究》", 《陕西理工学院学报（自然科学版）》, vol. 29, no. 4, 31 August 2013 (2013-08-31), pages 1 - 4 * |
| 赵付彬: "《短纤维增强氯丁橡胶基复合材料结构与力学性能研究》", 《中国优秀硕士学位论文全文数据库工程科技Ⅰ辑》, 15 June 2013 (2013-06-15), pages 020 - 49 * |
Cited By (6)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104086906A (en) * | 2014-05-30 | 2014-10-08 | 航天材料及工艺研究所 | Butyl rubber composition, preparation method and method for preparing pressure hose |
| CN104086906B (en) * | 2014-05-30 | 2016-06-01 | 航天材料及工艺研究所 | The preparation method of a kind of butyl rubber composition and prepare the method for pressure hose |
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104292554B (en) * | 2014-08-07 | 2016-05-11 | 茂泰(福建)鞋材有限公司 | A kind of dynamic Anti-skidding rubber sole of ice face and production method thereof |
| CN107163419A (en) * | 2017-05-23 | 2017-09-15 | 林玉萍 | A kind of anti-slip rubber sole |
| CN107586451A (en) * | 2017-10-25 | 2018-01-16 | 徐冰 | A kind of cold-proof rubber soles |
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| C02 | Deemed withdrawal of patent application after publication (patent law 2001) | ||
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Application publication date: 20140108 |