CN103497382A - Antiskid rubber sole composition and preparation method thereof - Google Patents
Antiskid rubber sole composition and preparation method thereof Download PDFInfo
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- CN103497382A CN103497382A CN201310473555.3A CN201310473555A CN103497382A CN 103497382 A CN103497382 A CN 103497382A CN 201310473555 A CN201310473555 A CN 201310473555A CN 103497382 A CN103497382 A CN 103497382A
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Abstract
The invention relates to an antiskid rubber sole composition. The composition consists of the following components in parts by weight: 80-100 parts of chloroprene rubber, 10-25 parts of butadiene rubber, 6-13 parts of short fiber, 4-10 parts of wood powder, 2-7 parts of an activating agent, 1-5 parts of a vulcanizing agent, 5-9 parts of a reinforcing agent and 15-30 parts of a filler. The antiskid rubber sole composition is prepared by mixing and vulcanizing various components depending on formula amounts. Antiskid soles prepared from the rubber composition can reach 1.0 in dry antiskid coefficient and 0.8 in wet antiskid coefficient, thus guaranteeing safety in a walking or moving process.
Description
Technical field
The present invention relates to the rubber soles technical field, relate in particular to a kind of Antiskid sole rubber combination and preparation method thereof.
Background technology
In general, rubber composition for footwear must be able to support wearer's body weight, the load that bears the motion generation and impact intensity of force, improves comfort level, security and the anti-skid of shoes.
Manufacture shoes and first will make the large end, the usually large end, consist of basic materials such as rubber.To the key property requirement at this large end, while walking exactly, be difficult for skidding, to demonstrate good grabbing property.Up to now, in order to improve the non-skid property at the large end, take a lot of methods, as selected specific rubber size to improve anti-skid etc.
The many employings of current Antiskid sole do not add the elastomeric material of any weighting agent, certain anti-skidding effect can only be played in the large end that this material is made on common road surface, for the road surface of smoother or under the environment of low temperature, will lose its non-skid property, therefore, there is the defect of non-skid property aspect.
Summary of the invention
The object of the present invention is to provide a kind of Antiskid sole rubber combination.
For reaching this purpose, the present invention by the following technical solutions:
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The present invention, by selecting the rational proportion of rational basic glue and adjustment basis glue and Synergist S-421 95, strengthens the synergy of basic glue and Synergist S-421 95, solves the problem of prior art, prepares the good rubber combination that disappears of non-skid property.
The parts by weight of chloroprene rubber of the present invention can select 80.01～99.6,83～92,86.7～90,88.6 etc.
The parts by weight of cis-1,4-polybutadiene rubber of the present invention can select 10.02～24.8,13～22,15.6～20.8,18.6 etc.
The parts by weight of staple fibre of the present invention can select 6.01～12.8,7.2～11.3,7.8～10.4,8.5 etc.
The parts by weight of wood powder of the present invention can select 4.02～9.6,4.6～9,5.3～8.2,6～7.5,6.8 etc.
The parts by weight of promoting agent of the present invention can select 2.01～6.89,2.5～6.43,2.89～6,3.3～5.4,4～5.1,4.6 etc.
The parts by weight of vulcanizing agent of the present invention can select 1.02～4.96,1.3～4.5,1.76～4.03,2～3.8,2.4～3.2,2.9 etc.
The parts by weight of strengthening agent of the present invention can select 5.01～8.97,5.43～8.56,5.8～8.2,6.5～7.5,7.1 etc.
The parts by weight of weighting agent of the present invention can select 15.01～29.8,17.6～26.7,18.9～23,21.7 etc.
As the preferred technical solution of the present invention, described composition comprises following component by weight:
Staple fibre of the present invention is selected from the mixture of a kind of in glass fibre, aramid fiber, carbon fiber bar, trevira or cotton fibre or at least two kinds, its typical but non-limiting example comprises: glass fibre, carbon fiber bar, aramid fiber, cotton fibre, the combination of glass fibre and aramid fiber, the combination of aramid fiber and trevira, the combination of glass fibre and cotton fibre, the combination of glass fibre, aramid fiber and trevira, the combination of glass fibre, carbon fiber bar, trevira and cotton fibre, all can be used for implementing the present invention.The mixture of a kind of in preferred glass fibers, aramid fiber or trevira or at least two kinds, further preferred glass fibers and/or aramid fiber.
The length of staple fibre of the present invention is less than 10mm, for example can select 9.9mm, 9mm, 7.6mm, 5.8mm, 5mm, 4.3mm, 3.5mm, 2mm, 1.4mm, 0.23mm, 0.15mm etc., preferred 0.2～5mm, further preferred 3mm.
Stearic acid selected by described promoting agent or/and Zinic stearas;
Described vulcanizing agent is that magnesium oxide is or/and zinc oxide, further preferential oxidation magnesium and zinc oxide.
Described strengthening agent is selected from the mixture of a kind of in carclazyte, carbon black N234, carbon black N220 or carbon black N330 or at least two kinds, typical but non-limiting example comprises: carclazyte, carbon black N220, carbon black N330, the combination of carclazyte and carbon black N330, the combination of carbon black 234 and carbon black N220, the combination of carclazyte, carbon black N234 and carbon black N330 etc., all can be used for implementing the present invention.Preferably carclazyte LT-102 is or/and carbon black N330.Described weighting agent is selected from calcium carbonate and/or potter's clay.
As the most preferred technical scheme of the present invention, described composition comprises following component by weight:
" comprising " of the present invention, mean it except described component, can also comprise other components, these other components give described rubber combination different characteristics.In addition, " comprising " of the present invention, can also replace with enclosed " being " or " by ... form ".
A kind of preparation method of Antiskid sole rubber combination as above, each component is mixing by formula ratio, sulfuration obtains the Antiskid sole rubber combination.
Described mixing time is 400～750s, for example can select 400.01～749.6s, 417～720s, 430～701.5s, 448～682s, 480～652s, 496～623s, 536～600s, 580s etc., further preferred 650s.
Described curing time is 3～8min, for example can select 3.02～7.96min, 3.6～7.56min, 4～7.2min, 4.6～6.5min, 5～6.2min, 5.7min etc., further preferred 6min.
With the prior art scheme, compare, the present invention has following beneficial effect:
The non-skid property of the Antiskid sole prepared by rubber combination of the present invention on smooth earth is outstanding.The present invention, by selecting rational Synergist S-421 95, makes the rubber combination finally made have good anti-skid and other mechanical propertys.The Antiskid sole of being produced by rubber combination of the present invention, its on-slip coefficient can reach dry type 1.0, and wet type 0.8 has guaranteed the safety in walking or moving process.
Below the present invention is described in more detail.But following example is only simple and easy example of the present invention, does not represent or limit the scope of the present invention, and protection scope of the present invention is as the criterion with claims.
Embodiment
For the present invention is described better, be convenient to understand technical scheme of the present invention, typical but non-limiting embodiment of the present invention is as follows:
Embodiment 1
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said staple fibre is 6mm.
Each component is mixing by formula ratio, sulfuration obtains the Antiskid sole rubber combination.Described mixing time is 400s; Described curing time is 8min.
Embodiment 2
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said staple fibre is 9.5mm.
Each component is mixing by formula ratio, sulfuration obtains the Antiskid sole rubber combination.Described mixing time is 750s; Described curing time is 3min.
Embodiment 3
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said staple fibre is 5mm.
Each component is mixing by formula ratio, sulfuration obtains the Antiskid sole rubber combination.Described mixing time is 720s; Described curing time is 5min.
Embodiment 4
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said staple fibre is 0.2mm.
Each component is mixing by formula ratio, sulfuration obtains the Antiskid sole rubber combination.Described mixing time is 620s; Described curing time is 4.5min.
Embodiment 5
A kind of Antiskid sole rubber combination, described composition comprises following component by weight:
The length of wherein said glass fibre is 3mm.
Each component is mixing by formula ratio, sulfuration obtains the Antiskid sole rubber combination.Described mixing time is 650s; Described curing time is 6min.
Applicant's statement, the person of ordinary skill in the field is on the basis of above-described embodiment, concrete content point value by above-described embodiment component, combined with the technical scheme of summary of the invention part, thereby the new numerical range produced, be also one of record scope of the present invention, the application, for making specification sheets simple and clear, is no longer enumerated these numerical ranges.
Claims (8)
1. an Antiskid sole rubber combination, is characterized in that, described composition comprises following component by weight:
2. rubber combination as claimed in claim 1, is characterized in that, described composition comprises following component by weight:
3. rubber combination as claimed in claim 1 or 2, it is characterized in that, described staple fibre is selected from the mixture of a kind of in glass fibre, aramid fiber, carbon fiber bar, trevira or cotton fibre or at least two kinds, the mixture of a kind of in preferred glass fibers, aramid fiber or trevira or at least two kinds, further preferred glass fibers and/or aramid fiber.
4. rubber combination as described as one of claim 1-3, is characterized in that, the length of described staple fibre is less than 10mm, preferred 0.2～5mm, further preferred 3mm.
5. rubber combination as described as one of claim 1-4, is characterized in that, stearic acid selected by described promoting agent or/and Zinic stearas;
Preferably, described vulcanizing agent is that magnesium oxide is or/and zinc oxide, further preferential oxidation magnesium and zinc oxide.
Preferably, described strengthening agent is selected from the mixture of a kind of in carclazyte, carbon black N234, carbon black N220 or carbon black N330 or at least two kinds, and preferably carclazyte LT-102 is or/and carbon black N330.
Preferably, described weighting agent is selected from calcium carbonate and/or potter's clay.
6. rubber combination as described as one of claim 1-5, is characterized in that, described composition comprises following component by weight:
7. the preparation method of an Antiskid sole rubber combination as described as one of claim 1-6, is characterized in that, each component is mixing by formula ratio, sulfuration obtains the Antiskid sole rubber combination.
8. preparation method as claimed in claim 7, is characterized in that, described mixing time is 400～750s, further preferred 650s; Preferably, described curing time is 3～8min, further preferred 6min.
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310473555.3A CN103497382A (en) | 2013-10-11 | 2013-10-11 | Antiskid rubber sole composition and preparation method thereof |
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| Application Number | Priority Date | Filing Date | Title |
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| CN201310473555.3A CN103497382A (en) | 2013-10-11 | 2013-10-11 | Antiskid rubber sole composition and preparation method thereof |
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| CN103497382A true CN103497382A (en) | 2014-01-08 |
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Cited By (2)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN108158129A (en) * | 2017-11-22 | 2018-06-15 | 海盐县硕创服装研究所 | A kind of light wear-resistant sole material |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101067029A (en) * | 2007-05-31 | 2007-11-07 | 青岛亨达集团有限公司 | Antislip sole material |
| CN101143039A (en) * | 2007-11-01 | 2008-03-19 | 青岛亨达集团有限公司 | Rubber and wood powder mixed non-slip sole material |
| CN102924772A (en) * | 2012-11-16 | 2013-02-13 | 东莞万泰橡胶有限公司 | Rubber composition used for anti-fire shoes and manufacturing method thereof |
-
2013
- 2013-10-11 CN CN201310473555.3A patent/CN103497382A/en active Pending
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101067029A (en) * | 2007-05-31 | 2007-11-07 | 青岛亨达集团有限公司 | Antislip sole material |
| CN101143039A (en) * | 2007-11-01 | 2008-03-19 | 青岛亨达集团有限公司 | Rubber and wood powder mixed non-slip sole material |
| CN102924772A (en) * | 2012-11-16 | 2013-02-13 | 东莞万泰橡胶有限公司 | Rubber composition used for anti-fire shoes and manufacturing method thereof |
Cited By (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN104292554A (en) * | 2014-08-07 | 2015-01-21 | 茂泰(福建)鞋材有限公司 | Ice-surface dynamic anti-slip rubber sole and production method thereof |
| CN104292554B (en) * | 2014-08-07 | 2016-05-11 | 茂泰(福建)鞋材有限公司 | A kind of dynamic Anti-skidding rubber sole of ice face and production method thereof |
| CN108158129A (en) * | 2017-11-22 | 2018-06-15 | 海盐县硕创服装研究所 | A kind of light wear-resistant sole material |
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Application publication date: 20140108 |