CN103483695A - Hanging application insolation-resistant cable material - Google Patents

Hanging application insolation-resistant cable material Download PDF

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Publication number
CN103483695A
CN103483695A CN201310381455.8A CN201310381455A CN103483695A CN 103483695 A CN103483695 A CN 103483695A CN 201310381455 A CN201310381455 A CN 201310381455A CN 103483695 A CN103483695 A CN 103483695A
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parts
add
raw material
stirring
powder
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CN201310381455.8A
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Chinese (zh)
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CN103483695B (en
Inventor
谢华
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Bengbu Shangwei Intellectual Property Operations Co ltd
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Lvbao Cable Group Co Ltd
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Priority to CN201310381455.8A priority Critical patent/CN103483695B/en
Publication of CN103483695A publication Critical patent/CN103483695A/en
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    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/03Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor characterised by the shape of the extruded material at extrusion
    • B29C48/04Particle-shaped
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C48/00Extrusion moulding, i.e. expressing the moulding material through a die or nozzle which imparts the desired form; Apparatus therefor
    • B29C48/25Component parts, details or accessories; Auxiliary operations
    • B29C48/92Measuring, controlling or regulating
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92504Controlled parameter
    • B29C2948/92704Temperature
    • BPERFORMING OPERATIONS; TRANSPORTING
    • B29WORKING OF PLASTICS; WORKING OF SUBSTANCES IN A PLASTIC STATE IN GENERAL
    • B29CSHAPING OR JOINING OF PLASTICS; SHAPING OF MATERIAL IN A PLASTIC STATE, NOT OTHERWISE PROVIDED FOR; AFTER-TREATMENT OF THE SHAPED PRODUCTS, e.g. REPAIRING
    • B29C2948/00Indexing scheme relating to extrusion moulding
    • B29C2948/92Measuring, controlling or regulating
    • B29C2948/92819Location or phase of control
    • B29C2948/92857Extrusion unit
    • B29C2948/92876Feeding, melting, plasticising or pumping zones, e.g. the melt itself
    • B29C2948/92895Barrel or housing
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2201/00Properties
    • C08L2201/08Stabilised against heat, light or radiation or oxydation
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Engineering & Computer Science (AREA)
  • Mechanical Engineering (AREA)
  • Chemical & Material Sciences (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a hanging application insolation-resistant cable material which comprises the following raw materials in parts by weight: 100-110 parts of ethylene propylene diene copolymer rubber K2340A, 10-20 parts of eva (Ethylene Vinyl Acetate) resin, 3-4 parts of fungacetin, 5-7 parts of octyl epoxy stearate, 4-6 parts of aluminum silicate, 20-25 parts of celestite powder, 4-5 parts of ceramic powder, 1-2 parts of polyacrylamide, 3-4 parts of hydrated zinc borate, 1-2 parts of anti-aging agents ODA, 0.2-0.5 part of 2-hydroxy-4-octyloxybenzophenone, 0.5-0.6 part of ultraviolet absorbents UV-329, 1-2 parts of gamma-aminopropyl triethoxysilane, 0.8-1 part of vulcanizing agents DCBP, 1-3 parts of accelerating agents DM and 20-25 parts of modified auxiliary agents. The hanging application insolation-resistant cable material disclosed by the invention has very good insolation-resistant property, can be adapted to a long-term outdoor hanging environment, enhances the compatibility of materials by adding the modified auxiliary agents, further enhances the tearing strength, the resilience property, and the like of a finished product and is excellent in physical property, heat-resistant property and ageing-resistant property.

Description

The sun-resistant CABLE MATERIALS of a kind of unsettled application
Technical field
The present invention relates generally to a kind of CABLE MATERIALS, relates in particular to the sun-resistant CABLE MATERIALS of a kind of unsettled application.
Background technology
Ethylene-propylene rubber(EPR) has excellent anti-weather, anti-ozone, heat-resisting, acid and alkali-resistance, water-fast steam, color, electrical property, oil-filled property and normal temperature mobility.But the ethylene-propylene rubber(EPR) goods are life-time service under 120 ℃, under 150-200 ℃, can of short duration or intermittently use.Add suitable anti-aging agent can improve its use temperature.Terpolymer EP rubber with peroxide crosslinking can more used under exacting terms.Terpolymer EP rubber, under ozone concn 50pphm, 30% the condition of stretching, can reach more than 150h and not chap.
Because ethylene-propylene rubber(EPR) lacks polarity, degree of unsaturation is low, thereby various polarity chemical are all had to anti-patience preferably as alcohol, acid, alkali, oxygenant, refrigeration agent, washing composition, vegetable and animals oils, ketone and fat etc.; But belong to poor with virtue genus solvent (as gasoline, benzene etc.) and mineral oil neutrality at fat.Therefore by adding New-type adjuvant to improve the over-all properties of traditional ethylene-propylene rubber(EPR), further improve the quality of CABLE MATERIALS highly significant.
Summary of the invention
The object of the invention just is to provide the sun-resistant CABLE MATERIALS of a kind of unsettled application.
The present invention is achieved by the following technical solutions:
The sun-resistant CABLE MATERIALS of a kind of unsettled application, it is comprised of the raw material of following weight parts:
Terpolymer EP rubber K2340A100-110, eva resin 10-20, Vanay 3-4, octyl epoxy stearate 5-7, pure aluminium silicate 4-6, celestite powder 20-25, ceramics powder 4-5, polyacrylamide 1-2, hydration zinc borate 3-4, anti-aging agent ODA 1-2, Octabenzone 0.2-0.5, UV light absorber UV-329 0.5-0.6, γ-aminopropyl triethoxysilane 1-2, vulcanizing agent DCBP0.8-1, altax 1-3, modified additive 20-25;
Described modified additive is comprised of the raw material of following weight parts:
Chlorinatedpolyethylene 90-100, aluminium nitride 4-5, morpholine 2-3, sodium polyacrylate 1-3, Silane coupling agent KH550 2-3, linking agent TAC3-5, nano diatomite powder 1-2;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, add chlorinatedpolyethylene, at 70-90 ℃ of lower reacting by heating 20-30 minute, be cooled to normal temperature, add sodium polyacrylate, aluminium nitride, morpholine, fully stir, the nano diatomite powder is heated to 90-100 ℃, add, 80-100 rev/min of dispersed with stirring 3-5 minute, dry, and obtains described modified additive.
The sun-resistant CABLE MATERIALS preparation method of a kind of unsettled application comprises the following steps:
Above-mentioned ceramics powder is heated to 100-120 ℃, add polyacrylamide, mixing and stirring, reduce the temperature to again 70-80 ℃, add octyl epoxy stearate, celestite powder, be cooled to normal temperature after fully stirring, add γ-aminopropyl triethoxysilane, 200-300 rev/min of dispersed with stirring 3-4 minute; Above-mentioned terpolymer EP rubber K2340A is put into to mill, mixing 4-6 minute under 75-80 ℃; Raw material after above-mentioned processing is mixed, add each raw material except vulcanizing agent DCBP, altax to mix, mixing 4-6 minute, add again each raw material of residue, after thin-pass 6-7 time, the extruder plastication granulation, the extrusion temperature of extruding machine is 160-170 ℃, obtains the sun-resistant CABLE MATERIALS of described unsettled application.
Advantage of the present invention is:
The CABLE MATERIALS that the present invention produces has good anti-Japanese solarization performance, can adapt to long-term outdoor unsettled environment, by the consistency of each storeroom that added modified additive to strengthen, further improved tearing toughness, screen resilience performance of finished product etc., CABLE MATERIALS physicals of the present invention, heat-resisting, ageing-resistant performance is outstanding.
Embodiment
Embodiment 1
The sun-resistant CABLE MATERIALS of a kind of unsettled application, it is comprised of the raw material of following weight parts (kilogram):
Terpolymer EP rubber K2340A110, eva resin 20, Vanay 4, octyl epoxy stearate 5, pure aluminium silicate 6, celestite powder 20-25, ceramics powder 5, polyacrylamide 2, hydration zinc borate 4, anti-aging agent ODA 2, Octabenzone 0.5, UV light absorber UV-329 0.6, γ-aminopropyl triethoxysilane 2, vulcanizing agent DCBP0.8, altax 3, modified additive 25;
Described modified additive is comprised of the raw material of following weight parts:
Chlorinatedpolyethylene 100, aluminium nitride 4, morpholine 3, sodium polyacrylate 3, Silane coupling agent KH550 3, linking agent TAC5, nano diatomite powder 2;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, added chlorinatedpolyethylene, 90 ℃ of lower reacting by heating 30 minutes, be cooled to normal temperature, add sodium polyacrylate, aluminium nitride, morpholine, fully stir, the nano diatomite powder is heated to 100 ℃, add, 100 rev/mins of dispersed with stirring 3 minutes, dry, and obtains described modified additive.
The sun-resistant CABLE MATERIALS preparation method of a kind of unsettled application comprises the following steps:
Above-mentioned ceramics powder is heated to 120 ℃, adds polyacrylamide, mixing and stirring, reduce the temperature to again 80 ℃, add octyl epoxy stearate, celestite powder, after fully stirring, be cooled to normal temperature, add γ-aminopropyl triethoxysilane, 300 rev/mins of dispersed with stirring 4 minutes; Above-mentioned terpolymer EP rubber K2340A is put into to mill, under 80 ℃ mixing 4 minutes; Raw material after above-mentioned processing is mixed, add each raw material except vulcanizing agent DCBP, altax to mix, mixing 6 minutes, add again each raw material of residue, after thin-pass 6 times, the extruder plastication granulation, the extrusion temperature of extruding machine is 170 ℃, obtains the sun-resistant CABLE MATERIALS of described unsettled application.
Performance test:
Hardness (Shao Shi A): 62;
Tensile strength (MPa): 17.7;
Elongation at break (%): 420;
Oil-proofness: 100 ℃ * 50h of 20# machine oil, elongation at break conservation rate 80.8%, tensile strength conservation rate 81.0%;
Anti-ozone: 26 ℃, 24h, ozone concn 0.030%, without cracking;
Ageing-resistant: 120 ℃, 100h, tensile strength conservation rate 90.8%, elongation at break conservation rate 92.1%.

Claims (2)

1. the sun-resistant CABLE MATERIALS of unsettled application is characterized in that what it was comprised of the raw material of following weight parts:
Terpolymer EP rubber K2340A 100-110, eva resin 10-20, Vanay 3-4, octyl epoxy stearate 5-7, pure aluminium silicate 4-6, celestite powder 20-25, ceramics powder 4-5, polyacrylamide 1-2, hydration zinc borate 3-4, anti-aging agent ODA 1-2, Octabenzone 0.2-0.5, UV light absorber UV-329 0.5-0.6, γ-aminopropyl triethoxysilane 1-2, vulcanizing agent DCBP0.8-1, altax 1-3, modified additive 20-25;
Described modified additive is comprised of the raw material of following weight parts:
Chlorinatedpolyethylene 90-100, aluminium nitride 4-5, morpholine 2-3, sodium polyacrylate 1-3, Silane coupling agent KH550 2-3, linking agent TAC3-5, nano diatomite powder 1-2;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, add chlorinatedpolyethylene, at 70-90 ℃ of lower reacting by heating 20-30 minute, be cooled to normal temperature, add sodium polyacrylate, aluminium nitride, morpholine, fully stir, the nano diatomite powder is heated to 90-100 ℃, add, 80-100 rev/min of dispersed with stirring 3-5 minute, dry, and obtains described modified additive.
2. the sun-resistant CABLE MATERIALS preparation method of unsettled application as claimed in claim 1 is characterized in that comprising the following steps:
Above-mentioned ceramics powder is heated to 100-120 ℃, add polyacrylamide, mixing and stirring, reduce the temperature to again 70-80 ℃, add octyl epoxy stearate, celestite powder, be cooled to normal temperature after fully stirring, add γ-aminopropyl triethoxysilane, 200-300 rev/min of dispersed with stirring 3-4 minute; Above-mentioned terpolymer EP rubber K2340A is put into to mill, mixing 4-6 minute under 75-80 ℃; Raw material after above-mentioned processing is mixed, add each raw material except vulcanizing agent DCBP, altax to mix, mixing 4-6 minute, add again each raw material of residue, after thin-pass 6-7 time, the extruder plastication granulation, the extrusion temperature of extruding machine is 160-170 ℃, obtains the sun-resistant CABLE MATERIALS of described unsettled application.
CN201310381455.8A 2013-08-28 2013-08-28 The sun-resistant CABLE MATERIALS of a kind of unsettled application Expired - Fee Related CN103483695B (en)

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109360680A (en) * 2018-09-16 2019-02-19 江苏亨通电力电缆有限公司 The environmentally protective DC traction cable of rail traffic high fire-retardance and its preparation process

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101921437A (en) * 2010-10-11 2010-12-22 天龙伟业线缆有限公司 Low smoke zero halogen thermoplastic elastomer flame-retardant cable material and production method thereof
CN101987902A (en) * 2009-07-31 2011-03-23 索肯(上海)科技有限公司 Halogen-free thermoplastic elastomer and manufacturing method thereof and environment-friendly electric wires and cables using halogen-free thermoplastic elastomer
CN103259241A (en) * 2013-06-08 2013-08-21 国家电网公司 High-memorability and dismounting-free seal cover at electric pipeline connecting part, processing technology and special extrusion head

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101987902A (en) * 2009-07-31 2011-03-23 索肯(上海)科技有限公司 Halogen-free thermoplastic elastomer and manufacturing method thereof and environment-friendly electric wires and cables using halogen-free thermoplastic elastomer
CN101921437A (en) * 2010-10-11 2010-12-22 天龙伟业线缆有限公司 Low smoke zero halogen thermoplastic elastomer flame-retardant cable material and production method thereof
CN103259241A (en) * 2013-06-08 2013-08-21 国家电网公司 High-memorability and dismounting-free seal cover at electric pipeline connecting part, processing technology and special extrusion head

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN109360680A (en) * 2018-09-16 2019-02-19 江苏亨通电力电缆有限公司 The environmentally protective DC traction cable of rail traffic high fire-retardance and its preparation process

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Granted publication date: 20160302