CN103483694B - A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS - Google Patents
A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS Download PDFInfo
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- CN103483694B CN103483694B CN201310381454.3A CN201310381454A CN103483694B CN 103483694 B CN103483694 B CN 103483694B CN 201310381454 A CN201310381454 A CN 201310381454A CN 103483694 B CN103483694 B CN 103483694B
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- 239000000463 material Substances 0.000 title claims abstract description 18
- 239000002994 raw material Substances 0.000 claims abstract description 16
- 239000003795 chemical substances by application Substances 0.000 claims abstract description 15
- VYPSYNLAJGMNEJ-UHFFFAOYSA-N Silicium dioxide Chemical compound O=[Si]=O VYPSYNLAJGMNEJ-UHFFFAOYSA-N 0.000 claims abstract description 13
- 239000000654 additive Substances 0.000 claims abstract description 10
- 230000000996 additive effect Effects 0.000 claims abstract description 10
- 229920001971 elastomer Polymers 0.000 claims abstract description 9
- 229920001897 terpolymer Polymers 0.000 claims abstract description 9
- ZFOZVQLOBQUTQQ-UHFFFAOYSA-N Tributyl citrate Chemical compound CCCCOC(=O)CC(O)(C(=O)OCCCC)CC(=O)OCCCC ZFOZVQLOBQUTQQ-UHFFFAOYSA-N 0.000 claims abstract description 8
- 239000005995 Aluminium silicate Substances 0.000 claims abstract description 7
- 239000004372 Polyvinyl alcohol Substances 0.000 claims abstract description 7
- 239000006004 Quartz sand Substances 0.000 claims abstract description 7
- 235000012211 aluminium silicate Nutrition 0.000 claims abstract description 7
- NLYAJNPCOHFWQQ-UHFFFAOYSA-N kaolin Chemical compound O.O.O=[Al]O[Si](=O)O[Si](=O)O[Al]=O NLYAJNPCOHFWQQ-UHFFFAOYSA-N 0.000 claims abstract description 7
- 239000004200 microcrystalline wax Substances 0.000 claims abstract description 7
- 235000019808 microcrystalline wax Nutrition 0.000 claims abstract description 7
- 229920002451 polyvinyl alcohol Polymers 0.000 claims abstract description 7
- 239000002253 acid Substances 0.000 claims abstract description 6
- YHMYGUUIMTVXNW-UHFFFAOYSA-N 1,3-dihydrobenzimidazole-2-thione Chemical compound C1=CC=C2NC(S)=NC2=C1 YHMYGUUIMTVXNW-UHFFFAOYSA-N 0.000 claims abstract description 4
- PDQAZBWRQCGBEV-UHFFFAOYSA-N Ethylenethiourea Chemical compound S=C1NCCN1 PDQAZBWRQCGBEV-UHFFFAOYSA-N 0.000 claims abstract description 4
- 239000003963 antioxidant agent Substances 0.000 claims abstract description 4
- 230000003078 antioxidant effect Effects 0.000 claims abstract description 4
- 239000003112 inhibitor Substances 0.000 claims abstract description 4
- PHQOGHDTIVQXHL-UHFFFAOYSA-N n'-(3-trimethoxysilylpropyl)ethane-1,2-diamine Chemical compound CO[Si](OC)(OC)CCCNCCN PHQOGHDTIVQXHL-UHFFFAOYSA-N 0.000 claims abstract description 4
- 230000003647 oxidation Effects 0.000 claims abstract description 4
- 238000007254 oxidation reaction Methods 0.000 claims abstract description 4
- 229920000728 polyester Polymers 0.000 claims abstract description 4
- ULWHHBHJGPPBCO-UHFFFAOYSA-N propane-1,1-diol Chemical compound CCC(O)O ULWHHBHJGPPBCO-UHFFFAOYSA-N 0.000 claims abstract description 4
- 238000003756 stirring Methods 0.000 claims description 15
- 238000002156 mixing Methods 0.000 claims description 12
- 239000003921 oil Substances 0.000 claims description 8
- 229910017083 AlN Inorganic materials 0.000 claims description 6
- PIGFYZPCRLYGLF-UHFFFAOYSA-N Aluminum nitride Chemical compound [Al]#N PIGFYZPCRLYGLF-UHFFFAOYSA-N 0.000 claims description 6
- 239000004709 Chlorinated polyethylene Substances 0.000 claims description 6
- 241000628997 Flos Species 0.000 claims description 6
- 239000006087 Silane Coupling Agent Substances 0.000 claims description 6
- 229920001495 poly(sodium acrylate) polymer Polymers 0.000 claims description 6
- 239000000843 powder Substances 0.000 claims description 6
- NNMHYFLPFNGQFZ-UHFFFAOYSA-M sodium polyacrylate Chemical compound [Na+].[O-]C(=O)C=C NNMHYFLPFNGQFZ-UHFFFAOYSA-M 0.000 claims description 6
- OKISUZLXOYGIFP-UHFFFAOYSA-N 4,4'-dichlorobenzophenone Chemical compound C1=CC(Cl)=CC=C1C(=O)C1=CC=C(Cl)C=C1 OKISUZLXOYGIFP-UHFFFAOYSA-N 0.000 claims description 3
- 238000006243 chemical reaction Methods 0.000 claims description 3
- 238000001125 extrusion Methods 0.000 claims description 3
- 238000005469 granulation Methods 0.000 claims description 3
- 230000003179 granulation Effects 0.000 claims description 3
- 238000010438 heat treatment Methods 0.000 claims description 3
- 238000000034 method Methods 0.000 claims description 3
- 238000002360 preparation method Methods 0.000 claims description 3
- 230000000704 physical effect Effects 0.000 abstract description 2
- 230000000087 stabilizing effect Effects 0.000 abstract description 2
- 229920000181 Ethylene propylene rubber Polymers 0.000 description 8
- CBENFWSGALASAD-UHFFFAOYSA-N Ozone Chemical compound [O-][O+]=O CBENFWSGALASAD-UHFFFAOYSA-N 0.000 description 4
- UHOVQNZJYSORNB-UHFFFAOYSA-N Benzene Chemical compound C1=CC=CC=C1 UHOVQNZJYSORNB-UHFFFAOYSA-N 0.000 description 3
- 230000014759 maintenance of location Effects 0.000 description 2
- LFQSCWFLJHTTHZ-UHFFFAOYSA-N Ethanol Chemical compound CCO LFQSCWFLJHTTHZ-UHFFFAOYSA-N 0.000 description 1
- 101000655188 Homo sapiens Tachykinin-3 Proteins 0.000 description 1
- 241001465754 Metazoa Species 0.000 description 1
- 102100033009 Tachykinin-3 Human genes 0.000 description 1
- 239000002671 adjuvant Substances 0.000 description 1
- 230000032683 aging Effects 0.000 description 1
- 239000003513 alkali Substances 0.000 description 1
- 230000003712 anti-aging effect Effects 0.000 description 1
- 238000005336 cracking Methods 0.000 description 1
- 238000004132 cross linking Methods 0.000 description 1
- 238000005516 engineering process Methods 0.000 description 1
- 150000002576 ketones Chemical class 0.000 description 1
- 239000010721 machine oil Substances 0.000 description 1
- 239000002480 mineral oil Substances 0.000 description 1
- 235000010446 mineral oil Nutrition 0.000 description 1
- 239000000203 mixture Substances 0.000 description 1
- 238000011056 performance test Methods 0.000 description 1
- 150000002978 peroxides Chemical class 0.000 description 1
- 238000005057 refrigeration Methods 0.000 description 1
- 239000002904 solvent Substances 0.000 description 1
- 230000035882 stress Effects 0.000 description 1
- 239000000126 substance Substances 0.000 description 1
- 235000013311 vegetables Nutrition 0.000 description 1
- 238000005406 washing Methods 0.000 description 1
- XLYOFNOQVPJJNP-UHFFFAOYSA-N water Chemical compound O XLYOFNOQVPJJNP-UHFFFAOYSA-N 0.000 description 1
Classifications
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L23/00—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
- C08L23/02—Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
- C08L23/16—Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B3/00—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
- H01B3/18—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
- H01B3/28—Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
-
- H—ELECTRICITY
- H01—ELECTRIC ELEMENTS
- H01B—CABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
- H01B7/00—Insulated conductors or cables characterised by their form
- H01B7/17—Protection against damage caused by external factors, e.g. sheaths or armouring
- H01B7/18—Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2203/00—Applications
- C08L2203/20—Applications use in electrical or conductive gadgets
- C08L2203/202—Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
-
- C—CHEMISTRY; METALLURGY
- C08—ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
- C08L—COMPOSITIONS OF MACROMOLECULAR COMPOUNDS
- C08L2205/00—Polymer mixtures characterised by other features
- C08L2205/03—Polymer mixtures characterised by other features containing three or more polymers in a blend
- C08L2205/035—Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend
Landscapes
- Chemical & Material Sciences (AREA)
- Health & Medical Sciences (AREA)
- Chemical Kinetics & Catalysis (AREA)
- Medicinal Chemistry (AREA)
- Polymers & Plastics (AREA)
- Organic Chemistry (AREA)
- Physics & Mathematics (AREA)
- Spectroscopy & Molecular Physics (AREA)
- Compositions Of Macromolecular Compounds (AREA)
- Organic Insulating Materials (AREA)
Abstract
The invention discloses a kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS, does is it made up of the raw material of following weight parts: terpolymer EP rubber K4802? 100-110, hexanodioic acid propanediol polyester 3-5, quartz sand 10-20, kaolin 10-20, polyvinyl alcohol 2-4, tributyl citrate 4-5, microcrystalline wax 4-5, oxidation inhibitor 1035? 1-2, antioxidant D FC-34? 1-2, antioxidant MB? 1-2, ethylene thiourea 1-2, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 1-2, vulcanizing agent DCBP0.8-1, promotor PZ1-2, Xylo-Mucine 0.2-1, modified additive 25-30, the CABLE MATERIALS excellent physical properties that the present invention produces, dimensional stabilizing, shrinking percentage is low, and product stress at definite elongation, hardness, wear resisting property are strong, and can adapt to the Working environment of household electrical appliances, instrument, power and lighting etc. completely, stability is high.
Description
Technical field
The present invention relates generally to a kind of CABLE MATERIALS, particularly relates to a kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS.
Background technology
Ethylene-propylene rubber(EPR) has excellent resistance to weather, resistance to ozone, heat-resisting, acid and alkali-resistance, resistance to water vapor, colour stability, electrical property, oil-filled property and normal temperature mobility.Ethylene-propylene rubber(EPR) goods can life-time service at 120 DEG C, can of short duration or interval use at 150-200 DEG C.Add suitable anti-aging agent and can improve its use temperature.Can use under more exacting terms with the terpolymer EP rubber of peroxide crosslinking.Terpolymer EP rubber, under the condition of ozone concn 50pphm, stretching 30%, can reach more than 150h and not chap.
Because ethylene-propylene rubber(EPR) lacks polarity, degree of unsaturation is low, thus all has good resistance to various polar chemical product such as alcohol, acid, alkali, oxygenant, refrigeration agent, washing composition, vegetable and animals oils, ketone and fat etc.; But belong at fat and belong to less stable in solvent (as gasoline, benzene etc.) and mineral oil with virtue.Therefore improving the over-all properties of traditional ethylene-propylene rubber(EPR) by adding New-type adjuvant, improving the quality of CABLE MATERIALS further highly significant.
Summary of the invention
The object of the invention is just to provide a kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS.
The present invention is achieved by the following technical solutions:
A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS, it is made up of the raw material of following weight parts:
Terpolymer EP rubber K4802100-110, hexanodioic acid propanediol polyester 3-5, quartz sand 10-20, kaolin 10-20, polyvinyl alcohol 2-4, tributyl citrate 4-5, microcrystalline wax 4-5, oxidation inhibitor 10351-2, antioxidant D FC-341-2, antioxidant MB 1-2, ethylene thiourea 1-2, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 1-2, vulcanizing agent DCBP0.8-1, promotor PZ1-2, Xylo-Mucine 0.2-1, modified additive 25-30;
Described modified additive is made up of the raw material of following weight parts:
Chlorinatedpolyethylene 90-100, aluminium nitride 4-5, Flos Rosae Rugosae quintessence oil 2-3, sodium polyacrylate 1-3, Silane coupling agent KH550 2-3, linking agent TAC3-5, nano diatomite powder 1-2;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, adds chlorinatedpolyethylene, reacting by heating 20-30 minute at 70-90 DEG C, be cooled to normal temperature, add sodium polyacrylate, aluminium nitride, Flos Rosae Rugosae quintessence oil, fully stir, nano diatomite powder is heated to 90-100 DEG C, add, 80-100 rev/min of dispersed with stirring 3-5 minute, dries, obtains described modified additive.
A kind of household electrical appliances, instrument, power and lighting cable preparation method for material, comprise the following steps:
Mixed with kaolin by above-mentioned quartz sand, calcine 10-12 minute, be cooled to normal temperature at 500-600 DEG C, add polyvinyl alcohol, Xylo-Mucine, at 70-80 DEG C, stirring reaction 20-30 minute, adds microcrystalline wax, fully stirs, and is cooled to normal temperature; Above-mentioned terpolymer EP rubber K4802 is put into mill, mixing 4-6 minute at 75-80 DEG C; By the raw material mixing after above-mentioned process, add each raw material mixing except vulcanizing agent DCBP, promotor PZ, mixing 4-6 minute, add each raw material of residue again, after thin-pass 6-7 time, extruder plastication granulation, the extrusion temperature of extruding machine is 160-175 DEG C, obtains described household electrical appliances, instrument, power and lighting CABLE MATERIALS.
Advantage of the present invention is:
The CABLE MATERIALS excellent physical properties that the present invention produces, dimensional stabilizing, shrinking percentage is low, and product stress at definite elongation, hardness, wear resisting property are strong, and can adapt to the Working environment of household electrical appliances, instrument, power and lighting etc. completely, stability is high.
Embodiment
Embodiment 1
A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS, it is made up of the raw material of following weight parts (kilogram):
Terpolymer EP rubber K4802110, hexanodioic acid propanediol polyester 5, quartz sand 20, kaolin 20, polyvinyl alcohol 4, tributyl citrate 4-5, microcrystalline wax 5, oxidation inhibitor 10352, antioxidant D FC-341, antioxidant MB 1, ethylene thiourea 1, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 2, vulcanizing agent DCBP0.8, promotor PZ1, Xylo-Mucine 0.2, modified additive 30;
Described modified additive is made up of the raw material of following weight parts:
Chlorinatedpolyethylene 100, aluminium nitride 4, Flos Rosae Rugosae quintessence oil 3, sodium polyacrylate 3, Silane coupling agent KH550 2-3, linking agent TAC3, nano diatomite powder 2;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, adds chlorinatedpolyethylene, reacting by heating 20-30 minute at 90 DEG C, be cooled to normal temperature, add sodium polyacrylate, aluminium nitride, Flos Rosae Rugosae quintessence oil, fully stir, nano diatomite powder is heated to 100 DEG C, add, 100 revs/min of dispersed with stirring 3 minutes, dry, obtain described modified additive.
A kind of household electrical appliances, instrument, power and lighting cable preparation method for material, comprise the following steps:
Mixed with kaolin by above-mentioned quartz sand, calcine 12 minutes at 600 DEG C, be cooled to normal temperature, add polyvinyl alcohol, Xylo-Mucine, at 80 DEG C, stirring reaction 30 minutes, adds microcrystalline wax, fully stirs, be cooled to normal temperature; Above-mentioned terpolymer EP rubber K4802 is put into mill, at 80 DEG C mixing 4 minutes; By the raw material mixing after above-mentioned process, add each raw material mixing except vulcanizing agent DCBP, promotor PZ, mixing 4 minutes, add each raw material of residue again, after thin-pass 6 times, extruder plastication granulation, the extrusion temperature of extruding machine is 175 DEG C, obtains described household electrical appliances, instrument, power and lighting CABLE MATERIALS.
Performance test:
Hardness (shore A): 63;
Tensile strength (MPa): 15.7;
Elongation at break (%): 445;
Oil-proofness: 20# machine oil 100 DEG C × 50h, elongation at break conservation rate 80.9%, tensile strength retention 81.5%;
Resistance to ozone: 26 DEG C, 24h, ozone concn 0.026%, without cracking;
Ageing-resistant: 120 DEG C, 100h, tensile strength retention 89.8%, elongation at break conservation rate 90.1%.
Claims (2)
1. household electrical appliances, instrument, power and lighting CABLE MATERIALS, it is characterized in that what it was made up of the raw material of following weight parts: terpolymer EP rubber K4802100-110, hexanodioic acid propanediol polyester 3-5, quartz sand 10-20, kaolin 10-20, polyvinyl alcohol 2-4, tributyl citrate 4-5, microcrystalline wax 4-5, oxidation inhibitor 10351-2, antioxidant D FC-341-2, antioxidant MB 1-2, ethylene thiourea 1-2, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 1-2, vulcanizing agent DCBP0.8-1, promotor PZ1-2, Xylo-Mucine 0.2-1, modified additive 25-30, described modified additive is made up of the raw material of following weight parts: chlorinatedpolyethylene 90-100, aluminium nitride 4-5, Flos Rosae Rugosae quintessence oil 2-3, sodium polyacrylate 1-3, Silane coupling agent KH550 2-3, linking agent TAC3-5, nano diatomite powder 1-2, above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, adds chlorinatedpolyethylene, reacting by heating 20-30 minute at 70-90 DEG C, be cooled to normal temperature, add sodium polyacrylate, aluminium nitride, Flos Rosae Rugosae quintessence oil, fully stir, nano diatomite powder is heated to 90-100 DEG C, add, 80-100 rev/min of dispersed with stirring 3-5 minute, dries, obtains described modified additive.
2. the preparation method of household electrical appliances as claimed in claim 1, instrument, power and lighting CABLE MATERIALS, it is characterized in that comprising the following steps: above-mentioned quartz sand is mixed with kaolin, 10-12 minute is calcined at 500-600 DEG C, be cooled to normal temperature, add polyvinyl alcohol, Xylo-Mucine, at 70-80 DEG C, stirring reaction 20-30 minute, adds microcrystalline wax, abundant stirring, is cooled to normal temperature; Above-mentioned terpolymer EP rubber K4802 is put into mill, mixing 4-6 minute at 75-80 DEG C; By the raw material mixing after above-mentioned process, add each raw material mixing except vulcanizing agent DCBP, promotor PZ, mixing 4-6 minute, add each raw material of residue again, after thin-pass 6-7 time, extruder plastication granulation, the extrusion temperature of extruding machine is 160-175 DEG C, obtains described household electrical appliances, instrument, power and lighting CABLE MATERIALS.
Priority Applications (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310381454.3A CN103483694B (en) | 2013-08-28 | 2013-08-28 | A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS |
Applications Claiming Priority (1)
| Application Number | Priority Date | Filing Date | Title |
|---|---|---|---|
| CN201310381454.3A CN103483694B (en) | 2013-08-28 | 2013-08-28 | A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS |
Publications (2)
| Publication Number | Publication Date |
|---|---|
| CN103483694A CN103483694A (en) | 2014-01-01 |
| CN103483694B true CN103483694B (en) | 2016-04-20 |
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| Application Number | Title | Priority Date | Filing Date |
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| CN201310381454.3A Expired - Fee Related CN103483694B (en) | 2013-08-28 | 2013-08-28 | A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS |
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| Country | Link |
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Families Citing this family (1)
| Publication number | Priority date | Publication date | Assignee | Title |
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| CN106221093A (en) * | 2016-08-22 | 2016-12-14 | 桂林福冈新材料有限公司 | A kind of fluorescent rubber |
Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205339A (en) * | 2006-12-21 | 2008-06-25 | 无锡江南电缆有限公司 | Ethylene-propylene rubber for electric wire and cable |
| CN102516675A (en) * | 2011-11-21 | 2012-06-27 | 安徽蓝德集团股份有限公司 | Mining cable rubber sheath glue |
| CN102746586A (en) * | 2012-06-20 | 2012-10-24 | 江苏远洋东泽电缆股份有限公司 | Insulation rubber of high flexible cable used for tow chain, and manufacture method for insulation rubber |
-
2013
- 2013-08-28 CN CN201310381454.3A patent/CN103483694B/en not_active Expired - Fee Related
Patent Citations (3)
| Publication number | Priority date | Publication date | Assignee | Title |
|---|---|---|---|---|
| CN101205339A (en) * | 2006-12-21 | 2008-06-25 | 无锡江南电缆有限公司 | Ethylene-propylene rubber for electric wire and cable |
| CN102516675A (en) * | 2011-11-21 | 2012-06-27 | 安徽蓝德集团股份有限公司 | Mining cable rubber sheath glue |
| CN102746586A (en) * | 2012-06-20 | 2012-10-24 | 江苏远洋东泽电缆股份有限公司 | Insulation rubber of high flexible cable used for tow chain, and manufacture method for insulation rubber |
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| CN103483694A (en) | 2014-01-01 |
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Inventor after: Liu Junxing Inventor before: Xie Hua |
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Effective date of registration: 20170913 Address after: The Inner Mongolia Autonomous Region Xingan Meng Dongfeng Village 029408 Keyouzhong colliers town board No. 60 Patentee after: Liu Junxing Address before: 230011 Yaohai Industrial Park, new station area, Anhui, Hefei Patentee before: LVBAO CABLE (Group) Co.,Ltd. |
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Effective date of registration: 20180608 Address after: 525024 206 group six, poxia village, Xintian, mannan Town, Maonan District, Maoming, Guangdong Patentee after: Zhong Mingle Address before: 029408 Xingan Meng, the Inner Mongolia Autonomous Region, Horqin Right Wing central banner, Gao Li Town, Dongfeng GA Cha 60. Patentee before: Liu Junxing |
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Address after: 313011 No. 1, No. 5, B block, Xiaodi double Industrial Park, 288 Yan San Road, old town, Huzhou, Zhejiang Patentee after: Zhong Mingle Address before: 525024 206 group six, poxia village, Xintian, mannan Town, Maonan District, Maoming, Guangdong Patentee before: Zhong Mingle |
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