CN103483693B - A kind of electric cable of submersible pump material - Google Patents

A kind of electric cable of submersible pump material Download PDF

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Publication number
CN103483693B
CN103483693B CN201310381407.9A CN201310381407A CN103483693B CN 103483693 B CN103483693 B CN 103483693B CN 201310381407 A CN201310381407 A CN 201310381407A CN 103483693 B CN103483693 B CN 103483693B
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China
Prior art keywords
minute
raw material
add
submersible pump
electric cable
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Expired - Fee Related
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CN201310381407.9A
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Chinese (zh)
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CN103483693A (en
Inventor
谢华
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Bengbu Shangwei Intellectual Property Operations Co ltd
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Lvbao Cable Group Co Ltd
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Priority to CN201310381407.9A priority Critical patent/CN103483693B/en
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Structures Of Non-Positive Displacement Pumps (AREA)

Abstract

The invention discloses a kind of electric cable of submersible pump material, it is made up of the raw material of following weight parts: German bright Sheng 3950 terpolymer EP rubber 100-105, isotatic polypropylene 20-25, Niobium Pentxoxide 4-6, coumarone 4-6, Diethylene Glycol Dibenzoate 4-5, Fluorspar Powder 20-30, clorafin 5-7, 1, 4-cyclohexanedimethanol 3-5, zinc oxide 2-3, Sodium hexametaphosphate 99 4-5, Potassium peroxide 1-2, antioxidant MB? 1-2, Di(dioctylpyrophosphato) ethylene titanate 1-2, vulcanizing agent DCBP0.8-1, altax 1-2, Vulcanization accelerator TMTD? 1-2, modified additive 25-30, the CABLE MATERIALS satisfactory mechanical property that the present invention produces, oil-proofness, chemical resistance are strong, the rugged environment such as High Temperature High Pressure in oil well, oil gas corrosion can be adapted to, the consistency of each storeroom is enhanced by adding modified additive, further increase the tearing toughness of finished product, screen resilience performance etc., CABLE MATERIALS of the present invention has the advantages such as environmental protection, heat-resisting, mechanical material performance be good.

Description

A kind of electric cable of submersible pump material
Technical field
The present invention relates generally to a kind of CABLE MATERIALS, particularly relates to a kind of electric cable of submersible pump material.
Background technology
Diglyhus isaea is the matching used private cable of Electric Submersible Pump Unit, is laid in oil well, and cable lower end is connected with jump lead, and upper end is connected with ground control cabinet.In oil well, working conditions is severe, be often in high temperature, high pressure, and in the very strong environment of the corrodibility such as oily.Diglyhus isaea can be divided into circular and flat two kinds.By the restriction of oil well casing small space, usual diglyhus isaea is based on flat.Because flat cable is unsymmetric structure, when power transmission, the electromagnetic induction produced because of the imbalance in magnetic field can cause magnetic hysteresis loss, makes electric cable heating.Round cable should be adopted when oil well casing size allows.Its uniform electromagnetic field distribution produced of the round cable of symmetrical configuration, interference is little mutually, and electromagnetic compatibility is good, is also convenient to retractable line when laying in oil well.
Summary of the invention
The object of the invention is just to provide a kind of electric cable of submersible pump material.
The present invention is achieved by the following technical solutions:
A kind of electric cable of submersible pump material, it is made up of the raw material of following weight parts:
The bright Sheng 3950 terpolymer EP rubber 100-105 of Germany, isotatic polypropylene 20-25, Niobium Pentxoxide 4-6, coumarone 4-6, Diethylene Glycol Dibenzoate 4-5, Fluorspar Powder 20-30, clorafin 5-7,1,4 cyclohexane dimethanol 3-5, zinc oxide 2-3, Sodium hexametaphosphate 99 4-5, Potassium peroxide 1-2, antioxidant MB 1-2, Di(dioctylpyrophosphato) ethylene titanate 1-2, vulcanizing agent DCBP0.8-1, altax 1-2, Vulcanization accelerator TMTD 1-2, modified additive 25-30;
Described modified additive is made up of the raw material of following weight parts:
Chlorinatedpolyethylene 90-100, aluminium nitride 4-5, Flos Rosae Rugosae quintessence oil 2-3, isotatic polypropylene acid sodium 1-3, Silane coupling agent KH550 2-3, linking agent TAC3-5, nano diatomite powder 1-2;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, adds chlorinatedpolyethylene, reacting by heating 20-30 minute at 70-90 DEG C, be cooled to normal temperature, add isotatic polypropylene acid sodium, aluminium nitride, Flos Rosae Rugosae quintessence oil, fully stir, nano diatomite powder is heated to 90-100 DEG C, add, 80-100 rev/min of dispersed with stirring 3-5 minute, dries, obtains described modified additive.
2, a kind of electric cable of submersible pump preparation method for material as claimed in claim 1, is characterized in that comprising the following steps:
Above-mentioned Fluorspar Powder is mixed with Di(dioctylpyrophosphato) ethylene titanate, add coumarone after stirring, reacting by heating 10-15 minute at 90-100 DEG C, is cooled to normal temperature, add Potassium peroxide, 400-500 rev/min of dispersed with stirring 3-5 minute; Bright for above-mentioned Germany Sheng 3950 terpolymer EP rubber is put into mill, mixing 4-6 minute at 75-80 DEG C; By the raw material mixing after above-mentioned process, add each raw material mixing except vulcanizing agent DCBP, altax, mixing 4-6 minute, add each raw material of residue again, after thin-pass 6-7 time, extruder plastication granulation, the extrusion temperature of extruding machine is 160-170 DEG C, obtains described electric cable of submersible pump material.
Advantage of the present invention is:
The CABLE MATERIALS satisfactory mechanical property that the present invention produces, oil-proofness, chemical resistance are strong, the rugged environment such as High Temperature High Pressure in oil well, oil gas corrosion can be adapted to, the consistency of each storeroom is enhanced by adding modified additive, further increase the tearing toughness of finished product, screen resilience performance etc., CABLE MATERIALS of the present invention has the advantages such as environmental protection, heat-resisting, mechanical material performance be good.
Embodiment
Embodiment 1
A kind of electric cable of submersible pump material, it is made up of the raw material of following weight parts (kilogram):
Germany bright Sheng 3950 terpolymer EP rubber 105, isotatic polypropylene 25, Niobium Pentxoxide 6, coumarone 6, Diethylene Glycol Dibenzoate 5, Fluorspar Powder 30, clorafin 5,1,4 cyclohexane dimethanol 5, zinc oxide 3, Sodium hexametaphosphate 99 4, Potassium peroxide 2, antioxidant MB 1, Di(dioctylpyrophosphato) ethylene titanate 2, vulcanizing agent DCBP0.8, altax 1, Vulcanization accelerator TMTD 1, modified additive 30;
Described modified additive is made up of the raw material of following weight parts:
The acid of chlorinatedpolyethylene 100, aluminium nitride 5, Flos Rosae Rugosae quintessence oil 3, isotatic polypropylene sodium 3, Silane coupling agent KH550 3, linking agent TAC5, nano diatomite powder 1;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, add chlorinatedpolyethylene, at 90 DEG C, reacting by heating 30 minutes, is cooled to normal temperature, add isotatic polypropylene acid sodium, aluminium nitride, Flos Rosae Rugosae quintessence oil, abundant stirring, is heated to 100 DEG C by nano diatomite powder, adds 100 revs/min of dispersed with stirring 5 minutes, dry, obtain described modified additive.
A kind of electric cable of submersible pump preparation method for material as claimed in claim 1, comprises the following steps:
Mixed with Di(dioctylpyrophosphato) ethylene titanate by above-mentioned Fluorspar Powder, add coumarone after stirring, at 100 DEG C, reacting by heating 15 minutes, is cooled to normal temperature, adds Potassium peroxide, 500 revs/min of dispersed with stirring 5 minutes; Bright for above-mentioned Germany Sheng 3950 terpolymer EP rubber is put into mill, at 80 DEG C mixing 4 minutes; By the raw material mixing after above-mentioned process, add each raw material mixing except vulcanizing agent DCBP, altax, mixing 4 minutes, add each raw material of residue again, after thin-pass 7 times, extruder plastication granulation, the extrusion temperature of extruding machine is 170 DEG C, obtains described electric cable of submersible pump material.
Performance test:
Hardness (shore A): 62;
Tensile strength (MPa): 19.0;
Elongation at break (%): 420;
Oil-proofness: 20# machine oil 100 DEG C × 50h, elongation at break conservation rate 82.0%, tensile strength retention 81.7%;
Resistance to ozone: 26 DEG C, 24h, ozone concn 0.026%, without cracking;
Ageing-resistant: 120 DEG C, 100h, tensile strength retention 90.1%, elongation at break conservation rate 92.1%.

Claims (2)

1. an electric cable of submersible pump material, it is characterized in that what it was made up of the raw material of following weight parts: German bright Sheng 3950 terpolymer EP rubber 100-105, isotatic polypropylene 20-25, Niobium Pentxoxide 4-6, coumarone 4-6, Diethylene Glycol Dibenzoate 4-5, Fluorspar Powder 20-30, clorafin 5-7, 1, 4-cyclohexanedimethanol 3-5, zinc oxide 2-3, Sodium hexametaphosphate 99 4-5, Potassium peroxide 1-2, antioxidant MB 1-2, Di(dioctylpyrophosphato) ethylene titanate 1-2, vulcanizing agent DCBP0.8-1, altax 1-2, Vulcanization accelerator TMTD 1-2, modified additive 25-30, described modified additive is made up of the raw material of following weight parts: chlorinatedpolyethylene 90-100, aluminium nitride 4-5, Flos Rosae Rugosae quintessence oil 2-3, isotatic polypropylene acid sodium 1-3, Silane coupling agent KH550 2-3, linking agent TAC3-5, nano diatomite powder 1-2, above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, adds chlorinatedpolyethylene, reacting by heating 20-30 minute at 70-90 DEG C, be cooled to normal temperature, add isotatic polypropylene acid sodium, aluminium nitride, Flos Rosae Rugosae quintessence oil, fully stir, nano diatomite powder is heated to 90-100 DEG C, add, 80-100 rev/min of dispersed with stirring 3-5 minute, dries, obtains described modified additive.
2. the preparation method of an electric cable of submersible pump material as claimed in claim 1, it is characterized in that comprising the following steps: above-mentioned Fluorspar Powder is mixed with Di(dioctylpyrophosphato) ethylene titanate, coumarone is added after stirring, reacting by heating 10-15 minute at 90-100 DEG C, be cooled to normal temperature, add Potassium peroxide, 400-500 rev/min of dispersed with stirring 3-5 minute; Bright for above-mentioned Germany Sheng 3950 terpolymer EP rubber is put into mill, mixing 4-6 minute at 75-80 DEG C; By the raw material mixing after above-mentioned process, add each raw material mixing except vulcanizing agent DCBP, altax, mixing 4-6 minute, add each raw material of residue again, after thin-pass 6-7 time, extruder plastication granulation, the extrusion temperature of extruding machine is 160-170 DEG C, obtains described electric cable of submersible pump material.
CN201310381407.9A 2013-08-28 2013-08-28 A kind of electric cable of submersible pump material Expired - Fee Related CN103483693B (en)

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Families Citing this family (2)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN104119570A (en) * 2014-06-26 2014-10-29 合肥和安机械制造有限公司 Special filler for tear-resistant cable sheath material and preparation method thereof
CN104774383A (en) * 2015-03-26 2015-07-15 安徽海纳川塑业科技有限公司 Bursting-resistant and heat-resistant polypropylene composite material

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1445279A (en) * 2003-04-10 2003-10-01 上海交通大学 Thermoplastic elastomer made from nylon/ethylene propylene rubber and its preparing method
CN102827429A (en) * 2011-06-17 2012-12-19 远东电缆有限公司 Low-cost insulation rubber prepared through combining olefin copolymer, chlorinated polyethylene (CPE) and ethylene propylene diene monomer (EPDM)
CN103224669A (en) * 2013-03-26 2013-07-31 江苏远洋东泽电缆股份有限公司 Salt corrosion resistance twisted cable insulation rubber used for ocean wind power and preparation method thereof

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN1445279A (en) * 2003-04-10 2003-10-01 上海交通大学 Thermoplastic elastomer made from nylon/ethylene propylene rubber and its preparing method
CN102827429A (en) * 2011-06-17 2012-12-19 远东电缆有限公司 Low-cost insulation rubber prepared through combining olefin copolymer, chlorinated polyethylene (CPE) and ethylene propylene diene monomer (EPDM)
CN103224669A (en) * 2013-03-26 2013-07-31 江苏远洋东泽电缆股份有限公司 Salt corrosion resistance twisted cable insulation rubber used for ocean wind power and preparation method thereof

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Inventor after: Liu Yanxia

Inventor before: Xie Hua

TR01 Transfer of patent right

Effective date of registration: 20170918

Address after: Factory Road 061699 Cangzhou City, Hebei province Dongguang Town, Dongguang County No. 175

Patentee after: Liu Yanxia

Address before: 230011 Yaohai Industrial Park, new station area, Anhui, Hefei

Patentee before: LVBAO CABLE (Group) Co.,Ltd.

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Effective date of registration: 20180530

Address after: 525024 206 group six, poxia village, Xintian, mannan Town, Maonan District, Maoming, Guangdong

Patentee after: Zhong Mingle

Address before: 061699 No. 175, Ji Chang Road, Dongguang Town, Dongguang County, Cangzhou, Hebei

Patentee before: Liu Yanxia

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Address after: 313011 No. 1, No. 5, B block, Xiaodi double Industrial Park, 288 Yan San Road, old town, Huzhou, Zhejiang

Patentee after: Zhong Mingle

Address before: 525024 206 group six, poxia village, Xintian, mannan Town, Maonan District, Maoming, Guangdong

Patentee before: Zhong Mingle

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Effective date of registration: 20190923

Address after: 233090 No. 10, 32 blocks, Guangcai Dachang 8 District, Bengbu City, Anhui Province

Patentee after: Bengbu Shangwei Intellectual Property Operations Co.,Ltd.

Address before: 313011 No. 5, 1st floor, Block B, Small and Double-wound Industrial Park, 288 Yansan Road, Jiuguan Town, Huzhou City, Zhejiang Province

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CF01 Termination of patent right due to non-payment of annual fee

Granted publication date: 20160413