CN103483694A - Cable material for household appliances, instruments and power lighting - Google Patents

Cable material for household appliances, instruments and power lighting Download PDF

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Publication number
CN103483694A
CN103483694A CN201310381454.3A CN201310381454A CN103483694A CN 103483694 A CN103483694 A CN 103483694A CN 201310381454 A CN201310381454 A CN 201310381454A CN 103483694 A CN103483694 A CN 103483694A
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parts
add
minute
raw material
cable material
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CN201310381454.3A
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CN103483694B (en
Inventor
谢华
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Bengbu Shangwei Intellectual Property Operations Co., Ltd.
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Lvbao Cable Group Co Ltd
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    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L23/00Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers
    • C08L23/02Compositions of homopolymers or copolymers of unsaturated aliphatic hydrocarbons having only one carbon-to-carbon double bond; Compositions of derivatives of such polymers not modified by chemical after-treatment
    • C08L23/16Elastomeric ethene-propene or ethene-propene-diene copolymers, e.g. EPR and EPDM rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B3/00Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties
    • H01B3/18Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances
    • H01B3/28Insulators or insulating bodies characterised by the insulating materials; Selection of materials for their insulating or dielectric properties mainly consisting of organic substances natural or synthetic rubbers
    • HELECTRICITY
    • H01ELECTRIC ELEMENTS
    • H01BCABLES; CONDUCTORS; INSULATORS; SELECTION OF MATERIALS FOR THEIR CONDUCTIVE, INSULATING OR DIELECTRIC PROPERTIES
    • H01B7/00Insulated conductors or cables characterised by their form
    • H01B7/17Protection against damage caused by external factors, e.g. sheaths or armouring
    • H01B7/18Protection against damage caused by wear, mechanical force or pressure; Sheaths; Armouring
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2203/00Applications
    • C08L2203/20Applications use in electrical or conductive gadgets
    • C08L2203/202Applications use in electrical or conductive gadgets use in electrical wires or wirecoating
    • CCHEMISTRY; METALLURGY
    • C08ORGANIC MACROMOLECULAR COMPOUNDS; THEIR PREPARATION OR CHEMICAL WORKING-UP; COMPOSITIONS BASED THEREON
    • C08LCOMPOSITIONS OF MACROMOLECULAR COMPOUNDS
    • C08L2205/00Polymer mixtures characterised by other features
    • C08L2205/03Polymer mixtures characterised by other features containing three or more polymers in a blend
    • C08L2205/035Polymer mixtures characterised by other features containing three or more polymers in a blend containing four or more polymers in a blend

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  • Chemical & Material Sciences (AREA)
  • Health & Medical Sciences (AREA)
  • Chemical Kinetics & Catalysis (AREA)
  • Medicinal Chemistry (AREA)
  • Polymers & Plastics (AREA)
  • Organic Chemistry (AREA)
  • Physics & Mathematics (AREA)
  • Spectroscopy & Molecular Physics (AREA)
  • Compositions Of Macromolecular Compounds (AREA)
  • Organic Insulating Materials (AREA)

Abstract

The invention discloses a cable material for household appliances, instruments and power lighting. The cable material comprises the following raw materials in parts by weight: 100-110 parts of ternary ethylene propylene rubber K4802, 3-5 parts of adipate propanediol polyester, 10-20 parts of quartz sand, 10-20 parts of kaolin, 2-4 parts of polyvinyl alcohol, 4-5 parts of tributyl citrate, 4-5 parts of microcrystalline wax, 1-2 parts of an antioxidant 1035, 1-2 parts of an anti-aging agent DFC-34, 1-2 parts of an anti-aging agent MB (2-Mercaptobenzimidazole), 1-2 parts of ethylene thiourea, 0.8-1 part of a vulcanizing agent DCBP (Dichlorobenzoyl Peroxide), 1-2 parts of an accelerant PZ (Zinc dimethyldithiocarbamate), 0.2-1 part of sodium carboxymethylcellulose and 25-30 parts of a performance additive. The cable material produced by the invention is excellent in physical property, stable in dimension, low in shrinking percentage and strong in stress at definite elongation of products, hardness and wear resistance, can be fully applicable to the working environments such as household appliances, instruments and power lighting, and is high in stability.

Description

A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS
Technical field
The present invention relates generally to a kind of CABLE MATERIALS, relates in particular to a kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS.
Background technology
Ethylene-propylene rubber(EPR) has excellent anti-weather, anti-ozone, heat-resisting, acid and alkali-resistance, water-fast steam, colour stability, electrical property, oil-filled property and normal temperature mobility.But the ethylene-propylene rubber(EPR) goods are life-time service under 120 ℃, under 150-200 ℃, can of short duration or intermittently use.Add suitable anti-aging agent can improve its use temperature.Terpolymer EP rubber with peroxide crosslinking can more used under exacting terms.Terpolymer EP rubber, under ozone concn 50pphm, 30% the condition of stretching, can reach more than 150h and not chap.
Because ethylene-propylene rubber(EPR) lacks polarity, degree of unsaturation is low, thereby various polarity chemical are all had to anti-patience preferably as alcohol, acid, alkali, oxygenant, refrigeration agent, washing composition, vegetable and animals oils, ketone and fat etc.; But less stable in fat genus and virtue genus solvent (as gasoline, benzene etc.) and mineral oil.Therefore by adding New-type adjuvant to improve the over-all properties of traditional ethylene-propylene rubber(EPR), further improve the quality of CABLE MATERIALS highly significant.
Summary of the invention
The object of the invention just is to provide a kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS.
The present invention is achieved by the following technical solutions:
A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS, it is comprised of the raw material of following weight parts:
Terpolymer EP rubber K4802 100-110, hexanodioic acid propanediol polyester 3-5, quartz sand 10-20, kaolin 10-20, polyvinyl alcohol 2-4, tributyl citrate 4-5, microcrystalline wax 4-5, oxidation inhibitor 1035 1-2, antioxidant D FC-34 1-2, antioxidant MB 1-2, ethylene thiourea 1-2, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 1-2, vulcanizing agent DCBP0.8-1, promotor PZ1-2, Xylo-Mucine 0.2-1, modified additive 25-30;
Described modified additive is comprised of the raw material of following weight parts:
Chlorinatedpolyethylene 90-100, aluminium nitride 4-5, Flos Rosae Rugosae quintessence oil 2-3, sodium polyacrylate 1-3, Silane coupling agent KH550 2-3, linking agent TAC3-5, nano diatomite powder 1-2;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, add chlorinatedpolyethylene, at 70-90 ℃ of lower reacting by heating 20-30 minute, be cooled to normal temperature, add sodium polyacrylate, aluminium nitride, Flos Rosae Rugosae quintessence oil, fully stir, the nano diatomite powder is heated to 90-100 ℃, add, 80-100 rev/min of dispersed with stirring 3-5 minute, dry, and obtains described modified additive.
A kind of household electrical appliances, instrument, power and lighting cable preparation method for material comprises the following steps:
Above-mentioned quartz sand is mixed with kaolin, and calcining 10-12 minute, be cooled to normal temperature under 500-600 ℃, adds polyvinyl alcohol, Xylo-Mucine, and 70-80 ℃ of lower stirring reaction 20-30 minute, add microcrystalline wax, fully stirs, and is cooled to normal temperature; Above-mentioned terpolymer EP rubber K4802 is put into to mill, mixing 4-6 minute under 75-80 ℃; Raw material after above-mentioned processing is mixed, add each raw material except vulcanizing agent DCBP, promotor PZ to mix, mixing 4-6 minute, add again each raw material of residue, after thin-pass 6-7 time, the extruder plastication granulation, the extrusion temperature of extruding machine is 160-175 ℃, obtains described household electrical appliances, instrument, power and lighting CABLE MATERIALS.
Advantage of the present invention is:
The CABLE MATERIALS physicals excellence that the present invention produces, dimensional stabilizing, shrinking percentage is low, and product stress at definite elongation, hardness, wear resisting property are strong, can adapt to the Working environment of household electrical appliances, instrument, power and lighting etc. fully, and stability is high.
Embodiment
Embodiment 1
A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS, it is comprised of the raw material of following weight parts (kilogram):
Terpolymer EP rubber K4802 110, hexanodioic acid propanediol polyester 5, quartz sand 20, kaolin 20, polyvinyl alcohol 4, tributyl citrate 4-5, microcrystalline wax 5, oxidation inhibitor 1,035 2, antioxidant D FC-34 1, antioxidant MB 1, ethylene thiourea 1, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 2, vulcanizing agent DCBP0.8, promotor PZ1, Xylo-Mucine 0.2, modified additive 30;
Described modified additive is comprised of the raw material of following weight parts:
Chlorinatedpolyethylene 100, aluminium nitride 4, Flos Rosae Rugosae quintessence oil 3, sodium polyacrylate 3, Silane coupling agent KH550 2-3, linking agent TAC3, nano diatomite powder 2;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, add chlorinatedpolyethylene, at 90 ℃ of lower reacting by heating 20-30 minute, be cooled to normal temperature, add sodium polyacrylate, aluminium nitride, Flos Rosae Rugosae quintessence oil, fully stir, the nano diatomite powder is heated to 100 ℃, add, 100 rev/mins of dispersed with stirring 3 minutes, dry, and obtains described modified additive.
A kind of household electrical appliances, instrument, power and lighting cable preparation method for material comprises the following steps:
Above-mentioned quartz sand is mixed with kaolin, and calcining is 12 minutes under 600 ℃, is cooled to normal temperature, adds polyvinyl alcohol, Xylo-Mucine, and 80 ℃ of lower stirring reactions 30 minutes, add microcrystalline wax, fully stirs, and is cooled to normal temperature; Above-mentioned terpolymer EP rubber K4802 is put into to mill, under 80 ℃ mixing 4 minutes; Raw material after above-mentioned processing is mixed, add each raw material except vulcanizing agent DCBP, promotor PZ to mix, mixing 4 minutes, add again each raw material of residue, after thin-pass 6 times, the extruder plastication granulation, the extrusion temperature of extruding machine is 175 ℃, obtains described household electrical appliances, instrument, power and lighting CABLE MATERIALS.
Performance test:
Hardness (Shao Shi A): 63;
Tensile strength (MPa): 15.7;
Elongation at break (%): 445;
Oil-proofness: 100 ℃ * 50h of 20# machine oil, elongation at break conservation rate 80.9%, tensile strength conservation rate 81.5%;
Anti-ozone: 26 ℃, 24h, ozone concn 0.026%, without cracking;
Ageing-resistant: 120 ℃, 100h, tensile strength conservation rate 89.8%, elongation at break conservation rate 90.1%.

Claims (2)

1. household electrical appliances, instrument, power and lighting CABLE MATERIALS is characterized in that what it was comprised of the raw material of following weight parts:
Terpolymer EP rubber K4802 100-110, hexanodioic acid propanediol polyester 3-5, quartz sand 10-20, kaolin 10-20, polyvinyl alcohol 2-4, tributyl citrate 4-5, microcrystalline wax 4-5, oxidation inhibitor 1035 1-2, antioxidant D FC-34 1-2, antioxidant MB 1-2, ethylene thiourea 1-2, N-2-(aminoethyl)-3-aminopropyl trimethoxysilane 1-2, vulcanizing agent DCBP0.8-1, promotor PZ1-2, Xylo-Mucine 0.2-1, modified additive 25-30;
Described modified additive is comprised of the raw material of following weight parts:
Chlorinatedpolyethylene 90-100, aluminium nitride 4-5, Flos Rosae Rugosae quintessence oil 2-3, sodium polyacrylate 1-3, Silane coupling agent KH550 2-3, linking agent TAC3-5, nano diatomite powder 1-2;
Above-mentioned Silane coupling agent KH550 is mixed with linking agent TAC, stirring and dissolving, add chlorinatedpolyethylene, at 70-90 ℃ of lower reacting by heating 20-30 minute, be cooled to normal temperature, add sodium polyacrylate, aluminium nitride, Flos Rosae Rugosae quintessence oil, fully stir, the nano diatomite powder is heated to 90-100 ℃, add, 80-100 rev/min of dispersed with stirring 3-5 minute, dry, and obtains described modified additive.
2. household electrical appliances as claimed in claim 1, instrument, a power and lighting cable preparation method for material is characterized in that comprising the following steps:
Above-mentioned quartz sand is mixed with kaolin, and calcining 10-12 minute, be cooled to normal temperature under 500-600 ℃, adds polyvinyl alcohol, Xylo-Mucine, and 70-80 ℃ of lower stirring reaction 20-30 minute, add microcrystalline wax, fully stirs, and is cooled to normal temperature; Above-mentioned terpolymer EP rubber K4802 is put into to mill, mixing 4-6 minute under 75-80 ℃; Raw material after above-mentioned processing is mixed, add each raw material except vulcanizing agent DCBP, promotor PZ to mix, mixing 4-6 minute, add again each raw material of residue, after thin-pass 6-7 time, the extruder plastication granulation, the extrusion temperature of extruding machine is 160-175 ℃, obtains described household electrical appliances, instrument, power and lighting CABLE MATERIALS.
CN201310381454.3A 2013-08-28 2013-08-28 A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS Active CN103483694B (en)

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CN201310381454.3A CN103483694B (en) 2013-08-28 2013-08-28 A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS

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CN201310381454.3A CN103483694B (en) 2013-08-28 2013-08-28 A kind of household electrical appliances, instrument, power and lighting CABLE MATERIALS

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Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106221093A (en) * 2016-08-22 2016-12-14 桂林福冈新材料有限公司 A kind of fluorescent rubber

Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101205339A (en) * 2006-12-21 2008-06-25 无锡江南电缆有限公司 Ethylene-propylene rubber for electric wire and cable
CN102516675A (en) * 2011-11-21 2012-06-27 安徽蓝德集团股份有限公司 Mining cable rubber sheath glue
CN102746586A (en) * 2012-06-20 2012-10-24 江苏远洋东泽电缆股份有限公司 Insulation rubber of high flexible cable used for tow chain, and manufacture method for insulation rubber

Patent Citations (3)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN101205339A (en) * 2006-12-21 2008-06-25 无锡江南电缆有限公司 Ethylene-propylene rubber for electric wire and cable
CN102516675A (en) * 2011-11-21 2012-06-27 安徽蓝德集团股份有限公司 Mining cable rubber sheath glue
CN102746586A (en) * 2012-06-20 2012-10-24 江苏远洋东泽电缆股份有限公司 Insulation rubber of high flexible cable used for tow chain, and manufacture method for insulation rubber

Cited By (1)

* Cited by examiner, † Cited by third party
Publication number Priority date Publication date Assignee Title
CN106221093A (en) * 2016-08-22 2016-12-14 桂林福冈新材料有限公司 A kind of fluorescent rubber

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Inventor after: Liu Junxing

Inventor before: Xie Hua

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Effective date of registration: 20170913

Address after: The Inner Mongolia Autonomous Region Xingan Meng Dongfeng Village 029408 Keyouzhong colliers town board No. 60

Patentee after: Liu Junxing

Address before: 230011 Yaohai Industrial Park, new station area, Anhui, Hefei

Patentee before: Lvbao Cable (Group) Co., Ltd.

TR01 Transfer of patent right
TR01 Transfer of patent right

Effective date of registration: 20180608

Address after: 525024 206 group six, poxia village, Xintian, mannan Town, Maonan District, Maoming, Guangdong

Patentee after: Zhong Mingle

Address before: 029408 Xingan Meng, the Inner Mongolia Autonomous Region, Horqin Right Wing central banner, Gao Li Town, Dongfeng GA Cha 60.

Patentee before: Liu Junxing

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Address after: 313011 No. 1, No. 5, B block, Xiaodi double Industrial Park, 288 Yan San Road, old town, Huzhou, Zhejiang

Patentee after: Zhong Mingle

Address before: 525024 206 group six, poxia village, Xintian, mannan Town, Maonan District, Maoming, Guangdong

Patentee before: Zhong Mingle

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TR01 Transfer of patent right

Effective date of registration: 20190923

Address after: 233090 No. 10, 32 blocks, Guangcai Dachang 8 District, Bengbu City, Anhui Province

Patentee after: Bengbu Shangwei Intellectual Property Operations Co., Ltd.

Address before: 313011 No. 5, 1st floor, Block B, Small and Double-wound Industrial Park, 288 Yansan Road, Jiuguan Town, Huzhou City, Zhejiang Province

Patentee before: Zhong Ming Le

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